CN106489956A - Composition pesticide and its application - Google Patents
Composition pesticide and its application Download PDFInfo
- Publication number
- CN106489956A CN106489956A CN201610498626.9A CN201610498626A CN106489956A CN 106489956 A CN106489956 A CN 106489956A CN 201610498626 A CN201610498626 A CN 201610498626A CN 106489956 A CN106489956 A CN 106489956A
- Authority
- CN
- China
- Prior art keywords
- thiophene
- amine
- composition pesticide
- plant growth
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
- A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
- A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of composition pesticide and its application, belongs to technical field of compounded pesticide, and its effective constituents A lures amine for first thiophene, and effective ingredient B is plant growth regulator, and effective constituents A is 2 with the weight ratio of effective ingredient B：1～2500：1, preferable ratio is 10：1～1000：1.Plant growth regulator B can select uniconazole P, brassin lactones, indolebutyric acid, compound sodium nitrophenolate, butralin etc..Effective constituents A has obvious potentiation with B compoundings, effectively reduces each single dose amount of application.Said composition can be added and be allowed the auxiliary element for using to be processed into arbitrary dosage form in other pesticide.It is mainly used in the crops such as Oryza sativa L., Semen Maydiss, Brassica campestris L, except inducing disease resistance, the effective control plant pathogenic fungi of crop generation system, the multiple diseases such as preventing and treating tomato virus disease, wheat powdery mildew, sclerotinia rot of colza, cabbage clubroot, rice blast, wheat sharp eyespot or downy mildew of garpe, moreover it is possible to which coordinate plant growth plays a part of crop yield.
Description
Technical field
The invention belongs to technical field of compounded pesticide, is related to a kind of composition pesticide, particularly relates to one kind and lure containing first thiophene
The composition pesticide and its application of amine and plant growth regulator.
Background technology
In agricultural production, pesticide has played huge effect, but not Scientific Usage of Drugs and single drug in increasing both production and income,
And frequently financial burden is also increased using pesticide, and result in environmental pollution and a series of serious lifes of agricultural product security
State problem and social problem.Therefore, how Scientific Usage of Drugs, reduces the consumption of chemical pesticide, improves drug effect, become plant protection neck
It is badly in need of the problem for solving in domain.
First thiophene lures a kind of thiadiazoles that amine (SZG) is that Lier Chemical Co., Ltd and Nankai University develop jointly
Class plant disease-proof activator, inducer, general entitled N- (5- methyl isophthalic acids, 3- the thiazol-2-yls) -4- methyl isophthalic acids of chemistry, 2,3- thiophenes
Diazole -5- Methanamides, its structural formula is as shown in formula I.Current result of study shows that the compounds on viral disease has very
Good induction disease resisting effect, to the generation systems such as virosiss, clubroot, rice blast, epidemic disease, nematicide, the anti-disease activity of wide spectrum, from
And reach the purpose of defending and fighting against diseases.Widely applied in agricultural production at present.But inducer first thiophene lures amine luring
While leading crop disease-resistant, the equilibrium of crop energy is had a certain impact, cause energy to be used for disease-resistant and have impact on plant
Growth.
Formula I first thiophene lures the structural formula of amine
Uniconazole P (uniconazole) be broad spectrum activity azole plant growth regulator, gibberellins synthetic inhibitor.Chemistry is logical
With name：(E)-(RS) -1- (4- chlorphenyls) -4,4- dimethyl -2- (1H-1,2,4- triazol-1-yls) -1-POL；S- alkene
Effect azoles.Another name：；High-Effective Thiazole, specially good effect azoles.Molecular formula is：C15H18ClN3O.Uniconazole P has control nutrient growth, suppresses cell to stretch
Long, shortening internode, dwarfed plant, promote lateral bud growth and flower_bud formation, promote the effect of resistance.It is applied to Oryza sativa L., Semen Tritici aestivi,
Increase tiller, control plant height, improve lodging tolerance.The tree-like of nutrient growth is controlled for fruit tree.For ornamental plant control
Plant shape, promotes bud differentiation and blooms more.
The molecular formula of brassin lactones (brassinolide) is C28H48O6, chemical name is (22R, 23R, 24R) -2 α, 3
α 22,23- tetrahydroxy-β-homogeneous -7- oxa-5 alphas-lumistane -6- ketone.Brassin lactones can effectively improve crop chlorophyll and contain
Amount, strengthens photosynthesis, promotes crop root growth, improves effective absorption of the crop to fertilizer.Brassin lactones are a kind of new
Type environmental protection plant growth regulator, which passes through the seed soaking of suitable concentration brassin lactones and stem and leaf sprays process.Can promote
The plant growths such as vegetable, melon, fruit, can improving quality, improve yield, beautiful in colour, blade is more abundant.Folium Camelliae sinensis can also be made
Sampling time shifts to an earlier date, and can also make melon and fruit higher containing sugared part, and individual bigger, yield is higher, more resistant to storage.Phytohormone, to people and animals
All it is harmless, normal using dosage is very safe and effective.
Indolebutyric acid (3-indolebutyric acid), another name：3- indole butyric acids, indole -3-butyric acid, IBA, chemistry
Title：3- indolebutyric acids, molecular formula：C12H13NO2.It is Endogenous auxin, cell division and cell growth, induced synthesis can be promoted
Adventitious root, increases setting, prevents shedding, changes female, male flower ratio etc..Can enter into via blade, the tender epidermis of branch, seed
In plant body, with the transporting of nutrition stream to the position that works.
Butralin (Butralin, Dibutaline, Amexine), another name：Amchem 70-25, only bud element, for tagging in simultaneous local
Absorption Suckering agents, belong to hypotoxic dinitroaniline tobacco germination inhibitor, high to the growth effect for suppressing axillary bud, and drug effect is fast.
Butralin is processing soil treatment agent before selectivity bud, after medicament enters plant, mainly suppresses merismatic cell division, so as to
Suppress the growth of weed bud and young root.Plant growth regulator use can also be made, the growth of tobacco axillary bud is controlled.
Compound sodium nitrophenolate (Sodium 5-nitroguaiacolate), chemical analysis:5 nitroguaiacol sodium, adjacent nitro
Sodium phenate, sodium paranitrophenol, compound sodium nitrophenolate are to penetrate into rapidly plant after a kind of strength cell vitalizing agent, with plant contact
In vivo, promote the protoplasm flowing of cell, improve cell viability.Can accelerate the speed of growth, breaking dormancy, enhancing development,
Fruit drop, dehiscent fruit, contracting fruit is prevented, is improved product quality, is improved yield, improve the disease-resistant, pest-resistant of crop, drought resisting, waterlogging-resistant, anti-
Cold, salt resistance alkali, the anti-adversity ability such as resistant to lodging.
In agricultural production, the volume of production and consumption of plant growth regulator are being improved year by year, although the plant of single variety
Thing growth regulator to the regulating effect of some the crop fields very well, but due to the application of single plant growth regulator narrower,
Crop-selective is stronger, and medicine residual is serious and only regulating crop growth, it is impossible to reach the not only disease-resistant but also effect of growth regulation.Cause
How this, inducing plant disease-resistant growth regulation, expansion use range simultaneously, be an urgent demand of current plant culture production.
Content of the invention
Invention technical problem to be solved is to provide a kind of composition pesticide, to meet the need of agricultural production
Will, the active component included in said composition has mutually potentiation, can effectively reduce the amount of application of each single dose, reduces production
Cost, simultaneously works as adjusting plant physiology and metabolism comprehensively, controlling disease, protects the effect for producing volume increase.
For solving above-mentioned technical problem, it is as follows that the present invention provides technical scheme：
The composition pesticide of the present invention, its contain effective ingredient first thiophene and lure amine and plant growth regulator, first thiophene lure amine and
The weight ratio of plant growth regulator is 2：1～2500：1, preferably weight ratio is 10：1～1000：1, more preferably weight ratio
For 50:1～500：1.
Plant growth regulator of the present invention is uniconazole P, brassin lactones, indolebutyric acid, compound sodium nitrophenolate, butralin
Deng one or more.
Plant growth regulator of the present invention mainly include brassin lactones, indolebutyric acid, compound sodium nitrophenolate, butralin,
Uniconazole P etc..In the different phase of plant growing, select different plant growth regulators to reach and adjust the growth of plant, protect flower
Do fruit, crop yield is played an important role.
Pesticidal preparations auxiliary element can also be contained in composition pesticide of the present invention, be suitable for agriculturally using to make
Dosage form.
The present invention composition pesticide can also add auxiliary addition agent include wetting agent, dispersant, emulsifying agent, solvent and
Filler etc. and other be beneficial to the known substance that effective ingredient is stable in the formulation and drug effect is played, be all conventional in pesticidal preparations
Or the various composition for using is allowed, specific restriction is had no, is possessed composition and consumption is determined by simple experiment according to recipe requirements.
The composition pesticide of the present invention can be prepared into any one dosage form of suitable agricultural use with known method, than
Preferably dosage form is water preparation, wettable powder, suspending agent, water dispersible granules etc..
Wettable powder (WP), i.e., can homodisperse solid powder preparation in water.During preparation, except in the usual way
Diluent that above-mentioned active drug composition is commonly used with such as white carbon, precipitated calcium carbonate, potter's clay, kieselguhr, attapulgite etc. or
Inert substance mixing is outer, and the usual manner that can also be prepared by pesticide adds other auxiliary elements, such as conventional alkyl benzene sulphonate
Salt (DBS-Na), alkylnaphthalene sulfonate (pull open powder), alkylphenol-polyethenoxy base ether sulfate, alkylphenol-polyethenoxy Ji Mijia
Aldehyde condensate sulfate, aliphatic alcohol sulfate, fatty alcohol ethylene oxide adduct sulfonate, fatty amine salt, alkyl bromination ammonium, sun
Ion-type alkyl amide taurate, aliphatic alcohol polyethenoxy base ether (JFC) naphthalene sulfonate, naphthalene or alkyl naphthalene formaldehyde condensation substance sulphur
Hydrochlorate (NO, NNO or MF etc.), lignin and its derivant sulfonate (M-9, POLYFON etc.), polyoxyethylene poly-oxygen propylene aether are embedding
Section copolymer, polycarboxylate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate (SOPA), polyvinyl alcohol (PVA), carboxylic first
One or more among base cellulose (CMC) and such as penetrating agent JFC, azone, thiophene ketone, penetrant t, and conventional stabilizer,
The complementary auxiliary component such as foam inhibitor, anticaking agent.
Suspending agent (SC), is the dispersion of water insoluble solids pesticide or immiscible liquids pesticide in water or oil.During preparation,
With water as disperse medium, by active compound, auxiliary agent (wetting dispersing agent, viscosifier, stabilizer, PH regulators and defoamer etc.) through wet method
Micronizing (as ground) is obtained.Dispersion moisture agent can typically use naphthalene or alkyl naphthalene formaldehyde condensate sulfonates
(TESPERSE 2425, EFW, UK), lignin and its derivant sulfonate, phosphate ester polyethers, alkylphenol-polyethenoxy base ether
Sulfonate, polyoxyethylene polyoxypropylene base ether block copolymers, acrylic acid minor matters copolymer (TESPERSE 2700), alkyl phenol
Polyoxyethylene groups phosphate ester, carboxymethyl cellulose (CMC), polyvinylpyrrolidone (PVP), Polyethylene Glycol (PEG), condensed phosphoric acid
One or more in salt etc..Further, it is also possible to use thickening agent and stabilizer, such as Xanthan gum (XG), polyvinyl alcohol
(PVA), one or more in Magnesiumaluminumsilicate etc.；Antifreezing agent such as sodium chloride, carbamide, ammonium sulfate, ethylene glycol, 1,2-PD etc.
One or more in polyhydric alcohol；And the pH such as conventional citric acid, dipotassium hydrogen phosphate, potassium dihydrogen phosphate, potassium carbonate, sodium carbonate
Regulator, and such as organic silicon defoamer, organosilicon foam inhibitor etc..
Water dispersible granules (WDG) for can very fast disintegrate in water, and be dispersed in water formed higher suspension dispersion
A kind of granule.Active compound, auxiliary agent, adjuvant etc. one can be reinstated comminution by gas stream or superfine grinding during preparation, be made wettable
Property powder, then carries out pelletize, and this is dry powder, and by active compound, auxiliary agent, adjuvant etc., with water as medium, grinds in sand mill
Carefully, suspending agent is made, then in drying-granulating, this is wet method.
Composition pesticide of the present invention, for preparing the pesticide system of coordinate plant growth and/or controlling plant diseases
Agent.
The plant subject of the composition pesticide is Oryza sativa L., Semen Tritici aestivi, Semen Maydiss, Fructus Lycopersici esculenti, Chinese cabbage, Brassica campestris L, pears, Fructus Vitis viniferae etc.
The section plant growing of plant speciess growing area and/or controlling plant diseases.
Composition pesticide of the present invention is being prepared for preventing and treating tomato virus disease, wheat powdery mildew, sclerotinia rot of colza, white
Application in the pesticidal preparations of dish clubroot, rice blast, wheat sharp eyespot or downy mildew of garpe.
Product described in the invention can be provided with finished product preparation form, i.e., in compound, each material is blended, combination
The composition of thing can also be provided with unit dose form, directly directly mixed in bucket or tank using front, needed for being then diluted to
Concentration.
The exploitation of the mixed and complex preparation between inducer and plant growth regulator, it has also become pesticide industry main
One of developing direction.Composition pesticide of the present invention lures amine to be compounded with plant growth regulator with inducer first thiophene, and decapacitation is lured
Lead plant disease-resistant, growth regulation and volume increase, expand outside use range, can also reduce the consumption of pesticide, relative reduction medication into
This, and shorten the longevity of residure of medicament, it is to avoid poisoning, make crop safety.
Composition pesticide of the present invention lures amine to be compounded as effective ingredient with plant growth regulator with first thiophene, its advantage and
Good effect is：
1st, the generation of the composition pesticide energy more effectively prevention and control disease, by selecting different regulations for Different Crop
Agent, adjusts plant physiology so that first thiophene lure amine can preferably with host's interaction, so as to play drug effect to greatest extent, strengthen and plant
The resistance of thing.
2nd, the composition pesticide can be protected product to greatest extent and increase production, and first thiophene lures amine to compound with plant growth regulator,
While disease is controlled, plant internal metabolism balance is adjusted, so that Symptoms mitigate, production loss reduces.
3rd, the composition pesticide has filled up the blank of pesticide market, responds national policy, meets the demand in market.At present
The medicament kind of domestic sterilization inducer and plant growth regulator compounding is little, as various wheat and barley, frumentum, soil are passed in recent years
The generation of disease disease gradually increases, especially powdery mildew, banded sclerotial blight, droop, leaf spot, rust, sclerotiniose, many crops
Field even faces the danger of total crop failure, and peasant is in the urgent need to preventive effect is more preferable, reasonable price medicament carrys out the generation of prevention and control disease, it is ensured that
The healthy growth of plant.
Specific embodiment
For making the technical problem to be solved in the present invention, technical scheme and advantage clearer, specific embodiment will be used below
It is described in detail, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, only in order to
The present invention is explained, therefore the restriction to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that all the present invention's
Any modification, equivalent and improvement that is made within spirit and principle etc., should be included within the scope of the present invention.
Therefore, the protection domain of patent of the present invention should be defined by claims.
The combination of active principles of different pesticide is made pesticide, is to develop and develop novel pesticide at present and prevent and treat agriculturally
A kind of effective and quick way of resistance pathogenic bacteria.After the pestsides synthesis of different cultivars, three kinds of type of action are typically exhibited：Phase
Plus effect, potentiation and antagonism.The good formula of compound synergic, can significantly improve actual prevention effect, reduce agriculture
The usage amount of medicine, so as to contribute to delaying the drug-fast generation speed of pathogenic bacteria, is the important means of integrated control disease.
The present composition lures amine as a kind of effective ingredient (A) with first thiophene, and plant growth regulator is another effective ingredient
(B), between them compounding can preferably controlling plant diseases generation, simultaneously work as adjusting crop metabolism and physiology be flat
The effect of weighing apparatus, with obvious synergistic function, and the simple superposition of not exclusively two kinds of pharmacy effects, this can be from following
It is clearly understood that in test result.
Toxicity Determination compound screening is tested：In order to preferably determine the screening of both ratios of compounding, interior has been carried out
Potted plant active evaluation test.
In order to prevent and treat the tomato virus disease in agricultural production, wheat powdery mildew, sclerotinia rot of colza, cabbage clubroot, Oryza sativa L.
Rice blast, wheat sharp eyespot or downy mildew of garpe, inventor lure amine and plant growth regulator with first thiophene：Brassin lactones, Yin
Diindyl butanoic acid, compound sodium nitrophenolate, butralin, uniconazole P, have carried out the potentiation research of mutual compounding.
Below equation calculating is used in test：
Calculate suppression ratio of the medicament to pathogenic bacteria.Then suppression ratio is changed into probit value (y), concentration changes into logarithm value
X (), obtains toxicity regression curve equation y=a+bx of each medicament to pathogenic bacteria, and concentration EC in effectively suppressing50Value and phase relation
Number r.
The co-toxicity coefficient (CTC values) of mixture is calculated by formula (1), formula (2), formula (3)：
In formula：ATI mixtures survey toxicity index；
The LC of S standard antiseptic agent50, unit is milligrams per liter (mg/L)；
The LC of M mixtures50, unit is milligrams per liter (mg/L).
TTI=A × PA+B×PB······················(2)
In formula：TTI mixture theoretical toxicity index；
A A medicament toxicity index；
PAPercentage composition of the A medicaments in mixture, unit are percentage rate (%)；
B B medicament toxicity index；
PBPercentage composition of the B medicaments in mixture, unit are percentage rate (%).
In formula：CTC co-toxicity coefficients.
The co-toxicity coefficient (CTC) >=120 of complex preparation shows as potentiation；CTC≤80 show as antagonism；80
CTC 120 shows as summation action.
Toxicity Determination (one)：
In order to prevent and treat the tomato virus disease in agricultural production, inventor lures amine and the compounding of brassin lactones to carry out to first thiophene
Potentiation research, concrete grammar is：
Test adopts tomato virus disease for test object.
The test medicine for being configured to need active compound, test method are referred to《People's Republic of China's agricultural industry criteria》.
Single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of pilot study result, according to different agents first
Combination is different with proportioning, and concentration setting is also different, and bacteriostasis rate is set in the range of 5%～95%).If clear water is compareed,
It is repeated 3 times.Using live body method, the tomato virus liquid for preparing is inoculated on tomato leaf, puts 25 DEG C of constant temperature and humidity incubators
5 7d of middle culture；Tomato leaf virosiss disease index is checked, each percentage rate for processing and suppressing virosiss is calculated, by suppressing
Linear regression analyses between the probit value of rate and the logarithm value of series concentration, obtain the EC of each medicament50Value, uses co-toxicity coefficient table
The co-toxicity coefficient (CTC) of mixture is calculated, and activity of the reagent agent to pathogenic bacteria is evaluated with this, 1 is the results are shown in Table.
1 first thiophene of table lures Toxicity Determination of the amine with brassin lactones compounding to tomato virus disease
Toxicity Determination result shows, compares 2 in weight:1-2500:In the range of 1, first thiophene lures amine multiple with brassin lactones
Match somebody with somebody, its co-toxicity coefficient is all higher than 120, show potentiation；Wherein, the amine is lured with brassin lactones weight ratio to be in first thiophene
10:1-1000:In the range of 1, it is 500 with brassin lactones weight ratio especially to lure amine in first thiophene:1-1000:In the range of 1, performance
For more obvious potentiation；First thiophene lures amine reach effectively preventing and treating agricultural disease with brassin lactones compounding, reduces single dose
The purpose of consumption, with extremely strong Development volue.
Toxicity Determination (two)：
In order to prevent and treat the rice blast in agricultural production, inventor lures amine and the compounding of uniconazole P to be increased to first thiophene
Effect is studied, and concrete grammar is：
Test adopts rice blast for test object.
The test medicine for being configured to need active compound, test method are referred to《People's Republic of China's agricultural industry criteria》.
Single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of pilot study result, according to different agents first
Combination is different with proportioning, and concentration setting is also different, and bacteriostasis rate is set in the range of 5%～95%).If clear water is compareed,
It is repeated 3 times.Using live body method, the rice blast strain for preparing is inoculated on rice leaf, puts 27 DEG C of constant temperature and humidity trainings
5 7d are cultivated in foster case；Rice leaf rice blast disease index is checked, each percentage rate for processing and suppressing rice blast is calculated, is passed through
Linear regression analyses between the probit value of suppression ratio and the logarithm value of series concentration, obtain the EC of each medicament50Value, with common poison be
Number meter calculates the co-toxicity coefficient (CTC) of mixture, evaluates activity of the reagent agent to pathogenic bacteria with this, the results are shown in Table 2.
2 first thiophene of table lures Toxicity Determination of the amine with uniconazole P compounding to rice blast
Toxicity Determination result table 2 shows, compares 5 in weight:1-2500:In the range of 1, first thiophene lures amine multiple with uniconazole P
Match somebody with somebody, its co-toxicity coefficient is all higher than 120, show potentiation；Wherein, it is 20 with uniconazole P weight ratio to lure amine in first thiophene:1-
1000:In the range of 1, it is 50 with uniconazole P weight ratio especially to lure amine in first thiophene:1-500:In the range of 1, show as more obviously
Potentiation；First thiophene lures amine reach effectively preventing and treating agricultural disease with uniconazole P compounding, reduces the purpose of single dose consumption, has
Extremely strong Development volue.
Toxicity Determination (three)：
In order to prevent and treat the graw mold of tomato in agricultural production, inventor lures amine and the compounding of indolebutyric acid to carry out to first thiophene
Potentiation is studied, and concrete grammar is：
Test adopts graw mold of tomato for test object.
The test medicine for being configured to need active compound, test method are referred to《People's Republic of China's agricultural industry criteria》.
Single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of pilot study result, according to different agents first
Combination is different with proportioning, and concentration setting is also different, and bacteriostasis rate is set in the range of 5%～95%).If clear water is compareed,
It is repeated 3 times.Using live body method, the graw mold of tomato strain for preparing is inoculated on Fructus Lycopersici esculenti piece, puts 27 DEG C of constant temperature and humidity cultures
5 7d are cultivated in case；Tomato leaf scab length is checked, each percentage rate for processing and suppressing gray mold is calculated, by suppression ratio
Linear regression analyses between probit value and the logarithm value of series concentration, obtain the EC of each medicament50Value, is calculated with co-toxicity coefficient meter
Go out the co-toxicity coefficient (CTC) of mixture, activity of the reagent agent to pathogenic bacteria is evaluated with this, 3 are the results are shown in Table.
3 first thiophene of table lures Toxicity Determination of the amine with indolebutyric acid compounding to graw mold of tomato
Toxicity Determination result table 3 shows, compares 5 in weight:1-2500:In the range of 1, first thiophene lures amine multiple with indolebutyric acid
Match somebody with somebody, its co-toxicity coefficient is all higher than 120, show potentiation；Wherein, it is 20 with indolebutyric acid weight ratio to lure amine in first thiophene:
1-1000:In the range of 1, it is 50 with indolebutyric acid weight ratio especially to lure amine in first thiophene:1-500:In the range of 1, show as brighter
Aobvious potentiation；First thiophene lures amine reach effectively preventing and treating agricultural disease with indolebutyric acid compounding, reduces the mesh of single dose consumption
, with extremely strong Development volue.
Toxicity Determination (four)：
In order to prevent and treat the rice sheath blight disease in agricultural production, inventor lures amine and the compounding of butralin to be increased to first thiophene
Effect is studied, and concrete grammar is：
Test adopts rice sheath blight disease for test object.
The test medicine for being configured to need active compound, test method are referred to《People's Republic of China's agricultural industry criteria》.
Single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of pilot study result, according to different agents first
Combination is different with proportioning, and concentration setting is also different, and bacteriostasis rate is set in the range of 5%～95%).If clear water is compareed,
It is repeated 3 times.Using live body method, the rice sheath blight disease strain for preparing is inoculated on rice leaf, puts 27 DEG C of constant temperature and humidity trainings
5 7d are cultivated in foster case；Rice leaf scab length is checked, each percentage rate for processing and suppressing banded sclerotial blight is calculated, by suppression ratio
Probit value and the logarithm value of series concentration between linear regression analyses, obtain the EC of each medicament50Value, uses co-toxicity coefficient meter
The co-toxicity coefficient (CTC) of mixture is calculated, and activity of the reagent agent to pathogenic bacteria is evaluated with this, 4 are the results are shown in Table.
4 first thiophene of table lures Toxicity Determination of the amine with butralin compounding to rice sheath blight disease
Toxicity Determination result table 4 shows, compares 4 in weight:1-2500:In the range of 1, first thiophene lures amine multiple with butralin
Match somebody with somebody, its co-toxicity coefficient is all higher than 120, show potentiation；Wherein, it is 20 with butralin weight ratio to lure amine in first thiophene:1-
1000:In the range of 1, it is 100 with butralin weight ratio especially to lure amine in first thiophene:1-500:In the range of 1, show as more obviously
Potentiation；First thiophene lures amine reach effectively preventing and treating agricultural disease with butralin compounding, reduces the purpose of single dose consumption, has
Extremely strong Development volue.
Toxicity Determination (five)：
In order to prevent and treat the wheat rust in agricultural production, inventor lures amine and the compounding of compound sodium nitrophenolate to be increased to first thiophene
Effect is studied, and concrete grammar is：
Test adopts wheat rust for test object.
The test medicine for being configured to need active compound, test method are referred to《People's Republic of China's agricultural industry criteria》.
Single dose and each Mixed Pharmacy are arranged 5 variable concentrations gradients (on the basis of pilot study result, according to different agents first
Combination is different with proportioning, and concentration setting is also different, and bacteriostasis rate is set in the range of 5%～95%).If clear water is compareed,
It is repeated 3 times.Using live body method, the wheat rust strain for preparing is inoculated on wheat leaf blade, puts 27 DEG C of constant temperature and humidity cultures
5 7d are cultivated in case；Wheat leaf blade morbidity disease index is checked, each percentage rate for processing and suppressing rust is calculated, by suppression ratio
Probit value and the logarithm value of series concentration between linear regression analyses, obtain the EC of each medicament50Value, uses co-toxicity coefficient meter
The co-toxicity coefficient (CTC) of mixture is calculated, and activity of the reagent agent to pathogenic bacteria is evaluated with this, 5 are the results are shown in Table.
5 first thiophene of table lures Toxicity Determination of the amine with compound sodium nitrophenolate compounding to wheat rust
Toxicity Determination result table 5 shows, compares 5 in weight:1-2500:In the range of 1, first thiophene lures amine multiple with compound sodium nitrophenolate
Match somebody with somebody, its co-toxicity coefficient is all higher than 120, show potentiation；Wherein, it is 20 with compound sodium nitrophenolate weight ratio to lure amine in first thiophene:
1-1000:In the range of 1, it is 50 with compound sodium nitrophenolate weight ratio especially to lure amine in first thiophene:1-500:In the range of 1, show as brighter
Aobvious potentiation；First thiophene lures amine reach effectively preventing and treating agricultural disease with compound sodium nitrophenolate compounding, reduces the mesh of single dose consumption
, with extremely strong Development volue.
The composition pesticide of the present invention can be prepared into any one dosage form of suitable agricultural use with known method, than
Preferably dosage form is wettable powder, aqueous emulsion, microemulsion, water dispersible granules, suspending agent, seed coat agent.Percentage in all formula
Than being weight percentage.The processing technique of the various dosage forms of the present composition is prior art, can be with according to different situations
It is varied from.
For making the technical problem to be solved in the present invention, technical scheme and advantage clearer, compare 2 in weight:1-2500:1
In the range of, build first thiophene and lure amine to lure amine and indolebutyric acid compounding, first thiophene to lure amine and uniconazole P multiple with brassin lactones compounding, first thiophene
Match somebody with somebody, first thiophene lures amine and compound sodium nitrophenolate compounding, first thiophene lure the embodiment that amine and butralin are compounded, be described in detail, but the present invention
It is limited to absolutely not these examples.
First thiophene lures amine and brassin lactones embodiment：
Embodiment 1：30% first thiophene lures amine brassin lactones suspending agent (2:1)
Component：First thiophene lures amine 20%, brassin lactones 10%, sodium lignin sulfonate 8%, agriculture breast 600# 3%, fat
Polyoxyethylenated alcohol 3%, water complementary.
Preparation method：Recipe ingredient is weighed in proportion, after being sufficiently stirred for mixing after sand milling reaches fineness 1-4 micron
Mix again and can be prepared by 30% first thiophene and lure amine brassin lactones suspending agent.
Embodiment 2：55% first thiophene lures amine brassinolide water dispersible granule (10:1)
Component：First thiophene lures amine 50%, brassin lactones 5%, Ketohexamethylene 13%, lignosulfonates 3.5%, agriculture breast
400# 3%, glycol ether 2%, silica gel 3%, bentonite complementary.
Preparation method：First it is subsequently adding the auxiliary agents such as wetting agent, disintegrating agent and is ground in water complete for active compound dissolving with solvent
The granule that particle diameter is 150～200 μm is obtained, be can be prepared by 55% first thiophene and lure amine brassin lactones moisture by drying, screening
Shot agent.
Embodiment 3：51% first thiophene lures amine brassin lactones aqueous emulsion (50:1)
Component：First thiophene lures amine 50%, brassin lactones 1%, lauryl sulphate acid calcium 2.5%, agriculture breast 1601#
3.3%, agriculture breast BY125 4%, Ketohexamethylene 10%, glycerol 3%, the poly- phenol polyethenoxy ether 3% of nonyl, water complementary.
Preparation method：After first active compound being dissolved completely with solvent, and wetting dispersing agent, water are added in cutter together and are carried out
Shear-mixed, obtains final product 51% first thiophene and lures amine brassin lactones aqueous emulsion.
Embodiment 4：50.1% first thiophene lures amine brassin lactones wettable powder (500:1)
Component:First thiophene lures amine 50%, brassin lactones 0.1%, sodium lauryl sulphate 2.5%, diffusant
NNO3.3%, dispersing agent MF 4%, white carbon 7%, Kaolin complementary.
Prepare：Various composition is mixed, and product is obtained final product through comminution by gas stream by 325 mesh sieves.
Embodiment 5:10.01% first thiophene lures amine brassin lactones microemulsion (1000:1)
Component:First thiophene lures amine 10%, brassin lactones 0.01%, lauryl sulphate acid calcium 2.5%, agriculture breast 600#
3.3%, fatty alcohol-polyoxyethylene ether 4%, Ketohexamethylene 7%, sulfuric ester 502 3%, water complementary.
Prepare：First with solvent active compound dissolving completely, be subsequently adding wetting dispersing agent and be stirred mixing and obtain final product oil phase, so
Add water to be uniformly mixed afterwards and obtain final product homogeneous liquid.
Embodiment 6:25.01% first thiophene lures amine brassin lactones suspension seed-coating agent (2500:1)
Component:First thiophene lures amine 25%, brassin lactones 0.01%, lauryl sulphate acid calcium 2.5%, agriculture breast 600#
3.3%, polyvinyl alcohol 4%, Ketohexamethylene 7%, Carboxymethyl cellulose sodium 3%, white carbon complementary.
Prepare：Various composition is mixed and added into a certain amount of filler and warning colorant machining is formed.
First thiophene lures amine and indolebutyric acid embodiment：
Embodiment 7：60% first thiophene lures amine indolebutyric acid suspending agent (5:1)
Component：First thiophene lures amine 50%, indolebutyric acid 10%, agriculture breast 550# 2%, ethylene glycol 8%, dispersant NNO
3%, hydroxymethyl cellulose 0.5%, water complementary.
Preparation method：Recipe ingredient is weighed in proportion, after being sufficiently stirred for mixing after sand milling reaches fineness 1-4 micron
Mix again and can be prepared by formulation products.
Embodiment 8：21% first thiophene lures amine indolebutyric acid wettable powder (20:1)
Component：First thiophene lures amine 20%, indolebutyric acid 1%, sodium lauryl sulphate 3%, dispersing agent NNO 3%, diffusion
Agent MF 4%, white carbon 7%, Kaolin complementary.
Prepare：Various composition is mixed, and product is obtained final product through comminution by gas stream by 325 mesh sieves.
Embodiment 9：50.5% first thiophene lures amine indolebutyric acid water dispersible granules (100:1)
Component：First thiophene lures amine 50%, indolebutyric acid 0.5%, Ketohexamethylene 13%, lignosulfonates 3.5%, agriculture breast
400# 3%, glycol ether 2%, silica gel 3%, bentonite complementary.
Preparation method：First it is subsequently adding the auxiliary agents such as wetting agent, disintegrating agent and is ground in water complete for active compound dissolving with solvent
The granule that particle diameter is 150～200 μm is obtained, be can be prepared by 50.5% first thiophene and lure amine indolebutyric acid moisture by drying, screening
Shot agent.
Embodiment 10：50.1% first thiophene lures amine indolebutyric acid aqueous emulsion (500:1)
Component：First thiophene lures amine 50%, indolebutyric acid 0.1%, lauryl sulphate acid calcium 2.5%, agriculture breast 1601#
3.3%, agriculture breast BY125 4%, Ketohexamethylene 7%, glycerol 3%, the poly- phenol polyethenoxy ether 3% of nonyl, water complementary.
Preparation method：After first active compound being dissolved completely with solvent, and wetting dispersing agent, water are added in cutter together and are carried out
Shear-mixed, obtains final product 50.1% first thiophene and lures amine indolebutyric acid aqueous emulsion.
Embodiment 11:50.05% first thiophene lures amine indolebutyric acid suspension seed-coating agent (1000:1)
Component:First thiophene lures amine 50%, indolebutyric acid 0.05%, lauryl sulphate acid calcium 2.5%, agriculture breast 600#
3.3%, polyvinyl alcohol 4%, Ketohexamethylene 7%, Carboxymethyl cellulose sodium 3%, white carbon complementary.
Prepare：Various composition is mixed and added into a certain amount of filler and warning colorant machining is formed.
Embodiment 12:25.01% first thiophene lures amine indolebutyric acid microemulsion (2500:1)
Component:First thiophene lures amine 25%, indolebutyric acid 0.01%, lauryl sulphate acid calcium 3%, agriculture breast 600# 3%, fat
Fat polyoxyethylenated alcohol 4%, Ketohexamethylene 7%, sulfuric ester 502 3%, water complementary.
Prepare：First with solvent active compound dissolving completely, be subsequently adding wetting dispersing agent and be stirred mixing and obtain final product oil phase, so
Add water to be uniformly mixed afterwards and obtain final product homogeneous liquid.
First thiophene lures amine and uniconazole P embodiment：
Embodiment 13：30% first thiophene lures amine uniconazole P wettable powder (2:1)
Component：First thiophene lures amine 20%, uniconazole P 10%, sodium lauryl sulphate 3%, dispersing agent NNO 3%, diffusion
Agent MF 4%, white carbon 7%, Kaolin complementary.
Prepare：Various composition is mixed, and product is obtained final product through comminution by gas stream by 325 mesh sieves.
Embodiment 14:22% first thiophene lures amine Uniconazole microemulsion (10:1)
Component:First thiophene lures amine 20%, uniconazole P 2%, lauryl sulphate acid calcium 3%, agriculture breast 600# 3%, fatty alcohol
Polyoxyethylene ether 4%, Ketohexamethylene 7%, sulfuric ester 502 3%, water complementary.
Prepare：First with solvent active compound dissolving completely, be subsequently adding wetting dispersing agent and be stirred mixing and obtain final product oil phase, so
Add water to be uniformly mixed afterwards and obtain final product homogeneous liquid.
Embodiment 15：51% first thiophene lures amine Uniconazole water dispersible granules (50:1)
Component：First thiophene lures amine 50%, uniconazole P 1%, Ketohexamethylene 13%, lignosulfonates 3.5%, agriculture breast 400#
3%, glycol ether 2%, silica gel 3%, bentonite complementary.
Preparation method：First it is subsequently adding the auxiliary agents such as wetting agent, disintegrating agent and is ground in water complete for active compound dissolving with solvent
The granule that particle diameter is 150～200 μm is obtained, be can be prepared by 51% first thiophene and lure amine uniconazole P water-dispersible grain by drying, screening
Agent.
Embodiment 16：50.1% first thiophene lures amine uniconazole P aqueous emulsion (500:1)
Component：First thiophene lures amine 50%, uniconazole P 0.1%, lauryl sulphate acid calcium 2.5%, agriculture breast 1601# 3.3%,
Agriculture breast BY125 4%, Ketohexamethylene 15%, glycerol 3%, the poly- phenol polyethenoxy ether 3% of nonyl, water complementary.
Preparation method：After first active compound being dissolved completely with solvent, and wetting dispersing agent, water are added in cutter together and are carried out
Shear-mixed, obtains final product 50.1% first thiophene and lures amine uniconazole P aqueous emulsion.
Embodiment 17:50.05% first thiophene lures amine uniconazole P suspension seed-coating agent (1000:1)
Component:First thiophene lures amine 50%, uniconazole P 0.05%, lauryl sulphate acid calcium 3%, agriculture breast 600# 3%, poly- second
Enol 4%, Ketohexamethylene 7%, Carboxymethyl cellulose sodium 3%, white carbon complementary.
Prepare：Various composition is mixed and added into a certain amount of filler and warning colorant machining is formed.
Embodiment 18：50.02% first thiophene lures amine uniconazole P suspending agent (2500:1)
Component：First thiophene lures amine 50%, uniconazole P 0.02%, agriculture breast 550# 2%, ethylene glycol 8%, dispersant NNO
3%, hydroxymethyl cellulose 0.5%, water complementary.
Preparation method：Recipe ingredient is weighed in proportion, after being sufficiently stirred for mixing after sand milling reaches fineness 1-4 micron
Mix again and can be prepared by formulation products.
First thiophene lures amine and compound sodium nitrophenolate embodiment：
Embodiment 19：30% first thiophene lures amine compound sodium nitrophenolate suspending agent (2:1)
Component：First thiophene lures amine 20%, compound sodium nitrophenolate 10%, sodium lignin sulfonate 8%, agriculture breast 600# 3%, fatty alcohol
Polyoxyethylene ether 3%, water complementary.
Preparation method：Recipe ingredient is weighed in proportion, after being sufficiently stirred for mixing after sand milling reaches fineness 1-4 micron
Mix again and can be prepared by 30% first thiophene and lure amine compound sodium nitrophenolate suspending agent.
Embodiment 20：55% first thiophene lures amine compound sodium nitrophenolate water dispersible granules (10:1)
Component：First thiophene lures amine 50%, compound sodium nitrophenolate 5%, Ketohexamethylene 13%, lignosulfonates 3.5%, agriculture breast
400# 3%, glycol ether 2%, silica gel 3%, bentonite complementary.
Preparation method：First it is subsequently adding the auxiliary agents such as wetting agent, disintegrating agent and is ground in water complete for active compound dissolving with solvent
The granule that particle diameter is 150～200 μm is obtained, 55% first thiophene be can be prepared by by drying, screening and lured amine compound sodium nitrophenolate moisture to dissipate
Granule.
Embodiment 21：51% first thiophene lures amine compound sodium nitrophenolate aqueous emulsion (50:1)
Component：First thiophene lures amine 50%, compound sodium nitrophenolate 1%, lauryl sulphate acid calcium 2.5%, agriculture breast 1601# 3.3%,
Agriculture breast BY125 4%, Ketohexamethylene 15%, glycerol 3%, the poly- phenol polyethenoxy ether 3% of nonyl, water complementary.
Preparation method：After first active compound being dissolved completely with solvent, and wetting dispersing agent, water are added in cutter together and are carried out
Shear-mixed, obtains final product 51% first thiophene and lures amine compound sodium nitrophenolate aqueous emulsion.
Embodiment 22:50.1% first thiophene lures amine compound sodium nitrophenolate suspension seed-coating agent (500:1)
Component:First thiophene lures amine 50%, compound sodium nitrophenolate 0.1%, lauryl sulphate acid calcium 3%, agriculture breast 600# 3% to gather
Vinyl alcohol 4%, Ketohexamethylene 7%, Carboxymethyl cellulose sodium 3%, white carbon complementary.
Prepare：Various composition is mixed and added into a certain amount of filler and warning colorant machining is formed.
Embodiment 23：30.03% first thiophene lures amine compound sodium nitrophenolate wettable powder (1000:1)
Component：First thiophene lures amine 30%, compound sodium nitrophenolate 0.03%, sodium lauryl sulphate 3%, dispersing agent NNO 3%,
Dispersing agent MF 4%, white carbon 7%, Kaolin complementary.
Prepare：Various composition is mixed, and product is obtained final product through comminution by gas stream by 325 mesh sieves.
Embodiment 24:25.01% first thiophene lures amine compound sodium nitrophenolate microemulsion (2500:1)
Component:First thiophene lures amine 25%, compound sodium nitrophenolate 0.01%, lauryl sulphate acid calcium 3%, agriculture breast 600# 3%, fat
Fat polyoxyethylenated alcohol 4%, Ketohexamethylene 7%, sulfuric ester 5023%, water complementary.
Prepare：First with solvent active compound dissolving completely, be subsequently adding wetting dispersing agent and be stirred mixing and obtain final product oil phase, so
Add water to be uniformly mixed afterwards and obtain final product homogeneous liquid.
First thiophene lures amine and butralin embodiment：
Embodiment 25：60% first thiophene lures amine Butralin wettable powder (2:1)
Component：First thiophene lures amine 40%, butralin 20%, sodium lauryl sulphate 3%, dispersing agent NNO 3%, diffusion
Agent MF 4%, white carbon 7%, Kaolin complementary.
Prepare：Various composition is mixed, and product is obtained final product through comminution by gas stream by 325 mesh sieves.
Embodiment 26:44% first thiophene lures amine butralin microemulsion (10:1)
Component:First thiophene lures amine 40%, butralin 4%, lauryl sulphate acid calcium 3%, agriculture breast 600# 4%, fatty alcohol
Polyoxyethylene ether 3.5%, Ketohexamethylene 7%, sulfuric ester 502 3%, water complementary.
Prepare：First with solvent active compound dissolving completely, be subsequently adding wetting dispersing agent and be stirred mixing and obtain final product oil phase, so
Add water to be uniformly mixed afterwards and obtain final product homogeneous liquid.
Embodiment 27:51% first thiophene lures amine butralin suspension seed-coating agent (50:1)
Component:First thiophene lures amine 50%, butralin 1%, lauryl sulphate acid calcium 3%, agriculture breast 600# 4%, polyethylene
Alcohol 2.5%, Ketohexamethylene 7%, Carboxymethyl cellulose sodium 3%, white carbon complementary.
Prepare：Various composition is mixed and added into a certain amount of filler and warning colorant machining is formed.
Embodiment 28：50.1% first thiophene lures amine butralin water dispersible granules (500:1)
Component：First thiophene lures amine 50%, butralin 0.1%, Ketohexamethylene 13%, lignosulfonates 3.5%, agriculture breast
400# 3%, glycol ether 2%, silica gel 3%, bentonite complementary
Preparation method：First it is subsequently adding the auxiliary agents such as wetting agent, disintegrating agent and is ground in water complete for active compound dissolving with solvent
The granule that particle diameter is 150～200 μm is obtained, 50.1% first thiophene be can be prepared by by drying, screening and lured amine butralin moisture to dissipate
Granule.
Embodiment 29：50.05% first thiophene lures amine butralin aqueous emulsion (1000:1)
Component：First thiophene lures amine 50%, butralin 0.05%, lauryl sulphate acid calcium 2.5%, agriculture breast 1601# 3.3%,
Agriculture breast BY125 4%, Ketohexamethylene 7%, glycerol 3%, the poly- phenol polyethenoxy ether 3% of nonyl, water complementary.
Preparation method：After first active compound being dissolved completely with solvent, and wetting dispersing agent, water are added in cutter together and are carried out
Shear-mixed, obtains final product 50.05% first thiophene and lures amine butralin aqueous emulsion.
Embodiment 30：25.01% first thiophene lures amine butralin suspending agent (2500:1)
Component：First thiophene lures amine 25%, butralin 0.01%, sodium lignin sulfonate 8%, agriculture breast 600# 3%, fatty alcohol
Polyoxyethylene ether 3%, water complementary.
Preparation method：Recipe ingredient is weighed in proportion, after being sufficiently stirred for mixing after sand milling reaches fineness 1-4 micron
Mix again and can be prepared by 25.01% first thiophene and lure amine butralin suspending agent.
Plant growth regulator in above example mutually can be replaced, and lure amine in plant growth regulator in first thiophene
Weight compares 2:1-2500:Weight ratio is adjusted arbitrarily in the range of 1, to form new embodiment.
Land for growing field crops application test：First thiophene lures amine to comment from different plant growth regulator complex preparation controlling plant diseases and volume increase
The field test of valency
In order to determine first thiophene lure amine and plant growth regulator respectively alone and compounding when to rice blast, white wheat
Powder disease and the prevention effect of sclerotinia rot of colza, different regions have carried out substantial amounts of field test to applicant at home.
(1) pesticidal preparations preventing and treating rice blast test obtained in above-described embodiment is used.
Test is carried out with reference to People's Republic of China's standard (pesticide field efficacy medicine test criterion).
Test method：Each plot area is 50m2, it is repeated 4 times, the inspection drug effect method after investigating before dispenser and preventing and treating
For：Per the sampling of cell diagonal, 10 plants are often clicked.With per plant of whole blades, the classification of severity of spike of rice, after maturation, with
Machine gathers in 30 plants, and threshing is dried, and is weighed, and calculates the rate of growth compared with CK.
Prevention effect is calculated as follows：
Grade scale：
0 grade：Disease-free；
1 grade：Leaf spot lesion is less than 5, and length is less than 1cm；
3 grades：Leaf spot lesion 6～10, part scab length are more than 1cm；
5 grades：Leaf spot lesion 11～25, part scab is linked to be piece, accounts for leaf area 10%～25%；
7 grades：Leaf spot lesion more than 26, scab is linked to be piece, accounts for leaf area 26%～50%；
9 grades：Scab is linked to be piece, accounts for leaf area more than 50%.
Result of the test see the table below 6, table 7：
Table 6：Field efficacy prevention effect of the reagent agent to rice blast
Table 7：Effect of increasing production of the reagent agent to Oryza sativa L.
From table 6,7, from the preventing and treating to rice blast and improve from rice yield, compare 2 in weight:1-2500:1
In the range of, first thiophene lures compositionss potentiation and the obvious effect of increasing production of amine and brassin lactones compounding, and is substantially better than first thiophene and lures amine
Or brassin lactones single dose is alone, and (plant growth regulator itself mainly adjusts the physiological growth of crop, therefore in field
During use, whether primary evaluation crop is increased production, and is not directed to the preventive effect of plant growth regulator in disease control.Make produce in evaluation
During amount, plant growth regulator consumption is strict control in field, excessively causes retroaction, therefore selects most rational using
Amount).
(2) pesticidal preparations preventing and treating wheat powdery mildew test obtained in above-described embodiment is used.
Test is carried out with reference to People's Republic of China's standard (pesticide field efficacy medicine test criterion).
Test method：Each plot area is 50m2, it is repeated 4 times, the inspection drug effect method after investigating before dispenser and preventing and treating
For：Per the sampling of cell diagonal, 10 plants are often clicked.With the classification of severity of per plant of whole blades, after maturation, random harvesting
30 plants, threshing is dried, and is weighed, and calculates the rate of growth compared with CK.
Prevention effect is calculated as follows：
Grade scale：
0 grade, Herb is disease-free；
1 grade, onset area accounts for less than the 5% of blade area；
3 grades, onset area accounts for the 6-15% of blade area；
5 grades, onset area accounts for the 16-25% of blade area；
7 grades, onset area accounts for the 26-50% of blade area；
9 grades, onset area accounts for the 50-75% of blade area；
11 grades, onset area accounts for more than the 75% of blade area.
Result of the test see the table below 8, table 9：
Table 8：Field efficacy prevention effect of the reagent agent to wheat powdery mildew
Table 9：Effect of increasing production of the reagent agent to Semen Tritici aestivi
From table 8,9, from the preventing and treating to wheat powdery mildew and improve from wheat yield, compare 2 in weight:1-2500:1
In the range of, first thiophene lure amine and indolebutyric acid compounding compositionss potentiation and obvious effect of increasing production, and be substantially better than first thiophene lure amine or
Person's indolebutyric acid single dose is alone, and (plant growth regulator itself mainly adjusts the physiological growth of crop, therefore uses in field
When primary evaluation crop whether increase production, be not directed to the preventive effect of plant growth regulator in disease control.When crop yield is evaluated,
As plant growth regulator consumption is strict control in field, retroaction is excessively caused, therefore select most rational using
Amount).
(3) pesticidal preparations preventing and treating tomato virus disease test obtained in above-described embodiment is used.
Test is carried out with reference to People's Republic of China's standard (pesticide field efficacy medicine test criterion).
Test method：Each plot area is 50m2, it is repeated 4 times, the inspection drug effect method after investigating before dispenser and preventing and treating
For：Per the sampling of cell diagonal, 10 plants are often clicked.With the classification of severity of per plant of whole blades, after maturation, random harvesting
30 plants, tomato weight is weighed, calculate the rate of growth compared with CK.
Prevention effect is calculated as follows：
Severity Scaling method：
0 grade：Without any symptom；
1 grade：The bright arteries and veins of lobus cardiacus or light floral leaf；
3 grades：Lobus cardiacus and middle leaf piece floral leaf, sometimes blade there is ecthyma gangrenosa；
5 grades：Most blade floral leaves, minority leaf malformation, shrinkage, sometimes blade or cervical region there is ecthyma gangrenosa, or cervical region goes out
Existing billet speckle；
7 grades：Most leaf malformations, elongated, or the necrosis of stalk, vein generation system, plant is downgraded；
9 grades：Plant serious systemic floral leaf, deformity, or serious systemic necrosis sometimes, plant are substantially downgraded, or even dead.
Result of the test see the table below 10, table 11：
Table 10：Field efficacy prevention effect of the reagent agent to tomato virus disease
Table 11：Effect of increasing production of the reagent agent to Fructus Lycopersici esculenti
From table 10,11, from the preventing and treating to tomato virus disease and improve from tomato yield, compare 2 in weight:1-
2500:In the range of 1, first thiophene lures compositionss potentiation and the obvious effect of increasing production of amine and uniconazole P compounding, and is substantially better than first thiophene and lures
(plant growth regulator itself mainly adjusts the physiological growth of crop, therefore makes in field for amine or the use of uniconazole P single dose
Whether used time primary evaluation crop is increased production, and is not directed to the preventive effect of plant growth regulator in disease control.Evaluating crop yield
When, plant growth regulator consumption is strict control in field, excessively causes retroaction, therefore selects most rational consumption).
(4) wheat rust test is prevented and treated with pesticidal preparations obtained in above-described embodiment.
Test is carried out with reference to People's Republic of China's standard (pesticide field efficacy medicine test criterion).
Test method：Each plot area is 50m2, it is repeated 4 times, the inspection drug effect method after investigating before dispenser and preventing and treating
For：Per the sampling of cell diagonal, 10 plants are often clicked.With the classification of severity of per plant of whole blades, after maturation, random harvesting
30 plants, wheat weight is weighed, calculate the rate of growth compared with CK.
Prevention effect is calculated as follows：
Grade scale：
0 grade, Herb is disease-free；
1 grade, onset area accounts for less than the 5% of blade area；
3 grades, onset area accounts for the 6-15% of blade area；
5 grades, onset area accounts for the 16-25% of blade area；
7 grades, onset area accounts for the 26-50% of blade area；
9 grades, onset area accounts for the 50-75% of blade area；
11 grades, onset area accounts for more than the 75% of blade area.
Result of the test see the table below 12, table 13：
Table 12：Field efficacy prevention effect of the reagent agent to wheat rust
Table 13：Effect of increasing production of the reagent agent to Semen Tritici aestivi
From table 12,13, from the preventing and treating to wheat rust and improve from wheat yield, compare 2 in weight:1-2500:1
In the range of, first thiophene lure amine and compound sodium nitrophenolate compounding compositionss potentiation and obvious effect of increasing production, and be substantially better than first thiophene lure amine or
(plant growth regulator itself mainly adjusts the physiological growth of crop to the use of person's compound sodium nitrophenolate single dose, therefore uses in field
When primary evaluation crop whether increase production, be not directed to the preventive effect of plant growth regulator in disease control.When crop yield is evaluated,
Plant growth regulator consumption is strict control in field, excessively causes retroaction, therefore selects most rational consumption).
(5) cercospora brown spot of peanut is prevented and treated with pesticidal preparations obtained in above-described embodiment.
Test is carried out with reference to People's Republic of China's standard (pesticide field efficacy medicine test criterion).
Test method：Each plot area is 50m2, it is repeated 4 times, the inspection drug effect method after investigating before dispenser and preventing and treating
For：Per the sampling of cell diagonal, 10 plants are often clicked.With the classification of severity of per plant of whole blades, after maturation, random harvesting
30 plants, the weight of Semen arachidis hypogaeae is weighed, calculate the rate of growth compared with CK.
Prevention effect is calculated as follows：
0 grade：Disease-free；
1 grade：Lesion area accounts for the 5% of full wafer leaf area once；
3 grades：Lesion area accounts for the 6%～25% of full wafer leaf area；
5 grades：Lesion area accounts for the 26%～50% of full wafer leaf area；
7 grades：Lesion area accounts for the 51%～75% of full wafer leaf area；
9 grades：Lesion area accounts for more than the 76% of full wafer leaf area.
Result of the test see the table below 14, table 15：
Table 14：Field efficacy prevention effect of the reagent agent to the cercospora brown spot of peanut
Table 15：Effect of increasing production of the reagent agent to Semen arachidis hypogaeae
From table 14,15, from the yield of the preventing and treating to the cercospora brown spot of peanut and raising Semen arachidis hypogaeae, compare 2 in weight:1-
2500:In the range of 1, first thiophene lures compositionss potentiation and the obvious effect of increasing production of amine and butralin compounding, and is substantially better than first thiophene and lures
(plant growth regulator itself mainly adjusts the physiological growth of crop, therefore makes in field for amine or the use of butralin single dose
Whether used time primary evaluation crop is increased production, and is not directed to the preventive effect of plant growth regulator in disease control.Evaluating crop yield
When, plant growth regulator consumption is strict control in field, excessively causes retroaction, therefore selects most rational consumption).
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, on the premise of without departing from principle of the present invention, some improvements and modifications can also be made, these improvements and modifications
Should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of composition pesticide, it is characterised in that lure amine and plant growth regulator, the first thiophene containing effective ingredient first thiophene
It is 2 with the weight ratio of plant growth regulator to lure amine：1～2500：1.
2. composition pesticide according to claim 1, it is characterised in that first thiophene lures the weight of amine and plant growth regulator
Than for 10：1～1000：1.
3. composition pesticide according to claim 2, it is characterised in that first thiophene lures the weight of amine and plant growth regulator
Than for 50：1～500：1.
4. according to the arbitrary described composition pesticide of claims 1 to 3, it is characterised in that the plant growth regulator is alkene
One or more of effect azoles, brassin lactones, indolebutyric acid, compound sodium nitrophenolate, butralin.
5. the composition pesticide according to any claim in Claims 1-4, it is characterised in that the pesticide combination
Also contain pesticidal preparations auxiliary element in thing, be suitable for the dosage form for agriculturally using to make.
6. composition pesticide according to claim 5, it is characterised in that the pesticidal preparations auxiliary element is solvent, breast
One or more in agent, dispersant, stabilizer, antifreezing agent or wetting agent.
7. composition pesticide according to claim 5, it is characterised in that the dosage form of the composition pesticide is wettable powder
Agent, suspending agent, water dispersion granule or aqueous emulsion.
8. the application of the composition pesticide described in claim 1, it is characterised in that for preparing coordinate plant growth and/or preventing
Control the pesticidal preparations for processing plant disease.
9. the application of composition pesticide according to claim 8, it is characterised in that the plant is Oryza sativa L., Semen Tritici aestivi, jade
Rice, Fructus Lycopersici esculenti, Chinese cabbage, Brassica campestris L, pears or Fructus Vitis viniferae.
10. the application of composition pesticide according to claim 8 or claim 9, it is characterised in that the composition pesticide is used for making
Standby preventing and treating tomato virus disease, wheat powdery mildew, sclerotinia rot of colza, cabbage clubroot, rice blast, wheat sharp eyespot or Fructus Vitis viniferae
The pesticidal preparations of downy mildew.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510562902 | 2015-09-07 | ||
| CN2015105629029 | 2015-09-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106489956A true CN106489956A (en) | 2017-03-15 |
Family
ID=58287259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610498626.9A Pending CN106489956A (en) | 2015-09-07 | 2016-06-28 | Composition pesticide and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106489956A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109122701A (en) * | 2017-06-16 | 2019-01-04 | 四川利尔作物科学有限公司 | Bactericidal composition and its application |
| TWI700034B (en) * | 2017-12-24 | 2020-08-01 | 日商日本歐愛特農業科技股份有限公司 | Synergistic bactericide composition containing nitrophenol compound and bactericidal active compound |
| CN111657288A (en) * | 2020-07-18 | 2020-09-15 | 江西鑫邦科技有限责任公司 | Pesticide composition containing brassin, indolebutyric acid and plant resistance inducer |
| CN112913863A (en) * | 2021-01-11 | 2021-06-08 | 四川省农业科学院植物保护研究所 | Green pepper tip control treatment agent and tip control treatment method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101091490A (en) * | 2007-01-12 | 2007-12-26 | 南开大学 | New type heterocycle bactericide and composition |
| CN101265240A (en) * | 2008-05-12 | 2008-09-17 | 南开大学 | Method for preventing and curing plant disease by increasing plant immunity and use thereof |
| CN101343269A (en) * | 2008-08-28 | 2009-01-14 | 南开大学 | 1,2,3-thiadiazoles derivants, synthesis and use thereof |
| CN101766171A (en) * | 2008-05-12 | 2010-07-07 | 南开大学 | Method for controlling plant virus harm by improving plant immunity and application thereof |
-
2016
- 2016-06-28 CN CN201610498626.9A patent/CN106489956A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101091490A (en) * | 2007-01-12 | 2007-12-26 | 南开大学 | New type heterocycle bactericide and composition |
| CN101265240A (en) * | 2008-05-12 | 2008-09-17 | 南开大学 | Method for preventing and curing plant disease by increasing plant immunity and use thereof |
| CN101766171A (en) * | 2008-05-12 | 2010-07-07 | 南开大学 | Method for controlling plant virus harm by improving plant immunity and application thereof |
| CN101343269A (en) * | 2008-08-28 | 2009-01-14 | 南开大学 | 1,2,3-thiadiazoles derivants, synthesis and use thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109122701A (en) * | 2017-06-16 | 2019-01-04 | 四川利尔作物科学有限公司 | Bactericidal composition and its application |
| TWI700034B (en) * | 2017-12-24 | 2020-08-01 | 日商日本歐愛特農業科技股份有限公司 | Synergistic bactericide composition containing nitrophenol compound and bactericidal active compound |
| CN111657288A (en) * | 2020-07-18 | 2020-09-15 | 江西鑫邦科技有限责任公司 | Pesticide composition containing brassin, indolebutyric acid and plant resistance inducer |
| CN112913863A (en) * | 2021-01-11 | 2021-06-08 | 四川省农业科学院植物保护研究所 | Green pepper tip control treatment agent and tip control treatment method |
| CN112913863B (en) * | 2021-01-11 | 2022-03-11 | 四川省农业科学院植物保护研究所 | Green pepper tip control treatment agent and tip control treatment method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104782649A (en) | Pyraclostrobin, ningnanmycin and imidacloprid-containing flowable concentrate for seed coating and preparation method thereof | |
| CN104322558A (en) | Sterilization composition and applications thereof | |
| CN106489956A (en) | Composition pesticide and its application | |
| CN104604895A (en) | Tetramycin compound and application | |
| CN105340911A (en) | Pesticide composition as well as preparation method and application thereof | |
| CN102696624A (en) | Bactericidal composition containing difenoconazole and kresoxim-methyl | |
| CN103039488B (en) | Disinfectant combination and preparation agent thereof and application thereof | |
| CN106857599A (en) | A kind of bactericidal composition containing pyraclostrobin and folpet and its application | |
| CN103960264B (en) | Bactericidal composition containing pyraclostrobin, mancozeb and compound sodium nitrophenolate | |
| CN104488893B (en) | A kind of complex composition and preparation of the azoles of bacterium containing methylsulfonyl and plant growth regulator | |
| CN114617127B (en) | Pesticide sterilization composition and application thereof | |
| CN102657180B (en) | Sterilization composition containing tetraconazole and trifloxystrobin | |
| CN107318865A (en) | The composition pesticide of captan and furametpyr compounding | |
| CN108207985A (en) | A kind of rice terrace ternary weeding composition | |
| CN107279161A (en) | A kind of bactericidal composition containing folpet and fluopyram | |
| CN107347907A (en) | A kind of ternary weeding composition containing glyphosate | |
| CN105685055B (en) | Composition pesticide and its application | |
| CN107306949A (en) | A kind of composition pesticide containing DCPTA | |
| CN107372548A (en) | Composition pesticide containing captan and fluorine azoles ring bacterium amine and application thereof | |
| CN107242242A (en) | Bactericidal composition comprising folpet and prothioconazoles | |
| CN101731238B (en) | Acibenzolar-containing sterilizing composition | |
| CN105766934B (en) | Composition pesticide and its application | |
| CN105638686B (en) | A kind of combination sterilization composition containing tiger glue adipic acid copper | |
| CN103271044B (en) | Sterilization composite containing tiadinil and thifluzamide | |
| CN101708004B (en) | Sterilizing composition containing active ester |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170315 |