CN103392706B - Pesticide for preventing and treating fungous and bacterial diseases of crop, and preparation of pesticide - Google Patents
Pesticide for preventing and treating fungous and bacterial diseases of crop, and preparation of pesticide Download PDFInfo
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- CN103392706B CN103392706B CN201310368191.2A CN201310368191A CN103392706B CN 103392706 B CN103392706 B CN 103392706B CN 201310368191 A CN201310368191 A CN 201310368191A CN 103392706 B CN103392706 B CN 103392706B
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- boscalid
- agricultural chemicals
- pyraclostrobin
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Abstract
The invention provides a pesticide for preventing and treating fungous and bacterial diseases of crop. The pesticide comprises boscalid with a mass fraction of 1-80% and a pesticide-acceptable auxiliary agent combination, or comprises the boscalid, pyraclostrobin and the pesticide-acceptable auxiliary agent combination, wherein a mass ratio of the boscalid to the pyraclostrobin is 25:5. The invention further provides a method for preparing the pesticide into products such as wettable powder, a water dispersible granule and a suspending agent. The pesticide has a significant effect on preventing and treating the fungous and bacterial diseases, is environment-friendly and low in pesticide use cost and has a good sterilizing effect; environmental pollution and pesticide residues are reduced; the pesticide resistance of pathogenic bacteria is overcome and delayed; and the pesticide is simple in production technique, convenient to use, wide in application scope, good in effect, low in cost and low in residue, has no three wastes, has effects of small dosage, rain-wash resistance and obvious synergism, and is safe to people, livestock, an environment and the like.
Description
Technical field
The invention belongs to technical field of pesticide, more particularly to a kind of agricultural chemicals for preventing and treating crop fungi and bacterial disease
And its prepare.
Background technology
In flowers, fruit tree, rape, vegetables or field crop, powdery mildew, gray mold, rice blast, it is various rot
The fungal diseases such as disease, brown rot and root rot and bacterial disease are very weighed so that crop failure even has no harvest.Current majority
Agricultural chemicals cannot meet requirement of the country to remaining, and cause environmental pollution.And multicomponent is single, drug effect is not enough, easily makes to fall ill
Evil develops immunity to drugs, and permanence operation is not good.
The content of the invention
In order to overcome the shortcoming of above-mentioned prior art, it is an object of the invention to provide it is a kind of for prevent and treat crop fungi and
The agricultural chemicals of bacterial disease and its preparation, can be configured to water dispersible granules, wettable powder, suspending agent for agriculturally allowing etc.,
There is good result to preventing and treating such disease.
To achieve these goals, the technical solution used in the present invention is:
A kind of agricultural chemicals for preventing and treating crop fungi and bacterial disease, including the Boscalid of mass fraction 1%~80%,
And acceptable auxiliary combination on agricultural chemicals.
When the auxiliary combination is dispersant, wetting agent, disintegrant and binding agent, each component accounts for quality percentage in agricultural chemicals
Than for:Boscalid 1%~80%, dispersant 3~12%, wetting agent 2~8%, disintegrant 0~8%, binding agent 0.001~5%, it is remaining
Measure as filler, now the agricultural chemicals is water dispersible granules.
Invention also provides preparing the agricultural chemicals for preventing and treating crop fungi and bacterial disease(Water-dispersible grain
Agent, single dose)Method, in proportion by other components in addition to bonding agent together Jing air-flow crushings obtain need particle diameter, then add
Enter binding agent, obtain materials of pelletizing, granulation is sent in fluidized bed granulating dryer after granulation and drying i.e. with materials quantitative
.
When the auxiliary combination is dispersant, wetting agent, defoamer, thickener and antifreezing agent, each component is accounted in agricultural chemicals
Mass percent is:Boscalid 1%~80%, dispersant 3~12%, wetting agent 2~10%, defoamer 0.1~0.5%, thickener
0~2%, antifreezing agent 0~8%, balance of deionized water, now the agricultural chemicals is suspending agent.
Invention also provides preparing the agricultural chemicals for preventing and treating crop fungi and bacterial disease(Suspending agent, it is single
Agent)Method, it is in proportion that dispersant, wetting agent, defoamer, thickener and antifreezing agent is uniform through shear-mixed, add
Boscalid, ball milling 2~3 hours in ball mill make diameter of particle all obtain final product below 5 μm.
When the auxiliary combination is dispersant and wetting agent, each component accounts for mass percent and is in agricultural chemicals:Boscalid
1%~80%, dispersant 3~15%, wetting agent 2~12%, balance of filler, now the agricultural chemicals is wettable powder.
Invention also provides preparing the agricultural chemicals for preventing and treating crop fungi and bacterial disease(Wettable powder
Agent, single dose)Method, in proportion by Boscalid, dispersant, wetting agent, filler mixing, be well mixed in mixed cylinder, Jing
Airslide disintegrating mill is remixed after crushing and uniformly obtained final product.
When the auxiliary combination is emulsifying agent, antifreezing agent and defoamer, each component accounts for mass percent and is in agricultural chemicals:Pyridine
Acyl bacterium amine 1%~80%, emulsifying agent 5~15%, antifreezing agent 0~8%, defoamer 0.1~0.5%, balance of solvent, the now agriculture
Medicine is microemulsion.
Invention also provides preparing the agricultural chemicals for preventing and treating crop fungi and bacterial disease(Microemulsion, it is single
Agent)Method, in proportion by Boscalid, emulsifying agent, antifreezing agent, defoamer, solvent mixing, in mixed cylinder mix glue stick it is equal
It is even to obtain final product.
Another kind of form of the present invention, a kind of agricultural chemicals for preventing and treating crop fungi and bacterial disease, using compounding system
Agent, including:Mass ratio is 25:Acceptable auxiliary combination on 5 Boscalid and pyraclostrobin, and agricultural chemicals.
When the auxiliary combination is dispersant and wetting agent, each component accounts for mass percent and is in agricultural chemicals:Boscalid
25%th, pyraclostrobin 5%, dispersant 5%, wetting agent 5%, balance of filler, now the agricultural chemicals is wettable powder.
When the auxiliary combination is wetting agent, dispersant, disintegrant, defoamer and binding agent, each component is accounted in agricultural chemicals
Mass percent is:Boscalid 25%, pyraclostrobin 5%, wetting agent 5%, dispersant 5%, disintegrant 2%, defoamer 0.5%,
Binding agent 0.5%, balance of filler, now the agricultural chemicals is water dispersible granules.
It is each in agricultural chemicals when the auxiliary combination is dispersant, wetting agent, thickener, antifreezing agent, defoamer and preservative
Component accounts for mass percent:It is Boscalid 25%, pyraclostrobin 5%, dispersant 5%, wetting agent 5%, thickener 0.5%, antifreeze
Agent 3%, defoamer 0.3%, preservative 0.2%, balance of deionized water, now the agricultural chemicals is suspending agent.
The preparation method of complex preparation is consistent with the single dose preparation process of respective type.
The above dispersant may be selected dodecyl sodium naphthalene sulfonate(NNO)Or sodium methylene bis-naphthalene sulfonate, wetting agent can
Select lauryl sodium sulfate or dodecyl sodium sulfate, defoamer that polysiloxanes or organosilicon may be selected, thickener may be selected
Xanthans, antifreezing agent may be selected ethylene glycol or glycerine, and disintegrant may be selected ammonium sulfate, and binding agent may be selected xanthans, emulsification
Agent may be selected phenethyl phenol polyethenoxy ether(602)Or 1601, filler may be selected kaolin.
Compared with prior art, present invention is mainly used for processing flowers, fruit tree, rape, vegetables or field crop, to anti-
Control fungal disease and the bacterial diseases such as powdery mildew, gray mold, rice blast, various rots, brown rot and root rot
Effect is significant, and it is environmentally friendly, and with good bactericidal effect, drug cost is low, reduces environmental pollution and residues of pesticides, also
Be conducive to overcoming and delaying the drug-fast generation of germ.Composition production process is simple, three wastes are easy to use.With medication
Little, resistance of rainwater washing against is measured, synergy is significantly acted on.Said composition is applied widely, effect is good, low cost, remain it is low, to people,
The safety such as poultry, environment.
Specific embodiment
Embodiments of the present invention are described in detail with reference to embodiment.
Embodiment 1
30% Boscalid water dispersible granules with when manufacturing process
Include following component according to percent by weight:Boscalid 30%, dispersant(Sodium methylene bis-naphthalene sulfonate)3%、
Wetting agent(Dodecyl sodium sulfate)2%th, disintegrant(Ammonium sulfate)1%th, binding agent(Xanthans)1%th, filler(Kaolin)Supply.
Boscalid active compound and dispersant, wetting agent, disintegrant, filler etc. are mixed, Jing air-flow crushings are obtained
The particle diameter of about 500 mesh, adds binding agent mixing, obtains materials of pelletizing.Item is quantitatively sent in fluidized bed granulating dryer
After granulation and drying, 30% Boscalid water dispersible granules product is obtained.Jing analyses are qualified, and packing completes entirely to produce
Journey,
Embodiment 2
The formula and technical process of 40% Boscalid suspending agent is as follows
Include following component according to percent by weight:Boscalid 40%, dispersant(Sodium methylene bis-naphthalene sulfonate)12%、
Wetting agent(Dodecyl sodium sulfate)10%th, defoamer (organosilicon) 0.5%, thickener(Xanthans)0.01%th, antifreezing agent(Second two
Alcohol)0.01%th, deionized water surplus.
Dispersant, wetting agent, defoamer, thickener, antifreezing agent in above-mentioned formulation material are well mixed through high speed shear,
Add Boscalid active compound, ball milling 2~3 hours in ball mill to make diameter of particle all below 5 μm, Boscalid is obtained
Suspending agent product, the qualified packing of Jing analyses then completes whole production process.
Embodiment 3
40% Boscalid wettable powder with when manufacturing process
Include following component according to percent by weight:Boscalid 40%, dispersant(Sodium methylene bis-naphthalene sulfonate)5%、
Wetting agent(Dodecyl sodium sulfate)4%th, filler(Kaolin)Supply.
Boscalid active compound and dispersant, wetting agent, disintegrant, filler etc. are mixed, Jing air-flow crushings are obtained
The particle diameter of about 500 mesh, then carries out secondary mixing, and 40% Boscalid wettable powder product is obtained.Jing analyses are qualified, dispense
Whole production process is completed,
Embodiment 4
20% Boscalid microemulsion with when manufacturing process.
Include following component according to percent by weight:Boscalid 20%, emulsifying agent(Phenethyl phenol polyethenoxy ether
(602))5%th, antifreezing agent(Ethylene glycol)4%th, defoamer(Polysiloxanes)0.5%, balance of solvent(Dimethylbenzene), the now agriculture
Medicine is microemulsion.
In proportion by Boscalid, emulsifying agent, antifreezing agent, defoamer, solvent mixing, glue stick is mixed in mixed cylinder uniform
20% Boscalid microemulsion is obtained final product, qualified rear packing is analyzed and is then completed whole production process.
Embodiment 5
30% Boscalid pyraclostrobin wettable powder
According to mass percent Boscalid 25%, pyraclostrobin 5%, dodecyl phenenyl sulfate 5%, lignin sulfonic acid
Sodium 5%, ethylene glycol 5%, white carbon 7%, diatomite supply 100%, and then feeding all infiltrates row air-flow crushing, and 30% pyridine acyl is obtained
Bacterium amine pyraclostrobin wettable powder.
Embodiment 6
30% Boscalid pyraclostrobin wettable powder
According to mass percent Boscalid 25%, pyraclostrobin 5%, dispersant(Sodium methylene bis-naphthalene sulfonate)5%th, it is wet
Profit agent(Dodecyl sodium sulfate)5%, filler(Kaolin)100% is supplied, then feeding all infiltrates row air-flow crushing, is obtained
30% Boscalid pyraclostrobin wettable powder.
Embodiment 7
30% Boscalid pyraclostrobin water dispersible granule
According to mass percent Boscalid 25%, pyraclostrobin 5%, alkyl benzene sulfonate calcium salt 5%, Nekal BX 5%, fourth
Diacid 3%, citric acid 2%, starch 10%, balance of precipitated calcium carbonate, feeding, will in addition to bonding agent other components Jing gas together
Stream crushes the particle diameter for obtaining needing, and adds binding agent, obtains materials of pelletizing, and granulation materials quantitative feeding fluidized bed granulation is done
30% Boscalid pyraclostrobin water dispersible granule is obtained final product after granulation and drying in dry machine.
Embodiment 8
30% Boscalid pyraclostrobin water dispersible granule
According to mass percent Boscalid 25%, pyraclostrobin 5%, wetting agent(Lauryl sodium sulfate)5%th, disperse
Agent(Sodium methylene bis-naphthalene sulfonate)5%th, disintegrant(Ammonium sulfate)2%th, defoamer(Polysiloxanes)0.5%th, binding agent(Xanthans)
0.5%, balance of filler(Kaolin), feeding, the grain that other components in addition to bonding agent together Jing air-flow crushings are obtained needing
Footpath, adds binding agent, obtains materials of pelletizing, and granulation is sent in fluidized bed granulating dryer through granulation and is done with materials quantitative
30% Boscalid pyraclostrobin water dispersible granule is obtained final product after dry.
Embodiment 9
30% Boscalid pyraclostrobin suspending agent
According to mass percent Boscalid 25%, pyraclostrobin 5%, alkyl benzene sulfonate calcium salt 4%, sodium lignin sulfonate
3%th, DBSA 4%, silicone oil 0.1%, xanthan gum 0.3%, deionized water adds to 100%, feeding, by alkyl benzene sulphonate
Calcium salt, sodium lignin sulfonate, DBSA, silicone oil and xanthan gum are uniform through shear-mixed, add pyridine acyl bacterium
Amine and pyraclostrobin, ball milling 2~3 hours in ball mill make diameter of particle all obtain final product below 5 μm and are mixed to prepare 30%
Boscalid pyraclostrobin suspending agent.
Embodiment 10
30% Boscalid pyraclostrobin suspending agent
According to mass percent Boscalid 25%, pyraclostrobin 5%, dispersant(Sodium methylene bis-naphthalene sulfonate)5%th, it is wet
Profit agent(Lauryl sodium sulfate)5%th, thickener(Xanthans)0.5%th, antifreezing agent(Glycerine)3%th, defoamer(Organosilicon)
0.3%th, preservative 0.2%, deionized water adds to 100%, and feeding is uniform through shear-mixed by each auxiliary agent, adds Boscalid
And pyraclostrobin, ball milling 2~3 hours in ball mill, diameter of particle is all obtained final product below 5 μm and be mixed to prepare 30% pyridine
Acyl bacterium amine pyraclostrobin suspending agent.
Virulence of the present invention is tested below according to following methods:
From Boscalid and pyraclostrobin compound product, measure object is powdery mildew of cucumber to test medicament, test wrapper
Border is interior, and test medicine is provided by Shaanxi Kang He Li Feng biotechnologies pharmaceutcal corporation, Ltd.
Jing after prerun determines the effective inhibition concentration scope of each medicament, each medicament sets respectively 5 agent by active constituent content
Amount process, if clear water control.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, surveyed using pastille culture medium method
Determine virulence of the medicament to cucumber powdery mildew's pathogen.Colony diameter is measured after 4 days, growth inhibition ratio is calculated.The result of the test such as institute of table 1
Show:
The toxicity test analysis of results table of the Boscalid of table 1, pyraclostrobin and its compounding to powdery mildew of cucumber
As shown in Table 1, the EC of Boscalid, pyraclostrobin to cucumber powdery mildew's pathogen50Respectively 13.74mg/L and
8.03mg/L.Virulence of the virulence of Boscalid higher than pyraclostrobin.Boscalid and pyraclostrobin proportioning 1:1、2:1、
3:1、4:1、5:1 co-toxicity coefficient is respectively 122.88,129.64,138.35,141.61,151.43, and both proportionings are 3:1、
4:1、5:Certain synergistic effect is shown as when 1, illustrates both Boscalid and pyraclostrobin 3:1~5:Mixture in the range of 1
It is relatively reasonable.
In various embodiments of the present invention, dispersant may be selected dodecyl sodium naphthalene sulfonate(NNO)Or sodium methylene bis-naphthalene sulfonate,
Wetting agent may be selected lauryl sodium sulfate or dodecyl sodium sulfate, and defoamer may be selected polysiloxanes or organosilicon, thickening
Agent may be selected xanthans, and antifreezing agent may be selected ethylene glycol or glycerine, and disintegrant may be selected ammonium sulfate, and binding agent may be selected xanthan
Glue, filler may be selected kaolin.
Claims (4)
1. a kind of agricultural chemicals for preventing and treating crop fungi and bacterial disease is used to prevent and treat the purposes of powdery mildew of cucumber, and its feature exists
In, including:Mass ratio is 25:Acceptable auxiliary combination on 5 Boscalid and pyraclostrobin, and agricultural chemicals.
2. it is used to prevent and treat the agricultural chemicals of crop fungi and bacterial disease according to claim 1 for preventing and treating powdery mildew of cucumber
Purposes, it is characterised in that the auxiliary combination is dispersant and wetting agent, each component accounts for mass percent and is in agricultural chemicals:Pyridine acyl
Bacterium amine 25%, pyraclostrobin 5%, dispersant 5%, wetting agent 5%, balance of filler, now the agricultural chemicals is wettable powder
Agent.
3. it is used to prevent and treat the agricultural chemicals of crop fungi and bacterial disease according to claim 1 for preventing and treating powdery mildew of cucumber
Purposes, it is characterised in that the auxiliary combination is wetting agent, dispersant, disintegrant, defoamer and binding agent, it is each in agricultural chemicals
Component accounts for mass percent:Boscalid 25%, pyraclostrobin 5%, wetting agent 5%, dispersant 5%, disintegrant 2%,
Defoamer 0.5%, binding agent 0.5%, balance of filler, now the agricultural chemicals is water dispersible granules.
4. it is used to prevent and treat the agricultural chemicals of crop fungi and bacterial disease according to claim 1 for preventing and treating powdery mildew of cucumber
Purposes, it is characterised in that the auxiliary combination be dispersant, wetting agent, thickener, antifreezing agent, defoamer and preservative, agriculture
Each component accounts for mass percent and is in medicine:Boscalid 25%, pyraclostrobin 5%, dispersant 5%, wetting agent 5%, thickening
Agent 0.5%, antifreezing agent 3%, defoamer 0.3%, preservative 0.2%, balance of deionized water, now the agricultural chemicals is to suspend
Agent.
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Families Citing this family (5)
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CN105052963A (en) * | 2015-09-08 | 2015-11-18 | 上海禾本药业股份有限公司 | Suspending agent containing pyraclostrobin and boscalid as well as preparation method and application of suspending agent |
GB2552694B (en) * | 2016-08-04 | 2020-03-04 | Rotam Agrochem Int Co Ltd | A Synergistic fungicidal composition and use thereof |
CN108260595A (en) * | 2016-12-30 | 2018-07-10 | 山东潍坊润丰化工股份有限公司 | A kind of bactericidal composition containing pyraclostrobin and Boscalid, fungicide and its application |
CN108669079A (en) * | 2018-08-16 | 2018-10-19 | 陈和平 | It is a kind of to be used to prevent Boscalid and eugenol compound pesticide preparation of eliminating vegetable botrytis and preparation method thereof |
CN111202072B (en) * | 2020-02-25 | 2022-04-19 | 贵州省烟草科学研究院 | Boscalid emulsion and preparation method thereof |
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WO2005018324A2 (en) * | 2003-08-26 | 2005-03-03 | Basf Aktiengesellschaft | Method of plant growth promotion using amide compounds |
WO2006002984A1 (en) * | 2004-07-06 | 2006-01-12 | Basf Aktiengesellschaft | Liquid pesticide compositions |
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2013
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WO2005018324A2 (en) * | 2003-08-26 | 2005-03-03 | Basf Aktiengesellschaft | Method of plant growth promotion using amide compounds |
WO2006002984A1 (en) * | 2004-07-06 | 2006-01-12 | Basf Aktiengesellschaft | Liquid pesticide compositions |
CN102014621A (en) * | 2008-05-09 | 2011-04-13 | 巴斯夫欧洲公司 | Process for the production of particles comprising active agrochemical ingredients in amorphous form |
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