CN103548744A - Method for cultivating color fresh water pearls with nucleuses - Google Patents
Method for cultivating color fresh water pearls with nucleuses Download PDFInfo
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- CN103548744A CN103548744A CN201310610985.5A CN201310610985A CN103548744A CN 103548744 A CN103548744 A CN 103548744A CN 201310610985 A CN201310610985 A CN 201310610985A CN 103548744 A CN103548744 A CN 103548744A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
- Y02A40/81—Aquaculture, e.g. of fish
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Abstract
The invention discloses a method for cultivating color fresh water pearls with nucleuses. The method includes the first step of setting an indoor closed pearl cultivating system, the second step of manufacturing imidazole carboxylic acid nickel complexes, and the third step of carrying out algae-shell-pearl transfer. On the basis of the indoor closed pearl cultivating system, and using the imidazole carboxylic acid nickel complexes as control materials, the method for cultivating the color fresh water pearls with the nucleuses after one to two years of pearl cultivation through the algae-shell-pearl transfer is simple and feasible. The method fully improves the yield of the color fresh water pearls and value of the pearls, and the pearls are more suitable for being produced in large scale, so the method has good development prospect and quite high economic value. Therefore, the method not only can greatly promote the additional value of the fresh water pearls in China, but also has important significance in revitalizing the pearl industry in China.
Description
Technical field
The invention belongs to pearl cultivation technology field, specifically relating to a kind of colour has core fresh water pearl breeding method.
Background technology
Pearl is the product of biomineralization in mollusk body, is a kind of typical case and precious living beings jewelry, is generally divided into sea water pearls and fresh water pearl.The height of pearl quality, depend primarily on size, glossiness, shape and the color etc. of pearl, and in the pearl of same class, color is larger on the impact of pearl price.
At present, about the research of colored pearl, mainly comprise that artificially colored, mantle piece is transplanted and the aspect such as pearl core processing.Wherein modal processing mode is artificially colored, by physical or chemical treatment mode, make extraneous coloring matter enter nacre and plate interspace, these coloring matters deposition, anchor in pearl and see through translucent pearl layer colour developing and make pearl painted, this method be often make organic dyestuff or other enter to form behind pearl inside colored substance under certain condition material along crack or micro-pore enter pearl inside.It is exactly the principle forming according to natural peral that mantle piece is transplanted, by artificial method, from pearl culturing clam outer embrane, cut epithelial cell small pieces alive (abbreviation mantle piece), the artificial nucleus who prepares with clam shell, together with implant in the outer embrane connective tissue of freshwater mussel, the mantle piece of implantation, the nutrition that relies on connective tissue to provide, around artificial nucleus, breed rapidly, form pearl sac, secretion nacre, thus generate artificial nucleated pearl.Before the pearl renucleation of cultivation fresh water pearl, pearl nucleus are carried out to color treatments, what obtain like this has core cultured pearl to see through thin nacre and presents pearl core color, and pearl core is processed and cultivated colored pearl.
All there is different defects in the method for existing acquisition colored pearl.As utilize mantle piece grafting to cultivate colored pearl, the limiting factor of this method is many, first be subject to the restriction of shellfish kind resource, next is because the factors such as environment change the change that causes pearl color, the randomness of color is large, the color of the pearl that will obtain is difficult to control, so the color kind of the pearl that the method obtains is very limited in breeding process.In artificially colored, dyestuff used is substantially all the chemical dye of organic synthesis, with compatibility, the safety of human body be all a potential problem, and in dyeing course many with an organic solvent, like this, in process, one is to cause the pollution of environment and the impact on operator ' s health, may also have potential harm to wearing human body simultaneously.
From the above, the cultivation of colored pearl has been the focus of domestic and international pearl research field, high-quality, jewelry level pearl always at home and abroad high-end market supply falls short of demand, although current improved breeding method and process technology have improved the quality of pearl to a certain extent, but all there are shortcoming or limitation in various degree, stable, the high effect culture of failing to realize high quality pearl, its correlation technique and method are urgently further studied and are improved.
So far, utilize metal complex regulation and control fresh water pearl color and luster, improve grading of pearls, give pearl natural colour and have not been reported.Therefore, utilize metal complex to cultivate the new breakthrough in characteristic pearl ，Shi China's pearl culture field.
Summary of the invention
Technical problem to be solved by this invention is just to provide a kind of colour core fresh water pearl breeding method, in indoor sealing, grow cultured pearls in system, adopt the synthetic imidazolyl carboxylic acid nickel complex of induction, through algae-shellfish-pearl, transmit, grow cultured pearls 1～2 year, colour is cultivated in regulation and control core fresh water pearl.
For solving the problems of the technologies described above, the present invention adopts following technical scheme: a kind of colour has core fresh water pearl breeding method, comprises the following steps successively:
Step 1, the indoor sealing system of growing cultured pearls is set: the indoor sealing system of growing cultured pearls comprises culturing pool, water purifying tank, tank and aerator, and described culturing pool and water purifying tank layering arrange, and culturing pool is arranged on the top of water purifying tank; This system is to transform on the basis of circulating water cultivation, by culturing pool, water purifying tank, tank and aerator, formed, culturing pool and water purifying tank layering arrange, upper two layers is used as culturing pool, bottom one deck is made water purifying tank, and aerator is arranged in culturing pool, and the draining of culturing pool enters water purifying tank and purifies, discharge afterwards enters tank and stores, and tank delivery port is connected with culturing pool water inlet.The two-layer culturing pool intercommunication that levels arranges, the water of discharge enters undermost water purifying tank and purifies.
Step 2, making imidazolyl carboxylic acid nickel complex: adopt hydrothermal synthesis method, by 2-ethyl-4,5-imidazoles dioctyl phthalate and nickel nitrate be soluble in water obtains prewired solution, with sodium hydrate aqueous solution, the pH value of prewired solution is adjusted to 5.5～6.5, the ultrasonic 25～35min that mixes, packs in reactor, crystallization 90～100h at 145～155 ℃, then the speed with 5 ℃ of reductions per hour is cooled to room temperature, opens axe filtration and obtains blue transparent cake crystal, is imidazolyl carboxylic acid nickel complex;
Step 3, algae-shellfish-pearl are transmitted: first by the heart-shaped flat algae enrichment through Asia of imidazolyl carboxylic acid nickel complex, then throw something and feed to hydriopsis cumingii or cristaria plicata, in hydriopsis cumingii or cristaria plicata body, transmit, and metabolism is to pearl, cultivate after 1～2 year, colour is cultivated in regulation and control core fresh water pearl.
Preferably, in described step 1, culturing pool has two-layer.
Preferably, in described step 2, by 1.0mmol2-ethyl-4,5-imidazoles dioctyl phthalate and 1.0mmol nickel nitrate are dissolved in and in 20.0mL water, obtain prewired solution.
Preferably, in described step 2, reactor is for having teflon-lined stainless steel cauldron.
Preferably, in described step 2, the volume of reactor is 25.0mL.
Preferably, in described step 3, by the heart-shaped flat algae enrichment through Asia of 2.0～5.0mg/L imidazolyl carboxylic acid nickel complex.
A kind of colour of the present invention has core fresh water pearl breeding method, based on the indoor sealing system of growing cultured pearls, take imidazolyl carboxylic acid nickel complex as regulation and control substance, through algae-shellfish-pearl pipeline, after growing cultured pearls 1～2 year, cultivating colour has the method for core fresh water pearl simple and feasible, not only fully improve the value of colored fresh water pearl output and pearl, be more suitable for a large amount of production, there is good DEVELOPMENT PROSPECT and high economic worth.The present invention not only can significantly promote China's fresh water pearl added value, and significant to revitalizing China's pearl sector.
Below in conjunction with embodiment, the invention will be further described:
Embodiment
A kind of colour of the present invention has core fresh water pearl breeding method embodiment 1, comprises the following steps successively:
Step 1, the indoor sealing system of growing cultured pearls is set: the indoor sealing system of growing cultured pearls comprises culturing pool, water purifying tank, tank and aerator, and described culturing pool and water purifying tank layering arrange, and culturing pool is arranged on the top of water purifying tank; Culturing pool has two-layer.This system is to transform on the basis of circulating water cultivation, by culturing pool, water purifying tank, tank and aerator, formed, culturing pool and water purifying tank layering arrange, upper two layers is used as culturing pool, bottom one deck is made water purifying tank, and aerator is arranged in culturing pool, and the draining of culturing pool enters water purifying tank and purifies, discharge afterwards enters tank and stores, and tank delivery port is connected with culturing pool water inlet.The two-layer culturing pool intercommunication that levels arranges, the water of discharge enters undermost water purifying tank and purifies.
Step 2, make imidazolyl carboxylic acid nickel complex: adopt hydrothermal synthesis method, by 1.0mmol2-ethyl-4, 5-imidazoles dioctyl phthalate and 1.0mmol nickel nitrate are dissolved in and in 20.0mL water, obtain prewired solution, with sodium hydrate aqueous solution, the pH value of prewired solution is adjusted to 5.5～6.5, ultrasonic 25～the 35min that mixes, what pack volume into and be 25.0mL has in teflon-lined stainless steel cauldron, crystallization 90～100h at 145～155 ℃, then the speed with 5 ℃ of reductions per hour is cooled to room temperature, open axe filtration and obtain blue transparent cake crystal, be imidazolyl carboxylic acid nickel complex, wherein, 2-ethyl-4,5-imidazoles dioctyl phthalate is as part, obtains prewired solution with nickel nitrate is soluble in water.
Step 3, algae-shellfish-pearl are transmitted: first by the heart-shaped flat algae enrichment through Asia of 2.0～5.0mg/L imidazolyl carboxylic acid nickel complex, then throw something and feed to hydriopsis cumingii or cristaria plicata, in hydriopsis cumingii or cristaria plicata body, transmit, and metabolism is to pearl, cultivate after 1～2 year, colour is cultivated in regulation and control core fresh water pearl.Insert about 20 days after core, pearl starts upper strata, along with the time advances, in indoor sealing, grow cultured pearls under system, coordinate imidazolyl carboxylic acid nickel complex as regulation and control substance, can promote freshwater mussel body to secrete more nacre parcel pearl core, after growing cultured pearls 1～2 year, cultivating colour has core fresh water pearl, and diameter is 10～11mm.
In the process of growing cultured pearls, nickel complex is with part or all of component metabolism to nacre, and after transmitting, nickel complex has participated in the organic formation of nacre, modifies pearl aragonite layer structure and then forms precious yellow green pearl.And under prior art, onesize pearl needed for 3 years, and irregular colour is even, single.
Take hydriopsis cumingii as example, and under prior art, the survival rate in a year is 80%～90%; Bead yield rate is 90%～97%; Color and luster mainly take white and pale pink as main, also have a small amount of purple and Yellow series; And colour of the present invention has core fresh water pearl breeding method, the survival rate in a year is 92%～97%; Bead yield rate is 96%～98%; Color and luster is precious yellow green, and gloss is through being accredited as high light pool, and perlitic texture is stable, and more anti-oxidant not easy to change, pearl can not faded, can only oxidized variable color, and the content that this depends primarily on the structure of pearl and causes color substance.
In sum, colour of the present invention has core fresh water pearl breeding method, based on the indoor sealing system of growing cultured pearls, take imidazolyl carboxylic acid nickel complex as regulation and control substance, through algae-shellfish-pearl pipeline, after growing cultured pearls 1～2 year, cultivating colour has core fresh water pearl, has good DEVELOPMENT PROSPECT and high economic worth.The present invention not only can significantly promote China's fresh water pearl added value, and significant to revitalizing China's pearl sector.
The foregoing is only specific embodiments of the invention, but technical characterictic of the present invention is not limited to this, any those skilled in the art is in the field of the invention, and the variation of doing or modification are all encompassed among the scope of the claims of the present invention.
Claims (6)
1. colour has a core fresh water pearl breeding method, it is characterized in that: comprise the following steps successively:
Step 1, the indoor sealing system of growing cultured pearls is set: the indoor sealing system of growing cultured pearls comprises culturing pool, water purifying tank, tank and aerator, and described culturing pool and water purifying tank layering arrange, and culturing pool is arranged on the top of water purifying tank;
Step 2, making imidazolyl carboxylic acid nickel complex: adopt hydrothermal synthesis method, by 2-ethyl-4,5-imidazoles dioctyl phthalate and nickel nitrate be soluble in water obtains prewired solution, with sodium hydrate aqueous solution, the pH value of prewired solution is adjusted to 5.5～6.5, the ultrasonic 25～35min that mixes, packs in reactor, crystallization 90～100h at 145～155 ℃, then the speed with 5 ℃ of reductions per hour is cooled to room temperature, opens axe filtration and obtains blue transparent cake crystal, is imidazolyl carboxylic acid nickel complex;
Step 3, algae-shellfish-pearl are transmitted: first by the heart-shaped flat algae enrichment through Asia of imidazolyl carboxylic acid nickel complex, then throw something and feed to hydriopsis cumingii or cristaria plicata, in hydriopsis cumingii or cristaria plicata body, transmit, and metabolism is to pearl, cultivate after 1～2 year, colour is cultivated in regulation and control core fresh water pearl.
2. a kind of colour has core fresh water pearl breeding method according to claim 1, it is characterized in that: in described step 1, culturing pool has two-layer.
3. a kind of colour has core fresh water pearl breeding method according to claim 1, it is characterized in that: in described step 2, by 1.0mmol2-ethyl-4,5-imidazoles dioctyl phthalate and 1.0mmol nickel nitrate are dissolved in and in 20.0mL water, obtain prewired solution.
4. a kind of colour has core fresh water pearl breeding method according to claim 1, it is characterized in that: in described step 2, reactor is for having teflon-lined stainless steel cauldron.
5. a kind of colour has core fresh water pearl breeding method according to claim 4, it is characterized in that: in described step 2, the volume of reactor is 25.0mL.
6. a kind of colour has core fresh water pearl breeding method according to claim 1, it is characterized in that: in described step 3, by the heart-shaped flat algae enrichment through Asia of 2.0～5.0mg/L imidazolyl carboxylic acid nickel complex.
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| CN201310610985.5A CN103548744A (en) | 2013-11-26 | 2013-11-26 | Method for cultivating color fresh water pearls with nucleuses |
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| CN201310610985.5A CN103548744A (en) | 2013-11-26 | 2013-11-26 | Method for cultivating color fresh water pearls with nucleuses |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104737954A (en) * | 2015-04-09 | 2015-07-01 | 广东海洋大学 | Super-green seawater pearl cultivation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87100994A (en) * | 1986-02-27 | 1987-09-09 | 詹森药业有限公司 | 1H-Imidazole-5-carboxylic acid derivatives |
| CN102258239A (en) * | 2011-04-29 | 2011-11-30 | 广东海洋大学 | Method for processing colorized pearls |
| CN103210860A (en) * | 2013-04-08 | 2013-07-24 | 诸暨博师珍珠业生产力促进中心有限公司 | Method for culturing fresh water colored pearls |
| CN103392634A (en) * | 2013-06-25 | 2013-11-20 | 段升华 | Molecular and genetic engineering technology for cultivating colorful fluorescent pearls |
-
2013
- 2013-11-26 CN CN201310610985.5A patent/CN103548744A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87100994A (en) * | 1986-02-27 | 1987-09-09 | 詹森药业有限公司 | 1H-Imidazole-5-carboxylic acid derivatives |
| CN102258239A (en) * | 2011-04-29 | 2011-11-30 | 广东海洋大学 | Method for processing colorized pearls |
| CN103210860A (en) * | 2013-04-08 | 2013-07-24 | 诸暨博师珍珠业生产力促进中心有限公司 | Method for culturing fresh water colored pearls |
| CN103392634A (en) * | 2013-06-25 | 2013-11-20 | 段升华 | Molecular and genetic engineering technology for cultivating colorful fluorescent pearls |
Non-Patent Citations (1)
| Title |
|---|
| 刘绢花: "室内封闭育珠系统中镍配合物对珍珠的形成及微结构的影响研究", 《中国优秀硕士学位论文全文数据库》, no. 3, 15 March 2013 (2013-03-15) * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104737954A (en) * | 2015-04-09 | 2015-07-01 | 广东海洋大学 | Super-green seawater pearl cultivation method |
| CN104737954B (en) * | 2015-04-09 | 2017-09-29 | 广东海洋大学 | A kind of breeding method of emerald green sea water pearls |
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Application publication date: 20140205 |