CN103459432B - 用于制备水性乙烯基聚合物分散体的方法 - Google Patents

用于制备水性乙烯基聚合物分散体的方法 Download PDF

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Publication number
CN103459432B
CN103459432B CN201280017932.6A CN201280017932A CN103459432B CN 103459432 B CN103459432 B CN 103459432B CN 201280017932 A CN201280017932 A CN 201280017932A CN 103459432 B CN103459432 B CN 103459432B
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monomer
water
polymer
dispersion
stage
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Chinese (zh)
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CN103459432A (zh
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D·E·P·梅斯塔切
M·赫茨
R·阿道夫斯
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Nicks Holland Co Ltd
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Nuplex Resins BV
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80—Processes for incorporating ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/06—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/022—Emulsions, e.g. oil in water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymerisation Methods In General (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201280017932.6A 2011-04-11 2012-04-11 用于制备水性乙烯基聚合物分散体的方法 Active CN103459432B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610821622.XA CN106883323B (zh) 2011-04-11 2012-04-11 用于制备水性乙烯基聚合物分散体的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11161907.8 2011-04-11
EP11161907 2011-04-11
PCT/EP2012/056522 WO2012140042A1 (en) 2011-04-11 2012-04-11 Process for preparing aqueous vinyl polymer dispersions

Related Child Applications (1)

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CN103459432A CN103459432A (zh) 2013-12-18
CN103459432B true CN103459432B (zh) 2016-10-12

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CN201610821622.XA Active CN106883323B (zh) 2011-04-11 2012-04-11 用于制备水性乙烯基聚合物分散体的方法

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US (1) US8975332B2 (enExample)
EP (2) EP2697267B1 (enExample)
JP (1) JP6137557B2 (enExample)
CN (2) CN103459432B (enExample)
AU (1) AU2012241914B2 (enExample)
DK (1) DK2982699T3 (enExample)
ES (1) ES2559405T3 (enExample)
PL (1) PL2697267T3 (enExample)
RU (1) RU2609010C2 (enExample)
SG (1) SG193940A1 (enExample)
TW (1) TWI508980B (enExample)
WO (1) WO2012140042A1 (enExample)

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US9688800B2 (en) * 2014-07-07 2017-06-27 Columbia Insurance Company Sequentially polymerized hybrid latex
JP2017537171A (ja) 2014-09-19 2017-12-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 微細な水性エマルションポリマー及び該エマルションポリマーの疎水性コーティングのための使用
BR112017011518A2 (pt) 2014-12-03 2018-02-27 Basf Se processo para preparar uma dispersão de polímero aquosa, dispersão de polímero aquosa, usos de uma dispersão de polímero aquosa e de uma formulação aquosa, e, formulação aquosa.
US20180223026A1 (en) * 2015-07-31 2018-08-09 Rohm And Haas Company Oligomer seed for synthesis of unimodal acrylic bead particles
KR20170050078A (ko) * 2015-10-29 2017-05-11 주식회사 엘지화학 리튬-황 이차전지 양극용 아크릴 바인더
BR112018068556A2 (pt) 2016-03-18 2019-02-12 Basf Se dispersão polimérica, método para produzir uma dispersão polimérica, material de revestimento, e, uso de uma dispersão polimérica.
EP4491678A3 (en) 2016-07-15 2025-02-12 Swimc Llc Latex coating composition having reduced flavor scalping properties
US10858510B2 (en) 2016-08-17 2020-12-08 Ineos Styrolution Group Gmbh Transparent graft copolymers based on acrylate soft phases
WO2018148388A1 (en) * 2017-02-08 2018-08-16 Swimc, Llc Environmentally friendly aqueous coating composition
US11186667B2 (en) 2017-07-12 2021-11-30 Covestro (Netherlands) B.V. Aqueous binder composition
EP3655486B8 (en) 2017-07-17 2022-05-18 Covestro (Netherlands) B.V. Aqueous crosslinkable coating composition
CN110914361B (zh) * 2017-09-29 2022-08-19 株式会社Lg化学 热塑性树脂组合物以及使用其制备的热塑性树脂模制品
WO2019152078A1 (en) * 2018-02-01 2019-08-08 Brewer Science, Inc. Gradient block copolymers for directed self-assembly
EP3818087B1 (en) 2018-07-05 2024-09-11 Basf Se Process for producing an aqueous polymer dispersion
CN110240821B (zh) 2019-05-07 2021-04-02 广东华润涂料有限公司 木器用涂料组合物以及由其制成的木制品
CN110105799B (zh) 2019-05-07 2021-10-01 广东华润涂料有限公司 木器用涂料组合物以及由其制成的木制品
KR20220118472A (ko) * 2019-12-18 2022-08-25 다우 글로벌 테크놀로지스 엘엘씨 흡장된 중합체 입자의 수성 분산액의 제조
EP3892682A1 (en) * 2020-04-09 2021-10-13 Allnex Netherlands B.V. Waterborne coating composition
CN111777349B (zh) * 2020-07-28 2022-05-10 陕西科技大学 一种水泥基复合材料抗减缩抗裂缝外加剂及其制备方法
CN116529277A (zh) 2020-11-26 2023-08-01 巴斯夫欧洲公司 用于双组分涂料组合物的水基粘合剂
EP4367151B1 (en) 2021-07-08 2025-07-16 Allnex Netherlands B.V. Aqueous vinyl polymer dispersion
CN114507321B (zh) * 2022-01-17 2025-01-17 东来涂料技术（上海）股份有限公司 一种抗菌无皂型聚合物分散体及其制备方法与应用
JP2025021447A (ja) * 2023-07-31 2025-02-13 花王株式会社 乳化重合用界面活性剤組成物
CN117603417B (zh) * 2023-10-08 2026-06-23 吉林大学 一种球状聚合物纳米颗粒的合成方法
WO2026003301A1 (en) 2024-06-28 2026-01-02 Akzo Nobel Coatings International B.V. Aqueous polymer dispersion for coatings and adhesives

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EP0338486B1 (en) * 1988-04-21 1996-12-11 S.C. Johnson & Son, Inc. Stable emulsion polymers and methods of preparing same
CN1256295A (zh) * 1998-12-08 2000-06-14 罗姆和哈斯公司 抗灰尘拾取性涂料粘结料及涂料
CN1965042A (zh) * 2004-06-11 2007-05-16 树脂核动力工业有限公司 水性多段聚合物分散体

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CN1256295A (zh) * 1998-12-08 2000-06-14 罗姆和哈斯公司 抗灰尘拾取性涂料粘结料及涂料
CN1965042A (zh) * 2004-06-11 2007-05-16 树脂核动力工业有限公司 水性多段聚合物分散体

Also Published As

Publication number Publication date
EP2982699B1 (en) 2019-01-30
US20140039122A1 (en) 2014-02-06
EP2697267B1 (en) 2015-11-04
ES2559405T3 (es) 2016-02-12
AU2012241914A1 (en) 2013-10-03
SG193940A1 (en) 2013-11-29
JP6137557B2 (ja) 2017-05-31
US8975332B2 (en) 2015-03-10
PL2697267T3 (pl) 2016-04-29
DK2982699T3 (da) 2019-05-06
CN106883323A (zh) 2017-06-23
CN103459432A (zh) 2013-12-18
AU2012241914B2 (en) 2015-07-16
EP2982699A1 (en) 2016-02-10
RU2013142194A (ru) 2015-05-20
TW201242982A (en) 2012-11-01
TWI508980B (zh) 2015-11-21
JP2014512437A (ja) 2014-05-22
EP2697267A1 (en) 2014-02-19
CN106883323B (zh) 2019-04-09
RU2609010C2 (ru) 2017-01-30
WO2012140042A1 (en) 2012-10-18

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Address after: Bergen Op Zoom Holland

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