BR112018068556A2 - dispersão polimérica, método para produzir uma dispersão polimérica, material de revestimento, e, uso de uma dispersão polimérica. - Google Patents

dispersão polimérica, método para produzir uma dispersão polimérica, material de revestimento, e, uso de uma dispersão polimérica.

Info

Publication number
BR112018068556A2
BR112018068556A2 BR112018068556-9A BR112018068556A BR112018068556A2 BR 112018068556 A2 BR112018068556 A2 BR 112018068556A2 BR 112018068556 A BR112018068556 A BR 112018068556A BR 112018068556 A2 BR112018068556 A2 BR 112018068556A2
Authority
BR
Brazil
Prior art keywords
carbon atoms
optionally
group
vinyl
ethylenically unsaturated
Prior art date
Application number
BR112018068556-9A
Other languages
English (en)
Inventor
Balk Roelof
LOHMEIJER Bastiaan
Wrazidlo Robert
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of BR112018068556A2 publication Critical patent/BR112018068556A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C09D5/027—Dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

a presente invenção provê dispersões poliméricas muito finamente divididas obteníveis por pelo menos uma polimerização em emulsão de dois estágios, em que 1) um primeiro polímero rico em ácido p1 é preparado por uma polimerização radical de uma 1ª composição compreendendo a) pelo menos um monômero selecionado do grupo de (met)acrilatos de (ciclo)alquila, vinilaromáticos com até 20 átomos de carbono, um composto polimerizável radicalmente selecionado do grupo de nitrilas etilenicamente insaturadas com até 20 átomos de carbono, ésteres vinílicos de ácidos carboxílicos contendo até 20 átomos de carbono, halogenetos de vinila com até 10 átomos de carbono e éteres de vinila de álcoois com 1 a 10 átomos de carbono b) pelo menos um ácido carboxílico a,ß-etilenicamente insaturado c) pelo menos um monômero de reticulação com um grupo ceto ou aldeído d) opcionalmente pelo menos um promotor de adesão e) opcionalmente acrilato de terc-butila f) opcionalmente outros monômeros m na presença de um agente de transferência de ligação de cadeia, 2) o polímero p1 preparado em 1) é misturado com uma base, 3) um polímero hidrofóbico p2 é preparado por polimerização radical, na presença do polímero p1 tratado sob 2), a partir de uma 2ª composição compreendendo a) pelo menos um monômero selecionado do grupo de (met)acrilatos de (ciclo)alquila, vinilaromáticos com até 20 átomos de carbono, um composto polimerizável radicalmente selecionado do grupo de nitrilas etilenicamente insaturadas com até 20 átomos de carbono, ésteres vinílicos de ácidos carboxílicos contendo até 20 átomos de carbono, halogenetos de vinila com até 10 átomos de carbono e éteres de vinila de álcoois com 1 a 10 átomos de carbono b) opcionalmente pelo menos um ácido carboxílico a,ß-etilenicamente insaturado c) pelo menos um monômero de reticulação com um grupo ceto ou aldeído d) opcionalmente pelo menos um promotor de adesão, e também e) opcionalmente outros monômeros m, 4) e por adição opcional, subsequente à polimerização de p1 e p2, de uma poliamina alcoxilada trifuncional pelo menos solúvel em água, mais particularmente uma triamina etoxilada e/ou propoxilada.
BR112018068556-9A 2016-03-18 2017-03-14 dispersão polimérica, método para produzir uma dispersão polimérica, material de revestimento, e, uso de uma dispersão polimérica. BR112018068556A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16161067.0 2016-03-18
EP16161067 2016-03-18
PCT/EP2017/055985 WO2017157934A1 (de) 2016-03-18 2017-03-14 Feinteilige wässrige mehrstufige polymerisatdispersion, verfahren zu deren herstellung und deren verwendung als bindemittel

Publications (1)

Publication Number Publication Date
BR112018068556A2 true BR112018068556A2 (pt) 2019-02-12

Family

ID=55650141

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018068556-9A BR112018068556A2 (pt) 2016-03-18 2017-03-14 dispersão polimérica, método para produzir uma dispersão polimérica, material de revestimento, e, uso de uma dispersão polimérica.

Country Status (8)

Country Link
US (1) US10913811B2 (pt)
EP (1) EP3430065A1 (pt)
KR (1) KR20180126517A (pt)
CN (1) CN109071733B (pt)
AU (1) AU2017234180B2 (pt)
BR (1) BR112018068556A2 (pt)
CA (1) CA3017548A1 (pt)
WO (1) WO2017157934A1 (pt)

Families Citing this family (8)

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Publication number Priority date Publication date Assignee Title
CN112166132B (zh) * 2018-06-07 2023-05-05 国际人造丝公司 聚合物分散体、它们的制备和用途
ES2966064T3 (es) 2018-08-02 2024-04-18 Basf Se Procedimiento para producir una dispersión polimérica acuosa
BR112021010033A2 (pt) * 2019-03-21 2021-10-13 Sika Technology Ag Composição à base de água com transparência aprimorada
US20220363938A1 (en) * 2019-09-20 2022-11-17 Basf Se Coatings with improved adhesion
CN114787205B (zh) * 2019-12-18 2024-04-16 陶氏环球技术有限责任公司 封闭聚合物粒子的含水分散体的制备
CA3168208A1 (en) * 2020-02-21 2021-08-26 Swimc Llc Stain-blocking polymers, primers, kits, and methods
CN116057128B (zh) * 2020-08-11 2024-06-28 湛新荷兰有限公司 水性涂料组合物
WO2024040010A1 (en) * 2022-08-15 2024-02-22 Ppg Industries Ohio, Inc. Coating compositions including acrylic polymers for cookware, bakeware and other cooking appliances

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Also Published As

Publication number Publication date
KR20180126517A (ko) 2018-11-27
US20190100613A1 (en) 2019-04-04
AU2017234180A1 (en) 2018-10-25
CA3017548A1 (en) 2017-09-21
EP3430065A1 (de) 2019-01-23
WO2017157934A1 (de) 2017-09-21
US10913811B2 (en) 2021-02-09
CN109071733B (zh) 2022-03-29
AU2017234180B2 (en) 2021-05-20
CN109071733A (zh) 2018-12-21

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B11A Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing
B11Y Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]