GB1329126A - Acrylic fibre and a method for manufacturing the same - Google Patents

Acrylic fibre and a method for manufacturing the same

Info

Publication number
GB1329126A
GB1329126A GB5722970A GB5722970A GB1329126A GB 1329126 A GB1329126 A GB 1329126A GB 5722970 A GB5722970 A GB 5722970A GB 5722970 A GB5722970 A GB 5722970A GB 1329126 A GB1329126 A GB 1329126A
Authority
GB
United Kingdom
Prior art keywords
polyethylene glycol
monomers
acrylonitrile
ether
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5722970A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Publication of GB1329126A publication Critical patent/GB1329126A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/42—Nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00—Chemistry of carbon compounds
    • Y10S260/21—Polymer chemically or physically modified to impart antistatic properties and methods of antistatic agent addition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Artificial Filaments (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1329126 Acrylonitrile copolymer fibres MITSUBISHI RAYON CO Ltd 1 Dec 1970 [11 Dec 1969 31 March 1970] 57229/70 Heading C3P Fibres are formed from acrylonitrile copolymers comprising at least 50% by wt. of (a) acrylonitrile and less than 50% but not less than 1% of (b) a compound of the formula RCOR<SP>1</SP>NHCOCR<SP>11</SP>=CH 2 in which R and R<SP>11</SP> are H or C 1 -C 10 alkyl and R<SP>1</SP> is ethylene or alkyl-substituted ethylene containing no more than 15 carbons, (c) a monomer selected from hydroxyl-containing monomers, carboxyl monomers or their salts, sulphonic acid monomers or their salts, amide monomers, polyethylene glycol acrylates and methacrylates, vinyl pyrrolidone and other monomers with polyethylene glycol side chains and optionally (d) a fourth monomer. The fibres may also be formed from a mixture of such a copolymer with a different copolymer containing at least 85% acrylonitrile. In examples, monomer (c) is sodium vinylbenzene sulphonate, acrylic acid, sodium acrylate, hydroxyethyl acrylate, N-vinylpyrrolidone, polyethylene glycol C 18 alkyl ether monoacrylate, polyethylene glycol monononylphenol ether monomethacrylate, a di-polyethyleneglycol ether itaconate, polyethyleneglycol ether acrylamide, itaconic acid, methacrylic acid, and other polyethylene glycol ether acrylates or itaconates. In two examples vinyl acetate is present as a fourth monomer. The other copolymers used in the examples contain vinyl acetate, methyl acrylate and sodium vinylbenzene sulphonate, methyl acrylate, or vinyl acetate and methacrylic acid as comonomers. The copolymer or mixture of copolymers is dissolved in dimethyl formamide or acetamide or dimethyl sulphoxide and wet or dry spun.
GB5722970A 1969-12-11 1970-12-01 Acrylic fibre and a method for manufacturing the same Expired GB1329126A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP9972869 1969-12-11
JP2655370 1970-03-31

Publications (1)

Publication Number Publication Date
GB1329126A true GB1329126A (en) 1973-09-05

Family

ID=26364357

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5722970A Expired GB1329126A (en) 1969-12-11 1970-12-01 Acrylic fibre and a method for manufacturing the same

Country Status (5)

Country Link
US (1) US3718716A (en)
DE (1) DE2061213A1 (en)
FR (1) FR2073674A5 (en)
GB (1) GB1329126A (en)
NL (1) NL7017676A (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3975337A (en) * 1972-04-20 1976-08-17 Bayer Aktiengesellschaft Process for the production of acrylic fibers processible into yarns with improved textile properties and low boiling-induced shrinkage values
DE2730643A1 (en) * 1977-07-07 1979-01-25 Bayer Ag FIBER AND FAED MIXTURES CONTAINING SOOT MODIFIED, HIGH-SHRINKAGE POLY (MOD) ACRYLIC BIFILAR FIBERS OR FIBERS
DE3536262A1 (en) * 1985-10-11 1987-04-16 Basf Ag STORAGE STABILITY, ORGANIC SOLVENT SOLVED OR DISPERSED CROSSLINKABLE COMPOSITIONS, THEIR PRODUCTION AND USE
US6713646B2 (en) 2002-04-12 2004-03-30 Biosphere Medical Degradable crosslinkers, and degradable crosslinked hydrogels comprising them
US7838699B2 (en) * 2002-05-08 2010-11-23 Biosphere Medical Embolization using degradable crosslinked hydrogels
US6884905B2 (en) * 2002-07-23 2005-04-26 Biosphere Medical Degradable carbamate-containing bis(acryloyl) crosslinkers, and degradable crosslinked hydrogels comprising them
NO2225337T3 (en) 2007-11-19 2018-01-20
KR20100100891A (en) 2007-11-19 2010-09-15 바스프 에스이 Use of highly-branched polymers for producing polymer dispersions with improved freeze/thaw stability
AU2009227048B2 (en) 2008-03-20 2014-07-17 Basf Se Polymer dispersions containing phosphorous polymers and emulsifiers
KR101731125B1 (en) 2008-12-01 2017-04-27 바스프 에스이 Aqueous binder composition comprising oligomers
CN102471632B (en) 2009-07-22 2014-12-03 巴斯夫欧洲公司 Aqueous polymer dispersion as a binding agent for plasters and coating materials having improved fire behavior
AU2010294679B2 (en) 2009-09-15 2014-09-18 Basf Se Aqueous dispersions containing antimicrobials in a hybrid network
US8785557B2 (en) 2009-12-16 2014-07-22 Basf Se Use of aqueous hybrid binders for gloss paints
ES2536704T3 (en) 2009-12-16 2015-05-27 Basf Se Process for the production of aqueous hybrid binders with low residual monomer content as well as their use for high gloss paints
CN102844354B (en) 2010-02-18 2015-07-08 巴斯夫欧洲公司 Polymer dispersion comprising highly branched polycarbonate with unsaturated fatty acid groups
CN102453252B (en) * 2010-10-20 2014-07-09 中国石油化工股份有限公司 Acrylamide macromonomer and comb type copolymer and preparation method and application thereof
CN103270061B (en) 2010-12-21 2016-04-06 巴斯夫欧洲公司 Multistage polymer dispersion and manufacture method thereof and purposes
US8754151B2 (en) 2010-12-21 2014-06-17 Basf Se Multistage polymer dispersions, processes for preparing them, and use thereof
HUE029856T2 (en) * 2011-07-22 2017-04-28 Mitsubishi Rayon Co Polyacrylonitrile-based copolymer, polyacrylonitrile-based precursor fiber for carbon fiber, carbon fiber bundles, process for producing flameproofed fiber bundles, and process for producing carbon fiber bundles
EP2636714A1 (en) 2012-03-09 2013-09-11 Basf Se Multistage preparation of aqueous adhesive dispersions for producing self-adhesive items
MX2014014975A (en) 2012-06-05 2015-08-05 Basf Se Use of multi-stage polymerizate dispersions to coat metal sheets.
BR112015000169A2 (en) 2012-07-06 2017-06-27 Basf Se aqueous hybrid binder, aqueous alkyd resin system, coating composition, process for preparing an aqueous hybrid binder, uses of an aqueous hybrid binder and an aqueous alkyd system, and method for enhancing hardness development
BR112018007784A2 (en) 2015-10-20 2018-10-30 Basf Se use of a coating composition, methods for coating a fiber cement slab and for producing an aqueous polymer dispersion, and, aqueous polymer dispersion
JP2019509357A (en) 2016-01-18 2019-04-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Use of one-component laminate adhesive for laminating composite films
ES2693976T3 (en) 2016-02-08 2018-12-17 Basf Se Use of an adhesive dispersion for the lamination of shiny films
CA3017548A1 (en) 2016-03-18 2017-09-21 Basf Se Finely divided aqueous multistage polymer dispersion, method for the production thereof, and use thereof as a binder
ES2931335T3 (en) 2018-04-20 2022-12-28 Basf Se Gel-containing adhesive composition based on crosslinking by keto or aldehyde groups
WO2020165125A1 (en) 2019-02-15 2020-08-20 Covestro Intellectual Property Gmbh & Co. Kg New systems for priming and adhesion of flooring

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL160413B (en) * 1950-04-26 Int Computers Ltd METHOD OF MANUFACTURING A MAGNETIC HEAD.
US2719138A (en) * 1952-01-17 1955-09-27 Eastman Kodak Co Polymerization of acrylonitrile in presence of n-acyl acrylamide and n-acyl methacrylamide polymers
US3277056A (en) * 1963-11-27 1966-10-04 Lubrizol Corp N-3-oxohydrocarbon-substituted acrylamides and polymers thereof
US3366613A (en) * 1964-08-17 1968-01-30 Rohm & Haas Monomers and polymers of n-(acryloxyalkyl)acylamides and methods of making them
US3341455A (en) * 1966-05-31 1967-09-12 Lubrizol Corp Lubricants containing copolymeric nitrogen compounds
BE704127A (en) * 1966-09-22 1968-03-21
US3607835A (en) * 1967-12-20 1971-09-21 Sir Soc Italiana Resine Spa Acrylonitrile copolymers and method of preparing them

Also Published As

Publication number Publication date
FR2073674A5 (en) 1971-10-01
US3718716A (en) 1973-02-27
DE2061213A1 (en) 1971-06-24
NL7017676A (en) 1971-06-15

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years