CN1034522C - 等离子体增强电化学表面陶瓷化方法及其制得的产品 - Google Patents
等离子体增强电化学表面陶瓷化方法及其制得的产品 Download PDFInfo
- Publication number
- CN1034522C CN1034522C CN95114880A CN95114880A CN1034522C CN 1034522 C CN1034522 C CN 1034522C CN 95114880 A CN95114880 A CN 95114880A CN 95114880 A CN95114880 A CN 95114880A CN 1034522 C CN1034522 C CN 1034522C
- Authority
- CN
- China
- Prior art keywords
- sodium
- electrolyte solution
- borax
- arc discharge
- described method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 58
- 239000000919 ceramic Substances 0.000 title claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 34
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 30
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 28
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 28
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 28
- 230000003647 oxidation Effects 0.000 claims abstract description 25
- 229910021538 borax Inorganic materials 0.000 claims abstract description 24
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 24
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 24
- 238000010891 electric arc Methods 0.000 claims abstract description 20
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011159 matrix material Substances 0.000 claims abstract description 13
- 239000004327 boric acid Substances 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 3
- 230000000996 additive effect Effects 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 17
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 17
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 15
- 239000001488 sodium phosphate Substances 0.000 claims description 15
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 13
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 13
- 235000011152 sodium sulphate Nutrition 0.000 claims description 13
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims description 11
- 241000220317 Rosa Species 0.000 claims description 8
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 8
- 235000019353 potassium silicate Nutrition 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 229940078494 nickel acetate Drugs 0.000 claims description 6
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 6
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 5
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 5
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 4
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 claims description 4
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 4
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 4
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 4
- 150000002815 nickel Chemical class 0.000 claims description 4
- PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 claims description 4
- 239000004246 zinc acetate Substances 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 3
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 3
- 239000001639 calcium acetate Substances 0.000 claims description 3
- 235000011092 calcium acetate Nutrition 0.000 claims description 3
- 229960005147 calcium acetate Drugs 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000007769 metal material Substances 0.000 abstract description 5
- 239000003086 colorant Substances 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract description 2
- 238000004381 surface treatment Methods 0.000 abstract description 2
- 238000007743 anodising Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 229940021013 electrolyte solution Drugs 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 238000007747 plating Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 5
- 229910052573 porcelain Inorganic materials 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 241000233855 Orchidaceae Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 241000238097 Callinectes sapidus Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- 241001460678 Napo <wasp> Species 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000010405 reoxidation reaction Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/026—Anodisation with spark discharge
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Detergent Compositions (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95114880A CN1034522C (zh) | 1995-04-18 | 1995-04-18 | 等离子体增强电化学表面陶瓷化方法及其制得的产品 |
| AU33788/95A AU3378895A (en) | 1995-04-18 | 1995-09-11 | Process for producing ceramic layer by plasma enhanced elect rolysis and product thereof |
| JP8531384A JP2937484B2 (ja) | 1995-04-18 | 1995-09-11 | プラズマ増強された電気化学的表面セラミックス化の方法および製品 |
| EP95930367A EP0823496B1 (de) | 1995-04-18 | 1995-09-11 | Herstellung einer keramischen schicht mit plasmaunterstützter elektrolyse und so hergestelltes produkt |
| PCT/CN1995/000072 WO1996033300A1 (en) | 1995-04-18 | 1995-09-11 | Process for producing ceramic layer by plasma enhanced electrolysis and product thereof |
| DE69526256T DE69526256T2 (de) | 1995-04-18 | 1995-09-11 | Herstellung einer keramischen schicht mit plasmaunterstützter elektrolyse und so hergestelltes produkt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95114880A CN1034522C (zh) | 1995-04-18 | 1995-04-18 | 等离子体增强电化学表面陶瓷化方法及其制得的产品 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1115793A CN1115793A (zh) | 1996-01-31 |
| CN1034522C true CN1034522C (zh) | 1997-04-09 |
Family
ID=5080362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95114880A Expired - Fee Related CN1034522C (zh) | 1995-04-18 | 1995-04-18 | 等离子体增强电化学表面陶瓷化方法及其制得的产品 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0823496B1 (de) |
| JP (1) | JP2937484B2 (de) |
| CN (1) | CN1034522C (de) |
| AU (1) | AU3378895A (de) |
| DE (1) | DE69526256T2 (de) |
| WO (1) | WO1996033300A1 (de) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050389C (zh) * | 1997-04-21 | 2000-03-15 | 哈尔滨环亚微弧技术有限公司 | 等离子体增强电化学表面陶瓷化能量控制方法 |
| US7452454B2 (en) | 2001-10-02 | 2008-11-18 | Henkel Kgaa | Anodized coating over aluminum and aluminum alloy coated substrates |
| US7569132B2 (en) | 2001-10-02 | 2009-08-04 | Henkel Kgaa | Process for anodically coating an aluminum substrate with ceramic oxides prior to polytetrafluoroethylene or silicone coating |
| US7820300B2 (en) | 2001-10-02 | 2010-10-26 | Henkel Ag & Co. Kgaa | Article of manufacture and process for anodically coating an aluminum substrate with ceramic oxides prior to organic or inorganic coating |
| US7578921B2 (en) * | 2001-10-02 | 2009-08-25 | Henkel Kgaa | Process for anodically coating aluminum and/or titanium with ceramic oxides |
| US20060016690A1 (en) | 2004-07-23 | 2006-01-26 | Ilya Ostrovsky | Method for producing a hard coating with high corrosion resistance on articles made anodizable metals or alloys |
| EP2371996B1 (de) * | 2008-12-26 | 2016-03-09 | Nihon Parkerizing Co., Ltd. | Verfahren für eine elektrolytische keramik-metallbeschichtung, elektrolyseanwendung für eine elektrolytische keramik-metallbeschichtung und metallisches material |
| US9701177B2 (en) | 2009-04-02 | 2017-07-11 | Henkel Ag & Co. Kgaa | Ceramic coated automotive heat exchanger components |
| CN102102217A (zh) * | 2009-12-18 | 2011-06-22 | 中国电子科技集团公司第四十九研究所 | 一种微弧氧化制造氧化铝薄膜方法 |
| CN103290448A (zh) * | 2013-05-07 | 2013-09-11 | 锡山区羊尖泓之盛五金厂 | 一种金属表面耐蚀处理方法 |
| JP2015074825A (ja) * | 2013-10-11 | 2015-04-20 | 株式会社栗本鐵工所 | プラズマ電解酸化による皮膜形成方法及び金属材料 |
| CN104404601B (zh) * | 2014-12-19 | 2017-09-29 | 中北大学 | Mg‑Gd‑Y‑Zr铸造镁合金的一种微弧氧化处理工艺 |
| CN105862131B (zh) * | 2016-06-03 | 2018-05-01 | 武汉工程大学 | 一种利用mpcvd制备碳化钼晶体时钼的引入方法 |
| GB201610615D0 (en) * | 2016-06-17 | 2016-08-03 | Keronite Int Ltd | Durable white inorganic finish for aluminium articles |
| CN107630185B (zh) * | 2017-09-15 | 2020-01-17 | 芜湖通潮精密机械股份有限公司 | 一种干刻机台内壁板再生方法 |
| CN111876811B (zh) * | 2020-07-27 | 2022-02-25 | 上海交通大学 | 一种铝锂合金微弧氧化方法及其采用的电解液 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3834999A (en) * | 1971-04-15 | 1974-09-10 | Atlas Technology Corp | Electrolytic production of glassy layers on metals |
| US4869798A (en) * | 1987-10-27 | 1989-09-26 | Flachglas Aktiengesellschaft | Apparatus for the galvanic reinforcement of a conductive trace on a glass pane |
| EP0462073A2 (de) * | 1990-06-14 | 1991-12-18 | JENOPTIK GmbH | Elektrolyt zur Erzeugung dünner schwarzer Konversionsschichten auf Leichtmetallen |
| RU1812247C (ru) * | 1990-08-24 | 1993-04-30 | Институт Прикладной Физики | Способ обработки деталей |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3328049A1 (de) * | 1983-08-03 | 1985-02-21 | Hoechst Ag, 6230 Frankfurt | Verfahren zur einstufigen anodischen oxidation von traegermaterialien aus aluminium fuer offsetdruckplatten |
| CN87103694A (zh) * | 1985-10-24 | 1988-11-09 | 鲁道夫·何拉德科夫斯基 | 铝制品的电镀方法及所用的电镀液 |
| DE3870925D1 (de) * | 1987-02-02 | 1992-06-17 | Friebe & Reininghaus Ahc | Verfahren zur herstellung dekorativer ueberzuege auf metallen. |
| CN2202135Y (zh) * | 1994-08-30 | 1995-06-28 | 哈尔滨环亚微弧技术有限公司 | 铝合金表面弧增强电化学沉积装置 |
-
1995
- 1995-04-18 CN CN95114880A patent/CN1034522C/zh not_active Expired - Fee Related
- 1995-09-11 DE DE69526256T patent/DE69526256T2/de not_active Expired - Fee Related
- 1995-09-11 AU AU33788/95A patent/AU3378895A/en not_active Abandoned
- 1995-09-11 JP JP8531384A patent/JP2937484B2/ja not_active Expired - Fee Related
- 1995-09-11 EP EP95930367A patent/EP0823496B1/de not_active Revoked
- 1995-09-11 WO PCT/CN1995/000072 patent/WO1996033300A1/zh not_active Application Discontinuation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3834999A (en) * | 1971-04-15 | 1974-09-10 | Atlas Technology Corp | Electrolytic production of glassy layers on metals |
| US4869798A (en) * | 1987-10-27 | 1989-09-26 | Flachglas Aktiengesellschaft | Apparatus for the galvanic reinforcement of a conductive trace on a glass pane |
| EP0462073A2 (de) * | 1990-06-14 | 1991-12-18 | JENOPTIK GmbH | Elektrolyt zur Erzeugung dünner schwarzer Konversionsschichten auf Leichtmetallen |
| RU1812247C (ru) * | 1990-08-24 | 1993-04-30 | Институт Прикладной Физики | Способ обработки деталей |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0823496A1 (de) | 1998-02-11 |
| EP0823496B1 (de) | 2002-04-03 |
| JP2937484B2 (ja) | 1999-08-23 |
| WO1996033300A1 (en) | 1996-10-24 |
| AU3378895A (en) | 1996-11-07 |
| DE69526256D1 (de) | 2002-05-08 |
| EP0823496A4 (de) | 1998-05-20 |
| JPH10509772A (ja) | 1998-09-22 |
| DE69526256T2 (de) | 2002-11-07 |
| CN1115793A (zh) | 1996-01-31 |
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