CN103380233B - 离子交换膜法电解槽 - Google Patents
离子交换膜法电解槽 Download PDFInfo
- Publication number
- CN103380233B CN103380233B CN201180068629.4A CN201180068629A CN103380233B CN 103380233 B CN103380233 B CN 103380233B CN 201180068629 A CN201180068629 A CN 201180068629A CN 103380233 B CN103380233 B CN 103380233B
- Authority
- CN
- China
- Prior art keywords
- exchange membrane
- ion
- coil
- electrolytic cell
- negative electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003014 ion exchange membrane Substances 0.000 title claims abstract description 102
- 238000000034 method Methods 0.000 title claims abstract description 58
- 229910052751 metal Inorganic materials 0.000 claims abstract description 35
- 239000002184 metal Substances 0.000 claims abstract description 35
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- 230000000630 rising effect Effects 0.000 abstract description 12
- 238000005868 electrolysis reaction Methods 0.000 description 30
- 239000003792 electrolyte Substances 0.000 description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 21
- 238000000354 decomposition reaction Methods 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 239000000758 substrate Substances 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 230000033228 biological regulation Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 208000016285 Movement disease Diseases 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910000457 iridium oxide Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/60—Constructional parts of cells
- C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/20—Improvements relating to chlorine production
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010292307A JP5693215B2 (ja) | 2010-12-28 | 2010-12-28 | イオン交換膜法電解槽 |
JP2010-292307 | 2010-12-28 | ||
PCT/JP2011/080295 WO2012091051A1 (ja) | 2010-12-28 | 2011-12-27 | イオン交換膜法電解槽 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103380233A CN103380233A (zh) | 2013-10-30 |
CN103380233B true CN103380233B (zh) | 2016-08-10 |
Family
ID=46383142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201180068629.4A Active CN103380233B (zh) | 2010-12-28 | 2011-12-27 | 离子交换膜法电解槽 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9476130B2 (ja) |
EP (1) | EP2660357B1 (ja) |
JP (1) | JP5693215B2 (ja) |
CN (1) | CN103380233B (ja) |
WO (1) | WO2012091051A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5583002B2 (ja) * | 2010-12-28 | 2014-09-03 | 東ソー株式会社 | イオン交換膜法電解槽 |
WO2015108115A1 (ja) | 2014-01-15 | 2015-07-23 | クロリンエンジニアズ株式会社 | イオン交換膜電解槽用陽極およびこれを用いたイオン交換膜電解槽 |
JP6408033B2 (ja) * | 2015-02-02 | 2018-10-17 | 株式会社東芝 | 電極ユニットおよびそれを用いた電解装置 |
US10815578B2 (en) * | 2017-09-08 | 2020-10-27 | Electrode Solutions, LLC | Catalyzed cushion layer in a multi-layer electrode |
DK3460101T3 (da) * | 2017-09-21 | 2020-06-02 | Hymeth Aps | Elektrode til en elektrolyseproces |
DE102018209520A1 (de) | 2018-06-14 | 2019-12-19 | Thyssenkrupp Uhde Chlorine Engineers Gmbh | Elektrolysezelle |
US20220145481A1 (en) * | 2019-03-18 | 2022-05-12 | Asahi Kasei Kabushiki Kaisha | Elastic mattress and electrolyzer |
US20220341049A1 (en) | 2019-06-18 | 2022-10-27 | Thyssenkrupp Uhde Chlorine Engineers Gmbh | Electrolysis electrode and electrolyzer |
WO2021085334A1 (ja) * | 2019-10-31 | 2021-05-06 | 株式会社トクヤマ | アルカリ水電解槽用弾性マット |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1537973A (zh) * | 2003-03-31 | 2004-10-20 | ̹�� | 电解电极和离子交换膜电解池 |
CN101175871A (zh) * | 2005-05-17 | 2008-05-07 | 氯工程公司 | 离子交换膜型电解槽 |
JP2009120882A (ja) * | 2007-11-13 | 2009-06-04 | Tosoh Corp | 電解槽構成部材及びそれを用いた電解槽 |
WO2010119918A1 (ja) * | 2009-04-16 | 2010-10-21 | クロリンエンジニアズ株式会社 | ガス拡散電極を有する2室法イオン交換膜食塩電解槽を用いる電解方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4615775A (en) | 1979-08-03 | 1986-10-07 | Oronzio De Nora | Electrolysis cell and method of generating halogen |
IT8025483A0 (it) | 1980-10-21 | 1980-10-21 | Oronzio De Nora Impianti | Elettrocdi per celle ad elettrolita solido applicati sulla superficie di membrane scambiatrici di ioni e procedimentodi prparazione ed uso degli stessi. |
US4444632A (en) | 1979-08-03 | 1984-04-24 | Oronzio Denora Impianti Elettrochimici S.P.A. | Electrolysis cell |
IT1122699B (it) | 1979-08-03 | 1986-04-23 | Oronzio De Nora Impianti | Collettore elettrico resiliente e cella elettrochimica ad elettrolita solido comprendente lo stesso |
US4693797A (en) * | 1979-08-03 | 1987-09-15 | Oronzio Denora Impianti Elettrochimici S.P.A. | Method of generating halogen and electrolysis cell |
US4340452A (en) | 1979-08-03 | 1982-07-20 | Oronzio deNora Elettrochimici S.p.A. | Novel electrolysis cell |
JPH0610352B2 (ja) | 1986-08-22 | 1994-02-09 | 日本真空技術株式会社 | Cvd装置 |
US5137743A (en) | 1990-09-07 | 1992-08-11 | Opta Food Ingredients, Inc. | Foods having an oil phase thickened with an oil soluble polyester |
DE69213362T2 (de) | 1991-06-26 | 1997-02-13 | Chlorine Eng Corp Ltd | Elektrolyseur und Herstellung davon |
JP3082315B2 (ja) | 1991-07-01 | 2000-08-28 | クロリンエンジニアズ株式会社 | 電解槽 |
JP3110551B2 (ja) | 1992-04-30 | 2000-11-20 | クロリンエンジニアズ株式会社 | 電解槽 |
US6042702A (en) * | 1993-11-22 | 2000-03-28 | E.I. Du Pont De Nemours And Company | Electrochemical cell having a current distributor comprising a conductive polymer composite material |
US6054228A (en) * | 1996-06-06 | 2000-04-25 | Lynntech, Inc. | Fuel cell system for low pressure operation |
JP3616265B2 (ja) * | 1998-12-10 | 2005-02-02 | 株式会社トクヤマ | イオン交換膜電解槽 |
JP3686270B2 (ja) | 1998-12-10 | 2005-08-24 | 株式会社トクヤマ | 電解槽 |
JP3772055B2 (ja) * | 1999-08-30 | 2006-05-10 | 株式会社トクヤマ | 電解槽 |
KR100583332B1 (ko) | 2002-11-27 | 2006-05-26 | 아사히 가세이 케미칼즈 가부시키가이샤 | 복극식 제로-갭 전해셀 |
JP3860132B2 (ja) * | 2003-03-31 | 2006-12-20 | クロリンエンジニアズ株式会社 | 水素発生陰極を使用するイオン交換膜電解槽 |
CN1938453B (zh) | 2004-04-23 | 2010-10-20 | 东曹株式会社 | 用于产生氢的电极及其制造方法和使用该电极的电解方法 |
JP4882218B2 (ja) | 2004-04-23 | 2012-02-22 | 東ソー株式会社 | 水素発生用電極およびその製造方法並びにこれを用いた電解方法 |
JP4305929B2 (ja) | 2006-06-05 | 2009-07-29 | クロリンエンジニアズ株式会社 | イオン交換膜電解槽 |
-
2010
- 2010-12-28 JP JP2010292307A patent/JP5693215B2/ja active Active
-
2011
- 2011-12-27 EP EP11852315.8A patent/EP2660357B1/en active Active
- 2011-12-27 WO PCT/JP2011/080295 patent/WO2012091051A1/ja active Application Filing
- 2011-12-27 CN CN201180068629.4A patent/CN103380233B/zh active Active
- 2011-12-27 US US13/977,301 patent/US9476130B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1537973A (zh) * | 2003-03-31 | 2004-10-20 | ̹�� | 电解电极和离子交换膜电解池 |
CN101175871A (zh) * | 2005-05-17 | 2008-05-07 | 氯工程公司 | 离子交换膜型电解槽 |
JP2009120882A (ja) * | 2007-11-13 | 2009-06-04 | Tosoh Corp | 電解槽構成部材及びそれを用いた電解槽 |
WO2010119918A1 (ja) * | 2009-04-16 | 2010-10-21 | クロリンエンジニアズ株式会社 | ガス拡散電極を有する2室法イオン交換膜食塩電解槽を用いる電解方法 |
Also Published As
Publication number | Publication date |
---|---|
US20130299342A1 (en) | 2013-11-14 |
EP2660357B1 (en) | 2017-09-27 |
JP5693215B2 (ja) | 2015-04-01 |
EP2660357A1 (en) | 2013-11-06 |
US9476130B2 (en) | 2016-10-25 |
WO2012091051A1 (ja) | 2012-07-05 |
CN103380233A (zh) | 2013-10-30 |
EP2660357A4 (en) | 2016-06-08 |
JP2012140654A (ja) | 2012-07-26 |
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