CN103254421A - 一种芳香族聚砜树脂的高压合成方法 - Google Patents
一种芳香族聚砜树脂的高压合成方法 Download PDFInfo
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- CN103254421A CN103254421A CN2013100181939A CN201310018193A CN103254421A CN 103254421 A CN103254421 A CN 103254421A CN 2013100181939 A CN2013100181939 A CN 2013100181939A CN 201310018193 A CN201310018193 A CN 201310018193A CN 103254421 A CN103254421 A CN 103254421A
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- 125000003118 aryl group Chemical group 0.000 title claims abstract description 17
- 239000011347 resin Substances 0.000 title claims abstract description 15
- 229920005989 resin Polymers 0.000 title claims abstract description 15
- 229920002492 poly(sulfone) Polymers 0.000 title claims abstract description 14
- 238000001308 synthesis method Methods 0.000 title abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 239000007789 gas Substances 0.000 claims abstract description 14
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 9
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- 150000001408 amides Chemical class 0.000 claims abstract description 6
- 239000011343 solid material Substances 0.000 claims abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 41
- 150000002500 ions Chemical class 0.000 claims description 24
- 239000006210 lotion Substances 0.000 claims description 24
- 238000005406 washing Methods 0.000 claims description 24
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 13
- 229910021641 deionized water Inorganic materials 0.000 claims description 13
- 238000006073 displacement reaction Methods 0.000 claims description 13
- 238000013467 fragmentation Methods 0.000 claims description 13
- 238000006062 fragmentation reaction Methods 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 238000010298 pulverizing process Methods 0.000 claims description 13
- 238000010792 warming Methods 0.000 claims description 13
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 8
- 238000010189 synthetic method Methods 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 239000004305 biphenyl Substances 0.000 claims description 4
- ZFVMWEVVKGLCIJ-UHFFFAOYSA-N bisphenol AF Chemical compound C1=CC(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C=C1 ZFVMWEVVKGLCIJ-UHFFFAOYSA-N 0.000 claims description 4
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 claims description 4
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 claims description 3
- 235000019628 coolness Nutrition 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 42
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 8
- 238000006116 polymerization reaction Methods 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 7
- 238000009835 boiling Methods 0.000 abstract description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract description 4
- 235000017550 sodium carbonate Nutrition 0.000 abstract description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 3
- 230000007062 hydrolysis Effects 0.000 abstract description 3
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- 239000008096 xylene Substances 0.000 abstract description 3
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- 229910001873 dinitrogen Inorganic materials 0.000 abstract 2
- GPAPPPVRLPGFEQ-UHFFFAOYSA-N 4,4'-dichlorodiphenyl sulfone Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC=C(Cl)C=C1 GPAPPPVRLPGFEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 7
- 150000001555 benzenes Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 0 CC(C=C1)=CCC1S(*)(C(C=C1)=CCC1Cl)=O Chemical compound CC(C=C1)=CCC1S(*)(C(C=C1)=CCC1Cl)=O 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- YYZNONMEYBVCCR-UHFFFAOYSA-N COC1C=CC(OC)=CC1 Chemical compound COC1C=CC(OC)=CC1 YYZNONMEYBVCCR-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277221A (zh) * | 2014-10-08 | 2015-01-14 | 江苏林泉汽车装饰件有限公司 | 界面缩聚法制备聚醚砜 |
CN104530431A (zh) * | 2014-12-17 | 2015-04-22 | 江门市优巨新材料有限公司 | 一种低色泽和高透光率聚砜树脂的工业化合成方法 |
CN104530419A (zh) * | 2014-12-17 | 2015-04-22 | 江门市优巨新材料有限公司 | 一种高热稳定性封端聚砜树脂的工业化合成方法 |
CN105331082A (zh) * | 2015-11-30 | 2016-02-17 | 江门市优巨新材料有限公司 | 一种纤维增强型低粘性聚砜树脂的制备方法 |
CN105330842A (zh) * | 2015-11-30 | 2016-02-17 | 江门市优巨新材料有限公司 | 一种含环烷烃基取代酚的高透明聚砜树脂的合成方法 |
CN105348513A (zh) * | 2015-11-30 | 2016-02-24 | 广东优巨先进材料研究有限公司 | 一种枝化高强度聚砜树脂的工业化合成方法 |
CN109422878A (zh) * | 2017-08-28 | 2019-03-05 | 北京师范大学 | 聚芳醚硫醚砜的制备方法及得到的聚芳醚硫醚砜 |
CN110183660A (zh) * | 2019-05-14 | 2019-08-30 | 万华化学集团股份有限公司 | 一种超支化砜聚合物的制备方法及其应用 |
Citations (4)
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CN101479321A (zh) * | 2006-06-22 | 2009-07-08 | 巴斯夫欧洲公司 | 黄度指数减少的聚砜和聚醚砜以及它们的制备方法 |
CN101903468A (zh) * | 2007-12-18 | 2010-12-01 | 索维高级聚合物股份有限公司 | 聚苯砜酮共聚物 |
US8110639B2 (en) * | 2006-11-17 | 2012-02-07 | Solvay Advanced Polymers, L.L.C. | Transparent and flame retardant polysulfone compositions |
CN102352033A (zh) * | 2011-09-14 | 2012-02-15 | 金发科技股份有限公司 | 一种制备粉末树脂的方法 |
-
2013
- 2013-01-18 CN CN201310018193.9A patent/CN103254421B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101479321A (zh) * | 2006-06-22 | 2009-07-08 | 巴斯夫欧洲公司 | 黄度指数减少的聚砜和聚醚砜以及它们的制备方法 |
US8110639B2 (en) * | 2006-11-17 | 2012-02-07 | Solvay Advanced Polymers, L.L.C. | Transparent and flame retardant polysulfone compositions |
CN101903468A (zh) * | 2007-12-18 | 2010-12-01 | 索维高级聚合物股份有限公司 | 聚苯砜酮共聚物 |
CN102352033A (zh) * | 2011-09-14 | 2012-02-15 | 金发科技股份有限公司 | 一种制备粉末树脂的方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277221A (zh) * | 2014-10-08 | 2015-01-14 | 江苏林泉汽车装饰件有限公司 | 界面缩聚法制备聚醚砜 |
CN104530431A (zh) * | 2014-12-17 | 2015-04-22 | 江门市优巨新材料有限公司 | 一种低色泽和高透光率聚砜树脂的工业化合成方法 |
CN104530419A (zh) * | 2014-12-17 | 2015-04-22 | 江门市优巨新材料有限公司 | 一种高热稳定性封端聚砜树脂的工业化合成方法 |
CN105331082A (zh) * | 2015-11-30 | 2016-02-17 | 江门市优巨新材料有限公司 | 一种纤维增强型低粘性聚砜树脂的制备方法 |
CN105330842A (zh) * | 2015-11-30 | 2016-02-17 | 江门市优巨新材料有限公司 | 一种含环烷烃基取代酚的高透明聚砜树脂的合成方法 |
CN105348513A (zh) * | 2015-11-30 | 2016-02-24 | 广东优巨先进材料研究有限公司 | 一种枝化高强度聚砜树脂的工业化合成方法 |
CN105330842B (zh) * | 2015-11-30 | 2018-04-20 | 江门市优巨新材料有限公司 | 一种含环烷烃基取代酚的高透明聚砜树脂的合成方法 |
CN109422878A (zh) * | 2017-08-28 | 2019-03-05 | 北京师范大学 | 聚芳醚硫醚砜的制备方法及得到的聚芳醚硫醚砜 |
CN109422878B (zh) * | 2017-08-28 | 2021-04-09 | 北京师范大学 | 聚芳醚硫醚砜的制备方法及得到的聚芳醚硫醚砜 |
CN110183660A (zh) * | 2019-05-14 | 2019-08-30 | 万华化学集团股份有限公司 | 一种超支化砜聚合物的制备方法及其应用 |
CN110183660B (zh) * | 2019-05-14 | 2021-07-23 | 万华化学集团股份有限公司 | 一种超支化砜聚合物的制备方法及其应用 |
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Address after: 264211 North West Kaiyuan Road, Lingang Economic and Technological Development Zone, Weihai, Shandong Patentee after: SHANDONG HAORAN SPECIAL PLASTIC CO.,LTD. Address before: 264211 North West Kaiyuan Road, Weihai Industrial Zone, Shandong Patentee before: Shandong Horan Super Engineering Plastics Co.,Ltd. |
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Denomination of invention: High pressure synthesis method for aromatic polysulfone resin Effective date of registration: 20200305 Granted publication date: 20150701 Pledgee: Weihai City Commercial Bank Limited by Share Ltd. high tech branch Pledgor: SHANDONG HAORAN SPECIAL PLASTIC CO.,LTD. Registration number: Y2020990000152 |
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Date of cancellation: 20230510 Granted publication date: 20150701 Pledgee: Weihai City Commercial Bank Limited by Share Ltd. high tech branch Pledgor: SHANDONG HAORAN SPECIAL PLASTIC CO.,LTD. Registration number: Y2020990000152 |
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Denomination of invention: A high-pressure synthesis method for aromatic polysulfone resin Effective date of registration: 20230516 Granted publication date: 20150701 Pledgee: Weihai City Commercial Bank Co.,Ltd. Park sub branch Pledgor: SHANDONG HAORAN SPECIAL PLASTIC CO.,LTD. Registration number: Y2023980040407 |