CN103221345B - 制备表面改性的电极材料的方法 - Google Patents

制备表面改性的电极材料的方法 Download PDF

Info

Publication number
CN103221345B
CN103221345B CN201180055691.XA CN201180055691A CN103221345B CN 103221345 B CN103221345 B CN 103221345B CN 201180055691 A CN201180055691 A CN 201180055691A CN 103221345 B CN103221345 B CN 103221345B
Authority
CN
China
Prior art keywords
phosphorus
mixed oxide
containing organic
sulfur
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201180055691.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN103221345A (zh
Inventor
M·舒尔茨-多布里克
B·埃瓦尔德
J·K·兰伯特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN103221345A publication Critical patent/CN103221345A/zh
Application granted granted Critical
Publication of CN103221345B publication Critical patent/CN103221345B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Complex oxides containing manganese and at least one other metal element
    • C01G45/1221Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Complex oxides containing manganese and at least one other metal element
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Complex oxides containing manganese and at least one other metal element
    • C01G45/1221Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/80Particles consisting of a mixture of two or more inorganic phases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
CN201180055691.XA 2010-09-21 2011-09-20 制备表面改性的电极材料的方法 Active CN103221345B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10177833 2010-09-21
EP10177833.0 2010-09-21
PCT/EP2011/066300 WO2012038412A1 (de) 2010-09-21 2011-09-20 Verfahren zur herstellung von oberflächenmodifizierten elektrodenmaterialien

Publications (2)

Publication Number Publication Date
CN103221345A CN103221345A (zh) 2013-07-24
CN103221345B true CN103221345B (zh) 2015-10-14

Family

ID=44719890

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180055691.XA Active CN103221345B (zh) 2010-09-21 2011-09-20 制备表面改性的电极材料的方法

Country Status (6)

Country Link
EP (1) EP2619139B1 (enExample)
JP (1) JP6305059B2 (enExample)
KR (1) KR20130097778A (enExample)
CN (1) CN103221345B (enExample)
TW (1) TW201219981A (enExample)
WO (1) WO2012038412A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9388045B2 (en) 2013-05-08 2016-07-12 Changs Ascending Enterprise Co. Synthesis and characterization of lithium nickel manganese cobalt phosphorous oxide
KR101684276B1 (ko) * 2013-09-06 2016-12-08 주식회사 엘지화학 복수의 전극활물질층을 갖는 전극, 이의 제조방법 및 이를 포함하는 전기화학 소자
CA2956032C (en) * 2014-07-24 2019-04-16 Changs Ascending Enterprise Co., Ltd. Synthesis and characterization of lithium nickel manganese cobalt phosphorous oxide
US12187021B2 (en) * 2020-06-17 2025-01-07 Grst International Limited Method for composite delamination

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101160684A (zh) * 2005-03-02 2008-04-09 U芝加哥阿谷尼有限公司 用于锂电池的充电过度保护的新型氧化还原穿梭化合物
CN101164187A (zh) * 2005-04-25 2008-04-16 费罗公司 具有混合盐的非水电解液
US20090286157A1 (en) * 2008-05-16 2009-11-19 Zonghai Chen Surface modification agents for lithium batteries
CN101707251A (zh) * 2008-11-28 2010-05-12 松下电器产业株式会社 含锂复合氧化物的制造方法及非水系二次电池
CN101789520A (zh) * 2009-01-23 2010-07-28 索尼公司 电解液和二次电池

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE60040964D1 (de) * 1999-06-04 2009-01-15 Panasonic Corp Yten und verfahen zu deren herstellung
JP2002270184A (ja) * 2001-03-14 2002-09-20 Hitachi Maxell Ltd 非水二次電池
JP2002352804A (ja) * 2001-05-28 2002-12-06 Hitachi Maxell Ltd 非水二次電池
JP4562496B2 (ja) * 2004-11-10 2010-10-13 日本化学工業株式会社 改質リチウムマンガン複合酸化物、その製造方法、リチウム二次電池正極活物質組成物及びリチウム二次電池
JP5083743B2 (ja) * 2005-07-06 2012-11-28 株式会社 東北テクノアーチ リチウム電池
JP4710916B2 (ja) * 2008-02-13 2011-06-29 ソニー株式会社 非水電解質二次電池用正極活物質、これを用いた非水電解質二次電池用正極および非水電解質二次電池
FR2937185B1 (fr) * 2008-10-09 2011-02-25 Batscap Sa Electrode comprenant un oxyde complexe modifie comme matiere active.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101160684A (zh) * 2005-03-02 2008-04-09 U芝加哥阿谷尼有限公司 用于锂电池的充电过度保护的新型氧化还原穿梭化合物
CN101164187A (zh) * 2005-04-25 2008-04-16 费罗公司 具有混合盐的非水电解液
US20090286157A1 (en) * 2008-05-16 2009-11-19 Zonghai Chen Surface modification agents for lithium batteries
CN101707251A (zh) * 2008-11-28 2010-05-12 松下电器产业株式会社 含锂复合氧化物的制造方法及非水系二次电池
CN101789520A (zh) * 2009-01-23 2010-07-28 索尼公司 电解液和二次电池

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
High capacity double-layer surface modified Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode with improved rate capability;Q.Y.Wang etc.;《Journal of Materials Chemistry》;20090605;第19卷(第28期);第4965-4972页 *

Also Published As

Publication number Publication date
CN103221345A (zh) 2013-07-24
KR20130097778A (ko) 2013-09-03
TW201219981A (en) 2012-05-16
EP2619139A1 (de) 2013-07-31
JP2013541147A (ja) 2013-11-07
JP6305059B2 (ja) 2018-04-04
EP2619139B1 (de) 2015-11-18
WO2012038412A1 (de) 2012-03-29

Similar Documents

Publication Publication Date Title
CN110582876B (zh) 负极活性材料、包含所述负极活性材料的负极、和包含所述负极的二次电池
CN106470949B (zh) 制造用于锂离子电池组的阴极材料的方法
CN115336043B (zh) 负极活性材料、包含所述负极活性材料的负极和包含所述负极的二次电池
CN103354959A (zh) 电极材料及其制备方法
CN114206783A (zh) 颗粒材料、其制备方法和用途
CN103221345B (zh) 制备表面改性的电极材料的方法
CN111316479B (zh) 负极活性材料、包含其的负极、包含所述负极的二次电池以及所述负极活性材料的制备方法
JP6062865B2 (ja) 遷移金属複合酸化物の前駆体の製造方法
CN103109409A (zh) 制备电极材料的方法
US20130175482A1 (en) Materials, and the production and use thereof
US9449729B2 (en) Process for producing electrode materials
JP6203053B2 (ja) 遷移金属複合酸化物前駆体の製造方法
CN103118985B (zh) 制备经改性的混合过渡金属氧化物的方法
CN102906910B (zh) 化合物及其在制备电化学电池中的用途
CN102893433A (zh) 电极材料及其在制备电化学电池中的用途
JP2024524023A (ja) 負極活物質、負極活物質の製造方法、負極スラリー、負極、および二次電池
US9090482B2 (en) Process for preparing modified mixed transition metal oxides
EP3218952B1 (en) Electrode materials, their manufacture and use
CN112272876B (zh) 负极活性材料、包含负极活性材料的负极、包含负极的二次电池和制备负极活性材料的方法
US20230223528A1 (en) Electrode active materials and method for their manufacture
JP2024524025A (ja) 負極活物質、負極、および二次電池

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant