CN103201034A - 用于聚合物合成的催化剂和方法 - Google Patents

用于聚合物合成的催化剂和方法 Download PDF

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Publication number
CN103201034A
CN103201034A CN2011800544344A CN201180054434A CN103201034A CN 103201034 A CN103201034 A CN 103201034A CN 2011800544344 A CN2011800544344 A CN 2011800544344A CN 201180054434 A CN201180054434 A CN 201180054434A CN 103201034 A CN103201034 A CN 103201034A
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group
ring
independently selected
nitrogen
heteroatomic
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Chinese (zh)
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杰伊·J·法默
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Novomer Inc
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Novomer Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20General preparatory processes
    • C08G64/32General preparatory processes using carbon dioxide
    • C08G64/34General preparatory processes using carbon dioxide and cyclic ethers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06Cobalt compounds
    • C07F15/065Cobalt compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06Aluminium compounds
    • C07F5/069Aluminium compounds without C-aluminium linkages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213Complexes without C-metal linkages
    • B01J2531/0216Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN2011800544344A 2010-09-14 2011-09-14 用于聚合物合成的催化剂和方法 Pending CN103201034A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US38286010P 2010-09-14 2010-09-14
US61/382,860 2010-09-14
PCT/US2011/051639 WO2012037282A2 (en) 2010-09-14 2011-09-14 Catalysts and methods for polymer synthesis

Publications (1)

Publication Number Publication Date
CN103201034A true CN103201034A (zh) 2013-07-10

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Country Status (6)

Country Link
US (2) US9284406B2 (https=)
EP (1) EP2616513B1 (https=)
JP (2) JP2013539802A (https=)
KR (1) KR101805648B1 (https=)
CN (1) CN103201034A (https=)
WO (1) WO2012037282A2 (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106536047A (zh) * 2014-07-22 2017-03-22 埃科尼克科技有限公司 催化剂
CN108291019A (zh) * 2015-08-28 2018-07-17 伊克尼克技术有限公司 用于制备多元醇的方法
CN110603279A (zh) * 2017-03-01 2019-12-20 伊克尼克技术有限公司 制备聚醚碳酸酯的方法
TWI723067B (zh) * 2015-11-11 2021-04-01 德商贏創運營有限公司 可固化聚合物

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
KR102128706B1 (ko) 2008-08-22 2020-07-02 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
CN103333330A (zh) 2008-09-08 2013-10-02 诺沃梅尔公司 聚碳酸酯多元醇组合物和方法
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
KR101963568B1 (ko) 2010-09-22 2019-07-31 사우디 아람코 테크놀로지스 컴퍼니 치환된 살리실알데하이드 유도체의 합성
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
WO2013096602A1 (en) 2011-12-20 2013-06-27 Novomer, Inc. Methods for polymer synthesis
EP2838954B1 (en) 2012-04-16 2024-09-18 Saudi Aramco Technologies Company Adhesive compositions and methods
JP6527080B2 (ja) 2012-05-24 2019-06-05 サウジ アラムコ テクノロジーズ カンパニー ポリカーボネートポリオール組成物および方法
EP2888271B1 (en) 2012-08-24 2019-11-06 Saudi Aramco Technologies Company Metal complexes
GB201308978D0 (en) 2013-05-17 2013-07-03 Imp Innovations Ltd Method for producing polymers and block copolymers
GB201402109D0 (en) * 2014-02-07 2014-03-26 Imp Innovations Ltd Catalyst
GB201514506D0 (en) 2015-08-14 2015-09-30 Imp Innovations Ltd Multi-block copolymers
WO2019126221A1 (en) 2017-12-22 2019-06-27 Saudi Aramco Technologies Company Catalysts for polycarbonate production
JP2021522355A (ja) 2018-04-18 2021-08-30 サウジ アラムコ テクノロジーズ カンパニー ポリ(アルキレンカーボネート)ポリマーの末端基異性化
WO2020028606A1 (en) 2018-08-02 2020-02-06 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
MA53727A (fr) 2018-09-24 2021-12-29 Saudi Aramco Tech Co Copolymères séquencés de polycarbonate et procédés associés
GB201906214D0 (en) 2019-05-02 2019-06-19 Econic Tech Ltd A polyol block copolymer, compositions and processes therefor
GB201906210D0 (en) 2019-05-02 2019-06-19 Econic Tech Limited A polyol block copolymer, compositions and processes therefor
GB202003003D0 (en) 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
GB202003002D0 (en) 2020-03-02 2020-04-15 Crane Ltd Method of preparation of a polyol block copolymer
TWI906317B (zh) 2020-06-24 2025-12-01 沙烏地阿拉伯商沙烏地阿美科技公司 多元醇組合物及方法
GB202017531D0 (en) 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer
WO2022153149A1 (en) 2021-01-12 2022-07-21 Saudi Aramco Technologies Company Continuous manufacturing of polyol
US12195576B2 (en) 2021-06-23 2025-01-14 Saudi Aramco Technologies Company Polyol compositions and methods
EP4384316A1 (en) 2021-08-11 2024-06-19 Econic Technologies Ltd Method for preparing surfactants by copolymerisation of epoxides and co2 using a mixture of a macrocyclic bimetal catalyst and a double metal cyanide catalyst
GB202115335D0 (en) 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent
GB2626546A (en) 2023-01-25 2024-07-31 Econic Tech Ltd Surface-active agent
GB2626989A (en) 2023-02-10 2024-08-14 Econic Tech Ltd Surface-active agent
GB2629367A (en) 2023-04-25 2024-10-30 Econic Tech Ltd Surface-active agent
EP4702078A1 (en) 2023-04-25 2026-03-04 Unilever IP Holdings B.V. Compositions

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223631A (en) * 1992-06-30 1993-06-29 National Science Council Bimetallic complexes as catalysts in an oxidation process
US20050192454A1 (en) * 2000-08-02 2005-09-01 Nesmeyanov Institute Of Organoelement Compounds And King's College London Process for the cyanation aldehydes
US20060089252A1 (en) * 2004-10-08 2006-04-27 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
US20060135743A1 (en) * 2004-12-16 2006-06-22 Park Young W Bimetallic zinc complex and process of producing polycarbonate using the same as polymerization catalyst
WO2009130470A1 (en) * 2008-04-25 2009-10-29 Imperial Innovations Limited Bimetallic catalytic complexes for the copolymerisation of carbon dioxide and an epoxide
WO2010022388A2 (en) * 2008-08-22 2010-02-25 Novomer, Inc. Catalysts and methods for polymer synthesis
CN101679343A (zh) * 2007-04-25 2010-03-24 泰恩河畔纽卡斯尔大学 在存在二聚铝(salen)催化剂的情况下,环状碳酸酯的合成

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4783445A (en) * 1987-12-14 1988-11-08 Arco Chemical Company Soluble epoxide/carbon dioxide copolymerization catalysts
US5637739A (en) 1990-03-21 1997-06-10 Research Corporation Technologies, Inc. Chiral catalysts and catalytic epoxidation catalyzed thereby
US5665890A (en) 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
WO1998004538A1 (en) 1996-07-26 1998-02-05 Princeton University Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes
TWI246520B (en) 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
US6130340A (en) 1998-01-13 2000-10-10 President And Fellows Of Harvard College Asymmetric cycloaddition reactions
US6521561B1 (en) 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
KR100342659B1 (en) 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
US6884750B2 (en) 2001-06-27 2005-04-26 Rs Tech Corp. Chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst
US6639087B2 (en) 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
US6870004B1 (en) 2001-08-24 2005-03-22 Northwestern University Metal-ligand complexes and related methods of chemical CO2 fixation
DE10235316A1 (de) 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
JP4238354B2 (ja) 2003-07-29 2009-03-18 独立行政法人産業技術総合研究所 鉄複核錯体中心をもつレドックス応答性有機分子からなる素子
WO2006099162A2 (en) 2005-03-14 2006-09-21 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof
US7399822B2 (en) 2005-06-21 2008-07-15 Cornell Research Foundation, Inc. Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide)
US20090062110A1 (en) 2006-02-08 2009-03-05 Sumitomo Chemical Company Limited Metal complex and use thereof
US8232267B2 (en) 2006-10-06 2012-07-31 The Trustees Of Princeton University Porphyrin catalysts and methods of use thereof
EP2573126B1 (en) 2007-05-04 2014-09-24 SK Innovation Co. Ltd. A process for producing polycarbonates and a coordination complex used therefor
WO2008150033A1 (ja) 2007-06-08 2008-12-11 The University Of Tokyo エポキシドと二酸化炭素との立体選択的交互共重合
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
EP2096132A1 (en) 2008-02-26 2009-09-02 Total Petrochemicals Research Feluy Monomers issued from renewable resources and process for polymerising them
BRPI0908982B8 (pt) 2008-03-07 2018-08-07 Univ Newcastle síntese de carbonatos cíclicos
CA2727959A1 (en) 2008-07-30 2010-02-04 Sk Energy, Co., Ltd. Novel coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst
CN103333330A (zh) 2008-09-08 2013-10-02 诺沃梅尔公司 聚碳酸酯多元醇组合物和方法
CA2639870A1 (en) 2008-09-29 2010-03-29 Nova Chemicals Corporation Trimerization
KR101503745B1 (ko) 2010-02-25 2015-03-19 에스케이이노베이션 주식회사 나이트레이트 음이온의 이산화탄소/에폭사이드 공중합 촉매 시스템
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
KR20190059988A (ko) 2011-08-08 2019-05-31 사우디 아람코 테크놀로지스 컴퍼니 폴리머 합성용 촉매 및 방법
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5223631A (en) * 1992-06-30 1993-06-29 National Science Council Bimetallic complexes as catalysts in an oxidation process
US20050192454A1 (en) * 2000-08-02 2005-09-01 Nesmeyanov Institute Of Organoelement Compounds And King's College London Process for the cyanation aldehydes
US20060089252A1 (en) * 2004-10-08 2006-04-27 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
US20060135743A1 (en) * 2004-12-16 2006-06-22 Park Young W Bimetallic zinc complex and process of producing polycarbonate using the same as polymerization catalyst
CN101679343A (zh) * 2007-04-25 2010-03-24 泰恩河畔纽卡斯尔大学 在存在二聚铝(salen)催化剂的情况下,环状碳酸酯的合成
WO2009130470A1 (en) * 2008-04-25 2009-10-29 Imperial Innovations Limited Bimetallic catalytic complexes for the copolymerisation of carbon dioxide and an epoxide
WO2010022388A2 (en) * 2008-08-22 2010-02-25 Novomer, Inc. Catalysts and methods for polymer synthesis
CN102164987A (zh) * 2008-08-22 2011-08-24 诺沃梅尔公司 用于合成聚合物的催化剂和方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106536047A (zh) * 2014-07-22 2017-03-22 埃科尼克科技有限公司 催化剂
CN106536047B (zh) * 2014-07-22 2020-10-30 埃科尼克科技有限公司 催化剂
CN108291019A (zh) * 2015-08-28 2018-07-17 伊克尼克技术有限公司 用于制备多元醇的方法
TWI723067B (zh) * 2015-11-11 2021-04-01 德商贏創運營有限公司 可固化聚合物
CN110603279A (zh) * 2017-03-01 2019-12-20 伊克尼克技术有限公司 制备聚醚碳酸酯的方法

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US9284406B2 (en) 2016-03-15
EP2616513A4 (en) 2017-04-05
WO2012037282A3 (en) 2012-05-10
KR20130103532A (ko) 2013-09-23
US20160137777A1 (en) 2016-05-19
US9856349B2 (en) 2018-01-02
EP2616513B1 (en) 2019-11-06
EP2616513A2 (en) 2013-07-24
KR101805648B1 (ko) 2017-12-14
US20130172524A1 (en) 2013-07-04
JP2013539802A (ja) 2013-10-28
WO2012037282A2 (en) 2012-03-22
JP2016216742A (ja) 2016-12-22

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