KR101805648B1 - 중합체 합성용의 촉매 및 방법 - Google Patents
중합체 합성용의 촉매 및 방법 Download PDFInfo
- Publication number
- KR101805648B1 KR101805648B1 KR1020137009218A KR20137009218A KR101805648B1 KR 101805648 B1 KR101805648 B1 KR 101805648B1 KR 1020137009218 A KR1020137009218 A KR 1020137009218A KR 20137009218 A KR20137009218 A KR 20137009218A KR 101805648 B1 KR101805648 B1 KR 101805648B1
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- South Korea
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- membered
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- nitrogen
- Prior art date
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- 0 CC(N(C)C(C)(C)*)N(*)C(N(*)C(C)(C)CC(C)(C)*)=O Chemical compound CC(N(C)C(C)(C)*)N(*)C(N(*)C(C)(C)CC(C)(C)*)=O 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38286010P | 2010-09-14 | 2010-09-14 | |
| US61/382,860 | 2010-09-14 | ||
| PCT/US2011/051639 WO2012037282A2 (en) | 2010-09-14 | 2011-09-14 | Catalysts and methods for polymer synthesis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20130103532A KR20130103532A (ko) | 2013-09-23 |
| KR101805648B1 true KR101805648B1 (ko) | 2017-12-14 |
Family
ID=45832225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137009218A Active KR101805648B1 (ko) | 2010-09-14 | 2011-09-14 | 중합체 합성용의 촉매 및 방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US9284406B2 (https=) |
| EP (1) | EP2616513B1 (https=) |
| JP (2) | JP2013539802A (https=) |
| KR (1) | KR101805648B1 (https=) |
| CN (1) | CN103201034A (https=) |
| WO (1) | WO2012037282A2 (https=) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0807607D0 (en) | 2008-04-25 | 2008-06-04 | Imp Innovations Ltd | Catalyst |
| KR102128706B1 (ko) | 2008-08-22 | 2020-07-02 | 사우디 아람코 테크놀로지스 컴퍼니 | 촉매 및 중합체 합성방법 |
| CN103333330A (zh) | 2008-09-08 | 2013-10-02 | 诺沃梅尔公司 | 聚碳酸酯多元醇组合物和方法 |
| KR101805648B1 (ko) | 2010-09-14 | 2017-12-14 | 사우디 아람코 테크놀로지스 컴퍼니 | 중합체 합성용의 촉매 및 방법 |
| KR101963568B1 (ko) | 2010-09-22 | 2019-07-31 | 사우디 아람코 테크놀로지스 컴퍼니 | 치환된 살리실알데하이드 유도체의 합성 |
| EP2707353B1 (en) | 2011-05-13 | 2021-03-31 | Novomer, Inc. | Carbonylation catalysts and method |
| GB201115565D0 (en) | 2011-09-08 | 2011-10-26 | Imp Innovations Ltd | Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent |
| WO2013096602A1 (en) | 2011-12-20 | 2013-06-27 | Novomer, Inc. | Methods for polymer synthesis |
| EP2838954B1 (en) | 2012-04-16 | 2024-09-18 | Saudi Aramco Technologies Company | Adhesive compositions and methods |
| JP6527080B2 (ja) | 2012-05-24 | 2019-06-05 | サウジ アラムコ テクノロジーズ カンパニー | ポリカーボネートポリオール組成物および方法 |
| EP2888271B1 (en) | 2012-08-24 | 2019-11-06 | Saudi Aramco Technologies Company | Metal complexes |
| GB201308978D0 (en) | 2013-05-17 | 2013-07-03 | Imp Innovations Ltd | Method for producing polymers and block copolymers |
| GB201402109D0 (en) * | 2014-02-07 | 2014-03-26 | Imp Innovations Ltd | Catalyst |
| AU2015293702B2 (en) * | 2014-07-22 | 2018-11-01 | Econic Technologies Ltd | Catalysts |
| GB201514506D0 (en) | 2015-08-14 | 2015-09-30 | Imp Innovations Ltd | Multi-block copolymers |
| GB201515350D0 (en) * | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
| ES2676430T3 (es) * | 2015-11-11 | 2018-07-19 | Evonik Degussa Gmbh | Polímeros curables |
| GB201703324D0 (en) * | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polyether carbonates |
| WO2019126221A1 (en) | 2017-12-22 | 2019-06-27 | Saudi Aramco Technologies Company | Catalysts for polycarbonate production |
| JP2021522355A (ja) | 2018-04-18 | 2021-08-30 | サウジ アラムコ テクノロジーズ カンパニー | ポリ(アルキレンカーボネート)ポリマーの末端基異性化 |
| WO2020028606A1 (en) | 2018-08-02 | 2020-02-06 | Saudi Aramco Technologies Company | Sustainable polymer compositions and methods |
| MA53727A (fr) | 2018-09-24 | 2021-12-29 | Saudi Aramco Tech Co | Copolymères séquencés de polycarbonate et procédés associés |
| GB201906214D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Ltd | A polyol block copolymer, compositions and processes therefor |
| GB201906210D0 (en) | 2019-05-02 | 2019-06-19 | Econic Tech Limited | A polyol block copolymer, compositions and processes therefor |
| GB202003003D0 (en) | 2020-03-02 | 2020-04-15 | Econic Tech Ltd | A polyol block copolymer |
| GB202003002D0 (en) | 2020-03-02 | 2020-04-15 | Crane Ltd | Method of preparation of a polyol block copolymer |
| TWI906317B (zh) | 2020-06-24 | 2025-12-01 | 沙烏地阿拉伯商沙烏地阿美科技公司 | 多元醇組合物及方法 |
| GB202017531D0 (en) | 2020-11-05 | 2020-12-23 | Econic Tech Limited | (poly)ol block copolymer |
| WO2022153149A1 (en) | 2021-01-12 | 2022-07-21 | Saudi Aramco Technologies Company | Continuous manufacturing of polyol |
| US12195576B2 (en) | 2021-06-23 | 2025-01-14 | Saudi Aramco Technologies Company | Polyol compositions and methods |
| EP4384316A1 (en) | 2021-08-11 | 2024-06-19 | Econic Technologies Ltd | Method for preparing surfactants by copolymerisation of epoxides and co2 using a mixture of a macrocyclic bimetal catalyst and a double metal cyanide catalyst |
| GB202115335D0 (en) | 2021-10-25 | 2021-12-08 | Econic Tech Ltd | Surface-active agent |
| GB2626546A (en) | 2023-01-25 | 2024-07-31 | Econic Tech Ltd | Surface-active agent |
| GB2626989A (en) | 2023-02-10 | 2024-08-14 | Econic Tech Ltd | Surface-active agent |
| GB2629367A (en) | 2023-04-25 | 2024-10-30 | Econic Tech Ltd | Surface-active agent |
| EP4702078A1 (en) | 2023-04-25 | 2026-03-04 | Unilever IP Holdings B.V. | Compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009130470A1 (en) * | 2008-04-25 | 2009-10-29 | Imperial Innovations Limited | Bimetallic catalytic complexes for the copolymerisation of carbon dioxide and an epoxide |
| WO2010022388A2 (en) * | 2008-08-22 | 2010-02-25 | Novomer, Inc. | Catalysts and methods for polymer synthesis |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US4783445A (en) * | 1987-12-14 | 1988-11-08 | Arco Chemical Company | Soluble epoxide/carbon dioxide copolymerization catalysts |
| US5637739A (en) | 1990-03-21 | 1997-06-10 | Research Corporation Technologies, Inc. | Chiral catalysts and catalytic epoxidation catalyzed thereby |
| US5223631A (en) * | 1992-06-30 | 1993-06-29 | National Science Council | Bimetallic complexes as catalysts in an oxidation process |
| US5665890A (en) | 1995-03-14 | 1997-09-09 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
| WO1998004538A1 (en) | 1996-07-26 | 1998-02-05 | Princeton University | Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes |
| TWI246520B (en) | 1997-04-25 | 2006-01-01 | Mitsui Chemicals Inc | Processes for olefin polymerization |
| US6130340A (en) | 1998-01-13 | 2000-10-10 | President And Fellows Of Harvard College | Asymmetric cycloaddition reactions |
| US6521561B1 (en) | 1998-05-01 | 2003-02-18 | President And Fellows Of Harvard College | Main-group metal based asymmetric catalysts and applications thereof |
| US6897332B2 (en) * | 2000-08-02 | 2005-05-24 | Nesmeyanov Institute Of Organoelement Compounds | Process for the cyanation of aldehydes |
| KR100342659B1 (en) | 2000-12-15 | 2002-07-04 | Rstech Co Ltd | Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same |
| US6884750B2 (en) | 2001-06-27 | 2005-04-26 | Rs Tech Corp. | Chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst |
| US6639087B2 (en) | 2001-08-22 | 2003-10-28 | Rhodia Pharma Solutions Inc. | Kinetic resolution method |
| US6870004B1 (en) | 2001-08-24 | 2005-03-22 | Northwestern University | Metal-ligand complexes and related methods of chemical CO2 fixation |
| DE10235316A1 (de) | 2002-08-01 | 2004-02-12 | Basf Ag | Katalysator und Verfahren zur Carbonylierung von Oxiranen |
| JP4238354B2 (ja) | 2003-07-29 | 2009-03-18 | 独立行政法人産業技術総合研究所 | 鉄複核錯体中心をもつレドックス応答性有機分子からなる素子 |
| US7304172B2 (en) * | 2004-10-08 | 2007-12-04 | Cornell Research Foundation, Inc. | Polycarbonates made using highly selective catalysts |
| KR100724550B1 (ko) * | 2004-12-16 | 2007-06-04 | 주식회사 엘지화학 | 이중 금속 아연 착화합물과 이를 촉매로 사용한폴리카보네이트의 제조 방법 |
| WO2006099162A2 (en) | 2005-03-14 | 2006-09-21 | Georgia Tech Research Corporation | Polymeric salen compounds and methods thereof |
| US7399822B2 (en) | 2005-06-21 | 2008-07-15 | Cornell Research Foundation, Inc. | Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide) |
| US20090062110A1 (en) | 2006-02-08 | 2009-03-05 | Sumitomo Chemical Company Limited | Metal complex and use thereof |
| US8232267B2 (en) | 2006-10-06 | 2012-07-31 | The Trustees Of Princeton University | Porphyrin catalysts and methods of use thereof |
| GB0708016D0 (en) | 2007-04-25 | 2007-06-06 | Univ Newcastle | Synthesis of cyclic carbonates |
| EP2573126B1 (en) | 2007-05-04 | 2014-09-24 | SK Innovation Co. Ltd. | A process for producing polycarbonates and a coordination complex used therefor |
| WO2008150033A1 (ja) | 2007-06-08 | 2008-12-11 | The University Of Tokyo | エポキシドと二酸化炭素との立体選択的交互共重合 |
| US7902415B2 (en) | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
| EP2096132A1 (en) | 2008-02-26 | 2009-09-02 | Total Petrochemicals Research Feluy | Monomers issued from renewable resources and process for polymerising them |
| BRPI0908982B8 (pt) | 2008-03-07 | 2018-08-07 | Univ Newcastle | síntese de carbonatos cíclicos |
| CA2727959A1 (en) | 2008-07-30 | 2010-02-04 | Sk Energy, Co., Ltd. | Novel coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst |
| CN103333330A (zh) | 2008-09-08 | 2013-10-02 | 诺沃梅尔公司 | 聚碳酸酯多元醇组合物和方法 |
| CA2639870A1 (en) | 2008-09-29 | 2010-03-29 | Nova Chemicals Corporation | Trimerization |
| KR101503745B1 (ko) | 2010-02-25 | 2015-03-19 | 에스케이이노베이션 주식회사 | 나이트레이트 음이온의 이산화탄소/에폭사이드 공중합 촉매 시스템 |
| KR101805648B1 (ko) | 2010-09-14 | 2017-12-14 | 사우디 아람코 테크놀로지스 컴퍼니 | 중합체 합성용의 촉매 및 방법 |
| KR20190059988A (ko) | 2011-08-08 | 2019-05-31 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리머 합성용 촉매 및 방법 |
| GB201115565D0 (en) | 2011-09-08 | 2011-10-26 | Imp Innovations Ltd | Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent |
-
2011
- 2011-09-14 KR KR1020137009218A patent/KR101805648B1/ko active Active
- 2011-09-14 EP EP11825894.6A patent/EP2616513B1/en active Active
- 2011-09-14 JP JP2013529307A patent/JP2013539802A/ja active Pending
- 2011-09-14 CN CN2011800544344A patent/CN103201034A/zh active Pending
- 2011-09-14 US US13/822,795 patent/US9284406B2/en active Active
- 2011-09-14 WO PCT/US2011/051639 patent/WO2012037282A2/en not_active Ceased
-
2016
- 2016-01-25 US US15/005,230 patent/US9856349B2/en active Active
- 2016-09-02 JP JP2016171972A patent/JP2016216742A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009130470A1 (en) * | 2008-04-25 | 2009-10-29 | Imperial Innovations Limited | Bimetallic catalytic complexes for the copolymerisation of carbon dioxide and an epoxide |
| WO2010022388A2 (en) * | 2008-08-22 | 2010-02-25 | Novomer, Inc. | Catalysts and methods for polymer synthesis |
Also Published As
| Publication number | Publication date |
|---|---|
| US9284406B2 (en) | 2016-03-15 |
| EP2616513A4 (en) | 2017-04-05 |
| WO2012037282A3 (en) | 2012-05-10 |
| KR20130103532A (ko) | 2013-09-23 |
| US20160137777A1 (en) | 2016-05-19 |
| US9856349B2 (en) | 2018-01-02 |
| EP2616513B1 (en) | 2019-11-06 |
| EP2616513A2 (en) | 2013-07-24 |
| US20130172524A1 (en) | 2013-07-04 |
| CN103201034A (zh) | 2013-07-10 |
| JP2013539802A (ja) | 2013-10-28 |
| WO2012037282A2 (en) | 2012-03-22 |
| JP2016216742A (ja) | 2016-12-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20130411 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
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