CN103180398A - 无光泽有纹理粉末单涂层涂料组合物 - Google Patents
无光泽有纹理粉末单涂层涂料组合物 Download PDFInfo
- Publication number
- CN103180398A CN103180398A CN201180051464XA CN201180051464A CN103180398A CN 103180398 A CN103180398 A CN 103180398A CN 201180051464X A CN201180051464X A CN 201180051464XA CN 201180051464 A CN201180051464 A CN 201180051464A CN 103180398 A CN103180398 A CN 103180398A
- Authority
- CN
- China
- Prior art keywords
- powder paint
- paint compositions
- acrylic resin
- combination
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/032—Powdery paints characterised by a special effect of the produced film, e.g. wrinkle, pearlescence, matt finish
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24405—Polymer or resin [e.g., natural or synthetic rubber, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
本发明包括可用于涂覆基质如汽车车身的无光泽有纹理粉末单涂层涂料组合物,和涂覆这类基质的方法。粉末涂料组合物可包含丙烯酸树脂、UV光稳定剂、消光剂和花纹造型添加剂,其中固化粉末涂料组合物透射在290nm下小于约0.1%的UV光和在400nm下小于约0.5%的UV光。
Description
发明背景
发明领域
本发明包括可用于涂覆基质如汽车车身的无光泽有纹理丙烯酸粉末单涂层涂料组合物,和涂覆该基质的方法。
发明概述
本发明包括可用于涂覆基质如汽车车身的无光泽有纹理丙烯酸粉末单涂层涂料组合物,和用无光泽有纹理丙烯酸粉末单涂层涂料组合物涂覆这类基质的方法。
汽车车身涂料与外表装饰涂料之间的区别之一是耐久性。对于许多OEM车身涂层规格,预期涂层在佛罗里达州曝露5+年会保持外观和功能膜完整性。对于高质量外表装饰涂料,不需要关于曝露持续时间和曝露以后功能膜完整性的严格要求。例如,一些OEM车身涂层要求需要在佛罗里达州曝露1年以后至少约90%,在佛罗里达州曝露3年以后至少约80%,和在佛罗里达州曝露5年以后至少约65%的光泽保持力。对于外表装饰涂料,相关耐久性要求为在佛罗里达州曝露1年以后至少约80%,在佛罗里达州曝露3年以后至少约50%的光泽保持力,没有关于在佛罗里达州曝露5年以后的要求。本发明涂料组合物满足这些要求中的一个或多个。
在本发明一个实施方案中,粉末涂料组合物包含丙烯酸树脂、UV光稳定剂、消光剂和花纹造型添加剂(texturing additive),其中固化粉末涂料组合物透过在290nm下小于约0.1%的UV光和在400nm下小于约0.5%的UV光。本发明还包括涂覆基质的方法,其包括将粉末涂料组合物施加于基质上并将粉末涂料组合物固化。
发明详述
本发明包括可用于涂覆基质的无光泽有纹理丙烯酸粉末单涂层涂料组合物,和用无光泽有纹理丙烯酸粉末单涂层涂料组合物涂覆这类基质的方法。涂覆且固化的粉末涂料组合物为无光泽的,具有细纹理并满足关于UV透射、耐化学性和耐久性的汽车工业标准。在一些实施方案中,将电涂层施加于基质上,并将本发明粉末涂料组合物施加于电涂层上。因此,本发明还包括涂有双涂层涂料组合物的基质,其中双涂层涂料组合物具有涂覆于基质与本发明粉末涂料组合物之间的电涂层。
本发明粉末涂料组合物可包含丙烯酸树脂、UV光稳定剂、消光剂和花纹造型添加剂。合适的丙烯酸树脂包括而不限于甲基丙烯酸缩水甘油酯丙烯酸树脂、羧基丙烯酸树脂、羟基丙烯酸树脂及其组合。
在一些实施方案中,丙烯酸树脂以粉末涂料组合物的约25至约65重量%的量存在。在本发明的某些实施方案中,丙烯酸树脂可包括甲基丙烯酸缩水甘油酯丙烯酸树脂、羧基丙烯酸树脂、羟基丙烯酸/四甲氧基甲基甘脲树脂或其组合。对于非限定性实例,丙烯酸树脂可包含涂料组合物的约30至约45重量%的量的甲基丙烯酸缩水甘油酯丙烯酸树脂、涂料组合物的约40至约70重量%的羧基丙烯酸树脂、涂料组合物的约50至约70重量%的量的羧基丙烯酸树脂/甲基丙烯酸缩水甘油酯丙烯酸树脂体系(其中羧基丙烯酸树脂以涂料组合物的约40至约70重量%的量存在,且甲基丙烯酸缩水甘油酯丙烯酸树脂以涂料组合物的约5至约15重量%的量存在)、涂料组合物的约30至约70重量%的量的羟基丙烯酸树脂或羟基丙烯酸树脂组合、涂料组合物的约45至约75重量%的量的羟基丙烯酸/四甲氧基甲基甘脲树脂,或其组合。在一些实施方案中,丙烯酸树脂为含有极性改性以增强颜料润湿和附着力的耐气候性树脂。
在一些实施方案中,粉末涂料组合物包含一种或多种充当固化剂和/或共反应树脂的化合物。固化剂和/或共反应树脂可包括非限定性实例脂族聚酐、二元酸如但不限于十二烷酸或癸二酸,羟烷基酰胺、异氰尿酸三缩水甘油酯、低环氧当量(EEW)甲基丙烯酸缩水甘油酯丙烯酸树脂如EEW为约250至约400的树脂、聚酯树脂、氢化双酚A环氧树脂、四甲氧基甲基甘脲、多异氰酸酯固化剂或其组合。在本发明的一些实施方案中,固化剂和/或共反应树脂以涂料组合物的约2至约30重量%的量存在。
用于本发明中的合适UV光稳定剂包括而不限于羟苯基苯并三唑、受阻胺光稳定剂、N,N’-二苯基乙二酰胺、羟基二苯甲酮、羟苯基-s-三嗪或其组合。在本发明的一些实施方案中,UV光稳定剂可以以粉末涂料组合物的约0.1至约5重量%,或涂料组合物的约1至约3重量%的量存在。UV光稳定剂可用于贡献于最佳耐候性和UV透射要求。
在本发明的一些实施方案中,具有UV光稳定剂的粉末涂料组合物满足汽车车身涂料的UV透射目标。对于非限定性实施例,本发明固化涂料组合物可透射在290nm下小于约0.1%的UV光和在400nm下小于约0.5%的UV光。
在一些实施方案中,本发明粉末涂料组合物可包含消光剂,其可提供给固化粉末涂料组合物无光泽外观,例如当固化涂料组合物显示出小于约10的60°光泽。消光剂可包括而不限于硫酸钡、硅酸镁、二氧化硅、铝硅酸盐,例如而不限于无水铝硅酸钾钠、碱性铝硅酸盐陶瓷微球、铝硅酸盐玻璃微球或薄片、与有机阴离子的盐组合的聚烯烃蜡、聚合蜡添加剂或其组合。消光剂可贡献于花纹造型添加剂的良好分散和加工,和/或贡献于限制涂料组合物的流动。在本发明的一些实施方案中,消光剂以涂料组合物的约0.1至约40%的量存在。
在一些实施方案中,粉末涂料组合物包含花纹造型添加剂以提供给固化涂层纹理,例如与光滑或橘皮状外观相反,当固化涂料组合物显示出粗糙、波纹或砂质外观时。花纹造型添加剂可包括非限定性实施例聚四氟乙烯粉末、PTFE/聚乙烯蜡混合物、PTFE/滑石混合物或其组合。聚四氟乙烯粉末可以以涂料组合物的约0.05至约0.5重量%,或涂料组合物的约0.1至约0.2重量%的量存在。在一些实施方案中,聚四氟乙烯粉末为具有平均粒度约5至约600μm,或者平均粒度约5至约25μm的粒度的粒状粉末。
可将本发明粉末涂料组合物施加于电涂层上以保护电涂层以防UV劣化。粉末涂料组合物可具有具有丘和谷的不均匀厚度,且在一些实施方案中,涂覆的粉末涂料组合物可具有约35至约200μm或约50至约100μm的测量膜厚度(当在丘的顶部测量时)。在本发明的一些涂料组合物中,谷:丘厚度比为约1:3或约1:4至约1:2。在本发明范围内的测量膜厚度帮助防止UV光透过涂层的谷并达到下面电涂层。因此,粉末涂料组合物的厚度贡献于下面电涂层的稳定性。另外,可存在于粉末涂料组合物中的UV光稳定剂还贡献于下面电涂层的稳定性,但UV光稳定剂对粉末涂料组合物本身具有很少或不具有益处。
本发明粉末涂料组合物还包含添加剂,例如而不限于颜料、脱气剂、抗氧化剂、填料、助流剂、催化剂或其组合。
用于本发明粉末涂料组合物中的颜料包括非限定性实例二氧化钛、铁氧化物(黄色、褐色、红色、黑色)、炭黑和有机颜料。这些颜料可以以本领域技术人员已知的常规量加入。
可将脱气剂加入组合物中以容许存在的任何挥发性材料在烘焙期间从膜中逸出。苯偶姻为脱气剂的实例,且在一些实施方案中使用时可以以粉末涂料组合物的约0.05至约0.8重量%的量存在。
合适的抗氧化剂包括而不限于苯酚、亚磷酸盐、亚膦酸盐和内酯类型抗氧化剂,例如十八烷基3-(3,5-二-叔丁基-4-羟苯基)-丙酸酯和季戊四醇四(3-(3,5-二-叔丁基-4-羟苯基)-丙酸酯,及其组合。在一些实施方案中,抗氧化剂以粉末涂料组合物的约1至约3重量%的量存在。
本发明粉末涂料组合物可包含一种或多种催化剂以加速固化或者催化该体系以增强涂料组合物的性能。合适的催化剂包括而不限于加速酚醛树脂、烷基铵盐如四丁基溴化铵、四丁基氯化铵、四丁基碘化铵和苄基三乙基氯化铵、季铵和盐、膦、咪唑如2-甲基咪唑和2-十七烷基咪唑、金属盐、2,4-二氨基-6(2-甲基咪唑基-(1))-乙基-s-三嗪、锡盐如二月桂酸二丁锡、乙基三苯基乙酸、三苯基膦或其组合。在一些实施方案中,催化剂以涂料组合物的约0.05至约1.5重量%的量存在。
本发明粉末涂料组合物适于施加于基质,例如而不限于汽车车身。然而,也可将涂料组合物施加于碳、木、玻璃、聚合物、塑料和其它基质上。
上述粉末涂料组合物的施加可通过任何已知的技术实现,包括而不限于静电喷涂或流化床。
实施例
参考以下非限定性实施例进一步描述本发明。应当理解本领域技术人员可不偏离本发明的精神和范围地作出这些实施例的变化和改进。
涂料组合物1-6如下制备:确保将所列成分(1)通过使用叶片式搅拌机在干燥的非熔融条件下,即以固态且组分实质不熔融地物理混合,从而结合成分通常均匀地分布于整个所得混合物中。(2)在如下条件下熔融混合,其中混合物通常处于液体条件,但混合物的一些组分可作为悬浮或分散固体存在或者可溶解而不是熔融。熔融混合通过在升高的温度下使用双螺杆压出机实现。(3)通过通过一对冷却辊而冷却。(4)排到磨机中,在那里将它研磨成小颗粒。(5)筛分以进一步粒度分级。
表1:以重量份表示的组成
1平均粒度为15μm的PTFE粉末。
2平均粒度为2.5-3μm的硫酸钡。
3平均初级粒度为13nm的氧化铝。
4中值粒度为2-3μm的硅酸镁。
5中值粒度为10μm的三水合铝(aluminum trihydrate)。
6中值粒度为10μm的二氧化硅。
将组合物1-5涂覆、固化并评价各种性能。评价结果显示于下表中。
表2:评价结果
上表和图1所示图证明组合物1-4和6具有可接受的颜色稳定性和耐久性。
Claims (13)
1.粉末涂料组合物,其包含:
a)丙烯酸树脂;
b)UV光稳定剂;
c)消光剂;和
d)花纹造型添加剂,
其中固化粉末涂料组合物透射在290nm下小于约0.1%的UV光和在400nm下小于约0.5%的UV光,且
其中丙烯酸树脂包括甲基丙烯酸缩水甘油酯丙烯酸树脂、羧基丙烯酸树脂、羟基丙烯酸/四甲氧基甲基甘脲树脂或其组合。
2.根据权利要求1的粉末涂料组合物,其中羧基丙烯酸树脂包括羧基丙烯酸树脂/β羟烷基酰胺树脂体系。
3.根据权利要求1的粉末涂料组合物,其进一步包含固化剂和/或共反应树脂,其中固化剂和/或共反应树脂包括脂族聚酐、二元酸、羟烷基酰胺、异氰脲酸三缩水甘油酯、甲基丙烯酸缩水甘油酯丙烯酸树脂、聚酯树脂、氢化双酚A环氧树脂、四甲氧基甲基甘脲、多异氰酸酯固化剂或其组合。
4.根据权利要求1的粉末涂料组合物,其中UV光稳定剂包括羟苯基苯并三唑、受阻胺光稳定剂、N,N’-二苯基乙二酰胺、羟基二苯甲酮、羟苯基-s-三嗪或其组合。
5.根据权利要求1的粉末涂料组合物,其中消光剂包括硫酸钡、硅酸镁、二氧化硅、铝硅酸盐、碱性铝硅酸盐陶瓷微球、铝硅酸盐玻璃微球或薄片、与有机阴离子的盐组合的聚烯烃蜡,聚合蜡添加剂或其组合。
6.根据权利要求1的粉末涂料组合物,其中花纹造型添加剂包括聚四氟乙烯粉末、PTFE/聚乙烯蜡混合物、PTFE/滑石混合物或其组合。
7.根据权利要求1的粉末组合物,其进一步包含颜料、脱气剂、抗氧化剂、填料、助流剂、催化剂或其组合。
8.涂覆基质的方法,其包括将根据权利要求1的粉末涂料组合物施加于基质上并将粉末涂料组合物固化。
9.根据权利要求8的方法,其中基质为汽车车身。
10.根据权利要求8的方法,其中将电涂层涂覆于基质与粉末涂料组合物之间。
11.涂有根据权利要求1的粉末涂料组合物的汽车车身。
12.根据权利要求11的汽车车身,其中将电涂层涂覆于汽车车身与粉末涂料组合物之间。
13.涂有双涂层涂料组合物的基质,其中双涂层涂料组合物包含涂覆于基质与根据权利要求1的粉末涂料组合物之间的电涂层。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US40931210P | 2010-11-02 | 2010-11-02 | |
US61/409,312 | 2010-11-02 | ||
EP10195681 | 2010-12-17 | ||
EP10195681.1 | 2010-12-17 | ||
PCT/EP2011/069195 WO2012059490A1 (en) | 2010-11-02 | 2011-11-02 | Matte textured powder monocoat coating compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103180398A true CN103180398A (zh) | 2013-06-26 |
CN103180398B CN103180398B (zh) | 2017-09-01 |
Family
ID=44148409
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201180051464.XA Expired - Fee Related CN103180398B (zh) | 2010-11-02 | 2011-11-02 | 无光泽有纹理粉末单涂层涂料组合物 |
Country Status (5)
Country | Link |
---|---|
US (2) | US10072156B2 (zh) |
EP (1) | EP2635644B1 (zh) |
CN (1) | CN103180398B (zh) |
PL (1) | PL2635644T3 (zh) |
WO (1) | WO2012059490A1 (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105505088A (zh) * | 2016-01-08 | 2016-04-20 | 金华市佳振科技发展有限公司 | 一种自清洁超耐候粉末涂料及其制备方法 |
CN108697295A (zh) * | 2016-02-26 | 2018-10-23 | 3M创新有限公司 | 具有无溶剂纹理层的消费者洗擦制品及其制造方法 |
CN110997164A (zh) * | 2017-07-07 | 2020-04-10 | 斯塔尔国际有限公司 | 粉末涂覆方法和涂覆的制品 |
CN112175471A (zh) * | 2020-09-30 | 2021-01-05 | 安徽省华安进出口有限公司 | 一种含酐基官能度的聚丙烯酸树脂/tgic体系消光粉末涂料 |
CN112409868A (zh) * | 2020-11-13 | 2021-02-26 | 安徽省华安进出口有限公司 | 一种具有冰花纹理效果的粉末涂料 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012059490A1 (en) | 2010-11-02 | 2012-05-10 | Akzo Nobel Coatings International B.V. | Matte textured powder monocoat coating compositions |
US10221284B2 (en) * | 2016-01-15 | 2019-03-05 | Hrl Laboratories, Llc | Resin formulations for polymer-derived ceramic materials |
CN107880632A (zh) * | 2017-11-15 | 2018-04-06 | 六安科瑞达新型材料有限公司 | 一种环氧聚酯型粉末涂料用消光剂 |
CN108531042A (zh) * | 2018-04-28 | 2018-09-14 | 万玉梅 | 一种耐磨水性哑光漆的制备方法 |
CN111978831A (zh) * | 2020-09-08 | 2020-11-24 | 湖南连心科技有限公司 | 一种高光亮粉末涂料及其制备方法 |
CN112430410A (zh) * | 2020-10-22 | 2021-03-02 | 宁波爱甬新材料科技有限公司 | 一种耐候防腐的粉末涂料及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0045040A2 (en) * | 1980-07-21 | 1982-02-03 | E.I. Du Pont De Nemours And Company | Powder coating composition for automotive topcoat and the coated article |
CN1308658A (zh) * | 1998-07-03 | 2001-08-15 | 国际涂料有限公司 | 粉末涂料组合物 |
CA2353041A1 (en) * | 2000-07-28 | 2002-01-28 | Rohm And Haas Company | Matte texture powder coatings |
WO2004005414A1 (en) * | 2002-07-09 | 2004-01-15 | Basf Corporation | Powder coatings compositions crosslinked with an acid functional reaction product of tris (2-hydroxiethyl) isocyanurate and a cyclic anhydride |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5440831A (en) | 1977-09-08 | 1979-03-31 | Dainippon Ink & Chem Inc | Resin composition for matte powder coating |
US5856378A (en) | 1988-12-02 | 1999-01-05 | Courtaulds Coatings (Holdings) Limited | Powder coating compositions |
US5116892A (en) * | 1991-07-22 | 1992-05-26 | Eastman Kodak Company | Thermosetting powder coating compositions |
US5270391A (en) | 1991-11-27 | 1993-12-14 | Mitsui Toatsu Chemicals, Inc. | Composition for thermosetting powder coating |
US5731043A (en) | 1992-02-14 | 1998-03-24 | Morton International, Inc. | Triboelectric coating powder and procees for coating wood substrates |
US6399670B1 (en) * | 2000-01-21 | 2002-06-04 | Congoleum Corporation | Coating having macroscopic texture and process for making same |
JP4910248B2 (ja) * | 2001-06-15 | 2012-04-04 | Dic株式会社 | 熱硬化性粉体塗料及び塗装物 |
US7041737B2 (en) | 2001-11-28 | 2006-05-09 | Rohm And Haas Company | Coating powder composition, method of use thereof, and articles formed therefrom |
US6784248B2 (en) * | 2002-02-15 | 2004-08-31 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing alternating copolymers of isobutylene type monomers |
DE102004056875A1 (de) | 2004-11-25 | 2006-06-01 | Clariant Gmbh | Verwendung von polar modifizierten Polyolefinwachsen zur Verbesserung der Haftung von Dichtstoffen auf Pulverlacken |
US20080090948A1 (en) | 2006-10-12 | 2008-04-17 | Dewitt Julie | Waterbased low noise generating coating |
US20080233300A1 (en) * | 2007-03-19 | 2008-09-25 | Cinoman Douglas S | Thermosetting powders comprising curing agent adducts of polyesters and strong, flexible powder coatings made therefrom |
TW200916561A (en) | 2007-05-07 | 2009-04-16 | Martinswerk Gmbh | Flame retarded thermosets |
DE102007034865A1 (de) | 2007-07-24 | 2009-01-29 | Evonik Degussa Gmbh | Beschichtungsstoffzusammensetzungen |
DE102007047586A1 (de) | 2007-10-05 | 2009-04-09 | Evonik Degussa Gmbh | Beschichtungsstoffzusammensetzungen |
US20110082254A1 (en) | 2008-03-18 | 2011-04-07 | Nano-X Gmbh | Method for the production of a highly abrasion-resistant vehicle paint, vehicle paint, and the use thereof |
EP2236541A1 (en) | 2009-03-25 | 2010-10-06 | DSM IP Assets B.V. | Polyesteramide macromolecule and composition comprising such a macromolecule. |
WO2012059490A1 (en) | 2010-11-02 | 2012-05-10 | Akzo Nobel Coatings International B.V. | Matte textured powder monocoat coating compositions |
WO2014140234A1 (en) | 2013-03-15 | 2014-09-18 | Akzo Nobel Coatings International B.V. | Acrylic grafted polyether resins based on phenol stearic acid and coating compositions formed therefrom |
-
2011
- 2011-11-02 WO PCT/EP2011/069195 patent/WO2012059490A1/en active Application Filing
- 2011-11-02 CN CN201180051464.XA patent/CN103180398B/zh not_active Expired - Fee Related
- 2011-11-02 US US13/882,420 patent/US10072156B2/en not_active Expired - Fee Related
- 2011-11-02 EP EP11778585.7A patent/EP2635644B1/en not_active Not-in-force
- 2011-11-02 PL PL11778585T patent/PL2635644T3/pl unknown
-
2018
- 2018-08-07 US US16/056,807 patent/US20190031884A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0045040A2 (en) * | 1980-07-21 | 1982-02-03 | E.I. Du Pont De Nemours And Company | Powder coating composition for automotive topcoat and the coated article |
CN1308658A (zh) * | 1998-07-03 | 2001-08-15 | 国际涂料有限公司 | 粉末涂料组合物 |
CA2353041A1 (en) * | 2000-07-28 | 2002-01-28 | Rohm And Haas Company | Matte texture powder coatings |
WO2004005414A1 (en) * | 2002-07-09 | 2004-01-15 | Basf Corporation | Powder coatings compositions crosslinked with an acid functional reaction product of tris (2-hydroxiethyl) isocyanurate and a cyclic anhydride |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105505088A (zh) * | 2016-01-08 | 2016-04-20 | 金华市佳振科技发展有限公司 | 一种自清洁超耐候粉末涂料及其制备方法 |
CN108697295A (zh) * | 2016-02-26 | 2018-10-23 | 3M创新有限公司 | 具有无溶剂纹理层的消费者洗擦制品及其制造方法 |
CN110997164A (zh) * | 2017-07-07 | 2020-04-10 | 斯塔尔国际有限公司 | 粉末涂覆方法和涂覆的制品 |
US11865574B2 (en) | 2017-07-07 | 2024-01-09 | Akzo Nobel Coatings International B.V. | Powder coating method and coated article |
CN112175471A (zh) * | 2020-09-30 | 2021-01-05 | 安徽省华安进出口有限公司 | 一种含酐基官能度的聚丙烯酸树脂/tgic体系消光粉末涂料 |
CN112175471B (zh) * | 2020-09-30 | 2021-11-23 | 安徽省华安进出口有限公司 | 一种含酐基官能度的聚丙烯酸树脂/tgic体系消光粉末涂料 |
CN112409868A (zh) * | 2020-11-13 | 2021-02-26 | 安徽省华安进出口有限公司 | 一种具有冰花纹理效果的粉末涂料 |
Also Published As
Publication number | Publication date |
---|---|
US20190031884A1 (en) | 2019-01-31 |
CN103180398B (zh) | 2017-09-01 |
US10072156B2 (en) | 2018-09-11 |
PL2635644T3 (pl) | 2015-01-30 |
WO2012059490A1 (en) | 2012-05-10 |
US20130216785A1 (en) | 2013-08-22 |
EP2635644A1 (en) | 2013-09-11 |
EP2635644B1 (en) | 2014-07-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103189456A (zh) | 无光泽有纹理粉末单涂层涂料组合物 | |
CN103180398A (zh) | 无光泽有纹理粉末单涂层涂料组合物 | |
CN103987799B (zh) | 耐腐蚀、耐碎裂和耐燃油组合物 | |
JP6567783B1 (ja) | 粉体塗料組成物及び塗膜形成方法 | |
CN106414621B (zh) | 具有防腐蚀效果的涂料组合物 | |
CN103260775B (zh) | 形成多层漆膜的方法 | |
KR20050067189A (ko) | 분체 도료, 그의 제조 방법, 이 분체 도료를 사용하는 방법및 도장 제품 | |
CN100342984C (zh) | 涂膜形成方法和涂覆制品 | |
EP3277756B1 (de) | Beschichtungszusammensetzung sowie daraus hergestellte lackierung | |
US20210380818A1 (en) | Pro gel cap style multifunctional composition | |
WO2004083320A1 (ja) | 艶消し粉体塗料組成物 | |
JP2006124660A (ja) | 水性樹脂組成物 | |
US11248128B2 (en) | UVA multifunctional powder coating additive composition | |
US11008474B2 (en) | Multi-purpose flexibility additive for chemical coating compositions | |
CN108300182A (zh) | 用于铝合金的低温固化粉末涂料及其制备方法 | |
CN102892841A (zh) | 生产赋予色彩和/或效果的多层涂漆的方法,其中形成色彩的涂料组合物包含取代的环己醇以减少针孔数量 | |
JP2021054935A (ja) | 塗料組成物、塗装物の製造方法および塗装物 | |
US10947395B2 (en) | Multi-functional flow modifier for chemical coating compositions | |
US20210139714A1 (en) | Multi-functional dispersant for chemical coating compositions | |
WO2020132221A1 (en) | Pro gel cap style multifunctional composition | |
CN102822287A (zh) | 具有阳极化外观的粉末涂层 | |
US20210130624A1 (en) | Multi-functional high performance hardness composition for chemical coating platforms | |
CN104364325A (zh) | 低应用温度的粉末涂料 | |
JP2021053574A (ja) | 塗装物の製造方法および塗料組成物 | |
JP2006182954A (ja) | 自動車内板部用中塗り塗料組成物、自動車内板部用塗膜形成方法および塗装物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170901 Termination date: 20201102 |
|
CF01 | Termination of patent right due to non-payment of annual fee |