CN103119072B - 二氯化镁-醇加合物和由其获得的催化剂组分 - Google Patents

二氯化镁-醇加合物和由其获得的催化剂组分 Download PDF

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Publication number
CN103119072B
CN103119072B CN201180047701.5A CN201180047701A CN103119072B CN 103119072 B CN103119072 B CN 103119072B CN 201180047701 A CN201180047701 A CN 201180047701A CN 103119072 B CN103119072 B CN 103119072B
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acid
metal
mgcl
salt
alcohol
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Chinese (zh)
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CN103119072A (zh
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G.科利纳
D.埃万格利斯蒂
B.加迪
A.法伊特
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Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/63—Pretreating the metal or compound covered by group C08F4/62 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/632—Pretreating with metals or metal-containing compounds
    • C08F4/634—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/26—Magnesium halides
    • C01F5/30—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CN201180047701.5A 2010-09-30 2011-09-29 二氯化镁-醇加合物和由其获得的催化剂组分 Expired - Fee Related CN103119072B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10183309 2010-09-30
EP10183309.3 2010-09-30
PCT/EP2011/066956 WO2012041944A1 (en) 2010-09-30 2011-09-29 Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom

Publications (2)

Publication Number Publication Date
CN103119072A CN103119072A (zh) 2013-05-22
CN103119072B true CN103119072B (zh) 2016-03-30

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US (1) US8940653B2 (enExample)
EP (1) EP2621964B1 (enExample)
JP (1) JP5745068B2 (enExample)
KR (1) KR101775317B1 (enExample)
CN (1) CN103119072B (enExample)
BR (1) BR112013006142A2 (enExample)
ES (1) ES2627928T3 (enExample)
RU (1) RU2576523C2 (enExample)
WO (1) WO2012041944A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2699605B1 (en) * 2011-04-18 2018-05-23 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
EP2712874A1 (en) * 2012-09-26 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
ES2974931T3 (es) 2014-03-14 2024-07-02 Basell Poliolefine Italia Srl Componentes catalizadores para la polimerización de olefinas
EA033278B1 (ru) * 2014-12-18 2019-09-30 Бореалис Аг СПОСОБ ПОЛУЧЕНИЯ ТВЕРДОГО КОМПОНЕНТА КАТАЛИЗАТОРА НА ПОДЛОЖКЕ MgCl
WO2018161854A1 (zh) * 2017-03-10 2018-09-13 北京利和知信科技有限公司 用于烯烃聚合的固体催化剂组分、催化剂及其应用
EP3724240A1 (en) * 2017-12-14 2020-10-21 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
IT202100029732A1 (it) * 2021-11-24 2023-05-24 Basell Poliolefine Italia Srl Processo per la preparazione di complessi di coordinazione in forma cristallina
CN114316102B (zh) * 2022-01-18 2023-12-22 北京吉海川科技发展有限公司 一种烷氧基镁载体、聚乙烯催化剂及其制备方法

Citations (8)

* Cited by examiner, † Cited by third party
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CN1068578A (zh) * 1991-07-12 1993-02-03 Ecp埃尼化学有限公司 用于乙烯和α-烯烃(共)聚合的催化剂固体组分
CN1226901A (zh) * 1997-03-29 1999-08-25 蒙特尔技术有限公司 氯化镁－醇加合物、其制备方法以及从中获得的催化剂组分
CN1358771A (zh) * 2000-12-14 2002-07-17 中国石油化工股份有限公司 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用
WO2003082930A2 (en) * 2002-03-29 2003-10-09 Basell Poliolefine Italia S.P.A. Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom
CN1659190A (zh) * 2002-06-13 2005-08-24 巴塞尔聚烯烃意大利有限公司 乙烯共聚物的制备方法
CN1726080A (zh) * 2002-12-18 2006-01-25 巴塞尔聚烯烃意大利有限公司 氯化镁基加合物及由其制备的催化剂组分
CN1898278A (zh) * 2003-12-23 2007-01-17 巴塞尔聚烯烃意大利有限责任公司 二氯化镁－乙醇加合物和由此得到的催化剂组分
CN101283006A (zh) * 2005-08-12 2008-10-08 巴斯夫欧洲公司 从异丁烯和至少一种乙烯基芳族化合物制备共聚物的方法

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JPS5425517B2 (enExample) * 1972-12-27 1979-08-28
DE3273399D1 (en) 1982-02-12 1986-10-30 Mitsui Petrochemical Ind Process for producing olefin polymers
US4612299A (en) * 1984-07-09 1986-09-16 Amoco Corporation Magnesium carboxylate supports
JPS6162505A (ja) * 1984-07-09 1986-03-31 アモコ・コ−ポレ−シヨン マグネシウムカルボキシレ−ト担体
JPS61195102A (ja) * 1985-02-25 1986-08-29 Idemitsu Kosan Co Ltd エチレン系重合体の製造方法
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
US6730627B1 (en) 1991-07-12 2004-05-04 Ecp Enichem Polimeri S.R.L. Solid component of catalyst for the (co) polymerization of ethylene and α-olefins
CN1169845C (zh) 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
BR0306437A (pt) * 2002-09-17 2005-01-11 Basell Poliolefine Spa Adutos de dicloreto de magnésio-etanol e componentes catalìticos obtidos a partir deles
AU2003293783A1 (en) * 2002-12-18 2004-07-09 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom
WO2005039745A1 (en) 2003-10-16 2005-05-06 Basell Poliolefine Italia S.R.L. Process for the continuous production of emulsions
CN1289542C (zh) * 2004-07-05 2006-12-13 中国石油化工股份有限公司 用于烯烃聚合反应的球形催化剂组分及其催化剂

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1068578A (zh) * 1991-07-12 1993-02-03 Ecp埃尼化学有限公司 用于乙烯和α-烯烃(共)聚合的催化剂固体组分
CN1226901A (zh) * 1997-03-29 1999-08-25 蒙特尔技术有限公司 氯化镁－醇加合物、其制备方法以及从中获得的催化剂组分
CN1358771A (zh) * 2000-12-14 2002-07-17 中国石油化工股份有限公司 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用
WO2003082930A2 (en) * 2002-03-29 2003-10-09 Basell Poliolefine Italia S.P.A. Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom
CN1551893A (zh) * 2002-03-29 2004-12-01 ��������ϩ����������޹�˾ 二氯化镁-乙醇加合物和由它获得的催化剂组分
CN1659190A (zh) * 2002-06-13 2005-08-24 巴塞尔聚烯烃意大利有限公司 乙烯共聚物的制备方法
CN1726080A (zh) * 2002-12-18 2006-01-25 巴塞尔聚烯烃意大利有限公司 氯化镁基加合物及由其制备的催化剂组分
CN1898278A (zh) * 2003-12-23 2007-01-17 巴塞尔聚烯烃意大利有限责任公司 二氯化镁－乙醇加合物和由此得到的催化剂组分
CN101283006A (zh) * 2005-08-12 2008-10-08 巴斯夫欧洲公司 从异丁烯和至少一种乙烯基芳族化合物制备共聚物的方法

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Publication number Publication date
US8940653B2 (en) 2015-01-27
WO2012041944A1 (en) 2012-04-05
JP5745068B2 (ja) 2015-07-08
KR101775317B1 (ko) 2017-09-19
US20130197172A1 (en) 2013-08-01
BR112013006142A2 (pt) 2017-11-07
ES2627928T3 (es) 2017-08-01
EP2621964A1 (en) 2013-08-07
KR20130114644A (ko) 2013-10-17
CN103119072A (zh) 2013-05-22
JP2013542278A (ja) 2013-11-21
RU2013120068A (ru) 2014-11-10
EP2621964B1 (en) 2017-05-17
RU2576523C2 (ru) 2016-03-10

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Termination date: 20190929