KR101775317B1 - 마그네슘 디클로라이드-알코올 부가물 및 그로부터 얻어지는 촉매 성분 - Google Patents

마그네슘 디클로라이드-알코올 부가물 및 그로부터 얻어지는 촉매 성분 Download PDF

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KR101775317B1
KR101775317B1 KR1020137006204A KR20137006204A KR101775317B1 KR 101775317 B1 KR101775317 B1 KR 101775317B1 KR 1020137006204 A KR1020137006204 A KR 1020137006204A KR 20137006204 A KR20137006204 A KR 20137006204A KR 101775317 B1 KR101775317 B1 KR 101775317B1
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South Korea
Prior art keywords
adduct
mgcl
carboxylic acid
solid
metal salt
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Expired - Fee Related
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English (en)
Korean (ko)
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KR20130114644A (ko
Inventor
잔니 콜리나
다니엘레 에반젤리스티
베네덱타 가디
안나 파이트
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바셀 폴리올레핀 이탈리아 에스.알.엘
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/63—Pretreating the metal or compound covered by group C08F4/62 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/632—Pretreating with metals or metal-containing compounds
    • C08F4/634—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/26—Magnesium halides
    • C01F5/30—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020137006204A 2010-09-30 2011-09-29 마그네슘 디클로라이드-알코올 부가물 및 그로부터 얻어지는 촉매 성분 Expired - Fee Related KR101775317B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP10183309 2010-09-30
EP10183309.3 2010-09-30
US40451810P 2010-10-05 2010-10-05
US61/404,518 2010-10-05
PCT/EP2011/066956 WO2012041944A1 (en) 2010-09-30 2011-09-29 Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom

Publications (2)

Publication Number Publication Date
KR20130114644A KR20130114644A (ko) 2013-10-17
KR101775317B1 true KR101775317B1 (ko) 2017-09-19

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KR1020137006204A Expired - Fee Related KR101775317B1 (ko) 2010-09-30 2011-09-29 마그네슘 디클로라이드-알코올 부가물 및 그로부터 얻어지는 촉매 성분

Country Status (9)

Country Link
US (1) US8940653B2 (enExample)
EP (1) EP2621964B1 (enExample)
JP (1) JP5745068B2 (enExample)
KR (1) KR101775317B1 (enExample)
CN (1) CN103119072B (enExample)
BR (1) BR112013006142A2 (enExample)
ES (1) ES2627928T3 (enExample)
RU (1) RU2576523C2 (enExample)
WO (1) WO2012041944A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2699605B1 (en) * 2011-04-18 2018-05-23 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
EP2712874A1 (en) * 2012-09-26 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
ES2974931T3 (es) 2014-03-14 2024-07-02 Basell Poliolefine Italia Srl Componentes catalizadores para la polimerización de olefinas
EA033278B1 (ru) * 2014-12-18 2019-09-30 Бореалис Аг СПОСОБ ПОЛУЧЕНИЯ ТВЕРДОГО КОМПОНЕНТА КАТАЛИЗАТОРА НА ПОДЛОЖКЕ MgCl
WO2018161854A1 (zh) * 2017-03-10 2018-09-13 北京利和知信科技有限公司 用于烯烃聚合的固体催化剂组分、催化剂及其应用
EP3724240A1 (en) * 2017-12-14 2020-10-21 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
IT202100029732A1 (it) * 2021-11-24 2023-05-24 Basell Poliolefine Italia Srl Processo per la preparazione di complessi di coordinazione in forma cristallina
CN114316102B (zh) * 2022-01-18 2023-12-22 北京吉海川科技发展有限公司 一种烷氧基镁载体、聚乙烯催化剂及其制备方法

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JPS5425517B2 (enExample) * 1972-12-27 1979-08-28
DE3273399D1 (en) 1982-02-12 1986-10-30 Mitsui Petrochemical Ind Process for producing olefin polymers
US4612299A (en) * 1984-07-09 1986-09-16 Amoco Corporation Magnesium carboxylate supports
JPS6162505A (ja) * 1984-07-09 1986-03-31 アモコ・コ−ポレ−シヨン マグネシウムカルボキシレ−ト担体
JPS61195102A (ja) * 1985-02-25 1986-08-29 Idemitsu Kosan Co Ltd エチレン系重合体の製造方法
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
US6730627B1 (en) 1991-07-12 2004-05-04 Ecp Enichem Polimeri S.R.L. Solid component of catalyst for the (co) polymerization of ethylene and α-olefins
IT1251462B (it) * 1991-07-12 1995-05-15 Enichem Polimeri Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine.
BR9804806A (pt) * 1997-03-29 1999-08-17 Montell Technology Company Bv Adutos de alcool-dicloreto de magnesio processo para sua prepara-Æo e componentes de catalisadores obtidos a partir deles
CN1131246C (zh) * 2000-12-14 2003-12-17 中国石油化工股份有限公司 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用
CN1169845C (zh) 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
ATE420121T1 (de) * 2002-03-29 2009-01-15 Basell Poliolefine Srl Magnesiumdichlorid-ethanol-addukte und daraus erhaltene katalysatorkomponenten
RU2004105852A (ru) * 2002-06-13 2005-06-27 Базель Полиолефин Италия С.П.А. (It) Способ получения сополимеров этилена
BR0306437A (pt) * 2002-09-17 2005-01-11 Basell Poliolefine Spa Adutos de dicloreto de magnésio-etanol e componentes catalìticos obtidos a partir deles
AU2003293783A1 (en) * 2002-12-18 2004-07-09 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom
EP1572756B1 (en) * 2002-12-18 2013-04-10 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
WO2005039745A1 (en) 2003-10-16 2005-05-06 Basell Poliolefine Italia S.R.L. Process for the continuous production of emulsions
CN100519597C (zh) * 2003-12-23 2009-07-29 巴塞尔聚烯烃意大利有限责任公司 二氯化镁-乙醇加合物和由此得到的催化剂组分
CN1289542C (zh) * 2004-07-05 2006-12-13 中国石油化工股份有限公司 用于烯烃聚合反应的球形催化剂组分及其催化剂
DE102005038282A1 (de) * 2005-08-12 2007-02-22 Basf Ag Verfahren zur Herstellung von Copolymeren aus Isobuten und wenigstens einer vinylaromatischen Verbindung

Also Published As

Publication number Publication date
US8940653B2 (en) 2015-01-27
WO2012041944A1 (en) 2012-04-05
JP5745068B2 (ja) 2015-07-08
US20130197172A1 (en) 2013-08-01
BR112013006142A2 (pt) 2017-11-07
ES2627928T3 (es) 2017-08-01
EP2621964A1 (en) 2013-08-07
KR20130114644A (ko) 2013-10-17
CN103119072A (zh) 2013-05-22
JP2013542278A (ja) 2013-11-21
RU2013120068A (ru) 2014-11-10
EP2621964B1 (en) 2017-05-17
RU2576523C2 (ru) 2016-03-10
CN103119072B (zh) 2016-03-30

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