CN103097466A - 颜料组合物 - Google Patents
颜料组合物 Download PDFInfo
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- CN103097466A CN103097466A CN2011800140726A CN201180014072A CN103097466A CN 103097466 A CN103097466 A CN 103097466A CN 2011800140726 A CN2011800140726 A CN 2011800140726A CN 201180014072 A CN201180014072 A CN 201180014072A CN 103097466 A CN103097466 A CN 103097466A
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- pigment
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- red
- yellow
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- 239000000203 mixture Substances 0.000 title claims abstract description 34
- 239000000049 pigment Substances 0.000 title claims abstract description 32
- 229920001577 copolymer Polymers 0.000 claims abstract description 15
- -1 amino alkyl methacrylate Chemical compound 0.000 claims description 16
- 229920002554 vinyl polymer Polymers 0.000 claims description 11
- 238000007639 printing Methods 0.000 claims description 7
- 239000003814 drug Substances 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 abstract description 22
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 229920003144 amino alkyl methacrylate copolymer Polymers 0.000 abstract 1
- 239000000825 pharmaceutical preparation Substances 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 21
- 229920003134 Eudragit® polymer Polymers 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229920000058 polyacrylate Polymers 0.000 description 9
- 239000007788 liquid Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 3
- 240000001592 Amaranthus caudatus Species 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- OIQPTROHQCGFEF-QIKYXUGXSA-L Sunset Yellow FCF Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=CC2=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 OIQPTROHQCGFEF-QIKYXUGXSA-L 0.000 description 3
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 description 3
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 239000004178 amaranth Substances 0.000 description 3
- 235000012735 amaranth Nutrition 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- MQWPIYMKAKYEEQ-UHFFFAOYSA-L dipotassium 2,3,4,5-tetrachloro-6-(2,4,5,7-tetrabromo-3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [K+].[K+].[O-]C(=O)c1c(Cl)c(Cl)c(Cl)c(Cl)c1-c1c2cc(Br)c([O-])c(Br)c2oc2c(Br)c(=O)c(Br)cc12 MQWPIYMKAKYEEQ-UHFFFAOYSA-L 0.000 description 3
- AHSJNHONMVUMLK-UHFFFAOYSA-L disodium;4',5'-diiodo-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C2=CC=CC=C2C21C1=CC=C([O-])C(I)=C1OC1=C(I)C([O-])=CC=C21 AHSJNHONMVUMLK-UHFFFAOYSA-L 0.000 description 3
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 description 3
- AZLXCBPKSXFMET-UHFFFAOYSA-M sodium 4-[(4-sulfophenyl)diazenyl]naphthalen-1-olate Chemical compound [Na+].C12=CC=CC=C2C(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 AZLXCBPKSXFMET-UHFFFAOYSA-M 0.000 description 3
- 235000012751 sunset yellow FCF Nutrition 0.000 description 3
- 239000004173 sunset yellow FCF Substances 0.000 description 3
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004214 Fast Green FCF Substances 0.000 description 2
- RZSYLLSAWYUBPE-UHFFFAOYSA-L Fast green FCF Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC(O)=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 RZSYLLSAWYUBPE-UHFFFAOYSA-L 0.000 description 2
- XKTMIJODWOEBKO-UHFFFAOYSA-M Guinee green B Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC=CC=2)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 XKTMIJODWOEBKO-UHFFFAOYSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- FIKBURFLPVUDAX-BAYNMDCWSA-M [Na+].Cc1ccc(\N=N\c2c(O)ccc(\N=N\c3ccc(cc3)S([O-])(=O)=O)c2O)c(C)c1 Chemical compound [Na+].Cc1ccc(\N=N\c2c(O)ccc(\N=N\c3ccc(cc3)S([O-])(=O)=O)c2O)c(C)c1 FIKBURFLPVUDAX-BAYNMDCWSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- YJVBLROMQZEFPA-UHFFFAOYSA-L acid red 26 Chemical compound [Na+].[Na+].CC1=CC(C)=CC=C1N=NC1=C(O)C(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=CC=C12 YJVBLROMQZEFPA-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 2
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 description 2
- 235000012732 erythrosine Nutrition 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 235000019240 fast green FCF Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- KHLVKKOJDHCJMG-QDBORUFSSA-L indigo carmine Chemical compound [Na+].[Na+].N/1C2=CC=C(S([O-])(=O)=O)C=C2C(=O)C\1=C1/NC2=CC=C(S(=O)(=O)[O-])C=C2C1=O KHLVKKOJDHCJMG-QDBORUFSSA-L 0.000 description 2
- 229960003988 indigo carmine Drugs 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 2
- 229940048276 new coccine Drugs 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
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- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 2
- 239000004172 quinoline yellow Substances 0.000 description 2
- 235000012752 quinoline yellow Nutrition 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- WDAWIIXWJBEKSA-UHFFFAOYSA-N sodium 4-(5-methyl-3-oxo-4-phenyldiazenyl-1H-pyrazol-2-yl)benzenesulfonic acid Chemical compound CC1=C(C(=O)N(N1)C2=CC=C(C=C2)S(=O)(=O)O)N=NC3=CC=CC=C3.[Na+] WDAWIIXWJBEKSA-UHFFFAOYSA-N 0.000 description 2
- DXKDBQWDRGRKGC-UHFFFAOYSA-M sodium;5-chloro-2-[3-methyl-4-[[4-(4-methylphenyl)sulfonyloxyphenyl]diazenyl]-5-oxo-4h-pyrazol-1-yl]benzenesulfonate Chemical compound [Na+].CC1=NN(C=2C(=CC(Cl)=CC=2)S([O-])(=O)=O)C(=O)C1N=NC(C=C1)=CC=C1OS(=O)(=O)C1=CC=C(C)C=C1 DXKDBQWDRGRKGC-UHFFFAOYSA-M 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- YJUUZFWMKJBVFJ-UHFFFAOYSA-N 1,3-dimethylimidazolidin-4-one Chemical compound CN1CN(C)C(=O)C1 YJUUZFWMKJBVFJ-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UBVSIAHUTXHQTD-UHFFFAOYSA-N 2-n-(4-bromophenyl)-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(NC=2C=CC(Br)=CC=2)=N1 UBVSIAHUTXHQTD-UHFFFAOYSA-N 0.000 description 1
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
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- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
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- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
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- 125000000129 anionic group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
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- JBTHDAVBDKKSRW-UHFFFAOYSA-N chembl1552233 Chemical compound CC1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 JBTHDAVBDKKSRW-UHFFFAOYSA-N 0.000 description 1
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- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004148 curcumin Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- VQHHOXOLUXRQFQ-UHFFFAOYSA-L dipotassium;4,5,6,7-tetrachloro-2',4',5',7'-tetraiodo-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [K+].[K+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C([O-])C(I)=C1OC1=C(I)C([O-])=C(I)C=C21 VQHHOXOLUXRQFQ-UHFFFAOYSA-L 0.000 description 1
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- WTOSNONTQZJEBC-UHFFFAOYSA-N erythrosin Chemical compound OC(=O)C1=CC=CC=C1C(C1C(C(=C(O)C(I)=C1)I)O1)=C2C1=C(I)C(=O)C(I)=C2 WTOSNONTQZJEBC-UHFFFAOYSA-N 0.000 description 1
- IINNWAYUJNWZRM-UHFFFAOYSA-L erythrosin B Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IINNWAYUJNWZRM-UHFFFAOYSA-L 0.000 description 1
- 239000004174 erythrosine Substances 0.000 description 1
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- C09B67/0084—Dispersions of dyes
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- C09B67/006—Preparation of organic pigments
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- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/0004—Coated particulate pigments or dyes
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- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
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Abstract
本发明提供一种颜料组合物，其中，含有a)颜料和b)聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物，所述颜料组合物可用于药品等，分散性优异。
Description
技术领域
本发明涉及含有丙烯酸类聚合物的颜料组合物。
背景技术
通常在液态介质中分散有颜料而成的颜料分散液普遍的做法为，掺混颜料、水、有机溶剂、树脂、其它添加剂等，使用分散器进行分散处理。特别是用于制备喷墨记录用颜料油墨的颜料分散液，是使用水溶性高分子化合物、表面活性剂等分散剂，将颜料分散于液态介质中进行制备的。所制备的颜料油墨为了确保保存稳定性、排出稳定性等，要求高度的分散性(凝集稳定性和沉降稳定性)。颜料油墨的凝集稳定性和沉降稳定性主要由所使用的分散剂的性能决定。
迄今为止已尝试非离子、阴离子型表面活性剂，具有亲水性嵌段和疏水性嵌段的嵌段共聚物，含有树脂粒子的树脂乳状液等各种分散剂(参照专利文献1、2)。但是，现有的分散剂不可用做药品添加剂和食品添加剂，或即使可使用也难以适宜的粘度分散颜料。即，若增加分散剂粘度来确保颜料油墨的凝集稳定性和沉降稳定性，则引起油墨粘度升高，热位差(thermal head)情况下产生焦糊等问题，难以使油墨的稳定性与作为油墨的性能并存。因此，尚无可以喷墨方式对药品等的片剂进行印字的技术的报告。
需说明的是，专利文献中记载有使用含有可用作药品添加剂的物质的丙烯酸类聚合物作为颜料的分散剂的内容(参照专利文献3、4)。
先前技术文献
专利文献
专利文献1：日本特开平1-204979号
专利文献2：日本特开平10-279870号
专利文献3：日本特开平3-121896号
专利文献4：日本特开2001-115199号。
发明内容
本发明的课题在于提供：可用于药品等的、分散性优异的含丙烯酸类聚合物的颜料组合物。
本发明人为解决上述问题而深入研究的结果发现，通过掺混聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物，可良好地分散颜料，从而完成本发明。
即，本发明为：
(1) 颜料组合物，其特征在于，含有a)颜料和b)聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物。
(2) (1)中记载的颜料组合物，其中，颜料为铝色淀。
(3) (1)或(2)中记载的颜料组合物，其中，相对于1重量份的a)成分，含有0.1重量份以上的b)成分。
(4) 含有(1)~(3)的任一项中记载的颜料组合物的药品印刷用油墨。
本发明的含丙烯酸类聚合物的颜料组合物的分散性优异。
具体实施方式
本发明的用作颜料分散剂的聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物为在部分皂化聚乙烯醇中共聚丙烯酸和甲基丙烯酸甲酯而成的合成高分子。另外，本发明的用作颜料分散剂的甲基丙烯酸氨基烷基酯共聚物为丙烯酸乙酯与丙烯酸甲酯和甲基丙烯酸三甲基氯化铵乙酯(trimethylammonium ethyl methacrylate chloride)的共聚物(甲基丙烯酸氨基烷基酯共聚物RS)或甲基丙烯酸甲酯与甲基丙烯酸丁酯和甲基丙烯酸二甲基氨基乙酯的共聚物(甲基丙烯酸氨基烷基酯共聚物E)，在本发明中优选使用甲基丙烯酸氨基烷基酯共聚物RS。
聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物的含量相对于1重量份的颜料优选为0.1~20重量份，更优选为0.1~10重量份。从分散性的观点出发，优选含有0.1重量份以上，但若含量过多，则粘度增加，例如作为喷墨用油墨使用时导致排出不良，所以优选含有10重量份以下。
另外，甲基丙烯酸氨基烷基酯共聚物的含量相对于1重量份的颜料优选为0.1~30重量份，更优选为0.1~15重量份。从分散性的观点出发，优选含有0.1重量份以上，但若含量过多，则粘度增加，例如作为喷墨用油墨使用时导致排出不良，所以优选含有15重量份以下。
本发明的用作颜料分散剂的聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物例如可使用制造商为大同化成工业(株)、销售商为日新化成(株)的POVACOAT (注册商标)。虽然有粘度、pH不相同的F型(粘度5.5mPa·s (5%水溶液、25℃)、pH 4.5~5.5)、R型(粘度20mPa·s (5%水溶液、25℃)、pH 4.5~5.5)、L型(相同粘度20mPa·s (5%水溶液、25℃)、pH 4.5~6.5))，但均可使用。
另外，甲基丙烯酸氨基烷基酯共聚物RS例如可使用Evonik Degussa Japan Co., Ltd. (エボニックデグサジャパン(株))的Eudragit (オイドラギット) (注册商标) RL100、Eudragit (オイドラギット) (注册商标) RLPO、Eudragit (オイドラギット) (注册商标) RL30D、Eudragit (オイドラギット) (注册商标) RS100、Eudragit (オイドラギット) (注册商标) RSPO和Eudragit (オイドラギット) (注册商标) RS30D等，甲基丙烯酸氨基烷基酯E同样可使用Evonik Degussa Japan Co., Ltd. (エボニックデグサジャパン(株))的Eudragit (オイドラギット) (注册商标) E100、Eudragit (オイドラギット) (注册商标) EPO等。Eudragit (オイドラギット) RL系列的单体组成为：丙烯酸乙酯:甲基丙烯酸甲酯:甲基丙烯酸三甲基氯化铵乙酯为1:2:0.2；Eudragit (オイドラギット) RS系列的单体组成为丙烯酸乙酯:甲基丙烯酸甲酯:甲基丙烯酸三甲基氯化铵乙酯为1:2:0.1。另外，Eudragit (オイドラギット) E系列的单体组成为：甲基丙烯酸甲酯:甲基丙烯酸丁酯:甲基丙烯酸二甲基氨基乙酯为1:1:2。
在本发明中，尽管不使用现有的阴离子类或非离子类表面活性剂等作为颜料的分散剂，但通过使用聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物，可获得分散性优异的颜料组合物。
本发明中使用的颜料的种类无特殊限定，但若示例出代表性的物质，则可列举出碳黑、药用炭、二氧化钛、三氧化二铁、黄色三氧化二铁、黑氧化铁、碳酸钙等无机类颜料。另外，可列举出属于食用焦油色素的红色2号(别名苋菜红(Amaranth))、红色3号(别名藻红(Erythrosine))、红色102号(别名新胭脂红(New Coccine))、红色104号(别名焰红B (Phloxine B))、红色105号(别名玫瑰红(Rose Bengal))、红色106号(别名酸性红(Acid Red))、黄色4号(别名柠檬黄(Tartrazine))、黄色5号(别名日落黄FCF (Sunset Yellow FCF))、绿色3号(别名固绿FCF (Fast Green FCF))、蓝色1号(别名亮蓝FCF (Brilliant Blue FCF))、蓝色2号(别名靛胭脂(Indigo Carmine))、红色227号(别名坚牢酸性品红(Fast Acid Magenta))、红色230号的(1) (别名曙红YS (Eosine YS))、红色230号的(2) (别名曙红YSK (Eosine YSK))、红色231号(别名焰红BK (Phloxine BK))、红色232号(别名玫瑰红K (Rose Bengal K))、橙色205号(别名橙色II (Orange II))、橙色207号(别名黄藻红NA (Erythrosine Yellowish NA))、黄色202号的(1) (别名荧光素钠(Uranine))、黄色202号的(2) (别名荧光素钠K (Uranine K))、黄色203号(别名喹啉黄WS (Quinoline Yellow WS))、绿色201号(别名茜素花青绿F (Alizarine Cyanine Green F))、绿色204号(别名溶剂绿7(Pyranine Conc))、绿色205号(别名亮绿SF黄(Light Green SF Yellowish))、蓝色205号(别名子种绿FG (Alphazurine FG))、褐色201号(别名间苯二酚棕(Resorcin Brown))、红色401号(别名紫胺R (Violamine R))、红色502号(别名丽春红3R (Ponceau 3R))、红色503号(别名丽春红R (Ponceau R))、红色504号(别名丽春红SX (Ponceau SX))、红色506号(别名固红S (Fast Red S))、橙色402号(别名橙色I (Orange I))、黄色402号(别名普拉黄5G (Polar Yellow 5G))、黄色403号的(1) (别名萘酚黄S (Naphthol Yellow S))、黄色406号(别名间胺黄(Metanil Yellow))、黄色407号(别名坚牢浅黄3G (Fast Light Yellow 3G))、绿色402号(别名基尼绿B (Guinea Green B))、紫色401号(别名酸性蒽醌紫(Alizurol Purple))、黑色401号(别名萘酚蓝黑(Naphthol Blue Black))的铝色淀等可用于药品等的色素。这些颜料相对于本发明的颜料组合物优选以0.1~20%重量的范围掺混。
本发明的含丙烯酸类聚合物的颜料组合物可用作油墨、涂料。另外，本发明的颜料组合物，颜料的分散性优异，对凝集和沉降稳定，因此特别可适合用作喷墨用油墨。另外，在本发明中由于使用聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或聚甲基丙烯酸酯树脂的甲基丙烯酸氨基烷基酯共聚物作为分散剂，所以可通过使用可口服的颜料，制成可口服的颜料组合物。即，可用作例如药品等的片剂的印刷用油墨。
本发明的含丙烯酸类聚合物的颜料组合物可通过以下方法制备：事先将聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物添加于液态介质中然后添加颜料，或在将液态介质与颜料混合后添加聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物，使用高压匀质机、球磨机、混砂机、砂磨机及珠磨机之类的分散器来分散颜料。
上述液态介质优选水或水与水溶性有机溶剂的混合溶剂。作为水溶性有机溶剂，例如可列举出甲醇、乙醇、正丁醇、异丁醇、叔丁醇、正丙醇、イン丙醇(インプロピルアルコール)等醇类，二甲基甲酰胺、二甲基乙酰胺等酰胺类，丙酮、甲乙酮等酮类，四氢呋喃、二噁烷、乙二醇甲醚、乙二醇乙醚、二甘醇甲醚、二甘醇乙醚、三甘醇单甲醚、三甘醇单乙醚等醚类，乙二醇、丙二醇、丁二醇、二甘醇、三甘醇、1,2,6-己三醇、硫二甘醇、聚乙二醇、聚丙二醇、甘油、双甘油、聚甘油等多元醇类，N-甲基吡咯烷酮、1,3-二甲基-2-咪唑啉酮等。
本发明的含丙烯酸类聚合物的颜料组合物中可根据需要添加水溶性树脂、有机胺、表面活性剂、pH调节剂、螯合剂、防腐剂、粘度调节剂、消泡剂等。
以下通过实施例和比较例对本发明进行具体说明，但本发明的范围不受这些实施例限定。
实施例
实施例1
将5g的蓝色2号铝色淀、2g的聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物、20g的甘油、73g的纯化水搅拌混合，制得分散液。
对分散液进行使用搅拌机和氧化锆珠的粉碎处理。混合粉碎时的珠与样品以容积比计设定为1:1，粉碎处理设定为粗粉碎和微粉碎的2步粉碎。需说明的是，粉碎处理于室温下(约25℃)实施。
实施例2~5、比较例1~14
按照与实施例1同样的方法，制备不掺混分散剂的比较例1、将分散剂由聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物变更为甲基丙烯酸氨基烷基酯共聚物的实施例2~5、将分散剂变更为它们以外的物质的比较例6~14。将实施例1~5和比较例1~14的组成示出于表1和2中。表1中成分名栏中的括号内示出所使用的丙烯酸类聚合物的商品名。需说明的是，Eudragit (オイドラギット) RL30D和Eudragit (オイドラギット) RS30D中的甲基丙烯酸氨基烷基酯共聚物RS含量、Eudragit (オイドラギット) NE30D中的丙烯酸乙酯-甲基丙烯酸甲酸共聚物含量以及Eudragit (オイドラギット) L30D-55中的甲基丙烯酸共聚物LD含量均为30%重量。表中各成分的掺混量单位为“g”。
就上述颜料组合物的分散性评价而言，是在混合后，于室温静置24小时，通过偏光显微镜在400倍的倍率下观察蓝色2号铝色淀的分散状态。将其结果示出于表1和2中。对于表中的分散性的评价，AA表示分散良好的状态，BB表示不可分散的状态。
[表1]
表1
[表2]
表2
由表1和2的结果可知，仅在掺混聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物(Eudragit RL30D或Eudragit RS30D)的情况下可获得优异的分散性。
产业上的可利用性
本发明的含丙烯酸类聚合物的颜料组合物由于分散性良好，所以可适合用作通常的圆珠笔等文具用油墨或涂料、特别是喷墨记录用颜料油墨。
Claims (4)
1. 颜料组合物，其中，含有a)颜料和b)聚乙烯醇-丙烯酸-甲基丙烯酸甲酯共聚物或甲基丙烯酸氨基烷基酯共聚物。
2. 权利要求1的颜料组合物，其中，颜料为铝色淀。
3. 权利要求1或2的颜料组合物，其中，相对于1重量份的a)成分，含有0.1重量份以上的b)成分。
4. 含有权利要求1~3中任一项的颜料组合物的药品印刷用油墨。
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| JP2010058045 | 2010-03-15 | ||
| JP2010-058045 | 2010-03-15 | ||
| PCT/JP2011/001473 WO2011114691A1 (ja) | 2010-03-15 | 2011-03-14 | 顔料組成物 |
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| EP (1) | EP2548928A4 (zh) |
| JP (1) | JPWO2011114691A1 (zh) |
| KR (1) | KR20130048725A (zh) |
| CN (1) | CN103097466A (zh) |
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| CN108026401A (zh) * | 2015-09-30 | 2018-05-11 | 富士胶片株式会社 | 喷墨记录用氧化铁分散物及其制造方法、以及喷墨记录方法 |
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| KR102050444B1 (ko) | 2013-04-30 | 2019-11-29 | 엘지디스플레이 주식회사 | 터치 입력 시스템 및 이를 이용한 터치 검출 방법 |
| JP5830551B2 (ja) * | 2014-01-30 | 2015-12-09 | 大原薬品工業株式会社 | 医薬品錠剤印刷用のインク組成物 |
| JP6742426B2 (ja) | 2016-09-30 | 2020-08-19 | 富士フイルム株式会社 | 分散物の製造方法、及びインクジェット記録用顔料分散物の製造方法 |
| JP7362252B2 (ja) * | 2018-01-19 | 2023-10-17 | 株式会社Ｓｃｒｅｅｎホールディングス | 顔料組成物、インクジェット用水性インク組成物及び固体製剤 |
| WO2019142899A1 (ja) * | 2018-01-19 | 2019-07-25 | 株式会社Ｓｃｒｅｅｎホールディングス | 顔料組成物、インクジェット用水性インク組成物及び固体製剤 |
| JP7361530B2 (ja) * | 2019-08-09 | 2023-10-16 | 株式会社Ｓｃｒｅｅｎホールディングス | 固体製剤及び固体製剤への印刷方法 |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2011114691A1 (ja) | 2011-09-22 |
| KR20130048725A (ko) | 2013-05-10 |
| EP2548928A4 (en) | 2013-09-18 |
| EP2548928A1 (en) | 2013-01-23 |
| US20130005874A1 (en) | 2013-01-03 |
| SG184086A1 (en) | 2012-10-30 |
| JPWO2011114691A1 (ja) | 2013-06-27 |
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