CN103013715B - Transparent soap - Google Patents
Transparent soap Download PDFInfo
- Publication number
- CN103013715B CN103013715B CN201210556941.4A CN201210556941A CN103013715B CN 103013715 B CN103013715 B CN 103013715B CN 201210556941 A CN201210556941 A CN 201210556941A CN 103013715 B CN103013715 B CN 103013715B
- Authority
- CN
- China
- Prior art keywords
- soap
- sodium
- salt
- transparent
- acid sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000344 soap Substances 0.000 title claims abstract description 85
- 239000001509 sodium citrate Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- 239000002253 acid Substances 0.000 claims description 38
- 159000000000 sodium salts Chemical class 0.000 claims description 35
- 239000011734 sodium Substances 0.000 claims description 33
- 229910052708 sodium Inorganic materials 0.000 claims description 33
- 239000003760 tallow Substances 0.000 claims description 31
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 28
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 21
- 229940038773 trisodium citrate Drugs 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 18
- 239000003346 palm kernel oil Substances 0.000 claims description 17
- 235000019865 palm kernel oil Nutrition 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000013543 active substance Substances 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 239000004519 grease Substances 0.000 claims description 8
- 238000007127 saponification reaction Methods 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000002075 main ingredient Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 3
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 5
- 239000000194 fatty acid Substances 0.000 abstract description 5
- 229930195729 fatty acid Natural products 0.000 abstract description 5
- 150000004665 fatty acids Chemical class 0.000 abstract description 5
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 abstract description 4
- 229910001425 magnesium ion Inorganic materials 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract description 3
- 229910001424 calcium ion Inorganic materials 0.000 abstract description 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- 239000002585 base Substances 0.000 description 13
- 239000011575 calcium Substances 0.000 description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
- 235000019832 sodium triphosphate Nutrition 0.000 description 8
- 229910052791 calcium Inorganic materials 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 5
- 238000007493 shaping process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 239000002085 irritant Substances 0.000 description 3
- 231100000021 irritant Toxicity 0.000 description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a transparent soap, which is mainly prepared by fatty acid, a transparent reagent, sodium citrate, a surfactant and deionized water, wherein the content of sodium citrate based on weight is 0.1-15%. The transparent soap has appropriate hardness and transparency; and the washing capability is not influenced by calcium ions and magnesium ions when in use.
Description
Technical field
The present invention relates to a kind of articles for washing, more specifically relate to a kind of transparent soap.
Background technology
Transparent soap is the large kind of one in soap, and along with the raising of living standards of the people, transparent soap highlights the quality, pure, attractive in appearance and senior of product with its transparency, day by day obtains liking of human consumer.Transparent soap commercially available at present generally adopts vacuum-drying and mechanical disruption explained hereafter, both after soap base having been carried out vacuum-drying, add appropriate amount of essence, tinting material, transparent base, sequestrant and special additive to mix, then form through mechanical disruption explained hereafter.But, there is certain defect in the transparent soap sold in the market, when washing for hard water, the calcium of sodium soap easily and in hard water, magnesium plasma are formed water insoluble and without the fatty acid calcium of washability and fatty acid magnesium (i.e. calcium, magnesium metallic soap), cause very large waste; Add the kind of essence, transparency that the consumption of essence, the instrument and supplies parameter of production all can affect soap.Therefore, usually can add the transparency that ethanol, glycerine, sorbyl alcohol and sucrose etc. improve transparent soaps, but this class transparent base need add certain amount just good transparent effect, but larger add-on can cause the hardness of transparent soap to decline, and affects machine-shaping.
Usually, transparent soap also adopts tripoly phosphate sodium STPP (STPP) as auxiliary agent, and play and help cleaning, chelating calcium and magnesium ion, have dispersion suspension effect to solids.But because tripoly phosphate sodium STPP is phosphorous assistant, phosphorus-containing wastewater is discharged into after in rivers and lakes, and the content of phosphorus in water can be made to increase, and eutrophication appears in water quality, has a strong impact on water quality.
Summary of the invention
For overcoming the defect existed in prior art, the object of the present invention is to provide a kind of transparent soap.This transparent soap has suitable hardness and transparency, and can not affect its washability because of calcium, magnesium ion in use.
The object of the invention is to be achieved through the following technical solutions, a kind of transparent soap, be prepared from primarily of sodium soap, transparent base, Trisodium Citrate, tensio-active agent and deionized water, wherein, the weight percent content of described Trisodium Citrate is 0.1 ~ 15%.
As an embodiment of the invention, the weight percent content of the main ingredient of described transparent soap is as follows:
Sodium soap 64 ~ 84%
Transparent base 0 ~ 15%
Trisodium Citrate 0.1 ~ 15%
Tensio-active agent 0 ~ 5%
Deionized water 10 ~ 24%.
Further, the weight percent content of the main ingredient of described transparent soap is as follows:
Sodium soap 69 ~ 79%
Transparent base 0 ~ 11%
Trisodium Citrate 5 ~ 10%
Tensio-active agent 0 ~ 2%
Deionized water 10 ~ 22%.
Further, the weight percent content of the main ingredient of described transparent soap is as follows:
Sodium soap 70 ~ 76%
Transparent base 5 ~ 11%
Trisodium Citrate 5 ~ 10%
Tensio-active agent 0 ~ 2%
Deionized water 11 ~ 18%.
In the present invention, on the basis of the components such as sodium soap, transparent base, tensio-active agent and deionized water, add appropriate Trisodium Citrate as auxiliary agent.In the inventive solutions, described Trisodium Citrate is current most important Citrate trianion, generates citric acid primarily of starchy material through fermentation, then produces with alkaloids neutralization, has following premium properties: (1) safety non-toxic performance.Owing to preparing the raw material basic source of Trisodium Citrate in grain, be thus perfectly safe reliable, can not harm be produced to human health.United Nations grain farmer and the World Health Organization measure do not impose any restrictions taking the photograph people its every day, can think that these product belong to No Poison.(2) there is biological degradability.Trisodium Citrate is after the water dilution that nature is a large amount of, and part becomes citric acid, and both coexist in same system.Citric acid and sodium citrate by oxygen in the water, heat, light, the action of bacteria and microorganisms, the biodegradation are likely to happen, the decomposition approach is generally by aconitic acid, itaconic acid, lemon acid yu, eventually turned into carbon dioxide and water, there is no other harmful material residues, and won't cause pollution to the environment.(3) there is complexing of metal ion ability.Trisodium Citrate is to Ca
2+, Mg
2+deng metal ion, there is good complex ability, to other metal ions, as Fe
2+plasma also has good complex ability, avoids Ca in hard water
2+, Mg
2+water-fast calcium, the magnesium metallic soap without washability is formed Deng metal ion and sodium soap.(4) fabulous solubility property, and solvability raises with water temperature and increases.(5) there is good pH regulator and shock-absorbing capacity.Trisodium Citrate is a kind of weak acid strong alkali salt, can form stronger pH buffer reagent with compatibility of citric acid, can control between 6.5 ~ 7.5 by the pH value of transparent soap, and making it can not be irritant to skin.(6) soap bar can be made to have better hardness, help shaping, improve the transparency of soap bar.In addition, Trisodium Citrate also has excellent retarding performance and stability.
Sodium soap grease carries out saponification reaction with sodium hydroxide and makes, and the grease for the production of transparent soap mainly contains: Tallow Inedible Grade, palm-kernel oil and Oleum Cocois.In the present invention, described sodium soap can be one or more the mixing in Tallow Inedible Grade acid sodium-salt, palm-kernel oil acid sodium-salt and cocinic acid sodium salt.
As an embodiment of the invention, described sodium soap is the mixture of Tallow Inedible Grade acid sodium-salt and palm-kernel oil acid sodium-salt, or the mixture of Tallow Inedible Grade acid sodium-salt and cocinic acid sodium salt.In order to regulate the zero pour of the fatty acid sodium soap of generation, can further, the mixture of described Tallow Inedible Grade acid sodium-salt and palm-kernel oil acid sodium-salt carries out saponification reaction by the grease of following weight percent and sodium hydroxide and makes:
Tallow Inedible Grade 75-85%
Palm-kernel oil 15-25%.
The mixture of described Tallow Inedible Grade acid sodium-salt and cocinic acid sodium salt carries out saponification reaction by the grease of following weight percent and sodium hydroxide and makes:
Tallow Inedible Grade 75-85%
Oleum Cocois 15-25%.
In the present invention, described transparent base is one or both and two or more composition in glycerine, ethanol, sucrose, sorbyl alcohol, propylene glycol, polyoxyethylene glycol.
In the present invention, described tensio-active agent is one in polyoxyethylenated alcohol sodium sulfate (AES), fatty alcohol-polyoxyethylene ether (AEO), alpha-olefin sodium sulfonate (AOS), linear alkylbenzene sulphonic acid salt (LAS) or two kinds and two or more composition.Described fatty alcohol-polyoxyethylene ether is AEO-7 or AEO-9.
Component of the present invention also comprises oxidation inhibitor, and its weight percent content is 0.02-0.05%.Described oxidation inhibitor adopts 2,6 di tert butyl 4 methyl phenol (BHT) etc.
The present invention also can add appropriate essence, to make transparent toilet soap.Particularly, the weight percent content of described essence is 1-1.8%.
The present invention compared with prior art has the following advantages:
1. the present invention is except comprising on the basis of the components such as sodium soap, transparent base, tensio-active agent and deionized water, also including content is that the Trisodium Citrate of transparent soap total weight percent 0.1-15% is as washing auxiliary detergent, with chelating and the function increasing transparent soap transparency, and tripoly phosphate sodium STPP (STPP) auxiliary agent function can be efficiently replaced and don't can environmental pollution be caused; And can adjust ph control between 6.5-7.5 again, so can not be irritant to skin; The hardness of transparent soap can also be improved simultaneously, make it better shaping, enhance the transparency.
Trisodium Citrate can with the metal ion-chelant such as calcium, magnesium ion, the generation of calcium, magnesium metallic soap can be avoided, ensure the scourability of transparent soap.Trisodium Citrate has excellent retarding performance and stability, can increase the usage quantity of transparent base, improves the transparency of soap, ensures the hardness of soap simultaneously, help shaping, improves use properties.In addition, Trisodium Citrate is a kind of weak acid strong alkali salt, after water dilution, part becomes citric acid, make Trisodium Citrate and citric acid coexist in same system, pH scope can be made to regulate between 2-10, therefore also serve the effect of pH adjusting agent, can the pH value of transparent soap be controlled between 6.5 ~ 7.5, make this transparent soap can not be irritant to skin.
2. the present invention is using sodium soap as soap base, sodium soap described in this sodium soap adopts can be one or more the mixing in Tallow Inedible Grade acid sodium-salt, palm-kernel oil acid sodium-salt and cocinic acid sodium salt, wherein, Tallow Inedible Grade acid sodium-salt and cocinic acid sodium salt can take the transparent feel of perfumed soap out of, and palm-kernel sodium oleate then can make transparent soap hard.
3. transparent soap of the present invention has high-clarity, good oxidation-resistance, durable, and foam is fine and smooth.
Embodiment
Sodium soap as soap base can be the mixture of Tallow Inedible Grade acid sodium-salt and palm-kernel oil acid sodium-salt, also can be the mixture of Tallow Inedible Grade acid sodium-salt and cocinic acid sodium salt.In order to regulate the zero pour of the fatty acid sodium soap of generation, in following examples, the mixture of Tallow Inedible Grade acid sodium-salt and palm-kernel oil acid sodium-salt carries out saponification reaction by the grease of following weight percent and sodium hydroxide and makes:
Tallow Inedible Grade 75-85%
Palm-kernel oil 15-25%.
The mixture of Tallow Inedible Grade acid sodium-salt and cocinic acid sodium salt carries out saponification reaction by the grease of following weight percent and sodium hydroxide and makes:
Tallow Inedible Grade 75-85%
Oleum Cocois 15-25%.
making method is as follows:
(1) get Tallow Inedible Grade and palm-kernel oil according to the above ratio, or get Tallow Inedible Grade and Oleum Cocois obtains soap base-sodium soap by soapmaking industry ordinary method, obtain through vacuum-drying the neat soap A that dry soap content is 80%;
(2) neat soap A is added in blending bin with glycerine, ethanol, sucrose, Trisodium Citrate, LAS, AES, AEO-9, deionized water mix;
(3) BHT essence is dissolved to add in blending bin mix;
(4) material will be mixed introduce after three Kun machines carry out grinding twice and enter the extruding of spiral shaping pump, then sieve with screen cloth;
(5) soap bar refined is entered vacuum transport belt, vacuum tightness is about about 40cmHg;
(6) cutting is positioned with rotary chain cutter;
(7) stamping.
Wherein
The sodium soap of embodiment 1 is followed in sodium hydroxide by above-mentioned steps 1 with 75% Tallow Inedible Grade and 25% palm-kernel oil and obtains;
The sodium soap of embodiment 2 is followed in sodium hydroxide by above-mentioned steps 1 with 85% Tallow Inedible Grade and 15% palm-kernel oil and obtains;
The sodium soap of embodiment 3 is followed in sodium hydroxide by above-mentioned steps 1 with 80% Tallow Inedible Grade and 20% Oleum Cocois and obtains;
The sodium soap of embodiment 4 is followed in sodium hydroxide by above-mentioned steps 1 with 85% Tallow Inedible Grade and 15% Oleum Cocois and obtains;
The sodium soap of embodiment 5 is followed in sodium hydroxide by above-mentioned steps 1 with 75% Tallow Inedible Grade and 25% Oleum Cocois and obtains;
The sodium soap of embodiment 6 is followed in sodium hydroxide by above-mentioned steps 1 with 78% Tallow Inedible Grade and 22% palm-kernel oil and obtains.
Above embodiment is only for setting forth the present invention, and protection scope of the present invention is not only confined to above embodiment.The those of ordinary skill of described technical field, according to above content disclosed by the invention and scope that each parameter is got, all can realize object of the present invention.In the present invention, do not add oxidation inhibitor to be fine yet.
Claims (2)
1. a Transparent Soap, is characterized in that, is prepared from primarily of the sodium soap of following weight percent content, transparent base, Trisodium Citrate, tensio-active agent and deionized water:
Sodium soap 69 ~ 79%
Transparent base 0 ~ 11%, and be not equal to zero
Trisodium Citrate 5 ~ 10%
Tensio-active agent 0 ~ 2%
Deionized water 10 ~ 22%.
2. Transparent Soap according to claim 1, is characterized in that, the weight percent content of the main ingredient of described transparent soap is:
Sodium soap 70 ~ 76%
Transparent base 5 ~ 11%
Trisodium Citrate 5 ~ 10%
Tensio-active agent 0 ~ 2%
Deionized water 11 ~ 18%.
3. Transparent Soap according to claim 1 and 2, is characterized in that, described component also comprises oxidation inhibitor, and its weight percent content is 0.02-0.05%.
4. Transparent Soap according to claim 1 and 2, is characterized in that, described sodium soap is one or more the mixing in Tallow Inedible Grade acid sodium-salt, palm-kernel oil acid sodium-salt and cocinic acid sodium salt.
5. Transparent Soap according to claim 1 and 2, is characterized in that, described sodium soap is the mixture of Tallow Inedible Grade acid sodium-salt and palm-kernel oil acid sodium-salt, or is the mixture of Tallow Inedible Grade acid sodium-salt and cocinic acid sodium salt.
6. Transparent Soap according to claim 5, is characterized in that, the mixture of described Tallow Inedible Grade acid sodium-salt and palm-kernel oil acid sodium-salt carries out saponification reaction by the grease of following weight percent and sodium hydroxide and makes:
Tallow Inedible Grade 75-85%
Palm-kernel oil 15-25%;
The mixture of described Tallow Inedible Grade acid sodium-salt and cocinic acid sodium salt carries out saponification reaction by the grease of following weight percent and sodium hydroxide and makes:
Tallow Inedible Grade 75-85%
Oleum Cocois 15-25%.
7. Transparent Soap according to claim 1 and 2, is characterized in that, described transparent base is one or both and two or more composition in glycerine, ethanol, sucrose, sorbyl alcohol, propylene glycol, polyoxyethylene glycol; Described tensio-active agent is one in AES, AEO-7, AEO-9, AOS, LAS or two kinds and two or more composition.
8. Transparent Soap according to claim 1 and 2, is characterized in that, also comprises the essence that weight percent content is 1-1.8%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210556941.4A CN103013715B (en) | 2012-12-20 | 2012-12-20 | Transparent soap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210556941.4A CN103013715B (en) | 2012-12-20 | 2012-12-20 | Transparent soap |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103013715A CN103013715A (en) | 2013-04-03 |
| CN103013715B true CN103013715B (en) | 2015-04-22 |
Family
ID=47962833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210556941.4A Expired - Fee Related CN103013715B (en) | 2012-12-20 | 2012-12-20 | Transparent soap |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103013715B (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289838B (en) * | 2013-06-26 | 2014-09-24 | 深圳职业技术学院 | Litchi transparent soap and preparation method thereof |
| TW201500544A (en) * | 2013-06-28 | 2015-01-01 | Cho-Liang Tsai | Translucent soap base and application thereof |
| CN104327979A (en) * | 2014-10-09 | 2015-02-04 | 浙江农林大学 | Honeysuckle washing powder prepared from drainage oil and preparation method thereof |
| CN104629951B (en) * | 2015-03-03 | 2018-05-04 | 上海制皂有限公司 | Transparent toilet soap |
| CN104762146B (en) * | 2015-03-27 | 2017-11-03 | 榆林学院 | The method that transparent soap is prepared with radiation treatment gutter oil |
| CN104862152B (en) * | 2015-05-19 | 2018-07-06 | 上海制皂有限公司 | Mosquito-expelling scented soap |
| CN104928082A (en) * | 2015-06-18 | 2015-09-23 | 罗晓安 | Preparing method for composite type gentle and moistening soap base |
| CN105505637A (en) * | 2016-01-12 | 2016-04-20 | 洛阳和梦科技有限公司 | Environment-friendly sterilization type toilet soap |
| CN105886164A (en) * | 2016-05-31 | 2016-08-24 | 李咏梅 | Gold pomelo seed oil soap and preparing method thereof |
| CN108004064A (en) * | 2016-11-01 | 2018-05-08 | 深圳市科迪生物科技有限公司 | A kind of high transparency craft essential oil soap and preparation method thereof |
| CN106867725A (en) * | 2017-03-29 | 2017-06-20 | 广州明成龙海生物科技有限公司 | Vanilla essential oil nurses one's health soap and preparation method |
| CN106978288A (en) * | 2017-05-05 | 2017-07-25 | 陈磊 | A kind of handmade soap containing Composition of Meteorite and preparation method thereof |
| CN107384648A (en) * | 2017-07-31 | 2017-11-24 | 安庆华威油脂科技有限公司 | A kind of germicidal soaps |
| CN107418797A (en) * | 2017-07-31 | 2017-12-01 | 安庆华威油脂科技有限公司 | A kind of easily rinsing antimicrobial soap |
| CN107760500B (en) * | 2017-09-11 | 2020-03-10 | 上海制皂有限公司 | Full transparent soap with antibacterial function |
| CN107974369B (en) * | 2017-10-12 | 2020-08-28 | 广州丹葶日用品实业有限公司 | Coconut soap and preparation method thereof |
| CN107955754A (en) * | 2017-11-20 | 2018-04-24 | 江门市蓬江区新科美日用工艺品厂有限公司 | A kind of antibacterial mite-removing perfumed soap |
| CN109825390A (en) * | 2019-03-05 | 2019-05-31 | 桂林理工大学 | A kind of handmade soap of the alcohol extracting thing of Enteromorpha containing intestines, soap lye and preparation method thereof |
| CN109777676A (en) * | 2019-03-18 | 2019-05-21 | 惠州市旭东实业有限公司 | A kind of craft facial soap |
| CN111423943B (en) * | 2020-04-09 | 2021-09-07 | 包头市红卫皂业有限公司 | Eucalyptus oil sterilization body-protecting soap |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1157632A (en) * | 1994-08-03 | 1997-08-20 | 普罗克特和甘保尔公司 | Transparent personal cleansing bar |
| CN102787037A (en) * | 2012-08-28 | 2012-11-21 | 广西奥奇丽股份有限公司 | Transparent soap |
-
2012
- 2012-12-20 CN CN201210556941.4A patent/CN103013715B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1157632A (en) * | 1994-08-03 | 1997-08-20 | 普罗克特和甘保尔公司 | Transparent personal cleansing bar |
| CN102787037A (en) * | 2012-08-28 | 2012-11-21 | 广西奥奇丽股份有限公司 | Transparent soap |
Non-Patent Citations (3)
| Title |
|---|
| 《机制透明皂》;胡佩红等;《日用化学工业》;20000228(第1期);第41-42页 * |
| 《透明皂的生产工艺及开发》;庄凤英;《福建化工》;20011231(第4期);第42页 * |
| 王云琴等.《复合皂》.《化妆品与化妆实用指南》.兵器工业出版社,1993,(第1版),第199页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103013715A (en) | 2013-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103013715B (en) | Transparent soap | |
| CN103642602B (en) | A kind of liquid detergent | |
| DE2161768A1 (en) | Builder mixtures | |
| CN101624559B (en) | Neutral soap | |
| KR20160061771A (en) | Dishwashing detergent composition comprising spinach extract and manufacturing method thereof | |
| CN102115696B (en) | Non-phosphate liquid detergent and preparation method thereof | |
| CN103520022B (en) | A kind of bacteriostatic hand sanitizer and preparation method thereof | |
| CN102198059B (en) | Novel cleaning material | |
| CN105039014A (en) | Essential oil condensation beads for washing clothes and preparing method thereof | |
| CN103725439B (en) | A kind of preparation method of liquid detergent | |
| CN102167997A (en) | Preservative-free natural disinfecting detergent composition | |
| CN103289832A (en) | Sodium lauryl sulfate decontamination agent and preparation method thereof | |
| CN103756802B (en) | Preparation method of efficient sterilization safe detergent | |
| KR20110019118A (en) | Liquid detergent composition | |
| CN1086198C (en) | Multifunctional concentrated phosphorus-free liquid detergent | |
| CN102732397B (en) | Boric acid decontamination soap | |
| CN101463305B (en) | Neutral non-sulfonic acid liquid detergent | |
| CN103695217A (en) | Tea saponin washing soap | |
| CN101514314B (en) | Transparent neutral laundry detergent containing high-concentration chelating agent and preparation method thereof | |
| CN105039012A (en) | Clothes washing agent | |
| KR20190002076A (en) | Baby detergents containing rosewater and natural water and meethods of making | |
| CN102115695B (en) | Environmentally-friendly phosphorous-free washing cream and preparation method thereof | |
| MXPA06005631A (en) | Improved low ph detergent composition. | |
| CN107937159B (en) | Low-viscosity super-concentrated fruit-vegetable tableware detergent composition and preparation method thereof | |
| CN102994243B (en) | Washing powder containing mineral ions and method for preparing same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20181120 Granted publication date: 20150422 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20190322 Granted publication date: 20150422 |
|
| PD01 | Discharge of preservation of patent | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20190322 Granted publication date: 20150422 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20220322 Granted publication date: 20150422 |
|
| PD01 | Discharge of preservation of patent | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150422 Termination date: 20191220 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |