CN102115696B - Non-phosphate liquid detergent and preparation method thereof - Google Patents
Non-phosphate liquid detergent and preparation method thereof Download PDFInfo
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- CN102115696B CN102115696B CN 201010032407 CN201010032407A CN102115696B CN 102115696 B CN102115696 B CN 102115696B CN 201010032407 CN201010032407 CN 201010032407 CN 201010032407 A CN201010032407 A CN 201010032407A CN 102115696 B CN102115696 B CN 102115696B
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Abstract
The invention provides a non-phosphate liquid detergent and a preparation method thereof. Currently, the sodium tripolyphosphate is the builder which is mostly used, the sodium tripolyphosphate has the main defect that the sodium tripolyphosphate contains the phosphate, and the sewage is discharged into the water body to perform the eutrophication to the water body, deteriorate the water quality, and seriously endanger the living environment and the life safety of human body. The non-phosphate liquid detergent comprises sodium dodecyl benzene sulfonate, oxidized corn starch, fatty alcohol-polyoxyethylene ether, coconut oleic acid di-glycollic amide, polyoxyethylene fatty alcohol sodium sulfate, triethanolamine, sodium silicate, additive and water, wherein the components have the parts by weight: 8-12 parts of the sodium dodecyl benzene sulfonate, 10-12 parts of the oxidized corn starch, 3-5 parts of the fatty alcohol-polyoxyethylene ether, 2-4 parts of the coconut oleic acid di-glycollic amide, 2-4 parts of the polyoxyethylene fatty alcohol sodium sulfate, 2-3 parts of the triethanolamine, 1-3 parts of vsodium silicate, 1-2 parts of the additive and 55-71 parts of the water. The non-phosphate liquid detergent is a non-phosphate cleaning product.
Description
Technical field:
The present invention relates to a kind of articles for washing, the spy relates to a kind of phosphate-free liquid detergent and preparation method thereof fully.
Background technology:
Present liquid washing agent is made up of tensio-active agent and washing assistant etc., tripoly phosphate sodium STPP is to use maximum a kind of washing assistants, its main shortcoming is phosphorous, sewage is discharged in the water body can cause body eutrophication, cause water quality deterioration, serious harm existent environment of people and life security.
Summary of the invention:
The purpose of this invention is to provide a kind of phosphate-free liquid detergent and preparation method thereof, can reduce the infringement to human body skin, solve the environmental issue that phosphorus pollutes, and reduce production costs.
Above-mentioned purpose realizes by following technical scheme:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its parts by weight are: Sodium dodecylbenzene sulfonate 8-12 part, oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part, water glass 1-3 part, additive 1-2 part, water 55-71 part.
A kind of phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its parts by weight are: Sodium dodecylbenzene sulfonate 8-12 part, oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part, water glass 1-3 part, 2-5 part α-sodium olefin sulfonate, additive 1-2 part, water 55-71 part.
Described phosphate-free liquid detergent, described additive comprises: essence, white dyes, Varion CDG-K, the ratio of weight and number between the described additive is: essence 0.1-0.5 part: white dyes 0.1-0.5 part: Varion CDG-K 1-2 part.
A kind of preparation method of phosphate-free liquid detergent is characterized in that: this method comprises the steps:
(1) by weight with oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part mixing;
(2) under agitation slowly Sodium dodecylbenzene sulfonate 8-12 part is added in the water of 95 ℃ of 55-71 parts, slowly add the dissolving of water glass 1-3 part again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1-2 part additive is joined in the mixture of step (3), the ratio of weight and number between the described additive is: essence 0.1-0.5 part: white dyes 0.1-0.5 part: Varion CDG-K 1-2 part;
(5) cooling, packing.
A kind of preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight with oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part mixing;
(2) under agitation slowly Sodium dodecylbenzene sulfonate 8-12 part and 2-5 part α-sodium olefin sulfonate are added in the water of 95 ℃ of 55-71 parts, slowly add the dissolving of water glass 1-3 part again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1-2 part additive is joined in the mixture of step (3), the ratio of weight and number between the described additive is: essence 0.1-0.5 part: white dyes 0.1-0.5 part: Varion CDG-K 1-2 part;
(5) cooling, packing.
Beneficial effect:
1. the present invention substitutes poly-phosphate with W-Gum hydrolysis oxidation thing, reduces the infringement to human body skin, solves the environmental issue that phosphorus pollutes, and reduces production costs.
2. W-Gum hydrolysis oxidation thing is a kind of polysaccharide that contains carboxyl, metal ions such as calcium, magnesium there is stronger complex ability, but softening of water, improve washing effect, do not injure the skin of human body, with tensio-active agent good compound property is arranged, the without phosphorus washing cream soil removability of production is strong, high bubble color and luster is attractive in appearance, easy to use, is fit to the various clothings of washing.
3. W-Gum wide material sources, price is lower, and its hydrolysis oxidation production technique is simple, and cost is low, is a kind of washing assistant with synthetic detergent of better development prospect.
Embodiment:
Embodiment 1:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its ratio of weight and number is: 12 parts of Sodium dodecylbenzene sulfonatees, 12 parts of oxidised maize starch, 5 parts of fatty alcohol-polyoxyethylene ether, 4 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, 3 parts of water glass, 2 parts of additives, 71 parts in water.
Described phosphate-free liquid detergent, described additive comprises: essence, white dyes, Varion CDG-K, the ratio of weight and number between the additive is: 0.1 part in essence: 0.1 part of white dyes: 1.8 parts of Varion CDG-Ks.
Described phosphate-free liquid detergent, its composition also comprises: 5 parts of α-sodium olefin sulfonates, can further improve washing effect.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight with 12 parts of oxidised maize starch, 5 parts of fatty alcohol-polyoxyethylene ether, 4 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, mixing.
Also can add 5 parts of α-sodium olefin sulfonates;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in 71 parts of 95 ℃ of hot water for 12 parts, slowly add 3 parts of dissolvings of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Embodiment 2:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its ratio of weight and number is: 8 parts of Sodium dodecylbenzene sulfonatees, 10 parts of oxidised maize starch, 3 parts of fatty alcohol-polyoxyethylene ether, 2 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 2 parts of trolamines, 2 parts of water glass, 2 parts of additives, 60 parts in water.
Described phosphate-free liquid detergent, described additive comprises: essence, white dyes, Varion CDG-K, the ratio of weight and number between the additive is: 0.1 part in essence, 0.1 part of white dyes, 1.8 parts of Varion CDG-Ks.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight several parts with 10 parts of oxidised maize starch, 3 parts of fatty alcohol-polyoxyethylene ether, 2 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 2 parts of mixings of trolamine;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in the hot water for 8 parts, slowly add 2 parts of dissolvings of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Embodiment 3:
Phosphate-free liquid detergent, its composition comprises (parts by weight): 10 parts of Sodium dodecylbenzene sulfonatees, 12 parts of oxidised maize starch, 3 parts of fatty alcohol-polyoxyethylene ether, 2 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, 2 parts of water glass, 2 parts of additives, 60 parts in water.
Described phosphate-free liquid detergent, described additive comprises: essence, white dyes, Varion CDG-K, the ratio of weight and number between the additive is: 0.1 part in essence, 0.1 part of white dyes, 1.8 parts of Varion CDG-Ks.
Described phosphate-free liquid detergent, its composition can also comprise: 3 parts of α-sodium olefin sulfonates.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) with 12 parts of oxidised maize starch, 3 parts of fatty alcohol-polyoxyethylene ether, 2 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, 3 parts of mixing of α-sodium olefin sulfonate;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in 60 parts of 95 ℃ of hot water for 10 parts, slowly add 3 parts of dissolvings of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Embodiment 4:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its ratio of weight and number is: Sodium dodecylbenzene sulfonate 12, oxidised maize starch 10, fatty alcohol-polyoxyethylene ether 5, coconut acid diethanolamide 3, polyoxyethylenated alcohol sodium sulfate 2, trolamine 2, water glass 2,1 part of additive, 57.5 parts in water.
Described phosphate-free liquid detergent, described additive comprises: 0.1 part in essence, 0.1 part of white dyes, 1.8 parts of Varion CDG-Ks.
Described phosphate-free liquid detergent, its composition also comprises: 2 parts of α-sodium olefin sulfonates.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight with 10 parts of oxidised maize starch, 5 parts of fatty alcohol-polyoxyethylene ether, 3 parts of coconut acid diethanolamides, 2 parts of polyoxyethylenated alcohol sodium sulfate, 2 parts of trolamines, 2 parts of mixing of α-sodium olefin sulfonate;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in 57 parts of 95 ℃ of hot water for 12 parts, slowly add 2 parts of dissolvings of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Embodiment 5:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its ratio of weight and number is: 8 parts of Sodium dodecylbenzene sulfonatees, 12 parts of oxidised maize starch, 4 parts of fatty alcohol-polyoxyethylene ether, 4 parts of coconut acid diethanolamides, 3 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, 1 part of water glass, 1 part of additive, 57.5 parts in water.
Described phosphate-free liquid detergent, described additive comprises: 0.1 part in essence, 0.1 part of white dyes, 1.8 parts of Varion CDG-Ks.
Described phosphate-free liquid detergent, its composition also comprises: 2 parts of α-sodium olefin sulfonates.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight with 12 parts of oxidised maize starch, 4 parts of fatty alcohol-polyoxyethylene ether, 4 parts of coconut acid diethanolamides, 3 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, 2 parts of mixing of α-sodium olefin sulfonate;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in 57.5 parts of 95 ℃ of hot water for 8 parts, slowly add 1 part of dissolving of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Embodiment 6:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its ratio of weight and number is: 10 parts of Sodium dodecylbenzene sulfonatees, 12 parts of oxidised maize starch, 3 parts of fatty alcohol-polyoxyethylene ether, 2 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 2 parts of trolamines, 2 parts of water glass, 1 part of additive, 59 parts in water.
Described phosphate-free liquid detergent, described additive comprises: 0.1 part in essence, 0.1 part of white dyes, 1.8 parts of Varion CDG-Ks.
Described phosphate-free liquid detergent, its composition also comprises: 2 parts of α-sodium olefin sulfonates.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight with 12 parts of oxidised maize starch, 3 parts of fatty alcohol-polyoxyethylene ether, 2 parts of coconut acid diethanolamides, 4 parts of polyoxyethylenated alcohol sodium sulfate, 2 parts of trolamines, 2 parts of mixing of α-sodium olefin sulfonate;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in 57.5 parts of 95 ℃ of hot water for 10 parts, slowly add 1 part of dissolving of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Embodiment 7:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its ratio of weight and number is: 12 parts of Sodium dodecylbenzene sulfonatees, 10 parts of oxidised maize starch, 5 parts of fatty alcohol-polyoxyethylene ether, 3 parts of coconut acid diethanolamides, 2 parts of polyoxyethylenated alcohol sodium sulfate, 2 parts of trolamines, 2 parts of water glass, 1 part of additive, 59 parts in water.
Described phosphate-free liquid detergent, described additive comprises: 0.1 part in essence, 0.1 part of white dyes, 1.8 parts of Varion CDG-Ks.
Described phosphate-free liquid detergent, its composition also comprises: 2 parts of α-sodium olefin sulfonates.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight with 10 parts of oxidised maize starch, 5 parts of fatty alcohol-polyoxyethylene ether, 3 parts of coconut acid diethanolamides, 2 parts of polyoxyethylenated alcohol sodium sulfate, 2 parts of trolamines, 2 parts of mixing of α-sodium olefin sulfonate;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in 59 parts of 95 ℃ of hot water for 12 parts, slowly add 1 part of dissolving of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Embodiment 8:
Phosphate-free liquid detergent, its composition comprises: Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive, water, its ratio of weight and number is: 8 parts of Sodium dodecylbenzene sulfonatees, 12 parts of oxidised maize starch, 4 parts of fatty alcohol-polyoxyethylene ether, 4 parts of coconut acid diethanolamides, 3 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, 2 parts of water glass, 5 parts of α-sodium olefin sulfonates, 1 part of additive, 59 parts in water.
Described phosphate-free liquid detergent, described additive comprises: 0.1 part in essence, 0.1 part of white dyes, 1.8 parts of Varion CDG-Ks.
The preparation method of phosphate-free liquid detergent, this method comprises the steps:
(1) by weight with 12 parts of oxidised maize starch, 4 parts of fatty alcohol-polyoxyethylene ether, 4 parts of coconut acid diethanolamides, 3 parts of polyoxyethylenated alcohol sodium sulfate, 3 parts of trolamines, 5 parts of mixing of α-sodium olefin sulfonate;
(2) under agitation slowly Sodium dodecylbenzene sulfonate is added in 59 parts of 95 ℃ of hot water for 8 parts, slowly add 1 part of dissolving of water glass again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1.8 parts in 0.1 part in essence, 0.1 part of white dyes, Varion CDG-K is joined in the mixture of step (3);
(5) cooling, packing.
Claims (2)
1.
A kind of phosphate-free liquid detergent, by Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, additive and water are formed, and it is characterized in that: its parts by weight are: Sodium dodecylbenzene sulfonate 8-12 part, oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part, water glass 1-3 part, additive 1-2 part, water 55-71 part;
(1) by weight with oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part mixing;
(2) under agitation slowly Sodium dodecylbenzene sulfonate 8-12 part is added in the water of 95 ℃ of 55-71 parts, slowly add the dissolving of water glass 1-3 part again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1-2 part additive is joined in the mixture of step (3), the ratio of weight and number between the described additive is: essence 0.1-0.5 part: white dyes 0.1-0.5 part: Varion CDG-K 1-2 part;
(5) cooling, packing.
2.
A kind of phosphate-free liquid detergent, by Sodium dodecylbenzene sulfonate, oxidised maize starch, fatty alcohol-polyoxyethylene ether, coconut acid diethanolamide, polyoxyethylenated alcohol sodium sulfate, trolamine, water glass, α-sodium olefin sulfonate, additive and water are formed, and it is characterized in that: its parts by weight are: Sodium dodecylbenzene sulfonate 8-12 part, oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part, water glass 1-3 part, 2-5 part α-sodium olefin sulfonate, additive 1-2 part, water 55-71 part;
(1) by weight with oxidised maize starch 10-12 part, fatty alcohol-polyoxyethylene ether 3-5 part, coconut acid diethanolamide 2-4 part, polyoxyethylenated alcohol sodium sulfate 2-4 part, trolamine 2-3 part mixing;
(2) under agitation slowly Sodium dodecylbenzene sulfonate 8-12 part and 2-5 part α-sodium olefin sulfonate are added in the water of 95 ℃ of 55-71 parts, slowly add the dissolving of water glass 1-3 part again;
(3) mixture in the step (1) is poured into be stirred in the solution of step (2) evenly;
(4) 1-2 part additive is joined in the mixture of step (3), the ratio of weight and number between the described additive is: essence 0.1-0.5 part: white dyes 0.1-0.5 part: Varion CDG-K 1-2 part;
(5) cooling, packing.
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| CN 201010032407 CN102115696B (en) | 2010-01-05 | 2010-01-05 | Non-phosphate liquid detergent and preparation method thereof |
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| CN 201010032407 CN102115696B (en) | 2010-01-05 | 2010-01-05 | Non-phosphate liquid detergent and preparation method thereof |
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| CN102115696B true CN102115696B (en) | 2013-08-07 |
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| CN103635566B (en) * | 2012-09-25 | 2015-06-03 | 李代虹 | Environmentally-friendly phosphorus-free cleaning agent for toilet |
| CN103897841A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Textile washing agent |
| CN103146499A (en) * | 2013-03-01 | 2013-06-12 | 洛阳市柯莱尔清洗材料有限公司 | Cleaning agent for waste polyester bottle pieces |
| CN103205333A (en) * | 2013-04-17 | 2013-07-17 | 武汉创新资源环保循环有限公司 | Detergent and preparation method thereof |
| CN103255010B (en) * | 2013-04-17 | 2014-11-12 | 武汉创新资源环保循环有限公司 | Dishwashing liquid and preparation method thereof |
| CN103205332A (en) * | 2013-04-17 | 2013-07-17 | 武汉创新资源环保循环有限公司 | Liquid laundry detergent and preparation method thereof |
| CN103421618A (en) * | 2013-07-24 | 2013-12-04 | 洛阳市柯莱尔清洗材料有限公司 | Scrap cleaning agent for edible oil packaging container |
| CN103556166A (en) * | 2013-11-05 | 2014-02-05 | 黄学松 | Degreasing agent and preparation method thereof |
| CN104450275A (en) * | 2014-05-25 | 2015-03-25 | 南京正亮医药科技有限公司 | Collar detergent |
| CN105567462A (en) * | 2016-01-05 | 2016-05-11 | 王玉芹 | High efficient washing agent composition for washing textiles |
| CN108774603A (en) * | 2018-08-26 | 2018-11-09 | 郭烽燕 | A kind of mothproof liquid detergent |
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