CN102732397B - Boric acid decontamination soap - Google Patents
Boric acid decontamination soap Download PDFInfo
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- CN102732397B CN102732397B CN 201110083020 CN201110083020A CN102732397B CN 102732397 B CN102732397 B CN 102732397B CN 201110083020 CN201110083020 CN 201110083020 CN 201110083020 A CN201110083020 A CN 201110083020A CN 102732397 B CN102732397 B CN 102732397B
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Abstract
The invention discloses a boric acid decontamination soap, which consists of the following components, by weight: 20-60 parts of neat soap, 20-60 parts of lauryl sodium sulfate, 10-20 parts of sodium tripolyphosphate, 2-8 parts of fatty alcohol polyoxyethylene ether, and 0.05-2 parts of boric acid. The boric acid decontamination soap of the invention has excellent hard water resistance and foaming power, and excellent washing effect in hard water, especially in seawater. The boric acid decontamination soap of the invention can also be used for decontamination of radioactive substances on human skin and overalls, and is especially suitable for decontamination of radioactive substances attached to the common dirt; and decontamination for 3-5 times gains better scrubbing or cleaning effect.
Description
Technical field
The present invention relates to a kind of compound soap, relate in particular to a kind of boric acid decontamination soap.
Background technology
Along with the raising of people's level of consumption, traditional articles for washing soap can not satisfy the demands of consumers, and this mainly is because common soap has following shortcoming: 1) detersive power is relatively low; 2) anti-performance of hard water is poor, washing meeting and Ca in hard water
2+, Mg
2+Generation is not dissolved in the calcium magnesium metallic soap that water does not have washability again, make a large amount of soap forfeiture washabilities, cause waste, and the metallic soap that generates can mix the tedious soap scum of formation with dirt, be adsorbed in and be washed on fabric and the container, make fabric be difficult to rinsing, cause that the fabric yellowing is hardened, embrittlement, density goes down; 3) solubility property is poor in cold water, influences its detersive power.Therefore, be the range of application of expansion soap, give full play to the advantage of soap, employ new technology soap is carried out modification, thereby the exploitation compound soap there is its necessity.
Compound soap, English name composite soap is a kind of soap that contains tensio-active agent or lime soap dispersing agent based on fatty acid sodium salt.This compound soap can overcome the not shortcoming of anti-hard water of common soap, has certain detersive power.Its method for making is identical with common washing soap and perfumed soap with purposes, but can use in general hard water.
But also there is weak point in common compound soap, uses low, the anti-performance of hard water of common compound soap foaming power not good in seawater for coastal resident and seaman especially, is difficult to effectively remove dirt, has brought very big inconvenience to life.
Summary of the invention
The technical problem that the present invention solves provides a kind of boric acid decontamination soap, to overcome the above-mentioned defective that prior art exists.
A kind of boric acid decontamination soap, formed by weight by following component:
20～60 parts of neat soaps;
20～60 parts of sodium lauryl sulphate;
10～20 parts of tripoly phosphate sodium STPPs;
2～8 parts of fatty alcohol-polyoxyethylene ether;
0.05～2 part of boric acid.
Preferably, described fatty alcohol-polyoxyethylene ether, chemical formula is RO-(CH
2CH
2O)
n-H, R=C12-18 in the formula, n=6-18.
Preferably, described boric acid decontamination soap, formed by weight by following component:
20～40 parts of neat soaps;
40～60 parts of sodium lauryl sulphate;
12～18 parts of tripoly phosphate sodium STPPs;
3～6 parts of fatty alcohol-polyoxyethylene ether;
0.08～1.0 part of boric acid.
Preferably, described boric acid decontamination soap, formed by weight by following component:
20～60 parts of neat soaps;
20～60 parts of sodium lauryl sulphate;
10～20 parts of tripoly phosphate sodium STPPs;
2～8 parts of fatty alcohol-polyoxyethylene ether;
0.05～2 part of boric acid;
2～5 parts of organic phosphine acids complexing agents;
0.1～0.5 part of tetrasodium ethylenediamine tetraacetate.
Described organic phosphine acids complexing agent is selected from a kind of or its mixture in 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid, Amino Trimethylene Phosphonic Acid four sodium, ethylenediamine tetramethylene fork Alendronate, diethylene triamine pentamethylene phosphonic, diethylene triamine pentamethylene phosphonic five sodium, ethylene diamine tetra methylene phosphonic acid, ethylene diamine tetra methylene phosphonic acid five sodium and the polyamino polyether base methylenephosphonic acid.
Preferably, described organic phosphine acids complexing agent is mixed by weight by following component:
1～3 part in 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium;
3～5 parts in Amino Trimethylene Phosphonic Acid four sodium;
1～3 part in diethylene triamine pentamethylene phosphonic five sodium;
6～8 parts in ethylene diamine tetra methylene phosphonic acid five sodium.
Optimum, described organic phosphine acids complexing agent is mixed by weight by following component:
2 parts in 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium;
4 parts in Amino Trimethylene Phosphonic Acid four sodium;
2 parts in diethylene triamine pentamethylene phosphonic five sodium;
7 parts in ethylene diamine tetra methylene phosphonic acid five sodium.
Preferably, described boric acid decontamination soap, formed by weight by following component:
20～40 parts of neat soaps;
40～60 parts of sodium lauryl sulphate;
12～18 parts of tripoly phosphate sodium STPPs;
3～6 parts of fatty alcohol-polyoxyethylene ether;
0.08～1.0 part of boric acid;
3～4 parts of organic phosphine acids complexing agents;
0.2～0.4 part of tetrasodium ethylenediamine tetraacetate.
Boric acid decontamination soap of the present invention can adopt the general equipment of this soapmaking industry to produce, for example each raw material is added in the kneader, stir to pulverize and mix, it is even to be delivered to grinding machine for grinding again, again material is sent into press strip moulding in the vacuum plodder, can be made boric acid decontamination soap of the present invention.
Obviously, can also add conventional additives such as general acceptable essence, titanium dioxide, glycerine, whitening agent and antiseptic-germicide in the soap series products in the present invention.
Each starting material to related among the present invention of following mask body are made simple introduction:
Neat soap refers to vegetables oil or animal oil by obtaining soap base with the sodium hydroxide saponification reaction, and then soap base vacuum-drying can be produced that it is mainly used in preparing hard soap class cleaning supplies such as perfumed soap, washing soap, transparent soap, washing powder.Usually the fatty acid content in neat soap is 68～82%.
Sodium lauryl sulphate, chemical formula: C
12H
25SO
4Na, white or faint yellow powdery has decontamination, emulsification and excellent foaming power.It is a kind of nontoxic anion surfactant.
Tripoly phosphate sodium STPP, molecular formula Na
5P
3O
10, white powder, soluble in water, metal ions such as calcium magnesium there is significant sequestering power, the energy softening of water makes suspension become solution, and weakly alkaline is arranged, and non-corrosiveness is a kind of inorganics tensio-active agent, and lubricated oil ﹠ fat is had strong emulsifying effect.
Fatty alcohol-polyoxyethylene ether, English name: Alcohol Ethoxylate.Its chemical formula is RO-(CH
2CH
2O)
n-H, R=C12-18 in the formula, n=6-18.Fatty alcohol-polyoxyethylene ether belongs to nonionic surface active agent, and outward appearance is oyster white or beige ointment shape, when molecular weight is higher, is solid state, and soluble in water, ethanol, ethylene glycol etc. have cloud point, and 1% aqueous ph value is neutral.Acidproof, alkaline-resisting, the anti-hard water of energy, heat-resisting, anti-heavy metallic salt.Have good wet performance, and have emulsification preferably, dispersion, performance such as clean, can with various surfactants and dyestuff with molten use.
Boric acid, molecular formula: H
3BO
3, for white powder crystallization or three clinopinacoid flakey gloss crystallizations, satiny feel is arranged, no stink.In water-soluble, alcohol, glycerine, ethers and the volatile oil, the aqueous solution is slightly acidic.The sanitising agent that can be used as skin lesion, external application sterilant, sterilizing agent, astringent matter and sanitas.Various bacteria, mould all there is restraining effect.Action principle is that it can the amino in bacterioprotein be combined and plays a role.Can be used for irrigation and disinfections such as skin, mucous membrane, wound, oral cavity, vagina, bladder, also can be used for otitis, burn, scald, eczema etc.In addition, in the nuclear radiation, though neutron neutral, but have very strong penetration power, it can propagate farther distance in air and other material, the X ray of the hazard ratio same dose that human body is produced is even more serious, boric acid is a kind of material of big neutron-absorption cross-section, can absorb the neutron in the ray, thereby can play certain radiation protection.
Described organic phosphine acids complexing agent is selected from: 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid HEDP, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium HEDPNa4, Amino Trimethylene Phosphonic Acid ATMP, Amino Trimethylene Phosphonic Acid four sodium ATMPNa4, ethylenediamine tetramethylene fork Alendronate EDTMPS, diethylene triamine pentamethylene phosphonic DTPMPA, diethylene triamine pentamethylene phosphonic five sodium DTPMPNa5, ethylene diamine tetra methylene phosphonic acid EDTMPA, ethylene diamine tetra methylene phosphonic acid five sodium EDTMPNa5, polyamino polyether base methylenephosphonic acid PAPEMP.
1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, be called for short HEDPNa4, another name: hydroxy ethylene diphosphonic acid four sodium CAS No number: 3794-83-0 (4-Na), it is the tetra-na salt of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, it is the inhibitor of the calcium carbonate scale of excellence, white powder solid, soluble in water, nonhygroscopic, convenient transportation is applicable under the severe cold condition and uses.1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium belong to organic phospho acid salt anti-incrustation corrosion inhibitor, can form stable complex compound with multiple metal ions such as iron, copper, zinc.
Amino Trimethylene Phosphonic Acid four sodium, another name: Amino Trimethylene Phosphonic Acid four sodium, CAS number: 20592-85-2.Be the neutral sodium-salt of Amino Trimethylene Phosphonic Acid ATMP, can stop scaling salt class formation incrustation scale in the water.
Diethylene triamine pentamethylene phosphonic five sodium, CAS number: 68155-78-2, diethylene triamine pentamethylene phosphonic five sodium are a kind of neutral products, and are nontoxic, solid, very easily the moisture absorption is soluble in water.
Ethylene diamine tetra methylene phosphonic acid five sodium, another name: sodium ethylenediamine tetramethylenephosphonate, ethylene diamine tetramethyl fork Alendronate, CAS number: 7651-99-2.Be nitrogenous organic multicomponent phosphonate, belong to the cathode type inhibiter.Can be miscible with water, nontoxic pollution-free, chemical stability and temperature tolerance are good.
Tetrasodium ethylenediamine tetraacetate, English name: Ethylene diamine tetraacetic acid tetrasodium, the product another name is EDTA four sodium or EDTA tetra-na salt.Be white crystalline powder, water-soluble and sour, be insoluble to alcohol, benzene and trichloromethane.Tetrasodium ethylenediamine tetraacetate can generate inner complex with multiple metal ion effect, is a kind of effective metal ion chelation agent.
Boric acid decontamination soap of the present invention has excellent anti-hard water and foaming power, in hard water, and washing effect excellence in seawater particularly.
Boric acid decontamination soap of the present invention is mainly used in the decontamination that radioactive substance is infected with on human body skin and the working suit.Adopt extraordinary compound surfactant to have infiltration and humidification, increase the ability of complexing agent, be used in particular for being attached to the decontamination of the radiocontamination of common dirt.In seawater or fresh water, all can use, decontamination number of times 3～5 times, scouring or washing effect are better.In boric acid decontamination soap of the present invention, add boric acid, can absorb the neutron in the ray, thereby can promote anti-nuclear radiation performance.
Boric acid decontamination soap of the present invention meet GBZ 113-2002 People's Republic of China (PRC) country occupational health standard, GB 9662-88 ionizing rays accident action level and medical treatment principle and GB 4792 " Basic Health Standards for Radiological Protection " to the public take emergent protection countermeasure action level, be subjected to according to and body surface polluted personnel's medical treatment and the requirement of rebuilding the protection principle of works better order.
Further, be added with machine phosphonic acid class complexing agent and tetrasodium ethylenediamine tetraacetate in boric acid decontamination soap of the present invention, anti-performance of hard water is more excellent.Particularly, add the organic phosphine acids complexing agent of optimum ratio, further promoted the anti-performance of hard water of boric acid decontamination soap.
The invention will be further described below by embodiment, but embodiment does not limit protection scope of the present invention.
Embodiment
Embodiment 1:
Take by weighing each raw material by corresponding embodiment 1 in the table 1.
At normal temperatures and pressures, each raw material is added in the kneader, stirs pulverizing and mix, it is even that mixture is delivered to grinding machine for grinding, material sent into press strip moulding in the vacuum plodder again, namely obtains decontamination soap of the present invention after the cutting.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C14 in the formula, n=12.
Table 1: boric acid decontamination soap formula table unit: kilogram
| Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Neat soap | 40 | 20 | 60 |
| Sodium lauryl sulphate | 40 | 60 | 20 |
| Tripoly phosphate sodium STPP | 15 | 20 | 10 |
| Fatty alcohol-polyoxyethylene ether | 5 | 2 | 8 |
| Boric acid | 0.5 | 2 | 0.05 |
In the table 1, the grease prescription of neat soap is: 85wt% Tallow Inedible Grade and 15wt% Oleum Cocois, fatty acid content is 69% in the neat soap.
Embodiment 2:
Take by weighing each raw material by corresponding embodiment 2 in the table 1.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12 in the formula, n=6.
Embodiment 3:
Take by weighing each raw material by corresponding embodiment 3 in the table 1.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C18 in the formula, n=18.
Embodiment 4:
Take by weighing each raw material by corresponding embodiment 4 in the table 2.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12 in the formula, n=6.
Described organic phosphine acids complexing agent is 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid.
Embodiment 5:
Take by weighing each raw material by corresponding embodiment 5 in the table 2.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C18 in the formula, n=18.
Described organic phosphine acids complexing agent is Amino Trimethylene Phosphonic Acid four sodium.
Embodiment 6:
Take by weighing each raw material by corresponding embodiment 6 in the table 2.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12 in the formula, n=18.
Described organic phosphine acids complexing agent is diethylene triamine pentamethylene phosphonic.
Table 2: boric acid decontamination soap formula table unit: kilogram
| Raw material | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Neat soap | 40 | 20 | 60 |
| Sodium lauryl sulphate | 40 | 60 | 20 |
| Tripoly phosphate sodium STPP | 15 | 20 | 10 |
| Fatty alcohol-polyoxyethylene ether | 5 | 2 | 8 |
| Boric acid | 0.5 | 2 | 0.05 |
| Organic phosphine acids complexing agent | 3.5 | 2 | 5 |
| Tetrasodium ethylenediamine tetraacetate | 0.3 | 0.5 | 0.1 |
In the table 2, the grease prescription of neat soap is: 80wt% Tallow Inedible Grade and 20wt% Oleum Cocois, fatty acid content is 82% in the neat soap.
Embodiment 7:
Take by weighing each raw material by corresponding embodiment 7 in the table 3.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12 in the formula, n=9.
Described organic phosphine acids complexing agent is 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium.
Embodiment 8:
Take by weighing each raw material by corresponding embodiment 8 in the table 3.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12 in the formula, n=9.
Described organic phosphine acids complexing agent is the mixture of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid four sodium, diethylene triamine pentamethylene phosphonic five sodium and ethylene diamine tetra methylene phosphonic acid five sodium, wherein the mass ratio of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid four sodium, diethylene triamine pentamethylene phosphonic five sodium and ethylene diamine tetra methylene phosphonic acid five sodium=1: 5: 1: 8.
Embodiment 9:
Take by weighing each raw material by corresponding embodiment 9 in the table 3.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12 in the formula, n=9.
Described organic phosphine acids complexing agent is the mixture of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid four sodium, diethylene triamine pentamethylene phosphonic five sodium and ethylene diamine tetra methylene phosphonic acid five sodium, wherein the mass ratio of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid four sodium, diethylene triamine pentamethylene phosphonic five sodium and ethylene diamine tetra methylene phosphonic acid five sodium=3: 3: 3: 6.
Embodiment 10:
Take by weighing each raw material by corresponding embodiment 10 in the table 3.
Prepare boric acid decontamination soap according to embodiment 1 described method.
Described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12 in the formula, n=9.
Described organic phosphine acids complexing agent is the mixture of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid four sodium, diethylene triamine pentamethylene phosphonic five sodium and ethylene diamine tetra methylene phosphonic acid five sodium, wherein the mass ratio of 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid four sodium, diethylene triamine pentamethylene phosphonic five sodium and ethylene diamine tetra methylene phosphonic acid five sodium=2: 4: 2: 7.
Table 3: boric acid decontamination soap formula table unit: kilogram
| Raw material | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 |
| Neat soap | 20 | 20 | 20 | 20 |
| Sodium lauryl sulphate | 60 | 60 | 60 | 60 |
| Tripoly phosphate sodium STPP | 18 | 18 | 18 | 18 |
| Fatty alcohol-polyoxyethylene ether | 6 | 6 | 6 | 6 |
| Boric acid | 0.5 | 0.5 | 0.5 | 0.5 |
| Organic phosphine acids complexing agent | 4 | 4 | 4 | 4 |
| Tetrasodium ethylenediamine tetraacetate | 0.3 | 0.3 | 0.3 | 0.3 |
In the table 3, the grease prescription of neat soap is: 80wt% Tallow Inedible Grade and 20wt% Oleum Cocois, fatty acid content is 78% in the neat soap.
Test case 1: foaming power is measured
Boric acid decontamination soap to embodiment 1～10 preparation carries out foaming power mensuration.
By 5.5 mensuration foaming powers in the Chinese industry standard QB/T 2486-2008 washing soap.
Concrete data see table 4 for details.
Test case 2: anti-hard water degree is measured
Boric acid decontamination soap to embodiment 1～10 preparation carries out anti-hard water degree mensuration.
By the anti-hard water degree of 4.4 mensuration in the compound washing soap of Chinese industry standard QB/T 2487-2008.
Concrete data see table 4 for details.
The anti-hard water degrees of data of embodiment 7 and embodiment 8～10 in the comparison sheet 4, the unexpected discovery, by the optimum ratio to organic phosphine acids complexing agent, the anti-hard water degree of boric acid decontamination soap performance is improved a lot in the present invention, its mechanism is still waiting the contriver and further studies.
In a word, the present invention can also have multiple conversion and remodeling, is not limited to the concrete structure of above-mentioned embodiment, and protection scope of the present invention should comprise those apparent conversion or alternative and remodeling to those skilled in the art.
Table 4: foaming power and anti-hard water degree determination data table
Claims (5)
1. a boric acid decontamination soap is characterized in that, is made up of by weight following component:
20～60 parts of neat soaps;
20～60 parts of sodium lauryl sulphate;
10～20 parts of tripoly phosphate sodium STPPs;
2～8 parts of fatty alcohol-polyoxyethylene ether;
0.05～2 part of boric acid;
2～5 parts of organic phosphine acids complexing agents;
0.1～0.5 part of tetrasodium ethylenediamine tetraacetate;
Wherein, described organic phosphine acids complexing agent is selected from a kind of or its mixture in 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid, 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium, Amino Trimethylene Phosphonic Acid, Amino Trimethylene Phosphonic Acid four sodium, ethylenediamine tetramethylene fork Alendronate, diethylene triamine pentamethylene phosphonic, diethylene triamine pentamethylene phosphonic five sodium, ethylene diamine tetra methylene phosphonic acid, ethylene diamine tetra methylene phosphonic acid five sodium and the polyamino polyether base methylenephosphonic acid.
2. boric acid decontamination soap as claimed in claim 1, it is characterized in that: described fatty alcohol-polyoxyethylene ether, chemical formula are RO-(CH
2CH
2O)
n-H, R=C12-18 in the formula, n=6-18.
3. boric acid decontamination soap as claimed in claim 1 is characterized in that, described organic phosphine acids complexing agent is mixed by weight by following component:
1～3 part in 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium;
3～5 parts in Amino Trimethylene Phosphonic Acid four sodium;
1～3 part in diethylene triamine pentamethylene phosphonic five sodium;
6～8 parts in ethylene diamine tetra methylene phosphonic acid five sodium.
4. boric acid decontamination soap as claimed in claim 3 is characterized in that, described organic phosphine acids complexing agent is mixed by weight by following component:
2 parts in 1-Hydroxy Ethylidene-1,1-Diphosphonic Acid four sodium;
4 parts in Amino Trimethylene Phosphonic Acid four sodium;
2 parts in diethylene triamine pentamethylene phosphonic five sodium;
7 parts in ethylene diamine tetra methylene phosphonic acid five sodium.
5. as each described boric acid decontamination soap in the claim 1～4, it is characterized in that, formed by weight by following component:
20～40 parts of neat soaps;
40～60 parts of sodium lauryl sulphate;
12～18 parts of tripoly phosphate sodium STPPs;
3～6 parts of fatty alcohol-polyoxyethylene ether;
0.08～1.0 part of boric acid;
3～4 parts of organic phosphine acids complexing agents;
0.2～0.4 part of tetrasodium ethylenediamine tetraacetate.
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|---|---|---|---|
| CN 201110083020 CN102732397B (en) | 2011-04-02 | 2011-04-02 | Boric acid decontamination soap |
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| CN103805345A (en) * | 2014-02-25 | 2014-05-21 | 江苏紫石化工科技有限公司 | Sodium tripolyphosphate detergent |
| CN104629952B (en) * | 2015-03-03 | 2018-01-23 | 上海制皂有限公司 | Cold process soap |
| CN107151136A (en) * | 2017-05-17 | 2017-09-12 | 马鞍山起劲磁塑科技有限公司 | A kind of preparation method of high-quality injection strontium ferrite magnetic powder |
| CN111269761B (en) * | 2020-02-13 | 2021-04-27 | 金丝甲(上海)安全防范技术有限公司 | Decontamination liquid and application thereof in decontamination of actinide nuclide and transition metal nuclide pollution |
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| CN1257116A (en) * | 1999-12-16 | 2000-06-21 | 赵军强 | Medicated soap with functions of tonifying skin and disinfection |
| CN101475883A (en) * | 2009-01-19 | 2009-07-08 | 广东拉芳日化有限公司 | Sterilizing perfumed soap composition |
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