CN102887977A - 苯乙烯改性羧基丁腈胶乳的生产方法 - Google Patents
苯乙烯改性羧基丁腈胶乳的生产方法 Download PDFInfo
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- CN102887977A CN102887977A CN2011102071807A CN201110207180A CN102887977A CN 102887977 A CN102887977 A CN 102887977A CN 2011102071807 A CN2011102071807 A CN 2011102071807A CN 201110207180 A CN201110207180 A CN 201110207180A CN 102887977 A CN102887977 A CN 102887977A
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- reaction
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- vinylbenzene
- add
- latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 239000004816 latex Substances 0.000 title claims abstract description 32
- 229920000126 latex Polymers 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 22
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 230000000694 effects Effects 0.000 claims abstract description 3
- 229920000459 Nitrile rubber Polymers 0.000 claims description 21
- 230000009466 transformation Effects 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 7
- ZMESHQOXZMOOQQ-UHFFFAOYSA-N 1-(naphthalen-1-ylmethyl)naphthalene Chemical compound C1=CC=C2C(CC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 ZMESHQOXZMOOQQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000006073 displacement reaction Methods 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 235000017550 sodium carbonate Nutrition 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical group CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 239000000049 pigment Substances 0.000 abstract description 3
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 abstract description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 2
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 239000002174 Styrene-butadiene Substances 0.000 description 5
- 239000011115 styrene butadiene Substances 0.000 description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 239000004159 Potassium persulphate Substances 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical class [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- -1 phenylethene modified carboxyl butyronitrile Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201110207180.7A CN102887977B (zh) | 2011-07-22 | 2011-07-22 | 苯乙烯改性羧基丁腈胶乳的生产方法 |
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CN201110207180.7A CN102887977B (zh) | 2011-07-22 | 2011-07-22 | 苯乙烯改性羧基丁腈胶乳的生产方法 |
Publications (2)
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CN102887977A true CN102887977A (zh) | 2013-01-23 |
CN102887977B CN102887977B (zh) | 2014-05-21 |
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CN201110207180.7A Active CN102887977B (zh) | 2011-07-22 | 2011-07-22 | 苯乙烯改性羧基丁腈胶乳的生产方法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105237682A (zh) * | 2015-10-19 | 2016-01-13 | 杭州蓝诚实业有限公司 | 一种高性能羧基丁腈胶乳的制备方法 |
CN105418846A (zh) * | 2015-12-21 | 2016-03-23 | 安庆华兰科技有限公司 | 一种高强高耐磨丁腈手套用羧基丁腈胶乳的制备方法 |
CN106279536A (zh) * | 2016-08-20 | 2017-01-04 | 山东成泰化工有限公司 | 一种一次性手套用耐化学腐蚀丁腈胶乳及其制备方法 |
CN107163693A (zh) * | 2016-03-07 | 2017-09-15 | 姜大喆锡 | 用于吸收红外线的耐寒性涂布组合物 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1919885A (zh) * | 2005-08-23 | 2007-02-28 | 江苏省润阳胶粘剂厂 | 一种低分子量橡胶型改性剂聚合物的制备方法 |
CN101624433A (zh) * | 2009-08-07 | 2010-01-13 | 华东理工大学 | 一种热敏性共聚物胶乳及其制备方法和应用 |
-
2011
- 2011-07-22 CN CN201110207180.7A patent/CN102887977B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1919885A (zh) * | 2005-08-23 | 2007-02-28 | 江苏省润阳胶粘剂厂 | 一种低分子量橡胶型改性剂聚合物的制备方法 |
CN101624433A (zh) * | 2009-08-07 | 2010-01-13 | 华东理工大学 | 一种热敏性共聚物胶乳及其制备方法和应用 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105237682A (zh) * | 2015-10-19 | 2016-01-13 | 杭州蓝诚实业有限公司 | 一种高性能羧基丁腈胶乳的制备方法 |
CN105418846A (zh) * | 2015-12-21 | 2016-03-23 | 安庆华兰科技有限公司 | 一种高强高耐磨丁腈手套用羧基丁腈胶乳的制备方法 |
CN107163693A (zh) * | 2016-03-07 | 2017-09-15 | 姜大喆锡 | 用于吸收红外线的耐寒性涂布组合物 |
CN107163693B (zh) * | 2016-03-07 | 2019-08-23 | 姜大喆锡 | 用于吸收红外线的耐寒性涂布组合物 |
CN106279536A (zh) * | 2016-08-20 | 2017-01-04 | 山东成泰化工有限公司 | 一种一次性手套用耐化学腐蚀丁腈胶乳及其制备方法 |
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CN102887977B (zh) | 2014-05-21 |
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Owner name: SHANDONG JIULONG PETROCHEMICAL CO., LTD. Free format text: FORMER OWNER: SHANDONG JINZEYUAN INDUSTRY + TRADE CO., LTD. Effective date: 20140313 |
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CB03 | Change of inventor or designer information |
Inventor after: Yu Bo Inventor after: Wang Hongjun Inventor before: Han Xiaofeng Inventor before: Yu Bo Inventor before: Wang Hongjun Inventor before: Zhang Qi |
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Free format text: CORRECT: INVENTOR; FROM: HAN XIAOFENG YU BO WANG HONGJUN ZHANG QI TO: YU BO WANG HONGJUN |
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Effective date of registration: 20140313 Address after: Zhu Town Industrial Park of Linzi District of Shandong city in Zibo province 255400 Applicant after: SHANDONG JINZEYUAN INDUSTRY & TRADE CO., LTD. Address before: 255400, Linzi, Shandong District, Zibo province Zhu Taiwan Industrial Zone South Applicant before: Shandong Jinzeyuan Industry & Trade Co., Ltd. |
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Denomination of invention: Production method of styrene modified carboxylic butadiene-acrylonitrite latex Effective date of registration: 20200619 Granted publication date: 20140521 Pledgee: Qi commercial bank Limited by Share Ltd. Linzi branch Pledgor: SHANDONG JINZEYUAN INDUSTRY & TRADE Co.,Ltd. Registration number: Y2020980003253 |