CN102695741B - 具有季铵官能团的降冰片烯类聚合物 - Google Patents

具有季铵官能团的降冰片烯类聚合物 Download PDF

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Publication number
CN102695741B
CN102695741B CN201080055973.5A CN201080055973A CN102695741B CN 102695741 B CN102695741 B CN 102695741B CN 201080055973 A CN201080055973 A CN 201080055973A CN 102695741 B CN102695741 B CN 102695741B
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norbornene
alkyl
polymer
membrane
solution
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CN102695741A (zh
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A·贝尔
E·埃尔斯
K·塞托
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Sumitomo Bakelite Co Ltd
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Promerus LLC
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    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
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    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
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CN201080055973.5A 2009-12-11 2010-12-13 具有季铵官能团的降冰片烯类聚合物 Expired - Fee Related CN102695741B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US28399409P 2009-12-11 2009-12-11
US61/283,994 2009-12-11
PCT/US2010/060144 WO2011072304A2 (en) 2009-12-11 2010-12-13 Norbornene-type polymers having quaternary ammonium functionality
US12/966,768 US8765893B2 (en) 2009-12-11 2010-12-13 Norbornene-type polymers having quaternary ammonium functionality
US12/966,768 2010-12-13

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CN102695741A CN102695741A (zh) 2012-09-26
CN102695741B true CN102695741B (zh) 2015-07-08

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US (1) US8765893B2 (https=)
EP (1) EP2510036A2 (https=)
JP (1) JP5964236B2 (https=)
KR (1) KR20120123663A (https=)
CN (1) CN102695741B (https=)
WO (1) WO2011072304A2 (https=)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516256A (zh) * 2011-07-21 2012-06-27 沈阳药科大学 一种环氧异吲哚酮类衍生物的制备方法
JP2014084349A (ja) * 2012-10-22 2014-05-12 Nitto Denko Corp アニオン伝導性高分子電解質膜およびその製造方法ならびにそれを用いた膜電極接合体および燃料電池
US9223214B2 (en) 2012-11-19 2015-12-29 The Texas A&M University System Self-assembled structures, method of manufacture thereof and articles comprising the same
US9447220B2 (en) 2012-11-19 2016-09-20 Rohm And Haas Electronic Materials Llc Self-assembled structures, method of manufacture thereof and articles comprising the same
US9325037B2 (en) 2013-03-13 2016-04-26 Fluidic, Inc. Hetero-ionic aromatic additives for electrochemical cells comprising a metal fuel
US10078261B2 (en) * 2013-09-06 2018-09-18 Rohm And Haas Electronic Materials Llc Self-assembled structures, method of manufacture thereof and articles comprising the same
US9405189B2 (en) 2013-09-06 2016-08-02 Rohm And Haas Electronic Materials Llc Self-assembled structures, method of manufacture thereof and articles comprising the same
CN103923282B (zh) * 2014-01-08 2018-04-06 南开大学 含多金属氧酸盐‑倍半硅氧烷的共聚物及制备方法
TWI579333B (zh) * 2015-12-28 2017-04-21 財團法人工業技術研究院 離子交換膜
TWI583708B (zh) * 2015-12-28 2017-05-21 財團法人工業技術研究院 聚合物及其製備方法
CN106866497B (zh) * 2017-01-22 2019-05-14 中北大学 一种降冰片烯类化合物及其制备方法和应用
CN108341964B (zh) * 2017-01-23 2021-04-06 多氟多化工股份有限公司 一种功能聚合物、锂电池用聚合物电解质及制备方法、聚合物电解质膜、锂离子电池
CN108400347B (zh) * 2018-03-09 2021-02-09 新乡学院 一种交联型聚苯并咪唑质子交换膜的制备方法
WO2020073035A1 (en) * 2018-10-05 2020-04-09 Rensselaer Polytechnic Institute Preparation of ion exchange membranes from polyolefins and polycyclic olefins
CN111063931B (zh) * 2018-10-16 2021-02-05 多氟多化工股份有限公司 一种固态聚合物电解质及其应用
CN109535062B (zh) * 2019-01-10 2021-03-23 中北大学 一种降冰片烯类两性离子单体及其制备方法
US12037255B2 (en) * 2019-08-27 2024-07-16 ExxonMobil Technology and Engineering Company Zeolite syntheses using diquaternary structure directing agents
CN110746561A (zh) * 2019-11-07 2020-02-04 合肥工业大学 一种含多季铵阳离子基团的聚合物及其制备方法和应用
CN112928316A (zh) * 2019-12-05 2021-06-08 西安交通大学 一种高离子传导率、高机械性能的阴离子交换薄膜的制备方法
US11597784B2 (en) 2020-03-30 2023-03-07 Saudi Arabian Oil Company Enhanced yield, structural control, and transport properties of polynorbornenes for natural gas upgrading through Mizoroki-Heck cross-couplings
JP7637760B2 (ja) 2020-07-30 2025-02-28 プロメラス， エルエルシー 多環オレフィン重合体とそれに由来するアニオン交換膜
CN115591418B (zh) * 2022-12-14 2023-06-09 佛山(华南)新材料研究院 一种捕集二噁英的隔膜及其制备方法
TW202440749A (zh) 2022-12-20 2024-10-16 美商普羅梅勒斯有限公司 藉由熱和uv引發塊狀聚合之支撐膜
CN116031456B (zh) * 2023-01-06 2025-05-16 武汉大学 一种高稳定性碱性聚电解质及其制备方法
CN116217805B (zh) * 2023-01-07 2024-08-02 中北大学 一种降冰片烯基三铵类阳离子聚合物及其制备方法和应用
CN116284916B (zh) * 2023-02-23 2025-05-09 中北大学 一种聚降冰片烯类阴离子交换膜及其制备方法
CN116284691B (zh) * 2023-03-27 2023-11-17 天津大学 一种具有抑菌性高透明的离子型环烯烃共聚物及其制备方法
WO2025035152A2 (en) * 2023-08-10 2025-02-13 Cornell University Thermoset materials and methods of making and using same
CN119528846B (zh) * 2024-02-08 2025-10-10 北京清玮膜科技有限公司 一种聚降冰片烯基互穿聚合物网络交联阴离子交换膜及其制备方法和应用
CN119569997A (zh) * 2024-03-14 2025-03-07 北京清玮膜科技有限公司 离子型聚降冰片烯交联阴离子交换隔膜及其制备方法和应用

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5312940A (en) * 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
JPH10152523A (ja) * 1996-09-30 1998-06-09 Nippon Zeon Co Ltd アリル基変性ノルボルネン系重合体及びその製造方法
US7329758B1 (en) * 1999-05-24 2008-02-12 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
US6838489B2 (en) * 2001-03-23 2005-01-04 Cymetech, Llc High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor
JP4645787B2 (ja) * 2001-05-30 2011-03-09 Ｊｓｒ株式会社 液晶配向膜形成基板および液晶表示素子
CA2459384A1 (en) * 2001-10-10 2003-04-24 Jsr Corporation Norbornene derivative and norbornene polymer obtained therefrom through ring-opening polymerization
US20060020068A1 (en) * 2004-07-07 2006-01-26 Edmund Elce Photosensitive compositions based on polycyclic polymers for low stress, high temperature films
US6946362B2 (en) * 2002-09-06 2005-09-20 Hewlett-Packard Development Company, L.P. Method and apparatus for forming high surface area material films and membranes
EP1597627A4 (en) * 2003-02-20 2008-01-09 Promerus Llc RESOLUTION SPEED MODULATORS FOR PHOTORESISTAL COMPOSITIONS
JP4180404B2 (ja) * 2003-03-05 2008-11-12 アイシン精機株式会社 燃料電池、酸化剤配流板
EP1687830B1 (en) * 2003-11-28 2010-07-28 Merck Patent GmbH Organic semiconducting layer formulations comprising polyacenes and organic binder polymers
FR2863777B1 (fr) * 2003-12-16 2006-02-17 Commissariat Energie Atomique Pile a combustible alcaline insensible a la carbonatation.
GB0329812D0 (en) * 2003-12-23 2004-01-28 Amersham Plc Romp polymer synthesis
JP4503394B2 (ja) * 2004-08-13 2010-07-14 富士通株式会社 燃料電池システム及び電気機器、並びに、燃料電池システムにおける発生水の回収方法
US7875686B2 (en) * 2004-08-18 2011-01-25 Promerus Llc Polycycloolefin polymeric compositions for semiconductor applications
JP4993867B2 (ja) * 2005-03-07 2012-08-08 ダイハツ工業株式会社 燃料電池
WO2007084155A2 (en) * 2005-03-24 2007-07-26 The Regents Of The University Of California Anion-conducting polymer, composition, and membrane
US20070259236A1 (en) * 2006-05-03 2007-11-08 Lang Christopher M Anionic fuel cells, hybrid fuel cells, and methods of fabrication thereof
JP2008088247A (ja) * 2006-09-29 2008-04-17 Univ Of Tokyo フルオロスルホニル基を有するノルボルネン重合体の製造方法、スルホン酸基を有する重合体および該重合体を用いた燃料電池用電解質膜
CN101669225B (zh) * 2007-04-25 2013-03-13 默克专利股份有限公司 电子器件的制备方法
US20110250525A1 (en) * 2007-08-23 2011-10-13 Tokuyama Corporation Separation membrane for direct liquid fuel cell and method for producing the same
JP2009256654A (ja) * 2008-03-27 2009-11-05 Sumitomo Chemical Co Ltd 高分子電解質組成物
US8026041B2 (en) * 2008-04-02 2011-09-27 Eastman Kodak Company Imageable elements useful for waterless printing
EP2216683B1 (en) * 2009-02-08 2018-11-14 Rohm and Haas Electronic Materials, L.L.C. Substrates coated with an antireflective composition and a photoresist
US9493397B2 (en) 2009-05-29 2016-11-15 Cornell University Ionomers and methods of making same and uses thereof

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WO2011072304A3 (en) 2011-10-06
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