CN102666378B - 用碳纳米管通过接触碱金属制备的石墨烯纳米带 - Google Patents

用碳纳米管通过接触碱金属制备的石墨烯纳米带 Download PDF

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CN102666378B
CN102666378B CN201080034953.XA CN201080034953A CN102666378B CN 102666378 B CN102666378 B CN 102666378B CN 201080034953 A CN201080034953 A CN 201080034953A CN 102666378 B CN102666378 B CN 102666378B
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methods
graphene nanoribbons
metal
alkali metal
functionalized
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CN102666378A (zh
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J·M·图尔
D·V·科森金
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William Marsh Rice University
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20—Polycyclic condensed hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/19—Preparation by exfoliation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/194—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/06—Multi-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/06—Graphene nanoribbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/895—Manufacture, treatment, or detection of nanostructure having step or means utilizing chemical property
    • Y10S977/896—Chemical synthesis, e.g. chemical bonding or breaking

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
CN201080034953.XA 2009-06-15 2010-06-11 用碳纳米管通过接触碱金属制备的石墨烯纳米带 Expired - Fee Related CN102666378B (zh)

Applications Claiming Priority (3)

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US18713009P 2009-06-15 2009-06-15
US61/187,130 2009-06-15
PCT/US2010/038368 WO2010147860A1 (en) 2009-06-15 2010-06-11 Graphene nanoribbons prepared from carbon nanotubes via alkali metal exposure

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CN102666378B true CN102666378B (zh) 2017-03-01

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US (1) US8992881B2 (https=)
EP (1) EP2443062A4 (https=)
JP (1) JP5613230B2 (https=)
KR (1) KR101763224B1 (https=)
CN (1) CN102666378B (https=)
BR (1) BRPI1016033A2 (https=)
CA (1) CA2765492C (https=)
MX (1) MX2011013545A (https=)
SG (2) SG10201403233XA (https=)
WO (1) WO2010147860A1 (https=)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9193879B2 (en) 2010-02-17 2015-11-24 Baker Hughes Incorporated Nano-coatings for articles
BR112013008481A2 (pt) * 2010-10-06 2016-08-09 Mi Llc material baseado em grafeno para estabilização de xisto e método de uso
KR101300765B1 (ko) 2011-04-29 2013-08-29 한국교통대학교산학협력단 가용성 그라핀 용액의 제조방법
US9040013B2 (en) * 2011-08-04 2015-05-26 Baker Hughes Incorporated Method of preparing functionalized graphene
US9428383B2 (en) 2011-08-19 2016-08-30 Baker Hughes Incorporated Amphiphilic nanoparticle, composition comprising same and method of controlling oil spill using amphiphilic nanoparticle
MX2014003058A (es) * 2011-09-14 2014-04-30 Univ Rice William M Metodos basados en solventes para la produccion de nanocintas de grafeno.
KR102514830B1 (ko) 2011-09-30 2023-03-30 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극, 리튬 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전기 기기
KR20140095062A (ko) 2011-10-21 2014-07-31 유니버시티 오브 유타 리서치 파운데이션 균질한 다중 밴드 갭 디바이스
WO2013093756A1 (en) * 2011-12-20 2013-06-27 Basf Se Polymeric precursors for producing graphene nanoribbons and methods for preparing them
US9441462B2 (en) 2012-01-11 2016-09-13 Baker Hughes Incorporated Nanocomposites for absorption tunable sandscreens
CN104520946A (zh) * 2012-01-27 2015-04-15 威廉马歇莱思大学 磁性碳纳米带和磁性功能化碳纳米带的合成
CN102616770B (zh) * 2012-03-28 2013-08-07 福州大学 一种水蒸气刻蚀碳纳米管制备石墨烯纳米带的方法
WO2013143147A1 (zh) * 2012-03-31 2013-10-03 海洋王照明科技股份有限公司 一种石墨烯纸的制备方法
JP6077347B2 (ja) 2012-04-10 2017-02-08 株式会社半導体エネルギー研究所 非水系二次電池用正極の製造方法
US9527043B2 (en) 2012-05-17 2016-12-27 Samsung Electronics Co., Ltd. Gas separation membrane and method of preparing the same
KR101920716B1 (ko) * 2012-05-17 2019-02-13 삼성전자주식회사 기체 분리막 및 그 제조방법
US20140004327A1 (en) * 2012-06-29 2014-01-02 The University Of Kentucky Research Foundation Few-layer graphene nanoribbon and a method of making the same
CN102757043B (zh) * 2012-08-10 2014-07-02 中国科学院苏州纳米技术与纳米仿生研究所 一种制备定向石墨烯纳米带阵列的方法
JP6207923B2 (ja) 2012-08-27 2017-10-04 株式会社半導体エネルギー研究所 二次電池用正極の製造方法
TW201431902A (zh) * 2012-11-16 2014-08-16 巴斯夫歐洲公司 用以生產石墨烯奈米帶之聚合前驅物，以及適用於製備彼等之寡伸苯基單體
CN103833023B (zh) * 2012-11-27 2015-10-28 海洋王照明科技股份有限公司 石墨烯纳米带及其制备方法
US8580658B1 (en) 2012-12-21 2013-11-12 Solan, LLC Methods for fabricating graphene device topography and devices formed therefrom
US10468152B2 (en) * 2013-02-21 2019-11-05 Global Graphene Group, Inc. Highly conducting and transparent film and process for producing same
US8664642B1 (en) 2013-03-15 2014-03-04 Solan, LLC Nonplanar graphite-based devices having multiple bandgaps
US9059013B2 (en) 2013-03-21 2015-06-16 International Business Machines Corporation Self-formation of high-density arrays of nanostructures
TWI529128B (zh) * 2013-08-19 2016-04-11 長庚大學 連續微波製作石墨烯奈米帶之系統
WO2015189335A1 (en) * 2014-06-12 2015-12-17 Centre National De La Recherche Scientifique - Cnrs - Aqueous and organic suspensions of exfoliated nanocarbon materials, method for making same and uses thereof
US9840418B2 (en) * 2014-06-16 2017-12-12 William Marsh Rice University Production of graphene nanoplatelets by oxidative anhydrous acidic media
WO2016133571A2 (en) * 2014-11-26 2016-08-25 William Marsh Rice University Laser induced graphene hybrid materials for electronic devices
US11772975B2 (en) * 2015-12-03 2023-10-03 Global Graphene Group, Inc. Chemical-free production of graphene materials
CN105543991B (zh) * 2016-01-13 2018-06-01 郑州大学 一种螺旋结构石墨烯纤维及其制备方法和应用
CN106115675B (zh) * 2016-06-24 2018-04-17 中国科学院电工研究所 一种制备介孔石墨烯的方法
US11246962B2 (en) 2016-08-22 2022-02-15 William Marsh Rice University Neuronal scaffold-water soluble graphene for treatment of severed spinal cords and neuronal repair
US10707524B2 (en) 2016-10-19 2020-07-07 Semiconductor Energy Laboratory Co., Ltd. Graphene compound and manufacturing method thereof, electrolyte, and power storage device
JP6839355B2 (ja) * 2017-02-08 2021-03-10 富士通株式会社 グラフェンナノリボン、グラフェンナノリボンの製造方法及び半導体装置
CN107200947B (zh) * 2017-05-22 2019-08-20 成都新柯力化工科技有限公司 一种石墨烯微片导电母料及其制备方法
KR102170675B1 (ko) * 2017-06-23 2020-10-27 주식회사 엘지화학 탄소 나노튜브 섬유 집합체의 인장강도 향상 방법
US10465291B2 (en) * 2017-09-26 2019-11-05 California Institute Of Technology Method and system for growth of graphene nanostripes by plasma enhanced chemical vapor deposition
CN108190959B (zh) * 2018-01-23 2020-05-08 福州大学 一种基于熔融碱金属液插入剥离制备单层硫化钼的方法
CN108117064B (zh) * 2018-03-01 2021-07-09 上海理工大学 一种褶皱石墨烯的制备方法
CN108383110B (zh) * 2018-04-18 2020-01-10 天津大学 一种氟化石墨烯纳米带的制备方法
CN109835884B (zh) * 2019-03-27 2022-07-19 王奉瑾 一种利用液态金属碱制备石墨烯的方法
CN111039284A (zh) * 2020-01-17 2020-04-21 中山大学 一种超窄石墨烯纳米带的制备方法
JP2023178878A (ja) * 2022-06-06 2023-12-18 株式会社Ｇｓユアサ 負極活物質、負極及び非水電解質蓄電素子
CN115650213A (zh) * 2022-06-28 2023-01-31 重庆大学 一种高单晶纯单层石墨烯纳米带阵列及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090029221A1 (en) * 2007-07-25 2009-01-29 Goddard William A Functional anchors connecting graphene-like carbon to metal

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006124055A2 (en) * 2004-10-12 2006-11-23 Nanosys, Inc. Fully integrated organic layered processes for making plastic electronics based on conductive polymers and semiconductor nanowires
TW201012749A (en) * 2008-08-19 2010-04-01 Univ Rice William M Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090029221A1 (en) * 2007-07-25 2009-01-29 Goddard William A Functional anchors connecting graphene-like carbon to metal

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Ex-MWNTs: Graphene Sheets andRibbons Produced by Lithium Intercalation and Exfoliation of Carbon Nanotubes;Abraham G.Cano-Ma´rquez,et al;《NANO LETTERS》;20090304;第9卷(第4期);1528页左栏最后一段至右栏第1段，1529页最后两段，1532页右栏第3段 *

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MX2011013545A (es) 2012-05-08
CA2765492C (en) 2018-01-02
JP2012530044A (ja) 2012-11-29
SG176826A1 (en) 2012-01-30
US20120197051A1 (en) 2012-08-02
EP2443062A1 (en) 2012-04-25
JP5613230B2 (ja) 2014-10-22
SG10201403233XA (en) 2014-10-30
CA2765492A1 (en) 2010-12-23
CN102666378A (zh) 2012-09-12
WO2010147860A1 (en) 2010-12-23
KR101763224B1 (ko) 2017-07-31
KR20120039634A (ko) 2012-04-25
BRPI1016033A2 (pt) 2016-05-10
EP2443062A4 (en) 2016-04-20
US8992881B2 (en) 2015-03-31

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