CN102603401A - High-potassium liquid organic fertilizer taking wood vinegar as matrix and production method thereof - Google Patents
High-potassium liquid organic fertilizer taking wood vinegar as matrix and production method thereof Download PDFInfo
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- CN102603401A CN102603401A CN2012100711288A CN201210071128A CN102603401A CN 102603401 A CN102603401 A CN 102603401A CN 2012100711288 A CN2012100711288 A CN 2012100711288A CN 201210071128 A CN201210071128 A CN 201210071128A CN 102603401 A CN102603401 A CN 102603401A
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- Prior art keywords
- potassium
- pyroligneous liquor
- organic fertilizer
- matrix
- acid
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Links
- 229910052700 potassium Inorganic materials 0.000 title claims abstract description 48
- 239000011591 potassium Substances 0.000 title claims abstract description 47
- 239000003895 organic fertilizer Substances 0.000 title claims abstract description 16
- 239000011159 matrix material Substances 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 239000007788 liquid Substances 0.000 title abstract description 10
- 235000021419 vinegar Nutrition 0.000 title abstract 6
- 239000000052 vinegar Substances 0.000 title abstract 6
- 239000002023 wood Substances 0.000 title abstract 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 42
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 27
- 150000001413 amino acids Chemical class 0.000 claims abstract description 20
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 14
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011574 phosphorus Substances 0.000 claims abstract description 13
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 11
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims abstract description 9
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002509 fulvic acid Substances 0.000 claims abstract description 9
- 229940095100 fulvic acid Drugs 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 238000011161 development Methods 0.000 claims abstract description 7
- 230000012010 growth Effects 0.000 claims abstract description 6
- 235000015097 nutrients Nutrition 0.000 claims abstract description 5
- 241000196324 Embryophyta Species 0.000 claims description 13
- 239000013543 active substance Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000005648 plant growth regulator Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 9
- 230000000050 nutritive effect Effects 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 239000004615 ingredient Substances 0.000 claims description 8
- 235000013305 food Nutrition 0.000 claims description 7
- 230000000536 complexating effect Effects 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 6
- 238000006386 neutralization reaction Methods 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000005416 organic matter Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 201000010099 disease Diseases 0.000 claims description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 229960002303 citric acid monohydrate Drugs 0.000 claims description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- SPFMQWBKVUQXJV-BTVCFUMJSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;hydrate Chemical compound O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O SPFMQWBKVUQXJV-BTVCFUMJSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 229960000673 dextrose monohydrate Drugs 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 210000004185 liver Anatomy 0.000 claims description 2
- 239000002773 nucleotide Substances 0.000 claims description 2
- 125000003729 nucleotide group Chemical group 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims 7
- BXMVKQIIJSXIBU-UHFFFAOYSA-N (2,5-dioxopyrrolidin-1-yl) diphenyl phosphate Chemical compound O=C1CCC(=O)N1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 BXMVKQIIJSXIBU-UHFFFAOYSA-N 0.000 claims 2
- 102000008186 Collagen Human genes 0.000 claims 2
- 108010035532 Collagen Proteins 0.000 claims 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- 108091005804 Peptidases Proteins 0.000 claims 2
- 108010073771 Soybean Proteins Proteins 0.000 claims 2
- 229920002494 Zein Polymers 0.000 claims 2
- 229920001184 polypeptide Polymers 0.000 claims 2
- 102000004196 processed proteins & peptides Human genes 0.000 claims 2
- 108090000765 processed proteins & peptides Proteins 0.000 claims 2
- 235000019710 soybean protein Nutrition 0.000 claims 2
- 239000005019 zein Substances 0.000 claims 2
- 229940093612 zein Drugs 0.000 claims 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims 1
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 claims 1
- 235000019743 Choline chloride Nutrition 0.000 claims 1
- POYYWDOFTRSMIX-UHFFFAOYSA-N FCC(=O)O.IC1=CC=CC=C1 Chemical compound FCC(=O)O.IC1=CC=CC=C1 POYYWDOFTRSMIX-UHFFFAOYSA-N 0.000 claims 1
- 241000238631 Hexapoda Species 0.000 claims 1
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 claims 1
- 102000035195 Peptidases Human genes 0.000 claims 1
- 239000004365 Protease Substances 0.000 claims 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 claims 1
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 claims 1
- 229960003178 choline chloride Drugs 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000012467 final product Substances 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 102000039446 nucleic acids Human genes 0.000 claims 1
- 108020004707 nucleic acids Proteins 0.000 claims 1
- 150000007523 nucleic acids Chemical class 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- NRHMKIHPTBHXPF-TUJRSCDTSA-M sodium cholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC([O-])=O)C)[C@@]2(C)[C@@H](O)C1 NRHMKIHPTBHXPF-TUJRSCDTSA-M 0.000 claims 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims 1
- 239000003337 fertilizer Substances 0.000 abstract description 21
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 11
- 239000002699 waste material Substances 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 5
- 239000012452 mother liquor Substances 0.000 abstract description 5
- 239000010902 straw Substances 0.000 abstract description 5
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 4
- 239000011573 trace mineral Substances 0.000 abstract description 3
- 235000013619 trace mineral Nutrition 0.000 abstract description 3
- 235000013311 vegetables Nutrition 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 238000003306 harvesting Methods 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 229940072033 potash Drugs 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- 235000015320 potassium carbonate Nutrition 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000002689 soil Substances 0.000 description 6
- 230000018109 developmental process Effects 0.000 description 5
- 239000010815 organic waste Substances 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000012827 research and development Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 208000019025 Hypokalemia Diseases 0.000 description 2
- 240000000111 Saccharum officinarum Species 0.000 description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
- -1 ammonium nitrate Citric acid monohydrate Chemical compound 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 208000007645 potassium deficiency Diseases 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- NAOLWIGVYRIGTP-UHFFFAOYSA-N 1,3,5-trihydroxyanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1 NAOLWIGVYRIGTP-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 208000018380 Chemical injury Diseases 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
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- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- URZQTUUFONXJPA-UHFFFAOYSA-L [O-]P([O-])(=O)OP(=O)(O)O.[K+].C(C1=CC=CC=C1)C1=C2NC=NC2=NC(=N1)N.[Na+] Chemical compound [O-]P([O-])(=O)OP(=O)(O)O.[K+].C(C1=CC=CC=C1)C1=C2NC=NC2=NC(=N1)N.[Na+] URZQTUUFONXJPA-UHFFFAOYSA-L 0.000 description 1
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- 239000003546 flue gas Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000009746 freeze damage Effects 0.000 description 1
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- 238000010413 gardening Methods 0.000 description 1
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- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000009335 monocropping Methods 0.000 description 1
- QEWYKACRFQMRMB-UHFFFAOYSA-N monofluoroacetic acid Natural products OC(=O)CF QEWYKACRFQMRMB-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
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- 239000001301 oxygen Substances 0.000 description 1
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- 239000000575 pesticide Substances 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a high-potassium liquid organic fertilizer taking wood vinegar as a matrix and a production method thereof. The high-potassium liquid organic fertilizer disclosed by the invention contains nitrogen, phosphorus, potassium, organic matters and amino acids. The production method comprises the following steps of: mixing biochemical fulvic acid potassium with the wood vinegar, adding potassium hydroxide, neutralizing with acid, finally sequentially adding raw materials containing nitrogen, phosphorus and potassium, a mixed solution of amino acids and auxiliaries, cooling and filling to get a finished product. The high-potassium liquid organic fertilizer disclosed by the invention has the following advantages: 1) the wood vinegar is taken as mother liquor, so that the penetration rate of the product is enhanced, and decrement and synergism are realized; 2) the technical difficult problem of lower content of nutrients in the liquid fertilizer containing the wood vinegar because most of production raw materials containing large quantity, medium quantity and trace elements can not be dissolved in the wood vinegar is solved; 3) agricultural and forestry straw wastes can be effectively utilized and turned into valuables; and 4) the product is environment-friendly and high-efficient, the production process is simple and easy to operate, energy conservation and consumption reduction are realized, and the output capacity of the finished product is 100%. The high-potassium liquid organic fertilizer disclosed by the invention can be sprayed on leaf surfaces of grains, cotton, oil, vegetables, flowers, forest trees and other various plants during the growth and development period, so that the harvest can be greatly increased.
Description
1. technical field
The present invention relates to a kind of is the high potassium organic fertilizer and the working method of matrix with the pyroligneous liquor; The pyroligneous liquor that relates to specifically utilize the agricultural stalk waste to produce is mother liquor, the height infiltration that makes, high nutrition, multifunctional type organic water-soluble fertilizer and working method in conjunction with macroelement nitrogen, phosphorus, potassium, amino acid and organic matter.
2. background technology
Pyroligneous liquor all obtains extensive promotion and application in the agriculture prodn of countries such as the U.S., Japan, Korea S.In the U.S., pyroligneous liquor is mainly used in garden gardening.In Japan, pyroligneous liquor is mainly used in soil improvement, flower culture and field of medicaments.In Korea S, pyroligneous liquor is mainly used on crop cut pesticide synergistic agent and the livestock feed additive.Utilize in the research and development of pyroligneous liquor, Japan is walked at the front end in the world.The annual pyroligneous liquor of approximately producing 40,000 tons of Japan, the agricultural that is used for wherein over half approximately, result of use remarkable and good economic benefit, social benefit and the environmental benefit obtained.China only has several family units that the method for manufacture and the method for use of pyroligneous liquor are carried out preliminary study since the nineties, and the research and development utilization of pyroligneous liquor still is in the starting stage, and its research and development utilization is failed to cause enough attention.
Agriculture and forestry organic waste material is divided into two types: agricultural crop straw and forest waste.Stalk is often referred to wheat, paddy rice, corn, potato class, oil plant, cotton, sugarcane and other farm crop rest parts behind the results seed; The forest waste mainly refers to non-moulding tree material, branch, tree root etc.The stalk amount that agricultural produces is quite surprising.According to UNEP (UNEP) statistics, the annual stalk that produces of the various farm crop of plantation is nearly 1,700,000,000 tons in the world.About 700,000,000 tons of China's agricultural crop straw YO at present.
Stalk is as the main sub product of farm crop, and utilization ratio is low for a long time, and waste is very serious.Many-sided reasons such as agriculture and forestry organic waste material is fluffy because of self, scope is wide, and fuel value is lower, people are in than primary the utilization of agriculture and forestry organic waste material always and utilize state.Owing to the straw-returning corruption time is longer, plantation brings very big inconvenience to second stubble crop, much plants the family with the stalk on-site incineration, to accelerate to receive the speed of planting and removing resistates.Yet a large amount of crop straw burnings have brought environmental pollution and disaster hidden-trouble.The photosynthetic product of farm crop has over half being present in the stalk, and stalk is rich in organic and multiple nutrients such as nitrogen, phosphorus, calcium, magnesium, sulphur, is a kind of renewable biological source that serves many purposes, and wherein major part does not obtain utilization.Make full use of agriculture and forestry organic waste material, for adjustment world energy sources structural system, improving environmental situation has good pushing effect.
Pyroligneous liquor is a kind of verivate of firing gained in the charcoal process, is that agriculture and forestry organic waste material is produced a kind of crude liq material that obtains after the flue gas naturally cooling liquefaction of emerging in the process of charcoal, is made up of more than 280 kinds of organic acids and organic cpds, and is pollution-free; Nuisanceless, people and animals are had no side effect, contain K, Ca; Mg, Zn, Ge; Mn, mineral substance such as Fe, VITAMINs and various plants organic composition; The all or part of replacement agrochemicals of ability can be used for producing in the ecological agriculture green food, Organic food, reduce the disadvantageous effect that chemical fertilizer and agricultural chemicals bring.
Research shows, pyroligneous liquor in the growth, the prevention and elimination of disease and pests that promote the root of the crop cauline leaf, alleviate continuous cropping obstacle, increase output, the aspect effects such as consumption, subduction chemical injury of crops, freeze injury of improving the soil, reduce agrochemical fertilizer are remarkable.
Water molecules group in the pyroligneous liquor is much smaller than tap water, and dissolved oxygen content is many, thereby perviousness is very strong.When using agrochemical fertilizer with, can infiltrate vegetable cell rapidly, make drug effect, fertilizer efficiency double to improve, under the situation of identical drug effect, fertilizer efficiency, consumption can reduce 1/3.
The present invention's article are mother liquor with the pyroligneous liquor, are aided with tensio-active agent and reduce surface tension, have strengthened the fertilizer perviousness greatly.Find that after deliberation pyroligneous liquor is water-soluble to have deposition to generate.Great majority contain, and raw material big or middle, trace element is insoluble to pyroligneous liquor.The unique raw material of the present invention's article is formed, and has successfully solved this difficult problem.Because pyroligneous liquor is the polymer fluid of natural organic acids and organic cpds, do not play any chemical reaction, so the present invention's article continuing to have property throughout the year.
Macroelement nitrogen phosphorus potassium plays crucial effects at growth and development of plants in life.Nitrogen is chlorophyllous integral part, and synthesizing of involved in plant body internal protein is the moity of enzyme.Research shows that under the equal conditions, plant is preferred the amino-acid state nitrogenous source.A large amount of using of ammonium nitrogen are the enrichment of plant materials betaine easily, have a negative impact.So nitric nitrogen, ammonium nitrogen mix use with amino acid, effect is far superior to use single nitrogenous source; Phosphorus is participated in the formation of phosphoric acid and Nucleotide, can promote cell fission, participates in organic conversion, synthetic and transportation, is the important participant of plant respiration and root system development; Potassium is to promoting the formation of glucide in the body, and the anti-adversity ability that improves plant has vital role, and the activation of 60 plurality of enzymes is described as the article prime element in the involved in plant body.
Potassium is higher at the crop in-vivo content, generally all surpasses phosphorus, not only the content of the total potassium of high-yield crop surpass phosphorus, even surpass nitrogen.Potassium can obviously improve the yield and quality of farm crop; Can improve the effect of increasing production of nitrogen, phosphate fertilizer, improve farm crop water conservation, water-retaining capacity, improve farm crop resistance; Like drought resisting, cold-resistant, disease-resistant, anti-salt, resistant to lodging etc., also can improve the fruit quality by enhancing crop photosynthesis.Execute potassium watermelon sugar amount and bring up to 10.7% from 7.5%, the artificial taste of tasting obviously becomes excellent, executes the potassium sugarcane and presses sugared rate and can improve 15%.Execute potassium oranges and tangerines saccharic acid ratio and bring up to 9.81 from 7.97, taste taste and obviously be superior to control group.In national chemical fertilizer try net potash fertilizer field experiment, on nitrogen phosphorus basis, use K2075～150mg/hm2, to grain, cotton, oil, fruit increase yield significantly, wherein increases in grain production 11.9%～22%.
China is far longer than supply to the demand of potassium in agriculture prodn.According to statistics, China's severe potassium deficiency soil (available potassium for＜50ppm) amount to general potassium deficiency soil (available potassium 50-70ppm) and reached 3.4 hundred million mu.
The Caidamu Basin in Qinghai is the maximum Repone K liquid potassium ore resources that present China finds, the Repone K total stocks reaches more than 1.45 hundred million tons, but poor because of conditions of transportation, has limited the application to it.On the whole, the potash fertilizer resource of China can not satisfy the demand of agriculture prodn development far away.Existing market is sold and the potash fertilizer of use mainly is inorganic potash fertilizer; Like vitriolate of tartar, Repone K and saltpetre etc., the throughput of the inorganic potash fertilizer of China and output constantly increase in recent years, but can't satisfy the demand; Whole nation potash fertilizer breach reaches more than 90%, all relies on external import to a great extent.Use inorganic potash fertilizer and can in soil, mend potassium, but long-term application makes soil compaction easily, the acid etching crop root, present many western countries are in order to protect environment, and the development green food progressively limits and uses inorganic potash fertilizer, and the development organic potassic fertilizer.
3. summary of the invention
It is the high potassium organic fertilizer and the working method of matrix with the pyroligneous liquor that the present invention will provide a kind of.It is a mother liquor with the pyroligneous liquor, is rich in nitrogen, phosphorus, potassium, organic matter, amino acid, plant-growth regulator and tensio-active agent, and the present invention's article are sprayed directly on to foliage applying after can diluting by a certain percentage.
Working method of the present invention is:
The raw material that will contain each nutritive ingredient calculates, after the weighing, subsequent use.
1) mixes: pyroligneous liquor is added in the reaction kettle, slowly add biochemical fulvic acid potassium after the turn on agitator;
2) complexing: add Pottasium Hydroxide and carry out complexing;
3) neutralization: slowly add in phosphoric acid, Citric acid monohydrate Food grade, the acetate one or more and carry out neutralization reaction, in the entire reaction course, temperature is controlled at below 80 ℃;
4) dissolving cooling: after adding the mixed amino acid solution, will be rich in nitrogen, phosphorus, potassium and organic raw material successively and slowly add reaction kettle, and treat to dissolve fully and temperature is reduced to below 50 ℃;
5) dissolving: add plant-growth regulator, tensio-active agent, cooling, can is finished product.
The present invention has the following advantages:
1) broken through liquid fertilizer with water as this idea of mother liquor, replace with pyroligneous liquor, rationally use the ability of enhancing crop disease resistance greatly, improve crop quality output;
2) solved, trace element big or middle and can not be dissolved in the liquid fertilizer nutrient content technical barrier on the low side that pyroligneous liquor causes containing pyroligneous liquor because of great majority;
3) unique system component has strengthened the rate of permeation of product greatly, has promoted the utilization ratio of nutrient;
4) can effectively utilize the straw refuse in the agriculture prodn, turn waste into wealth;
5) production process is energy-saving and cost-reducing, environment-friendly high-efficiency, and the finished product output capacity reaches 100%;
6) environment-friendly high-efficiency can be widely used in each kind of plant such as grain, cotton, oil, dish, flowers, forest.
7) be rich in the necessary macroelement of growth and development of plants, amino acid and organic matter, can effectively improve crop yield, quality; Unique prescription is formed combines supply nutriment and disease-resistant, insect-prevention together.
8) use conveniently, drip irrigation, foliage-spray all can.Can use mutual synergy with desinsection, sterilant.
4. embodiment of the present invention
Further specify the present invention through the specific embodiment that provides below, but not as to qualification of the present invention.
Embodiment 1:
Pyroligneous liquor Pottasium Hydroxide agricultural ammonium nitrate Citric acid monohydrate Food grade saltpetre
Biochemical fulvic acid potassium mixed amino acid solution liver and gall acid sodium 6-benzyl aminopurine potassium pyrophosphate
Embodiment 2:
Pyroligneous liquor Pottasium Hydroxide mixed amino acid solution DEXTROSE MONOHYDRATE BP Secondary ammonium phosphate
Bright fat 98% potassium primary phosphate of biochemical fulvic acid potassium phosphoric acid organic silicon surfactant amine
Embodiment 3:
Pyroligneous liquor Pottasium Hydroxide acetate Citric acid monohydrate Food grade urea
Biochemical fulvic acid potassium mixed amino acid solution Triple Pressed Stearic Acid 4-iodobenzene fluoroacetic acid sucrose
Working method: with each formula nutritional composition according to the form below content preparation of above embodiment
| Nutritive ingredient | Nitrogen | Phosphorus | Potassium | Organic |
| Content (grams per liter) | 50-150 | 30-80 | 150-280 | 80-300 |
Step is following:
The raw material that 1) will contain each nutritive ingredient calculates, after the weighing, subsequent use;
2) take by weighing amino acid mixing liquid, tensio-active agent, plant-growth regulator, subsequent use;
3) mix: pyroligneous liquor and mixed amino acid solution are added in the reaction kettle, slowly add biochemical fulvic acid potassium after the turn on agitator;
4) complexing: add Pottasium Hydroxide and carry out complexing;
5) neutralization: neutralization reaction is carried out in the acid that slowly adds among each embodiment, in the entire reaction course, temperature is controlled at below 80 ℃;
6) dissolving cooling: will be rich in nitrogen, phosphorus, potassium and organic raw material successively and slowly add reaction kettle, and treat to dissolve fully and temperature is reduced to below 50 ℃;
7) dissolving: add plant-growth regulator, tensio-active agent, cooling, can is finished product.
The optimum content of this each nutritive ingredient of foliage fertilizer is:
| Nutritive ingredient | Nitrogen | Phosphorus | Potassium | Organic |
| Content (grams per liter) | 120 | 70 | 230 | 280 |
Pyroligneous liquor 400
Mixed amino acid solution 130
Tensio-active agent 3
Plant-growth regulator 7
The present invention can dilute 600-800 doubly to crop growth phase foliage-sprays such as corn, wheat, soybean, vegetables, melon and fruit, flowers, forests; Through test in the past few years; Proving that it has promotes crop growth, improves effect such as fruit quality, can increase production about 9-18%.
Claims (8)
1. one kind is the high potassium organic fertilizer of matrix with the pyroligneous liquor; It is characterized in that having the necessary nutritive element of growth and development of plants, main nutrient is nitrogen, phosphorus, potassium, organic matter; These nutrients are dissolved in mixed amino acid solution, the pyroligneous liquor, and add tensio-active agent and plant-growth regulator composition.It consists of: (grams per liter)
Pyroligneous liquor 200-500
Mixed amino acid solution 50-200
Tensio-active agent 1-10
Plant-growth regulator 1-15
Claim 1 described a kind of be the high potassium organic fertilizer of matrix with the pyroligneous liquor; It is characterized in that the raw material that contains macroelement nitrogen, phosphorus, potassium is multiple in saltpetre, agricultural ammonium nitrate, Secondary ammonium phosphate, potassium primary phosphate, phosphoric acid, Pottasium Hydroxide, urea, potassium pyrophosphate, the biochemical fulvic acid potassium; The raw material that contains organic matter is one or more in DEXTROSE MONOHYDRATE BP, Citric acid monohydrate Food grade, acetate, biochemical fulvic acid potassium, the sucrose; The mixed amino acid solution is dissolved in water by in animal proteinum, Zein powder, soybean protein powder, polypeptide albumen powder, collagen protein powder, the SDPP one or more, gets through protease hydrolysis; Auxiliary agent is tensio-active agent and plant-growth regulator.
Claim 1 described a kind of be the high potassium organic fertilizer of matrix with the pyroligneous liquor; It is characterized in that plant-growth regulator is one or more in multiple phthalein nucleic acid 98%, the bright fat 98% of amine, 6-benzyl aminopurine, choline chloride 60, Nucleotide, the 4-iodobenzene fluoroacetic acid.
Claim 1 described a kind of be the high potassium organic fertilizer of matrix with the pyroligneous liquor; It is characterized in that tensio-active agent is one or more in X 2073, Triple Pressed Stearic Acid, Yelkin TTS, fatty acid glycerine fat, organic silicon surfactant, the liver Sodium cholic acid.
Claim 1 described a kind of be the high potassium organic fertilizer of matrix with the pyroligneous liquor, it is characterized in that effective constitutive material of disease and insect resistance is a pyroligneous liquor.
Claim 1 described a kind of be the high potassium organic fertilizer of matrix with the pyroligneous liquor; It is characterized in that; Described amino acid preparation method is: take by weighing in 50-100 kilogram animal proteinum, zein, soybean protein powder, polypeptide albumen powder, collagen protein powder, the SDPP one or more; Be dissolved in 100 kg of water, add proteolytic enzyme and got final product in 12 hours in 40-55 ℃ of placement.
Claim 1 described a kind of be the production technique of the high potassium organic fertilizer of matrix with the pyroligneous liquor, step is following:
(1) mixes: pyroligneous liquor and mixed amino acid solution are added in the reaction kettle, slowly add biochemical fulvic acid potassium after the turn on agitator;
(2) complexing: add Pottasium Hydroxide and carry out complexing;
(3) neutralization: slowly add in Citric acid monohydrate Food grade, phosphoric acid, the acetate one or more, carry out neutralization reaction, in the entire reaction course, temperature is controlled at below 80 ℃;
(4) dissolving cooling: will be rich in nitrogen, phosphorus, potassium and organic raw material successively and slowly add reaction kettle, and treat to dissolve fully and temperature is reduced to below 50 ℃;
(5) dissolving: add tensio-active agent and plant-growth regulator, cooling, can is finished product.
Claim 1 described a kind of be the high potassium organic fertilizer of matrix with the pyroligneous liquor, it is characterized in that each nutritive ingredient optimum content is: (grams per liter)
Pyroligneous liquor 400
Mixed amino acid solution 130
Tensio-active agent 3
Plant-growth regulator 7.
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Addressee: Shaanxi Han Tang environmental protection agriculture Co.,Ltd. Chen Yi Document name: Notification of Publication of the Application for Invention |
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Denomination of invention: High-potassium liquid organic fertilizer taking wood vinegar as matrix and production method thereof Effective date of registration: 20190918 Granted publication date: 20160803 Pledgee: Xixian New District Financing Guarantee Co.,Ltd. Pledgor: Shaanxi Hantang Environment Protection Agriculture Co.,Ltd. Registration number: Y2019980000171 |
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Date of cancellation: 20220707 Granted publication date: 20160803 Pledgee: Xixian New District Financing Guarantee Co.,Ltd. Pledgor: Shaanxi Hantang Environment Protection Agriculture Co.,Ltd. Registration number: Y2019980000171 |