CN102585747B - 一种适用于ffc的无卤素热熔胶粘剂及其制备方法 - Google Patents
一种适用于ffc的无卤素热熔胶粘剂及其制备方法 Download PDFInfo
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- CN102585747B CN102585747B CN2011103840290A CN201110384029A CN102585747B CN 102585747 B CN102585747 B CN 102585747B CN 2011103840290 A CN2011103840290 A CN 2011103840290A CN 201110384029 A CN201110384029 A CN 201110384029A CN 102585747 B CN102585747 B CN 102585747B
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- 238000000034 method Methods 0.000 title claims abstract description 8
- 239000000853 adhesive Substances 0.000 title abstract description 6
- 230000001070 adhesive effect Effects 0.000 title abstract description 6
- 238000002844 melting Methods 0.000 title abstract description 5
- 230000008018 melting Effects 0.000 title abstract description 5
- 239000003063 flame retardant Substances 0.000 claims abstract description 76
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 31
- 239000011574 phosphorus Substances 0.000 claims abstract description 31
- 239000002904 solvent Substances 0.000 claims abstract description 24
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 229920001225 polyester resin Polymers 0.000 claims abstract description 6
- 239000004645 polyester resin Substances 0.000 claims abstract description 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 69
- 239000007822 coupling agent Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 29
- 239000004831 Hot glue Substances 0.000 claims description 25
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 24
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
- 239000000945 filler Substances 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 229910019142 PO4 Inorganic materials 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 14
- 239000010452 phosphate Substances 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 11
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000008096 xylene Substances 0.000 claims description 6
- 238000011049 filling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims 1
- 238000007789 sealing Methods 0.000 abstract description 11
- 238000009413 insulation Methods 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- -1 phosphate ester Chemical class 0.000 description 3
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
实施例 | A组份 | 含磷阻燃剂 | 含氮阻燃剂 | 填料 | 偶联剂 | 溶剂 | 总量 | 阻燃等级(UL94) | 产品成本降低程度 | 剥离强度(kgf/cm) |
1 | 45 | 12.8 | 8 | 5 | 0.2 | 29 | 100 | VTM-0 | >10% | 0.8~0.9 |
2 | 45 | 10 | 8 | 5 | 0.3 | 31.7 | 100 | VTM-0 | >10% | 0.9~1.0 |
3 | 50 | 11 | 9 | 5 | 0.1 | 24.9 | 100 | VTM-0 | >10% | 0.9~1.0 |
Claims (2)
Priority Applications (1)
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CN2011103840290A CN102585747B (zh) | 2011-11-28 | 2011-11-28 | 一种适用于ffc的无卤素热熔胶粘剂及其制备方法 |
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CN2011103840290A CN102585747B (zh) | 2011-11-28 | 2011-11-28 | 一种适用于ffc的无卤素热熔胶粘剂及其制备方法 |
Publications (2)
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CN102585747A CN102585747A (zh) | 2012-07-18 |
CN102585747B true CN102585747B (zh) | 2013-12-04 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107446537A (zh) * | 2017-06-25 | 2017-12-08 | 桐乡市卓源纺织有限公司 | 一种烫金胶水 |
CN107267100A (zh) * | 2017-06-25 | 2017-10-20 | 桐乡市卓源纺织有限公司 | 一种热溶胶 |
CN108682495B (zh) * | 2018-04-26 | 2020-04-14 | 广东莱尔新材料科技股份有限公司 | 一种咬合连接器高温抗流动ffc线材用热熔胶膜 |
CN108899142A (zh) * | 2018-07-16 | 2018-11-27 | 苏州艾斯肯机电设备有限公司 | 一种机电设备用表面高绝缘处理工艺 |
CN109722200A (zh) * | 2018-12-27 | 2019-05-07 | 东莞市澳中电子材料有限公司 | 一种耐热性优异的热熔胶粘剂及热熔胶带 |
CN110452653B (zh) * | 2019-07-29 | 2021-09-07 | 广东莱尔新材料科技股份有限公司 | 一种高粘力的耐候热熔胶及其制备方法和热熔胶膜 |
CN111019534B (zh) * | 2019-12-24 | 2022-05-17 | 广东莱尔新材料科技股份有限公司 | 一种ffc线材用的抗孔洞聚酯热熔胶膜及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009028477A1 (ja) * | 2007-08-29 | 2009-03-05 | Toagosei Co., Ltd. | 飽和ポリエステル系樹脂組成物及びホットメルト接着剤組成物 |
CN101613580A (zh) * | 2009-04-17 | 2009-12-30 | 深圳市飞荣达科技有限公司 | 一种无卤阻燃热熔胶膜及其制备方法 |
CN102010578A (zh) * | 2010-07-16 | 2011-04-13 | 广东生益科技股份有限公司 | 黑色无卤树脂组合物、使用其制备的覆盖膜及其制作方法 |
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2011
- 2011-11-28 CN CN2011103840290A patent/CN102585747B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009028477A1 (ja) * | 2007-08-29 | 2009-03-05 | Toagosei Co., Ltd. | 飽和ポリエステル系樹脂組成物及びホットメルト接着剤組成物 |
CN101613580A (zh) * | 2009-04-17 | 2009-12-30 | 深圳市飞荣达科技有限公司 | 一种无卤阻燃热熔胶膜及其制备方法 |
CN102010578A (zh) * | 2010-07-16 | 2011-04-13 | 广东生益科技股份有限公司 | 黑色无卤树脂组合物、使用其制备的覆盖膜及其制作方法 |
Non-Patent Citations (2)
Title |
---|
向明等.热熔胶粘剂.《热熔胶粘剂》.化学工业出版社,2002,(第1版), * |
李子东等.胶黏剂助剂.《胶黏剂助剂》.化学工业出版社,2005,(第1版), * |
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Application publication date: 20120718 Assignee: Anhui Xinchen New Optical Material Co., Ltd. Assignor: Wuxi Qunyue Electronics Technology Co., Ltd. Contract record no.: 2014340000092 Denomination of invention: Halogen-free hot melting adhesive suitable for flexible flat cables (FFCs) and preparing method thereof Granted publication date: 20131204 License type: Exclusive License Record date: 20140424 |
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