CN102432377B - 用于保鲜的纳米硒/剑麻碳纤维复合材料的水热合成方法 - Google Patents
用于保鲜的纳米硒/剑麻碳纤维复合材料的水热合成方法 Download PDFInfo
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- CN102432377B CN102432377B CN 201110276774 CN201110276774A CN102432377B CN 102432377 B CN102432377 B CN 102432377B CN 201110276774 CN201110276774 CN 201110276774 CN 201110276774 A CN201110276774 A CN 201110276774A CN 102432377 B CN102432377 B CN 102432377B
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- distilled water
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- carbon fiber
- sisal hemp
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- 244000198134 Agave sisalana Species 0.000 title claims abstract description 30
- 239000011669 selenium Substances 0.000 title claims abstract description 25
- 229910052711 selenium Inorganic materials 0.000 title claims abstract description 24
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 16
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000002131 composite material Substances 0.000 title claims abstract description 14
- 238000004321 preservation Methods 0.000 title abstract description 5
- 238000010189 synthetic method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000012153 distilled water Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003763 carbonization Methods 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims abstract description 4
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 4
- 239000010935 stainless steel Substances 0.000 claims abstract description 4
- 238000005303 weighing Methods 0.000 claims abstract description 4
- 235000011624 Agave sisalana Nutrition 0.000 claims description 23
- 239000000835 fiber Substances 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000011010 flushing procedure Methods 0.000 claims description 6
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- VWDWKYIASSYTQR-YTBWXGASSA-N sodium;dioxido(oxo)azanium Chemical compound [Na+].[O-][15N+]([O-])=O VWDWKYIASSYTQR-YTBWXGASSA-N 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 17
- 235000015097 nutrients Nutrition 0.000 abstract description 5
- 230000002035 prolonged effect Effects 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 229910018162 SeO2 Inorganic materials 0.000 abstract 1
- 239000004809 Teflon Substances 0.000 abstract 1
- 229920006362 Teflon® Polymers 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 abstract 1
- 230000000050 nutritive effect Effects 0.000 description 9
- 241000196324 Embryophyta Species 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- -1 seleno-protein Chemical compound 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229920001277 pectin Polymers 0.000 description 2
- 235000010987 pectin Nutrition 0.000 description 2
- 239000001814 pectin Substances 0.000 description 2
- FDKWRPBBCBCIGA-REOHCLBHSA-N (2r)-2-azaniumyl-3-$l^{1}-selanylpropanoate Chemical compound [Se]C[C@H](N)C(O)=O FDKWRPBBCBCIGA-REOHCLBHSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FDKWRPBBCBCIGA-UWTATZPHSA-N D-Selenocysteine Natural products [Se]C[C@@H](N)C(O)=O FDKWRPBBCBCIGA-UWTATZPHSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- RJFAYQIBOAGBLC-BYPYZUCNSA-N Selenium-L-methionine Chemical compound C[Se]CC[C@H](N)C(O)=O RJFAYQIBOAGBLC-BYPYZUCNSA-N 0.000 description 1
- RJFAYQIBOAGBLC-UHFFFAOYSA-N Selenomethionine Natural products C[Se]CCC(N)C(O)=O RJFAYQIBOAGBLC-UHFFFAOYSA-N 0.000 description 1
- 102000008114 Selenoproteins Human genes 0.000 description 1
- 108010074686 Selenoproteins Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- XOCUXOWLYLLJLV-UHFFFAOYSA-N [O].[S] Chemical compound [O].[S] XOCUXOWLYLLJLV-UHFFFAOYSA-N 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- ZKZBPNGNEQAJSX-UHFFFAOYSA-N selenocysteine Natural products [SeH]CC(N)C(O)=O ZKZBPNGNEQAJSX-UHFFFAOYSA-N 0.000 description 1
- 229940055619 selenocysteine Drugs 0.000 description 1
- 235000016491 selenocysteine Nutrition 0.000 description 1
- 229960002718 selenomethionine Drugs 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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CN 201110276774 CN102432377B (zh) | 2011-09-16 | 2011-09-16 | 用于保鲜的纳米硒/剑麻碳纤维复合材料的水热合成方法 |
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CN 201110276774 CN102432377B (zh) | 2011-09-16 | 2011-09-16 | 用于保鲜的纳米硒/剑麻碳纤维复合材料的水热合成方法 |
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CN102432377A CN102432377A (zh) | 2012-05-02 |
CN102432377B true CN102432377B (zh) | 2013-05-01 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103043952A (zh) * | 2013-01-18 | 2013-04-17 | 西部中大建设集团有限公司 | 一种利用剑麻纤维增强改性沥青制备沥青混合料的方法 |
CN108452767A (zh) * | 2018-01-27 | 2018-08-28 | 桂林理工大学 | 一种纳米氧化锌-剑麻纤维炭复合物的制备方法 |
CN111193015A (zh) * | 2020-01-09 | 2020-05-22 | 桂林理工大学 | 一种MoSe2-MoO2@剑麻纤维活性炭锂离子电池负极材料的制备方法 |
CN111575834B (zh) * | 2020-05-28 | 2021-03-09 | 中国科学院化学研究所 | 一种基于天然麻纤维原料的碳纳米纤维及其制备方法 |
CN115259957B (zh) * | 2022-06-29 | 2023-09-08 | 河北工业大学 | 蓝藻基碳量子点纳米硒肥的制备方法及其应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1166541A (zh) * | 1997-04-18 | 1997-12-03 | 中山大学 | 天然纤维基活性炭纤维的制备方法 |
CN1386575A (zh) * | 2002-04-05 | 2002-12-25 | 中山大学 | 一种改性活性碳纤维及其制备方法和用途 |
CN101066053A (zh) * | 2007-06-09 | 2007-11-07 | 桂林工学院 | 一种纳米硒/竹炭保鲜剂的水热合成方法 |
CN101947460A (zh) * | 2010-09-07 | 2011-01-19 | 桂林理工大学 | 一种纳米硫化锌/竹炭光催化材料的水热法合成方法 |
-
2011
- 2011-09-16 CN CN 201110276774 patent/CN102432377B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1166541A (zh) * | 1997-04-18 | 1997-12-03 | 中山大学 | 天然纤维基活性炭纤维的制备方法 |
CN1386575A (zh) * | 2002-04-05 | 2002-12-25 | 中山大学 | 一种改性活性碳纤维及其制备方法和用途 |
CN101066053A (zh) * | 2007-06-09 | 2007-11-07 | 桂林工学院 | 一种纳米硒/竹炭保鲜剂的水热合成方法 |
CN101947460A (zh) * | 2010-09-07 | 2011-01-19 | 桂林理工大学 | 一种纳米硫化锌/竹炭光催化材料的水热法合成方法 |
Non-Patent Citations (2)
Title |
---|
剑麻纤维的处理方法对其热性能和形态结构的影响;牟秋红等;《桂林工学院学报》;20041031;第24卷(第4期);第469-473页 * |
牟秋红等.剑麻纤维的处理方法对其热性能和形态结构的影响.《桂林工学院学报》.2004,第24卷(第4期),第469-473页. |
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Application publication date: 20120502 Assignee: Guangxi manjin Energy Saving Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2022450000619 Denomination of invention: Hydrothermal synthesis of nano selenium/sisal carbon fiber composite for preservation Granted publication date: 20130501 License type: Common License Record date: 20221230 |
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