CN102421507B - 从流体流中选择性除去硫化氢的吸收剂 - Google Patents
从流体流中选择性除去硫化氢的吸收剂 Download PDFInfo
- Publication number
- CN102421507B CN102421507B CN201080020874.3A CN201080020874A CN102421507B CN 102421507 B CN102421507 B CN 102421507B CN 201080020874 A CN201080020874 A CN 201080020874A CN 102421507 B CN102421507 B CN 102421507B
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- China
- Prior art keywords
- amine
- absorbing medium
- acid
- amino
- methyl
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
- B01J20/292—Liquid sorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/70—Organic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Organic Chemistry (AREA)
- Gas Separation By Absorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09160039 | 2009-05-12 | ||
| EP09160039.5 | 2009-05-12 | ||
| PCT/EP2010/056556 WO2010130787A1 (de) | 2009-05-12 | 2010-05-12 | Absorptionsmittel zum selektiven entfernen von schwefelwasserstoff aus fluidströmen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102421507A CN102421507A (zh) | 2012-04-18 |
| CN102421507B true CN102421507B (zh) | 2014-07-23 |
Family
ID=42272085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080020874.3A Active CN102421507B (zh) | 2009-05-12 | 2010-05-12 | 从流体流中选择性除去硫化氢的吸收剂 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US8221712B2 (https=) |
| EP (1) | EP2429686B1 (https=) |
| JP (1) | JP5665855B2 (https=) |
| KR (1) | KR20120020167A (https=) |
| CN (1) | CN102421507B (https=) |
| AU (1) | AU2010247405B2 (https=) |
| BR (1) | BRPI1011367A2 (https=) |
| CA (1) | CA2760732C (https=) |
| EA (1) | EA020754B1 (https=) |
| ES (1) | ES2425429T3 (https=) |
| PE (1) | PE20121040A1 (https=) |
| PL (1) | PL2429686T3 (https=) |
| UA (1) | UA106753C2 (https=) |
| WO (1) | WO2010130787A1 (https=) |
| ZA (1) | ZA201109017B (https=) |
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| AU2008321326B2 (en) | 2007-11-12 | 2013-04-18 | Exxonmobil Upstream Research Company | Methods of generating and utilizing utility gas |
| BRPI0911224A2 (pt) | 2008-04-30 | 2015-09-29 | Exxonmobil Upstream Res Co | sistema e método para tratar uma corrente de alimentação gasosa, e, contactador adsorvente estruturado |
| CN102449124A (zh) | 2009-05-26 | 2012-05-09 | 巴斯夫欧洲公司 | 由流体料流,尤其是由合成气回收二氧化碳的方法 |
| US9067168B2 (en) | 2010-05-28 | 2015-06-30 | Exxonmobil Upstream Research Company | Integrated adsorber head and valve design and swing adsorption methods related thereto |
| TWI495501B (zh) | 2010-11-15 | 2015-08-11 | Exxonmobil Upstream Res Co | 動力分餾器及用於氣體混合物之分餾的循環法 |
| CA2825148C (en) | 2011-03-01 | 2017-06-20 | Exxonmobil Upstream Research Company | Methods of removing contaminants from a hydrocarbon stream by swing adsorption and related apparatus and systems |
| BR112013018597A2 (pt) | 2011-03-01 | 2019-01-08 | Exxonmobil Upstream Res Co | aparelho e sistemas tendo um contator adsorvente encaixado e processos de adsorção oscilante |
| AU2012223554B2 (en) * | 2011-03-01 | 2016-02-18 | Exxonmobil Research And Engineering Company | Rapid temperature swing adsorption contactors for gas separation |
| WO2012118757A1 (en) | 2011-03-01 | 2012-09-07 | Exxonmobil Upstream Research Company | Apparatus and systems having a reciprocating valve head assembly and swing adsorption processes related thereto |
| BR112013017837A2 (pt) | 2011-03-01 | 2016-10-11 | Exxonmobil Upstream Res Co | aparelho e sistemas tendo múltiplos leitos de adsorção oscilante de configuração compacta e métodos relacionados com eles |
| CA2842928A1 (en) | 2011-03-01 | 2012-11-29 | Exxonmobil Upstream Research Company | Apparatus and systems having a rotary valve assembly and swing adsorption processes related thereto |
| CA2824162A1 (en) | 2011-03-01 | 2012-09-07 | Exxonmobil Upstream Research Company | Apparatus and systems having a rotary valve assembly and swing adsorption processes related thereto |
| JP6035553B2 (ja) | 2011-03-01 | 2016-11-30 | エクソンモービル アップストリーム リサーチ カンパニー | スイング吸着により炭化水素流から汚染物質を除去する方法並びに関連装置及びシステム |
| US8529857B2 (en) | 2011-03-31 | 2013-09-10 | Basf Se | Retention of amines in the removal of acid gases by means of amine absorption media |
| US20130243677A1 (en) * | 2012-03-14 | 2013-09-19 | Exxonmobil Research And Engineering Company | Amine treating process for selective acid gas separation |
| FR2990950B1 (fr) | 2012-05-25 | 2014-06-13 | Total Sa | Procede de purification d'une charge liquide d'hydrocarbures contenant des composes acides. |
| FR2990880B1 (fr) | 2012-05-25 | 2017-04-28 | Total Sa | Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene. |
| FR2990878B1 (fr) | 2012-05-25 | 2014-05-16 | Total Sa | Procede de purification de melanges gazeux contenant des gaz acides. |
| FR2990879B1 (fr) * | 2012-05-25 | 2014-09-26 | Total Sa | Procede de decarbonatation de fumees. |
| JP5868795B2 (ja) * | 2012-06-25 | 2016-02-24 | 株式会社東芝 | 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置 |
| WO2014004020A1 (en) * | 2012-06-29 | 2014-01-03 | Dow Global Technologies Llc | Aqueous alkanolamine solution and process for the removal of h2s from gaseous mixtures |
| US8808426B2 (en) | 2012-09-04 | 2014-08-19 | Exxonmobil Research And Engineering Company | Increasing scales, capacities, and/or efficiencies in swing adsorption processes with hydrocarbon gas feeds |
| US9034078B2 (en) | 2012-09-05 | 2015-05-19 | Exxonmobil Upstream Research Company | Apparatus and systems having an adsorbent contactor and swing adsorption processes related thereto |
| CN103043744B (zh) * | 2012-12-07 | 2014-06-11 | 常州大学 | 一种煤渣灰处理工业废水的方法 |
| FR2999449B1 (fr) * | 2012-12-13 | 2015-04-03 | IFP Energies Nouvelles | Procede d'elimination de composes acides d'un effluent gazeux par une solution absorbante a base de 1,2-bis(2-dimethylaminoethoxy)-ethane et d'un activateur |
| US20150027055A1 (en) * | 2013-07-29 | 2015-01-29 | Exxonmobil Research And Engineering Company | Separation of hydrogen sulfide from natural gas |
| WO2015065842A1 (en) | 2013-10-30 | 2015-05-07 | Dow Global Technologies Llc | Hybrid solvent formulations for total organic sulfur removal and total acidic gas removal |
| EP3074488A1 (en) | 2013-10-30 | 2016-10-05 | Dow Global Technologies LLC | Hybrid solvent formulations for selective h2s removal |
| FR3020965B1 (fr) * | 2014-05-16 | 2016-05-27 | Ifp Energies Now | Solution absorbante a base de diamines tertiaires beta hydroxylees et procede d'elimination de composes acides d'un effluent gazeux |
| US9533253B2 (en) | 2014-06-05 | 2017-01-03 | Phillips 66 Company | Amine solvent blends |
| CN105344205A (zh) * | 2014-08-20 | 2016-02-24 | 中国石油化工股份有限公司 | 一种能从含co2的混合气中选择性脱除h2s的吸收剂 |
| EP3186222B1 (de) * | 2014-08-25 | 2018-06-06 | Basf Se | Diamin mit tert-alkylamino- und primärer aminogruppe zur verwendung in der gaswäsche |
| CN106794414B (zh) * | 2014-08-25 | 2020-11-06 | 巴斯夫欧洲公司 | 从流体流中移除硫化氢和二氧化碳 |
| EP2990090A1 (de) * | 2014-08-25 | 2016-03-02 | Basf Se | Absorptionsmittel zur selektiven Entfernung von Schwefelwasserstoff aus einem Fluidstrom |
| CN107073386B (zh) * | 2014-08-25 | 2020-07-03 | 巴斯夫欧洲公司 | 使用叔丁胺和活化剂从流体流中移除二氧化碳 |
| KR20160058296A (ko) * | 2014-11-14 | 2016-05-25 | (주)티피티퍼시픽 | 2-아미노 2-메틸 1-프로판올(amp)를 포함하는 산성가스 제거용 흡수제 조성물 및 이를 이용한 산성가스 제거방법 |
| CN108136367A (zh) | 2015-08-28 | 2018-06-08 | 塞里奥尼克斯股份有限公司 | 用于碱性污染物的气体过滤器 |
| WO2017040291A1 (en) | 2015-08-28 | 2017-03-09 | Serionix, Inc. | Gas filters for acidic contaminants |
| BR112018003738A2 (pt) * | 2015-09-29 | 2018-09-25 | Basf Se | amina cíclica para remoção seletiva de sulfeto de hidrogênio |
| SG11201801360PA (en) | 2015-09-29 | 2018-04-27 | Basf Se | Absorbent for the selective removal of hydrogen sulfide |
| WO2017055087A1 (de) * | 2015-09-29 | 2017-04-06 | Basf Se | Absorptionsmittel und verfahren zur selektiven entfernung von schwefelwasserstoff |
| CN105413396A (zh) * | 2015-10-21 | 2016-03-23 | 中石化节能环保工程科技有限公司 | 捕集尾气中co2的分层吸收剂 |
| BR112018010703A8 (pt) * | 2015-12-09 | 2019-02-26 | Basf Se | ?processo para tratar um fluxo de fluido e planta? |
| US11045759B2 (en) * | 2016-04-18 | 2021-06-29 | Basf Se | Premix for producing an absorption agent for removing acid gases from a fluid flow |
| WO2018026517A1 (en) | 2016-08-04 | 2018-02-08 | Exxonmobil Research And Engineering Company | Increasing scales, capacities, and/or efficiencies in swing adsorption processes with hydrocarbon gas feeds |
| US11241652B2 (en) * | 2017-05-15 | 2022-02-08 | Basf Se (Reitstötter, Kinzebach & Partner) | Absorbent and process for selectively removing hydrogen sulfide |
| US10940407B2 (en) | 2017-07-12 | 2021-03-09 | Baker Hughes Holdings Llc | Application of formaldehyde sulfoxylates for scavenging H2S |
| CN109276987B (zh) * | 2018-10-25 | 2022-01-25 | 中国石油化工股份有限公司 | 一种用于工业尾气脱硫脱硝处理的吸收剂 |
| MY205026A (en) * | 2019-02-26 | 2024-09-27 | Mitsubishi Heavy Ind Eng Ltd | Off-gas treatment device and fertilizer production plant including the same |
| US11229875B1 (en) | 2020-09-25 | 2022-01-25 | Ineos Americas, Llc | Scrubbing fluid and methods for using same |
| WO2022129977A1 (en) | 2020-12-17 | 2022-06-23 | Totalenergies Onetech | Method for recovering high purity carbon dioxide from a gas mixture |
| WO2022129975A1 (en) | 2020-12-17 | 2022-06-23 | Totalenergies Onetech | Method for the selective removal of hydrogen sulfide from a gas stream |
| CN113318586B (zh) * | 2021-06-09 | 2022-07-19 | 华东理工大学 | 一种胺类化合物在提高有机硫溶解和吸收脱除中的应用 |
| CA3235954A1 (en) | 2021-10-26 | 2023-05-04 | Frederick De Meyer | Method for the purification of a gas mixture comprising carbon dioxide and optionally hydrogen sulfide |
| CN115554955B (zh) * | 2022-10-08 | 2025-04-25 | 中建安装集团有限公司 | 一种连续化生产n,n-二甲基乙二胺的装置及工艺 |
| WO2025108960A1 (en) | 2023-11-22 | 2025-05-30 | Clariant International Ltd | Method and system for removing co2 gas from a gas stream |
| WO2026004775A1 (ja) * | 2024-06-28 | 2026-01-02 | 株式会社日本触媒 | 組成物および二酸化炭素吸収剤 |
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| US4892674A (en) * | 1987-10-13 | 1990-01-09 | Exxon Research And Engineering Company | Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S |
| CN1228715A (zh) * | 1996-09-03 | 1999-09-15 | 孟山都公司 | 使用有机磷溶剂从流出气中选择性除去和回收二氧化硫的方法 |
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| DE2551717C3 (de) * | 1975-11-18 | 1980-11-13 | Basf Ag, 6700 Ludwigshafen | und ggf. COS aus Gasen |
| DE3236600A1 (de) * | 1982-10-02 | 1984-04-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und gegebenenfalls h(pfeil abwaerts)2(pfeil abwaerts)s aus erdgasen |
| DE3308088A1 (de) * | 1983-03-08 | 1984-09-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
| EP0134948A3 (en) | 1983-06-30 | 1987-10-14 | Union Carbide Corporation | Absorbent formulation for enhanced removal of acid gases from gas mixtures and processes using same |
| US4553984A (en) * | 1984-03-06 | 1985-11-19 | Basf Aktiengesellschaft | Removal of CO2 and/or H2 S from gases |
| DE3408851A1 (de) | 1984-03-10 | 1985-09-12 | Basf Ag, 6700 Ludwigshafen | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
| DE3445063A1 (de) | 1984-12-11 | 1986-06-12 | Basf Ag, 6700 Ludwigshafen | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
| DE3518368A1 (de) | 1985-05-22 | 1986-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zum entfernen von co(pfeil abwaerts)2(pfeil abwaerts) und/oder h(pfeil abwaerts)2(pfeil abwaerts)s aus gasen |
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| CA2861539C (en) * | 2006-05-18 | 2016-01-12 | Norbert Asprion | Carbon dioxide absorbent requiring less regeneration energy |
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| JP5794913B2 (ja) | 2008-06-23 | 2015-10-14 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 吸収剤及び流体流、特に排ガスからの酸性ガスの除去のための方法 |
| DK2300127T3 (en) | 2008-06-23 | 2015-07-06 | Basf Se | ABSORPENT AND PROCEDURE FOR THE REMOVAL OF ACID GASES FROM LIQUID FLOWS, PARTICULARLY FROM Flue gases |
-
2009
- 2009-10-09 US US12/576,277 patent/US8221712B2/en active Active
-
2010
- 2010-05-12 BR BRPI1011367A patent/BRPI1011367A2/pt not_active Application Discontinuation
- 2010-05-12 AU AU2010247405A patent/AU2010247405B2/en active Active
- 2010-05-12 KR KR1020117029541A patent/KR20120020167A/ko not_active Withdrawn
- 2010-05-12 EA EA201171402A patent/EA020754B1/ru not_active IP Right Cessation
- 2010-05-12 PE PE2011001951A patent/PE20121040A1/es not_active Application Discontinuation
- 2010-05-12 UA UAA201114649A patent/UA106753C2/uk unknown
- 2010-05-12 ES ES10721454T patent/ES2425429T3/es active Active
- 2010-05-12 CA CA2760732A patent/CA2760732C/en active Active
- 2010-05-12 JP JP2012510293A patent/JP5665855B2/ja not_active Expired - Fee Related
- 2010-05-12 PL PL10721454T patent/PL2429686T3/pl unknown
- 2010-05-12 CN CN201080020874.3A patent/CN102421507B/zh active Active
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| US4892674A (en) * | 1987-10-13 | 1990-01-09 | Exxon Research And Engineering Company | Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S |
| CN1228715A (zh) * | 1996-09-03 | 1999-09-15 | 孟山都公司 | 使用有机磷溶剂从流出气中选择性除去和回收二氧化硫的方法 |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN102421507A (zh) | 2012-04-18 |
| US8221712B2 (en) | 2012-07-17 |
| AU2010247405B2 (en) | 2015-10-01 |
| EP2429686B1 (de) | 2013-07-17 |
| JP5665855B2 (ja) | 2015-02-04 |
| CA2760732C (en) | 2017-05-09 |
| KR20120020167A (ko) | 2012-03-07 |
| JP2012526648A (ja) | 2012-11-01 |
| EA020754B1 (ru) | 2015-01-30 |
| US20100288125A1 (en) | 2010-11-18 |
| EP2429686A1 (de) | 2012-03-21 |
| PE20121040A1 (es) | 2012-07-31 |
| UA106753C2 (uk) | 2014-10-10 |
| WO2010130787A1 (de) | 2010-11-18 |
| PL2429686T3 (pl) | 2013-12-31 |
| ES2425429T3 (es) | 2013-10-15 |
| EA201171402A1 (ru) | 2012-05-30 |
| ZA201109017B (en) | 2013-02-27 |
| BRPI1011367A2 (pt) | 2016-03-15 |
| AU2010247405A1 (en) | 2011-12-22 |
| CA2760732A1 (en) | 2010-11-18 |
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