FR2990880B1 - Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene. - Google Patents

Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene.

Info

Publication number
FR2990880B1
FR2990880B1 FR1254842A FR1254842A FR2990880B1 FR 2990880 B1 FR2990880 B1 FR 2990880B1 FR 1254842 A FR1254842 A FR 1254842A FR 1254842 A FR1254842 A FR 1254842A FR 2990880 B1 FR2990880 B1 FR 2990880B1
Authority
FR
France
Prior art keywords
hydrogen sulfide
selective removal
thioalcanol
gaseous mixtures
selective
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1254842A
Other languages
English (en)
Other versions
FR2990880A1 (fr
Inventor
Claire Weiss
Renaud Cadours
Jing Zhao
Virenkumar Shah
Serge Capdeville
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Onetech SAS
Original Assignee
Total SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1254842A priority Critical patent/FR2990880B1/fr
Application filed by Total SE filed Critical Total SE
Priority to CN201380027182.5A priority patent/CN104334253A/zh
Priority to PCT/EP2013/060578 priority patent/WO2013174902A1/fr
Priority to BR112014028971-9A priority patent/BR112014028971A2/pt
Priority to CA2874361A priority patent/CA2874361C/fr
Priority to MYPI2014003217A priority patent/MY175564A/en
Priority to EA201491941A priority patent/EA201491941A1/ru
Priority to US14/402,515 priority patent/US20150147254A1/en
Publication of FR2990880A1 publication Critical patent/FR2990880A1/fr
Priority to NO20141522A priority patent/NO20141522A1/no
Application granted granted Critical
Publication of FR2990880B1 publication Critical patent/FR2990880B1/fr
Priority to US15/662,518 priority patent/US20170320008A1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/103—Sulfur containing contaminants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/205—Other organic compounds not covered by B01D2252/00 - B01D2252/20494
    • B01D2252/2056—Sulfur compounds, e.g. Sulfolane, thiols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/602—Activators, promoting agents, catalytic agents or enzymes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/12—Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541—Absorption of impurities during preparation or upgrading of a fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
FR1254842A 2012-05-25 2012-05-25 Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene. Active FR2990880B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR1254842A FR2990880B1 (fr) 2012-05-25 2012-05-25 Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene.
US14/402,515 US20150147254A1 (en) 2012-05-25 2013-05-23 Process for selectively removing hydrogen sulphide from gaseous mixtures and use of a thioalkanol for selectively removing hydrogen sulphide
BR112014028971-9A BR112014028971A2 (pt) 2012-05-25 2013-05-23 processo de remoção seletiva de sulfeto de hidrogênio de misturas gasosas e uso de um tioalcanol para remoção seletiva de sulfeto de hidrogênio
CA2874361A CA2874361C (fr) 2012-05-25 2013-05-23 Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene
MYPI2014003217A MY175564A (en) 2012-05-25 2013-05-23 Process for selective removal of hydrogen sulphide from gas mixtures and use of a thioalkanol for the selectve removal of hydrogen sulphide
EA201491941A EA201491941A1 (ru) 2012-05-25 2013-05-23 Способ селективного удаления сульфида водорода из газовых смесей и применение тиоалканола для селективного удаления сульфида водорода
CN201380027182.5A CN104334253A (zh) 2012-05-25 2013-05-23 从气体混合物中选择性去除硫化氢的方法以及硫代烷醇用于选择性去除硫化氢的用途
PCT/EP2013/060578 WO2013174902A1 (fr) 2012-05-25 2013-05-23 Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene
NO20141522A NO20141522A1 (no) 2012-05-25 2014-12-17 Fremgangsmåte for selektiv fjerning av hydrogensulfid fra gassblandinger samt anvendelse av en tioalkanol for selektivt å fjerne hydrogensulfid
US15/662,518 US20170320008A1 (en) 2012-05-25 2017-07-28 Process For Selectively Removing Hydrogen Sulphide From Gaseous Mixtures And Use Of A Thioalkanol For Selectively Removing Hydrogen Sulphide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1254842A FR2990880B1 (fr) 2012-05-25 2012-05-25 Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene.

Publications (2)

Publication Number Publication Date
FR2990880A1 FR2990880A1 (fr) 2013-11-29
FR2990880B1 true FR2990880B1 (fr) 2017-04-28

Family

ID=46785599

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1254842A Active FR2990880B1 (fr) 2012-05-25 2012-05-25 Procede d'elimination selective du sulfure d'hydrogene de melanges gazeux et utilisation d'un thioalcanol pour l'elimination selective du sulfure d'hydrogene.

Country Status (9)

Country Link
US (2) US20150147254A1 (fr)
CN (1) CN104334253A (fr)
BR (1) BR112014028971A2 (fr)
CA (1) CA2874361C (fr)
EA (1) EA201491941A1 (fr)
FR (1) FR2990880B1 (fr)
MY (1) MY175564A (fr)
NO (1) NO20141522A1 (fr)
WO (1) WO2013174902A1 (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201600125TA (en) * 2013-07-29 2016-02-26 Exxonmobil Res & Eng Co Separation of hydrogen sulfide from natural gas
DE102014118345A1 (de) * 2014-12-10 2016-06-16 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren und Anlage zur Reinigung von Rohsynthesegas
WO2016116815A1 (fr) * 2015-01-22 2016-07-28 Carbon Clean Solutions Limited Solvant et procédé permettant d'éliminer des gaz acides d'un mélange gazeux
EP3250311A4 (fr) 2015-01-28 2019-02-13 Fluor Technologies Corporation Procédés et systèmes d'amélioration du rendement énergétique de la capture du dioxyde de carbone
CA3061843A1 (fr) * 2017-05-15 2018-11-22 Basf Se Absorbant et procede d'elimination selective de sulfure d'hydrogene
US10376829B2 (en) 2017-06-13 2019-08-13 Fluor Technologies Corporation Methods and systems for improving the energy efficiency of carbon dioxide capture
CN109529541B (zh) * 2017-09-21 2022-07-22 株式会社东芝 二氧化碳吸收剂及二氧化碳分离回收装置
CN110385022B (zh) * 2018-04-19 2022-07-15 中国石油化工股份有限公司 脱硫剂及其应用和轻烃脱硫加工的方法
CN110052119B (zh) * 2019-03-26 2021-12-07 昆明理工大学 有机溶剂吸收提浓工业酸性气中硫化氢及资源利用的方法
CA3153809A1 (fr) 2019-09-10 2021-03-18 Basf Se Procede d'elimination de gaz acides contenus dans un courant de fluide
CN111013368B (zh) * 2019-11-25 2021-12-21 北京化工大学 同时吸收多种酸性气体的反应系统、吸收液及方法
US20230226483A1 (en) * 2020-07-07 2023-07-20 ExxonMobil Technology and Engineering Company Acid Gas Scrubbing Methods Featuring Amine Phase Separation for Hydrogen Sulfide Capture
WO2022129974A1 (fr) 2020-12-17 2022-06-23 Totalenergies Onetech Milieu d'élimination sélective de sulfure d'hydrogène à partir d'un courant gazeux
WO2022129977A1 (fr) 2020-12-17 2022-06-23 Totalenergies Onetech Procédé de récupération de dioxyde de carbone de haute pureté à partir d'un mélange gazeux
WO2022129975A1 (fr) 2020-12-17 2022-06-23 Totalenergies Onetech Procédé pour l'élimination sélective du sulfure d'hydrogène à partir d'un courant de gaz
CN113318586B (zh) * 2021-06-09 2022-07-19 华东理工大学 一种胺类化合物在提高有机硫溶解和吸收脱除中的应用
CN114768477B (zh) * 2022-03-18 2023-11-17 中国科学技术大学 一种二氧化碳捕集方法
CN114797425A (zh) * 2022-04-18 2022-07-29 成都中科绿生环境科技有限公司 一种可针对性去除h2s与硫醇的试剂及其制备方法和应用

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US3864460A (en) * 1973-07-12 1975-02-04 Nrg Inc Method for removing hydrogen sulfide from hydrocarbon gas streams without pollution of the atmosphere
FR2328657A1 (fr) 1975-10-21 1977-05-20 Elf Aquitaine Procede d'enrichissement en h2s des gaz acides
IT1132170B (it) 1980-07-04 1986-06-25 Snam Progetti Processo di separazione selettiva di idrogeno solforato da miscele gassose contenenti anche anidride carbonica
FR2537888B1 (fr) 1982-12-21 1985-06-28 Elf Aquitaine Perfectionnement a l'enrichissement en hydrogene sulfure de gaz qui en contiennent
FR2589752B1 (fr) 1985-10-04 1987-12-11 Elf Aquitaine Procede et dispositif pour l'extraction selective de l'h2s d'un gaz en contenant
ES2054049T5 (es) 1988-05-24 1997-12-16 Elf Aquitaine Liquido absorbente de gases acidos que contiene una alcanol-amina terciaria y un activador de absorcion del co2, y su aplicacion a la desacidificacion de gas conteniendo co2 y eventualmente otros gases acidos.
EP1474218B1 (fr) * 2002-01-14 2008-12-10 Shell Internationale Researchmaatschappij B.V. Procede d'elimination de dioxyde de carbone de melanges de gaz
DE102004011429A1 (de) 2004-03-09 2005-09-29 Basf Ag Verfahren zum Entfernen von Kohlendioxid aus Gasströmen mit niedrigen Kohlendioxid-Partialdrücken
FR2896244B1 (fr) * 2006-01-18 2013-04-12 Total Sa Procede de purification de melanges gazeux contenant des mercaptans et autres gaz acides
FR2911516B1 (fr) * 2007-01-19 2009-11-13 Total Sa Procede de purification d'un melange gazeux contenant des gaz acides
FR2933008B1 (fr) * 2008-06-27 2011-03-18 Inst Francais Du Petrole Solution absorbante contenant un inhibiteur de degradation organique soufre et methode pour limiter la degradation d'une solution absorbante
US8221712B2 (en) 2009-05-12 2012-07-17 Basf Se Absorption medium for the selective removal of hydrogen sulfide from fluid streams
FR2947185B1 (fr) * 2009-06-26 2011-07-01 Total Sa Procede de traitement de gaz acides
CN101844035A (zh) * 2010-06-28 2010-09-29 四川省精细化工研究设计院 一种从混合气体中脱除硫化氢和有机硫醇的高效脱硫剂

Also Published As

Publication number Publication date
BR112014028971A2 (pt) 2020-11-03
CA2874361C (fr) 2021-03-30
MY175564A (en) 2020-07-01
WO2013174902A1 (fr) 2013-11-28
US20150147254A1 (en) 2015-05-28
US20170320008A1 (en) 2017-11-09
EA201491941A1 (ru) 2015-03-31
CN104334253A (zh) 2015-02-04
FR2990880A1 (fr) 2013-11-29
CA2874361A1 (fr) 2013-11-28
NO20141522A1 (no) 2014-12-17

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