CN102395427B - 在Ru(II)催化剂存在下氢化酮类的方法 - Google Patents

在Ru(II)催化剂存在下氢化酮类的方法 Download PDF

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CN102395427B
CN102395427B CN201080016781.3A CN201080016781A CN102395427B CN 102395427 B CN102395427 B CN 102395427B CN 201080016781 A CN201080016781 A CN 201080016781A CN 102395427 B CN102395427 B CN 102395427B
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branched
cyclic
optionally substituted
straight chain
formula
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CN102395427A (zh
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A·戴克
D·M·格兰杰
J·A·梅德洛克
H·G·内登
J·J·M·勒佩
S·J·罗斯布雷德
A·赛格
V·西瓦库玛
A·扎诺蒂-杰罗萨
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Johnson Matthey PLC
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
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    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
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    • C07C303/40—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids by reactions not involving the formation of sulfonamide groups
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    • C07C311/03—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the sulfonamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C311/05—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the sulfonamide groups bound to hydrogen atoms or to acyclic carbon atoms to acyclic carbon atoms of hydrocarbon radicals substituted by nitrogen atoms, not being part of nitro or nitroso groups
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    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/07—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the sulfonamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring
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    • C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
    • C07C311/18—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom to an acyclic carbon atom of a hydrocarbon radical substituted by nitrogen atoms, not being part of nitro or nitroso groups
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    • C07C311/20—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring
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    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
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    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
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    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
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    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

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  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201080016781.3A 2009-03-17 2010-03-17 在Ru(II)催化剂存在下氢化酮类的方法 Active CN102395427B (zh)

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CN201610855651.8A CN106466641B (zh) 2009-03-17 2010-03-17 在Ru(II)催化剂存在下氢化酮类的方法
CN201410219928.9A CN104030950B (zh) 2009-03-17 2010-03-17 在Ru(II)催化剂存在下氢化酮类的方法

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GB0904553A GB0904553D0 (en) 2009-03-17 2009-03-17 Process
GB0904553.5 2009-03-17
US22169009P 2009-06-30 2009-06-30
US61/221,690 2009-06-30
GB0913166A GB0913166D0 (en) 2009-07-29 2009-07-29 Process
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PCT/GB2010/050456 WO2010106364A2 (en) 2009-03-17 2010-03-17 Process

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US9217005B2 (en) 2010-08-26 2015-12-22 Takasago International Corporation Ruthenium-diamine complexes and method for producing optically active compounds
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JP6048762B2 (ja) * 2011-10-31 2016-12-21 高砂香料工業株式会社 光学活性β−ヒドロキシ−α−アミノカルボン酸エステルの製造方法
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CN104854068A (zh) * 2012-12-18 2015-08-19 帝斯曼知识产权资产管理有限公司 由(r)-6,10-14-三甲基十五碳-5-烯-2-酮制备的(6r,10r)-6,10,14-三甲基十五烷-2-酮
CN103408597B (zh) * 2013-06-06 2015-12-09 温州大学 一种芳烃钌配合物及其合成方法
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US20180264449A1 (en) * 2014-10-10 2018-09-20 Takasago International Corporation Solid-supported ruthenium-diamine complexes, and methods for producing optically active compounds
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CN106466641B (zh) 2020-06-09
WO2010106364A2 (en) 2010-09-23
US20180290133A1 (en) 2018-10-11
US20120123142A1 (en) 2012-05-17
JP2012520865A (ja) 2012-09-10
JP2018048135A (ja) 2018-03-29
US10406514B2 (en) 2019-09-10
CN104030950A (zh) 2014-09-10
US20140357903A1 (en) 2014-12-04
ES2628755T3 (es) 2017-08-03
US9416100B2 (en) 2016-08-16
WO2010106364A3 (en) 2011-06-30
US20160271599A1 (en) 2016-09-22
EP2805765A1 (en) 2014-11-26
CN102395427A (zh) 2012-03-28
JP6510848B2 (ja) 2019-05-08
JP5721695B2 (ja) 2015-05-20
CN104030950B (zh) 2017-01-04
SI2805765T1 (sl) 2021-04-30
JP2015157819A (ja) 2015-09-03
CN106466641A (zh) 2017-03-01
EP2408557B1 (en) 2017-03-15
EP2408557A2 (en) 2012-01-25
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EP2805765B1 (en) 2020-12-23
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