CN102391596A - 一种用于制备太阳能光伏背膜的改性含氟树脂切片及其制备方法 - Google Patents
一种用于制备太阳能光伏背膜的改性含氟树脂切片及其制备方法 Download PDFInfo
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- CN102391596A CN102391596A CN2011102561632A CN201110256163A CN102391596A CN 102391596 A CN102391596 A CN 102391596A CN 2011102561632 A CN2011102561632 A CN 2011102561632A CN 201110256163 A CN201110256163 A CN 201110256163A CN 102391596 A CN102391596 A CN 102391596A
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Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
含氟树脂 | 增塑剂 | 稳定剂 | 偶联剂 | 抗氧化剂 | 填充剂 | |
实施例六 | 70% | 2% | 1% | 2% | 3% | 22% |
实施例七 | 73% | 3% | 2% | 3% | 4% | 15% |
实施例八 | 69% | 5% | 1% | 4% | 1% | 20% |
实施例九 | 65% | 4% | 3% | 1% | 2% | 25% |
实施例十 | 78% | 2% | 0.5 | 0.5 | 5% | 14% |
实施例十一 | 80% | 3.5% | 1.5% | 3% | 3% | 9% |
实施例十二 | 81% | 2% | 1% | 4% | 2% | 10% |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1654531A (zh) * | 2005-01-06 | 2005-08-17 | 武汉大学 | 一种共混膜及其制备方法和用途 |
CN101359695A (zh) * | 2008-09-02 | 2009-02-04 | 中国乐凯胶片集团公司 | 一种太阳能电池背板 |
CN101696309A (zh) * | 2009-10-13 | 2010-04-21 | 常熟市冠日新材料有限公司 | 含氟薄膜及其制备方法 |
WO2011065234A1 (ja) * | 2009-11-30 | 2011-06-03 | 電気化学工業株式会社 | ポリフッ化ビニリデン系樹脂組成物、フィルム、バックシート及び太陽電池モジュール |
CN102134359A (zh) * | 2011-01-07 | 2011-07-27 | 东华大学 | 一种太阳能电池背膜及其制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2613210B2 (ja) * | 1987-05-12 | 1997-05-21 | 旭硝子株式会社 | 難燃性樹脂フイルム |
CN101558092B (zh) * | 2006-12-21 | 2011-11-16 | 纳幕尔杜邦公司 | 可交联的氟乙烯共聚物涂层薄膜以及它们的制备方法 |
CN101177514B (zh) * | 2007-11-08 | 2010-06-09 | 中国乐凯胶片集团公司 | 一种太阳能电池背板及其制备方法 |
US20110297228A1 (en) * | 2009-12-07 | 2011-12-08 | Rongfu Li | Uv blocking fluoropolymer film |
CN102167836B (zh) * | 2011-03-01 | 2012-11-14 | 宜兴市高拓高分子材料有限公司 | 一种聚偏氟乙烯薄膜的制备方法 |
-
2011
- 2011-09-01 CN CN201310161690.4A patent/CN103265779B/zh active Active
- 2011-09-01 CN CN 201110256163 patent/CN102391596B/zh active Active
- 2011-09-01 CN CN201310161686.8A patent/CN103265778B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1654531A (zh) * | 2005-01-06 | 2005-08-17 | 武汉大学 | 一种共混膜及其制备方法和用途 |
CN101359695A (zh) * | 2008-09-02 | 2009-02-04 | 中国乐凯胶片集团公司 | 一种太阳能电池背板 |
CN101696309A (zh) * | 2009-10-13 | 2010-04-21 | 常熟市冠日新材料有限公司 | 含氟薄膜及其制备方法 |
WO2011065234A1 (ja) * | 2009-11-30 | 2011-06-03 | 電気化学工業株式会社 | ポリフッ化ビニリデン系樹脂組成物、フィルム、バックシート及び太陽電池モジュール |
CN102134359A (zh) * | 2011-01-07 | 2011-07-27 | 东华大学 | 一种太阳能电池背膜及其制备方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3266841A4 (en) * | 2015-03-02 | 2018-12-12 | AGC Inc. | Composition for powder paint, powder paint, and painted article |
CN104893188A (zh) * | 2015-04-22 | 2015-09-09 | 杭州福膜新材料科技有限公司 | 一种低表面光泽度聚偏氟乙烯薄膜及其制备方法 |
CN105428444A (zh) * | 2015-12-18 | 2016-03-23 | 常熟高嘉能源科技有限公司 | 一种薄膜型光伏组件 |
CN106317710A (zh) * | 2016-08-15 | 2017-01-11 | 苏州扬子江新型材料股份有限公司 | 高抗刮船舶装饰用磨砂覆膜板 |
WO2022113926A1 (ja) * | 2020-11-25 | 2022-06-02 | Agc株式会社 | テトラフルオロエチレン系ポリマーの組成物、積層体およびフィルム |
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