CN102307660A - 氢化催化剂及其制备和用途 - Google Patents

氢化催化剂及其制备和用途 Download PDF

Info

Publication number
CN102307660A
CN102307660A CN2010800069702A CN201080006970A CN102307660A CN 102307660 A CN102307660 A CN 102307660A CN 2010800069702 A CN2010800069702 A CN 2010800069702A CN 201080006970 A CN201080006970 A CN 201080006970A CN 102307660 A CN102307660 A CN 102307660A
Authority
CN
China
Prior art keywords
catalyst
earth metals
hydrogenation
weight
cobalt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010800069702A
Other languages
English (en)
Chinese (zh)
Inventor
C·W·维格博斯
J·施泰纳
M·恩斯特
B·W·霍费尔
E·施瓦布
J-P·梅尔德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN102307660A publication Critical patent/CN102307660A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0234—Impregnation and coating simultaneously
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2010800069702A 2009-02-09 2010-02-01 氢化催化剂及其制备和用途 Pending CN102307660A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09152406 2009-02-09
EP09152406.6 2009-02-09
PCT/EP2010/051143 WO2010089266A2 (de) 2009-02-09 2010-02-01 Verfahren zur verbesserung der katalytischen aktivität von monolithischen katalysatoren

Publications (1)

Publication Number Publication Date
CN102307660A true CN102307660A (zh) 2012-01-04

Family

ID=42315924

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010800069702A Pending CN102307660A (zh) 2009-02-09 2010-02-01 氢化催化剂及其制备和用途

Country Status (5)

Country Link
US (1) US20110313187A1 (cg-RX-API-DMAC7.html)
EP (1) EP2393593A2 (cg-RX-API-DMAC7.html)
JP (1) JP2012517332A (cg-RX-API-DMAC7.html)
CN (1) CN102307660A (cg-RX-API-DMAC7.html)
WO (1) WO2010089266A2 (cg-RX-API-DMAC7.html)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103664638A (zh) * 2013-12-31 2014-03-26 张锦碧 一种异佛尔酮二胺的简易制备方法
CN107365257A (zh) * 2017-08-02 2017-11-21 厦门大学 一种2‑甲基戊二腈加氢制备2‑甲基戊二胺及3‑甲基哌啶的方法
CN109803949A (zh) * 2016-10-10 2019-05-24 巴斯夫欧洲公司 在硝基化合物的连续液相氢化中使用碱金属离子、碱土金属离子或稀土金属离子进行催化剂改性
CN113226531A (zh) * 2019-09-25 2021-08-06 赢创运营有限公司 催化反应器
US11180440B2 (en) 2017-12-22 2021-11-23 Zhejiang Nhu Company Ltd. Method for preparing isophorone diamine by means of hydrogenation reduction of isophorone nitrile imine
CN114990617A (zh) * 2022-05-17 2022-09-02 浙江工业大学 一种碳化硼负载钯钴双金属催化剂及其制备方法和应用

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8933223B2 (en) 2010-10-14 2015-01-13 Basf Se Process for preparing a cyclic tertiary amine
IN2014DN10668A (cg-RX-API-DMAC7.html) 2012-06-01 2015-08-28 Basf Se
US8884015B2 (en) 2012-06-01 2014-11-11 Basf Se Process for the preparation of a mono-N-alkypiperazine
US8981093B2 (en) 2012-06-06 2015-03-17 Basf Se Process for preparing piperazine
CN103752315B (zh) * 2014-01-15 2016-08-10 易高环保能源研究院有限公司 一种金属相载体负载型催化剂及其制备方法和用途
JP6671350B2 (ja) * 2014-08-28 2020-03-25 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ コバルト完全接触触媒を使用して第一級アミンを製造する方法
CN105032433B (zh) * 2015-06-08 2017-08-25 上海应用技术学院 一种以TiO2纳米管为载体的己二腈加氢催化剂的制备方法
TWI565686B (zh) * 2015-11-26 2017-01-11 南亞塑膠工業股份有限公司 一種ｎ，ｎ’－雙（３－胺基丙基）－１，２－乙二胺的製備方法
KR102362247B1 (ko) * 2020-08-10 2022-02-16 한국에너지기술연구원 Pem 수전해용 촉매의 제조방법 및 pem 수전해용 촉매
KR102288276B1 (ko) * 2019-11-22 2021-08-11 한국에너지기술연구원 Pem 수전해용 촉매의 제조방법 및 pem 수전해용 촉매
CN113457699B (zh) * 2020-03-31 2023-11-10 中国石油化工股份有限公司 一种含磷的基质材料及其制备方法与应用
CN117205923A (zh) * 2022-06-02 2023-12-12 中国科学院过程工程研究所 氮掺杂碳包覆型催化剂、其制备方法及间苯二甲腈制备间苯二甲胺的方法
EP4549620A1 (en) 2023-10-31 2025-05-07 Basf Se Process for making amines from nitrile compounds using hydrogen having low deuterium content produced with non-fossil energy in the absence of ammonia

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2004135A (en) * 1932-12-23 1935-06-11 Du Pont Production of polyhydric alcohols
US2449036A (en) 1939-11-02 1948-09-07 Grunfeld Maximilien Manufacture of primary amines
US3752774A (en) * 1971-06-07 1973-08-14 Du Pont Zirconia silica promoted cobalt oxide catalyst
DE2445303C3 (de) 1974-09-21 1979-04-05 Basf Ag, 6700 Ludwigshafen Basisches, zur Herstellung eines Kupfer enthaltenden Katalysators geeignetes Carbonat
JPS61111140A (ja) * 1984-11-06 1986-05-29 Toyota Central Res & Dev Lab Inc 炭化水素合成用触媒
FR2605531B1 (fr) * 1986-10-27 1990-11-23 Rhone Poulenc Chimie Procede de preparation d'un support de catalyseur mettant en oeuvre de la gomme xanthane et support obtenu
US5151543A (en) 1991-05-31 1992-09-29 E. I. Du Pont De Nemours And Company Selective low pressure hydrogenation of a dinitrile to an aminonitrile
DE4325847A1 (de) 1993-07-31 1995-02-02 Basf Ag Kobaltkatalysatoren
DE4428004A1 (de) 1994-08-08 1996-02-15 Basf Ag Verfahren zur Herstellung von Aminen
EP0742045B1 (de) 1995-05-09 2001-12-12 Basf Aktiengesellschaft Kobaltkatalysatoren
US5869653A (en) 1997-10-30 1999-02-09 Air Products And Chemicals, Inc. Hydrogenation of nitriles to produce amines
DE19826396A1 (de) 1998-06-12 1999-12-16 Basf Ag Verfahren zur Herstellung von Aminen
DE10011738A1 (de) 2000-03-13 2002-03-28 Porzellanwerk Kloster Veilsdor Keramischer Katalysatorformkörper und Verfahren zur Herstellung solcher Katalysatorformkörper
US6649799B2 (en) * 2000-12-23 2003-11-18 Degussa Ag Method for producing primary and secondary amines by hydrogenation of nitriles and imines
US20030036477A1 (en) * 2001-04-20 2003-02-20 Nordquist Andrew Francis Coated monolith substrate and monolith catalysts
US6762324B2 (en) * 2002-05-01 2004-07-13 Air Products And Chemicals, Inc. Metal modified Pd/Ni catalysts
WO2004000454A1 (en) * 2002-06-20 2003-12-31 The Regents Of The University Of California Supported metal catalyst with improved thermal stability
DE10313702A1 (de) 2003-03-27 2004-10-07 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
KR100542911B1 (ko) * 2003-10-25 2006-01-11 한국과학기술연구원 연료전지 자동차에 이용되는 가솔린 개질용 저압차 촉매와 이의 제조방법
DE102004033554A1 (de) 2004-07-09 2006-02-16 Basf Ag Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen
DE102004033556A1 (de) 2004-07-09 2006-02-16 Basf Ag Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen
US6998507B1 (en) * 2004-08-24 2006-02-14 Air Products And Chemicals, Inc. Hydrogenation of methylenedianiline
EP1809596A1 (en) * 2004-11-10 2007-07-25 Degussa GmbH The fixed bed hydrogenation of fatty nitriles to fatty amines
GB0501783D0 (en) 2005-01-28 2005-03-09 Johnson Matthey Plc Catalysts and preparation method
US20090018366A1 (en) 2005-09-08 2009-01-15 Monika Berweiler Production and use of supported activated base metal catalysts for organic transformation
DE102005060488A1 (de) * 2005-12-15 2007-06-28 Basf Ag Verfahren zur Hydrierung von Nitrilen zu primären Aminen oder Aminonitrilen und dafür geeignete Katalysatoren
EP1981917A1 (de) * 2006-01-30 2008-10-22 Basf Se Verfahren zur hydrierung von polymeren und dafür geeignete hydrierkatalysatoren
WO2007104663A1 (de) * 2006-03-10 2007-09-20 Basf Se Mischoxid-katalysatoren
CN101378822A (zh) * 2006-04-20 2009-03-04 揖斐电株式会社 蜂窝结构体、蜂窝结构体制造方法、壳体和废气净化装置
DE102007011483A1 (de) * 2007-03-07 2008-09-18 Evonik Degussa Gmbh Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103664638A (zh) * 2013-12-31 2014-03-26 张锦碧 一种异佛尔酮二胺的简易制备方法
CN103664638B (zh) * 2013-12-31 2016-04-13 张锦碧 一种异佛尔酮二胺的简易制备方法
CN109803949A (zh) * 2016-10-10 2019-05-24 巴斯夫欧洲公司 在硝基化合物的连续液相氢化中使用碱金属离子、碱土金属离子或稀土金属离子进行催化剂改性
CN109803949B (zh) * 2016-10-10 2023-04-14 巴斯夫欧洲公司 在硝基化合物的连续液相氢化中使用碱金属离子、碱土金属离子或稀土金属离子进行催化剂改性
CN107365257A (zh) * 2017-08-02 2017-11-21 厦门大学 一种2‑甲基戊二腈加氢制备2‑甲基戊二胺及3‑甲基哌啶的方法
US11180440B2 (en) 2017-12-22 2021-11-23 Zhejiang Nhu Company Ltd. Method for preparing isophorone diamine by means of hydrogenation reduction of isophorone nitrile imine
CN113226531A (zh) * 2019-09-25 2021-08-06 赢创运营有限公司 催化反应器
CN114990617A (zh) * 2022-05-17 2022-09-02 浙江工业大学 一种碳化硼负载钯钴双金属催化剂及其制备方法和应用
CN114990617B (zh) * 2022-05-17 2024-04-16 浙江工业大学 一种碳化硼负载钯钴双金属催化剂及其制备方法和应用

Also Published As

Publication number Publication date
US20110313187A1 (en) 2011-12-22
JP2012517332A (ja) 2012-08-02
WO2010089266A3 (de) 2010-12-23
EP2393593A2 (de) 2011-12-14
WO2010089266A2 (de) 2010-08-12

Similar Documents

Publication Publication Date Title
CN102307660A (zh) 氢化催化剂及其制备和用途
CN102307659A (zh) 氢化催化剂及其制备和用途
US20110313186A1 (en) Hydrogenation catalysts, the production and the use thereof
RU2434676C9 (ru) Катализатор на основе смешанных оксидов для гидрирования органических соединений, способ его получения и способ гидрирования
CN103429563A (zh) 氢化腈类的方法
CN106795095B (zh) 使用钴基全接触催化剂生产伯胺的方法
US7468342B2 (en) Catalysts and process for producing aromatic amines
JP5490129B2 (ja) Ｎ，ｎ−置換−３−アミノプロパン−１−オールの製造方法
KR102154370B1 (ko) 혼합 금속 산화물 암모니아산화 촉매용 전하소 첨가제
CN1106377A (zh) 链烷醇胺的制备方法，该方法使用的催化剂和该催化剂的制备方法
JP2014516342A (ja) ニトリルの水素化法
CN104557562A (zh) 二甲基乙醇胺直接催化胺化生产n，n，n，，n，-四甲基乙二胺的方法
US20080146846A1 (en) Direct Amination of Hydrocarbons
CN1321973C (zh) 高选择性生产二(氨甲基)取代的芳族化合物的方法
CN102026956A (zh) 生产n，n-取代的1，3-丙二胺的方法
CN105272868B (zh) 一种羰基化制备甲酰胺的方法
JP4938125B2 (ja) ３級アミンの製造方法
JP4182324B2 (ja) 芳香族アミン製造触媒の製法
PL168248B1 (pl) Sposób wytwarzania mieszaniny ewentualnie podstawionej cykloheksyloaminy oraz ewentualnie podstawionej dicykloheksyloaminy PL
JP3020697B2 (ja) 脂環式アミンの製造方法
CN117983226A (zh) 具有催化氨解功能的催化剂及其制备方法和应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20120104