CN102216480B - 磁性不灵敏高硬度恒弹性合金及其制造方法、以及游丝、机械式驱动装置及钟表 - Google Patents

磁性不灵敏高硬度恒弹性合金及其制造方法、以及游丝、机械式驱动装置及钟表 Download PDF

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Publication number
CN102216480B
CN102216480B CN200980145779.3A CN200980145779A CN102216480B CN 102216480 B CN102216480 B CN 102216480B CN 200980145779 A CN200980145779 A CN 200980145779A CN 102216480 B CN102216480 B CN 102216480B
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alloy
modulus
temperature
hardness
magnetic
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Chinese (zh)
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CN102216480A (zh
Inventor
村上雄悦
重城幸一郎
高桥修
恒吉润
菅原量
高野健志
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Research Institute Of Electromagnetic Materials
Seiko Chronometer Co ltd
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Foundation Research Institute For Electric And Magnetic Materials
Seiko Instruments Inc
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/007—Heat treatment of ferrous alloys containing Co
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0242—Flattening; Dressing; Flexing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0075—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/02—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/07—Alloys based on nickel or cobalt based on cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B17/00—Mechanisms for stabilising frequency
    • G04B17/04—Oscillators acting by spring tension
    • G04B17/06—Oscillators with hairsprings, e.g. balance
    • G04B17/066—Manufacture of the spiral spring
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B43/00—Protecting clockworks by shields or other means against external influences, e.g. magnetic fields
    • G04B43/007—Antimagnetic alloys

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
CN200980145779.3A 2008-11-17 2009-11-16 磁性不灵敏高硬度恒弹性合金及其制造方法、以及游丝、机械式驱动装置及钟表 Active CN102216480B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2008293713 2008-11-17
JP2008-293713 2008-11-17
PCT/JP2009/069458 WO2010055943A1 (ja) 2008-11-17 2009-11-16 磁性不感高硬度恒弾性合金及びその製造法、並びにひげぜんまい、機械式駆動装置及び時計

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CN102216480A CN102216480A (zh) 2011-10-12
CN102216480B true CN102216480B (zh) 2014-08-20

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US (1) US8684594B2 (enExample)
EP (1) EP2351864B1 (enExample)
JP (1) JP5189580B2 (enExample)
CN (1) CN102216480B (enExample)
WO (1) WO2010055943A1 (enExample)

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DE102011001783B4 (de) * 2011-04-04 2022-11-24 Vacuumschmelze Gmbh & Co. Kg Feder für ein mechanisches Uhrwerk, mechanisches Uhrwerk, Uhr mit einem mechanischen Uhrwerk und Verfahren zur Herstellung einer Feder
EP2570862B1 (fr) * 2011-09-15 2014-03-05 ETA SA Manufacture Horlogère Suisse Ensemble barillet d'horlogerie à diamètre de bonde réduit
US9395692B2 (en) 2012-08-31 2016-07-19 Citizen Holdings Co., Ltd. Hairspring material for mechanical timepiece and hairspring using the same
EP2757423B1 (fr) * 2013-01-17 2018-07-11 Omega SA Pièce pour mouvement d'horlogerie
CN104313395A (zh) * 2014-10-14 2015-01-28 杨雯雯 一种弹性合金
CA2996175C (en) 2015-09-08 2022-04-05 Scoperta, Inc. Non-magnetic, strong carbide forming alloys for powder manufacture
EP3208664B1 (de) * 2016-02-19 2023-08-16 Omega SA Uhrwerk oder uhr ohne magnetische signatur
EP3301520A1 (fr) * 2016-09-30 2018-04-04 Nivarox-FAR S.A. Composant horloger comportant un alliage haute entropie
JP6789140B2 (ja) * 2017-01-31 2020-11-25 セイコーインスツル株式会社 温度補償型てんぷ、ムーブメント及び時計
EP3422116B1 (fr) * 2017-06-26 2020-11-04 Nivarox-FAR S.A. Ressort spiral d'horlogerie
EP4151765A1 (en) * 2017-08-09 2023-03-22 Hitachi Metals, Ltd. Alloy member, process for producing said alloy member, and product including said alloy member
CN108193149B (zh) * 2018-01-05 2020-11-03 广东电科院能源技术有限责任公司 一种碳纤维增强合金复合材料及其制备方法
US20210164081A1 (en) 2018-03-29 2021-06-03 Oerlikon Metco (Us) Inc. Reduced carbides ferrous alloys
CN113195759B (zh) 2018-10-26 2023-09-19 欧瑞康美科（美国）公司 耐腐蚀和耐磨镍基合金
WO2020198302A1 (en) 2019-03-28 2020-10-01 Oerlikon Metco (Us) Inc. Thermal spray iron-based alloys for coating engine cylinder bores
AU2020269275B2 (en) 2019-05-03 2025-05-22 Oerlikon Metco (Us) Inc. Powder feedstock for wear resistant bulk welding configured to optimize manufacturability
CN110923539B (zh) * 2019-12-17 2021-10-08 南方科技大学 一种高熵合金及其制备方法和压缩性能测试方法
CN111455199A (zh) * 2020-04-16 2020-07-28 江苏星火特钢有限公司 一种高温合金真空感应炉冶炼工艺
CN112301255B (zh) * 2020-10-27 2021-07-30 上海交通大学 一种模具用高导热高强Co-Fe-Ni合金及其增材制造方法
CN119040771B (zh) * 2024-09-05 2025-06-06 重庆材料研究院有限公司 一种高机械品质因数马氏体弹性合金

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Publication number Publication date
WO2010055943A9 (ja) 2010-09-23
EP2351864B1 (en) 2016-08-10
CN102216480A (zh) 2011-10-12
US20110286312A1 (en) 2011-11-24
US8684594B2 (en) 2014-04-01
JP5189580B2 (ja) 2013-04-24
JP2010138491A (ja) 2010-06-24
WO2010055943A1 (ja) 2010-05-20
EP2351864A1 (en) 2011-08-03
EP2351864A4 (en) 2013-02-27

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Address after: Sendai City, Miyagi Prefecture, Japan

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