JP5189580B2 - 磁性不感高硬度恒弾性合金及びその製造法、並びにひげぜんまい、機械式駆動装置及び時計 - Google Patents
磁性不感高硬度恒弾性合金及びその製造法、並びにひげぜんまい、機械式駆動装置及び時計 Download PDFInfo
- Publication number
- JP5189580B2 JP5189580B2 JP2009261376A JP2009261376A JP5189580B2 JP 5189580 B2 JP5189580 B2 JP 5189580B2 JP 2009261376 A JP2009261376 A JP 2009261376A JP 2009261376 A JP2009261376 A JP 2009261376A JP 5189580 B2 JP5189580 B2 JP 5189580B2
- Authority
- JP
- Japan
- Prior art keywords
- alloy
- temperature
- modulus
- young
- wire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910045601 alloy Inorganic materials 0.000 title claims description 107
- 239000000956 alloy Substances 0.000 title claims description 107
- 230000005291 magnetic effect Effects 0.000 title claims description 81
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000000034 method Methods 0.000 title description 19
- 238000010438 heat treatment Methods 0.000 claims description 45
- 230000004907 flux Effects 0.000 claims description 31
- 238000012545 processing Methods 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 25
- 229910052750 molybdenum Inorganic materials 0.000 claims description 16
- 229910052804 chromium Inorganic materials 0.000 claims description 15
- 230000009467 reduction Effects 0.000 claims description 14
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 229910052790 beryllium Inorganic materials 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 238000005242 forging Methods 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000000835 fiber Substances 0.000 description 30
- 238000005096 rolling process Methods 0.000 description 24
- 239000011651 chromium Substances 0.000 description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
- 230000008569 process Effects 0.000 description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 10
- 230000001965 increasing effect Effects 0.000 description 10
- 230000005389 magnetism Effects 0.000 description 10
- 239000013078 crystal Substances 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 9
- 238000010622 cold drawing Methods 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 8
- 230000007423 decrease Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 230000008859 change Effects 0.000 description 6
- 238000000265 homogenisation Methods 0.000 description 6
- 229910018490 Ni—Cr—Mo—W Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 230000036544 posture Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005491 wire drawing Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 238000005482 strain hardening Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000013013 elastic material Substances 0.000 description 2
- 230000005294 ferromagnetic effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000010583 slow cooling Methods 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- 229910002058 ternary alloy Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000009774 resonance method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/007—Heat treatment of ferrous alloys containing Co
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0242—Flattening; Dressing; Flexing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0075—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/02—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/07—Alloys based on nickel or cobalt based on cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/10—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/04—Oscillators acting by spring tension
- G04B17/06—Oscillators with hairsprings, e.g. balance
- G04B17/066—Manufacture of the spiral spring
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B43/00—Protecting clockworks by shields or other means against external influences, e.g. magnetic fields
- G04B43/007—Antimagnetic alloys
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009261376A JP5189580B2 (ja) | 2008-11-17 | 2009-11-16 | 磁性不感高硬度恒弾性合金及びその製造法、並びにひげぜんまい、機械式駆動装置及び時計 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008293713 | 2008-11-17 | ||
| JP2008293713 | 2008-11-17 | ||
| JP2009261376A JP5189580B2 (ja) | 2008-11-17 | 2009-11-16 | 磁性不感高硬度恒弾性合金及びその製造法、並びにひげぜんまい、機械式駆動装置及び時計 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010138491A JP2010138491A (ja) | 2010-06-24 |
| JP2010138491A5 JP2010138491A5 (enExample) | 2010-08-05 |
| JP5189580B2 true JP5189580B2 (ja) | 2013-04-24 |
Family
ID=42170072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009261376A Active JP5189580B2 (ja) | 2008-11-17 | 2009-11-16 | 磁性不感高硬度恒弾性合金及びその製造法、並びにひげぜんまい、機械式駆動装置及び時計 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8684594B2 (enExample) |
| EP (1) | EP2351864B1 (enExample) |
| JP (1) | JP5189580B2 (enExample) |
| CN (1) | CN102216480B (enExample) |
| WO (1) | WO2010055943A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2447387B1 (fr) * | 2010-10-28 | 2013-11-13 | Générale Ressorts SA | Ressort de barillet de pièce d'horlogerie |
| DE102011001783B4 (de) * | 2011-04-04 | 2022-11-24 | Vacuumschmelze Gmbh & Co. Kg | Feder für ein mechanisches Uhrwerk, mechanisches Uhrwerk, Uhr mit einem mechanischen Uhrwerk und Verfahren zur Herstellung einer Feder |
| EP2570862B1 (fr) * | 2011-09-15 | 2014-03-05 | ETA SA Manufacture Horlogère Suisse | Ensemble barillet d'horlogerie à diamètre de bonde réduit |
| US9395692B2 (en) | 2012-08-31 | 2016-07-19 | Citizen Holdings Co., Ltd. | Hairspring material for mechanical timepiece and hairspring using the same |
| EP2757423B1 (fr) * | 2013-01-17 | 2018-07-11 | Omega SA | Pièce pour mouvement d'horlogerie |
| CN104313395A (zh) * | 2014-10-14 | 2015-01-28 | 杨雯雯 | 一种弹性合金 |
| CA2996175C (en) | 2015-09-08 | 2022-04-05 | Scoperta, Inc. | Non-magnetic, strong carbide forming alloys for powder manufacture |
| EP3208664B1 (de) * | 2016-02-19 | 2023-08-16 | Omega SA | Uhrwerk oder uhr ohne magnetische signatur |
| EP3301520A1 (fr) * | 2016-09-30 | 2018-04-04 | Nivarox-FAR S.A. | Composant horloger comportant un alliage haute entropie |
| JP6789140B2 (ja) * | 2017-01-31 | 2020-11-25 | セイコーインスツル株式会社 | 温度補償型てんぷ、ムーブメント及び時計 |
| EP3422116B1 (fr) * | 2017-06-26 | 2020-11-04 | Nivarox-FAR S.A. | Ressort spiral d'horlogerie |
| EP4151765A1 (en) * | 2017-08-09 | 2023-03-22 | Hitachi Metals, Ltd. | Alloy member, process for producing said alloy member, and product including said alloy member |
| CN108193149B (zh) * | 2018-01-05 | 2020-11-03 | 广东电科院能源技术有限责任公司 | 一种碳纤维增强合金复合材料及其制备方法 |
| US20210164081A1 (en) | 2018-03-29 | 2021-06-03 | Oerlikon Metco (Us) Inc. | Reduced carbides ferrous alloys |
| CN113195759B (zh) | 2018-10-26 | 2023-09-19 | 欧瑞康美科（美国）公司 | 耐腐蚀和耐磨镍基合金 |
| WO2020198302A1 (en) | 2019-03-28 | 2020-10-01 | Oerlikon Metco (Us) Inc. | Thermal spray iron-based alloys for coating engine cylinder bores |
| AU2020269275B2 (en) | 2019-05-03 | 2025-05-22 | Oerlikon Metco (Us) Inc. | Powder feedstock for wear resistant bulk welding configured to optimize manufacturability |
| CN110923539B (zh) * | 2019-12-17 | 2021-10-08 | 南方科技大学 | 一种高熵合金及其制备方法和压缩性能测试方法 |
| CN111455199A (zh) * | 2020-04-16 | 2020-07-28 | 江苏星火特钢有限公司 | 一种高温合金真空感应炉冶炼工艺 |
| CN112301255B (zh) * | 2020-10-27 | 2021-07-30 | 上海交通大学 | 一种模具用高导热高强Co-Fe-Ni合金及其增材制造方法 |
| CN119040771B (zh) * | 2024-09-05 | 2025-06-06 | 重庆材料研究院有限公司 | 一种高机械品质因数马氏体弹性合金 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2859149A (en) | 1952-01-14 | 1958-11-04 | Straumann Reinhard | Manufacture of watch springs utilizing wire converted into strip |
| GB918620A (en) | 1959-09-25 | 1963-02-13 | Straumann Inst Ag | Improvements in clockwork and like mechanisms |
| US3148092A (en) * | 1960-11-17 | 1964-09-08 | Westinghouse Electric Corp | Process for producing sheets of magnetic materials |
| JPS5019511B1 (enExample) | 1970-03-18 | 1975-07-08 | ||
| US3673010A (en) | 1970-05-19 | 1972-06-27 | Tohoku Special Steel Works Ltd | Cold-workable permanent magnet alloy |
| CN1006237B (zh) * | 1985-04-01 | 1989-12-27 | 首都钢铁公司特殊钢公司冶金研究所 | 高性能正频率温度系数恒弹性合金 |
| JPS63195249A (ja) | 1987-02-10 | 1988-08-12 | Res Inst Electric Magnetic Alloys | 高温恒弾性合金 |
| JP3110507B2 (ja) | 1991-09-19 | 2000-11-20 | ウエスト電気株式会社 | フィルム電動巻上げ装置 |
| US6863435B2 (en) * | 1997-08-11 | 2005-03-08 | Seiko Epson Corporation | Spring, mainspring, hairspring, and driving mechanism and timepiece based thereon |
| JP3982290B2 (ja) * | 1997-08-28 | 2007-09-26 | セイコーエプソン株式会社 | バネ、ヒゲゼンマイ、および時計 |
| KR100244232B1 (en) * | 1997-12-03 | 2000-02-01 | Lg Electronics Inc | Shadow mask for cathode ray tube and method of manufacturing thereof |
| CN1344386A (zh) | 2000-01-21 | 2002-04-10 | 精工电子有限公司 | 机械表制造方法 |
| CA2422753C (en) * | 2000-09-21 | 2007-11-27 | Nippon Steel Corporation | Steel plate excellent in shape freezing property and method for production thereof |
| JP4421877B2 (ja) * | 2003-03-26 | 2010-02-24 | セイコーインスツル株式会社 | Ｃｏ−Ｎｉ基高弾性合金及びＣｏ−Ｎｉ基高弾性合金を用いた動力ぜんまいとその製造方法 |
| JP2004308827A (ja) * | 2003-04-09 | 2004-11-04 | Sii Micro Parts Ltd | ぜんまいの製造方法 |
| JP4357977B2 (ja) * | 2004-02-04 | 2009-11-04 | 住友電工スチールワイヤー株式会社 | ばね用鋼線 |
| US8591669B2 (en) * | 2004-11-23 | 2013-11-26 | University Of Maryland | Method of texturing polycrystalline iron/gallium alloys and compositions thereof |
| JP2006214822A (ja) | 2005-02-02 | 2006-08-17 | Seiko Instruments Inc | 緩急可能なひげぜんまいを含む機械式時計 |
| JP2007327084A (ja) * | 2006-06-06 | 2007-12-20 | Kobe Steel Ltd | 伸線加工性に優れた線材およびその製造方法 |
-
2009
- 2009-11-16 US US13/125,831 patent/US8684594B2/en active Active
- 2009-11-16 WO PCT/JP2009/069458 patent/WO2010055943A1/ja not_active Ceased
- 2009-11-16 CN CN200980145779.3A patent/CN102216480B/zh active Active
- 2009-11-16 EP EP09826188.6A patent/EP2351864B1/en active Active
- 2009-11-16 JP JP2009261376A patent/JP5189580B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010055943A9 (ja) | 2010-09-23 |
| EP2351864B1 (en) | 2016-08-10 |
| CN102216480A (zh) | 2011-10-12 |
| US20110286312A1 (en) | 2011-11-24 |
| US8684594B2 (en) | 2014-04-01 |
| JP2010138491A (ja) | 2010-06-24 |
| CN102216480B (zh) | 2014-08-20 |
| WO2010055943A1 (ja) | 2010-05-20 |
| EP2351864A1 (en) | 2011-08-03 |
| EP2351864A4 (en) | 2013-02-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5189580B2 (ja) | 磁性不感高硬度恒弾性合金及びその製造法、並びにひげぜんまい、機械式駆動装置及び時計 | |
| JP2010138491A5 (enExample) | ||
| JP5215855B2 (ja) | Ｆｅ基合金及びその製造方法 | |
| JP5065904B2 (ja) | 形状記憶性及び超弾性を有する鉄系合金及びその製造方法 | |
| Wang et al. | Ternary Fe–P–C bulk metallic glass with good soft-magnetic and mechanical properties | |
| CN108754333B (zh) | 奥氏体系不锈钢板及使用其的高弹性极限非磁性钢材的制造方法 | |
| JP5005834B2 (ja) | Ｆｅ基形状記憶合金及びその製造方法 | |
| JP2013542322A (ja) | 強靭鉄系バルク金属ガラス合金 | |
| JP4421877B2 (ja) | Ｃｏ−Ｎｉ基高弾性合金及びＣｏ−Ｎｉ基高弾性合金を用いた動力ぜんまいとその製造方法 | |
| JP5059035B2 (ja) | 高弾性・恒弾性合金及びその製造法並びに精密機器 | |
| JP5486050B2 (ja) | 高弾性・恒弾性合金及びその製造法並びに精密機器 | |
| CN109477175A (zh) | Fe基形状记忆合金材料及其制造方法 | |
| JP2021500469A (ja) | 変態誘起塑性高エントロピー合金及びその製造方法 | |
| JP2004238720A (ja) | 形状記憶合金 | |
| JP2006183104A (ja) | 冷間加工性に優れた高強度チタン合金 | |
| JPWO2007066555A1 (ja) | Ｃｏ基合金及びその製造方法 | |
| WO2014157146A1 (ja) | オーステナイト系ステンレス鋼板およびそれを用いた高強度鋼材の製造方法 | |
| JP2003268501A (ja) | Ｆｅ基形状記憶合金及びその製造方法 | |
| US20250320585A1 (en) | Fe-Mn ALLOY, HAIRSPRING FOR TIMEPIECE, AND METHOD FOR PRODUCING Fe-Mn ALLOY | |
| JP6459078B2 (ja) | Ｆｅ−Ｍｎ系恒弾性・不感磁性合金 | |
| JP4037104B2 (ja) | 高耐食性磁石合金及び製造法 | |
| Ikram et al. | Effect of copper and zirconium addition on properties of Fe-Co-Si-B-Nb bulk metallic glasses | |
| JPH0310052A (ja) | 高耐食性，高強度，高耐摩耗性に優れる高透磁率非晶質合金とその合金の磁気特性の改善方法 | |
| WO2025225580A1 (ja) | Ｆｅ―Ｍｎ合金及びＦｅ―Ｍｎ合金からなる時計用ひげぜんまい | |
| JPS6130405B2 (enExample) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100512 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100512 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20121023 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121207 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130115 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130124 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20160201 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 Ref document number: 5189580 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313117 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |