CN102212251B - 由聚合物酸性胶体制备的水分散性聚噻吩 - Google Patents

由聚合物酸性胶体制备的水分散性聚噻吩 Download PDF

Info

Publication number
CN102212251B
CN102212251B CN2011100999483A CN201110099948A CN102212251B CN 102212251 B CN102212251 B CN 102212251B CN 2011100999483 A CN2011100999483 A CN 2011100999483A CN 201110099948 A CN201110099948 A CN 201110099948A CN 102212251 B CN102212251 B CN 102212251B
Authority
CN
China
Prior art keywords
formula
acid
dispersion
ether
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2011100999483A
Other languages
English (en)
Chinese (zh)
Other versions
CN102212251A (zh
Inventor
C·-H·修
Y·曹
S·H·金
D·D·莱克洛克斯
H·李
C·D·麦克弗森
C·张
H·斯库拉森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/669,494 external-priority patent/US7431866B2/en
Priority claimed from US10/802,704 external-priority patent/US7390438B2/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN102212251A publication Critical patent/CN102212251A/zh
Application granted granted Critical
Publication of CN102212251B publication Critical patent/CN102212251B/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H10K85/1135—Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/08—Polysulfonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Electroluminescent Light Sources (AREA)
CN2011100999483A 2003-04-22 2004-04-22 由聚合物酸性胶体制备的水分散性聚噻吩 Expired - Fee Related CN102212251B (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US46437003P 2003-04-22 2003-04-22
US60/464,370 2003-04-22
US10/669,494 2003-09-24
US10/669,494 US7431866B2 (en) 2002-09-24 2003-09-24 Water dispersible polythiophenes made with polymeric acid colloids
US10/802,704 US7390438B2 (en) 2003-04-22 2004-03-17 Water dispersible substituted polydioxythiophenes made with fluorinated polymeric sulfonic acid colloids
US10/802,704 2004-03-17

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN2004800107982A Division CN1777648B (zh) 2003-04-22 2004-04-22 由聚合物酸性胶体制备的水分散性聚噻吩

Publications (2)

Publication Number Publication Date
CN102212251A CN102212251A (zh) 2011-10-12
CN102212251B true CN102212251B (zh) 2013-06-19

Family

ID=46123579

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2011100999483A Expired - Fee Related CN102212251B (zh) 2003-04-22 2004-04-22 由聚合物酸性胶体制备的水分散性聚噻吩
CN2004800107982A Expired - Lifetime CN1777648B (zh) 2003-04-22 2004-04-22 由聚合物酸性胶体制备的水分散性聚噻吩

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN2004800107982A Expired - Lifetime CN1777648B (zh) 2003-04-22 2004-04-22 由聚合物酸性胶体制备的水分散性聚噻吩

Country Status (3)

Country Link
JP (1) JP4851323B2 (https=)
CN (2) CN102212251B (https=)
TW (1) TWI373483B (https=)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4464277B2 (ja) 2002-09-24 2010-05-19 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 導電性有機ポリマー／ナノ粒子複合材料およびその使用方法
US7317047B2 (en) 2002-09-24 2008-01-08 E.I. Du Pont De Nemours And Company Electrically conducting organic polymer/nanoparticle composites and methods for use thereof
AU2003275203A1 (en) 2002-09-24 2004-04-19 E.I. Du Pont De Nemours And Company Water dispersible polythiophenes made with polymeric acid colloids
CA2499364A1 (en) 2002-09-24 2004-04-08 E. I. Du Pont De Nemours And Company Water dispersible polyanilines made with polymeric acid colloids for electronics applications
US20050175861A1 (en) * 2004-02-10 2005-08-11 H.C. Starck Gmbh Polythiophene compositions for improving organic light-emitting diodes
US7250461B2 (en) * 2004-03-17 2007-07-31 E. I. Du Pont De Nemours And Company Organic formulations of conductive polymers made with polymeric acid colloids for electronics applications, and methods for making such formulations
US7351358B2 (en) 2004-03-17 2008-04-01 E.I. Du Pont De Nemours And Company Water dispersible polypyrroles made with polymeric acid colloids for electronics applications
JP5241997B2 (ja) * 2005-03-08 2013-07-17 信越ポリマー株式会社 導電性高分子溶液および導電性塗膜
WO2007002740A2 (en) * 2005-06-28 2007-01-04 E. I. Du Pont De Nemours And Company Buffer compositions
KR101356296B1 (ko) 2005-06-28 2014-02-06 이 아이 듀폰 디 네모아 앤드 캄파니 높은 일 함수의 투명한 도체
US20060292362A1 (en) * 2005-06-28 2006-12-28 Che-Hsiung Hsu Bilayer anode
KR101193180B1 (ko) * 2005-11-14 2012-10-19 삼성디스플레이 주식회사 전도성 고분자 조성물 및 이로부터 얻은 막을 구비한 전자소자
US8216680B2 (en) 2006-02-03 2012-07-10 E I Du Pont De Nemours And Company Transparent composite conductors having high work function
US20070278458A1 (en) * 2006-04-13 2007-12-06 Martello Mark T Electrically conductive polymer compositions
US20080191172A1 (en) 2006-12-29 2008-08-14 Che-Hsiung Hsu High work-function and high conductivity compositions of electrically conducting polymers
EP2143144B1 (en) * 2007-04-27 2018-11-28 Merck Patent GmbH Organic photovoltaic cells
CN101125950B (zh) * 2007-08-03 2010-05-26 上海复旦天臣新技术有限公司 空穴传输材料的制备方法
US8183319B2 (en) * 2007-10-31 2012-05-22 Air Products And Chemicals, Inc. Film forming additive formulations of conductive polymers
JP5243067B2 (ja) * 2008-03-10 2013-07-24 日機装株式会社 導電性ポリマーの導電性向上方法
EP2280433A1 (en) * 2008-04-28 2011-02-02 Sumitomo Chemical Company, Limited Organic photoelectric conversion element and manufacturing method thereof
JP2010192863A (ja) * 2008-05-23 2010-09-02 Sumitomo Chemical Co Ltd 有機光電変換素子およびその製造方法
US8785913B2 (en) 2008-12-27 2014-07-22 E I Du Pont De Nemours And Company Buffer bilayers for electronic devices
US8766239B2 (en) 2008-12-27 2014-07-01 E I Du Pont De Nemours And Company Buffer bilayers for electronic devices
CN102395628B (zh) 2009-04-21 2016-01-20 E.I.内穆尔杜邦公司 导电聚合物组合物和由其制得的膜
JP2012524834A (ja) 2009-04-24 2012-10-18 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 導電性ポリマー組成物およびそれから作製されたフィルム
JP2011093993A (ja) * 2009-10-28 2011-05-12 Marubishi Oil Chem Co Ltd 導電性ポリ（３，４−エチレンジオキシチオフェン）コロイド水溶液及びその製造方法
WO2011105148A1 (ja) * 2010-02-24 2011-09-01 コニカミノルタホールディングス株式会社 透明導電膜、および有機エレクトロルミネッセンス素子
CN101812171B (zh) * 2010-04-13 2012-01-25 无锡中美亿芯生物科技有限公司 一种用于生物传感器的导电聚合物及其制备方法
JP5573539B2 (ja) * 2010-09-21 2014-08-20 トヨタ自動車株式会社 燃料電池用電極の製造方法
WO2013047660A1 (ja) 2011-09-28 2013-04-04 コニカミノルタホールディングス株式会社 透明電極、有機電子素子および透明電極の製造方法
JP5764092B2 (ja) * 2012-06-04 2015-08-12 Ｊｆｅケミカル株式会社 導電性高分子の分散体およびその製造方法
TWI644463B (zh) * 2012-10-26 2018-12-11 黑拉耶烏斯貴金屬公司 在ＯＬＥＤｓ中具有高導電度及高效能之透明層及其製造方法
JP5955786B2 (ja) 2013-01-07 2016-07-20 出光興産株式会社 導電性高分子組成物
CN103709417B (zh) * 2013-12-24 2016-06-29 深圳新宙邦科技股份有限公司 一种聚噻吩类衍生物水分散体及其制备方法
CN104448256B (zh) * 2014-12-02 2017-04-12 浙江中科立德新材料有限公司 高导电pedot：pss水溶液的制备方法
JP6724526B2 (ja) * 2016-04-27 2020-07-15 東ソー株式会社 水溶性導電性高分子、その製造方法、その導電性高分子水溶液、及びその用途
JP7077944B2 (ja) * 2017-01-18 2022-05-31 日産化学株式会社 インク組成物
CN111192966B (zh) * 2020-01-09 2023-07-25 通威太阳能(眉山)有限公司 钙钛矿太阳能电池及其制备方法
US11492547B2 (en) 2020-06-04 2022-11-08 UbiQD, Inc. Low-PH nanoparticles and ligands
CN114316223B (zh) * 2021-12-31 2022-09-27 华中科技大学 一种导电聚乙烯二氧噻吩的醇分散液及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0440957A2 (de) * 1990-02-08 1991-08-14 Bayer Ag Neue Polythiophen-Dispersionen, ihre Herstellung und ihre Verwendung
EP0564911A2 (de) * 1992-04-06 1993-10-13 Agfa-Gevaert AG Antistatische Kunststoffteile
US6391481B1 (en) * 1998-09-12 2002-05-21 Bayer Aktiengesellschaft Auxiliary layers for electroluminescent assemblies

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69319200T2 (de) * 1992-10-14 1999-01-28 Agfa-Gevaert N.V., Mortsel Antistatische Beschichtungszusammensetzung
ATE287929T1 (de) * 1994-05-06 2005-02-15 Bayer Ag Leitfähige beschichtungen hergestellt aus mischungen enthaltend polythiophen und lösemittel
JP3937113B2 (ja) * 1998-06-05 2007-06-27 日産化学工業株式会社 有機−無機複合導電性ゾル及びその製造法
EP1054414B1 (en) * 1999-05-20 2003-03-12 Agfa-Gevaert Method for patterning a layer of conductive polymer
JP4363050B2 (ja) * 2002-01-31 2009-11-11 住友化学株式会社 有機エレクトロルミネッセンス素子
AU2003275203A1 (en) * 2002-09-24 2004-04-19 E.I. Du Pont De Nemours And Company Water dispersible polythiophenes made with polymeric acid colloids
JP4464277B2 (ja) * 2002-09-24 2010-05-19 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 導電性有機ポリマー／ナノ粒子複合材料およびその使用方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0440957A2 (de) * 1990-02-08 1991-08-14 Bayer Ag Neue Polythiophen-Dispersionen, ihre Herstellung und ihre Verwendung
EP0564911A2 (de) * 1992-04-06 1993-10-13 Agfa-Gevaert AG Antistatische Kunststoffteile
US6391481B1 (en) * 1998-09-12 2002-05-21 Bayer Aktiengesellschaft Auxiliary layers for electroluminescent assemblies

Also Published As

Publication number Publication date
CN1777648B (zh) 2011-06-08
JP2006527277A (ja) 2006-11-30
CN102212251A (zh) 2011-10-12
TW200502278A (en) 2005-01-16
CN1777648A (zh) 2006-05-24
TWI373483B (en) 2012-10-01
JP4851323B2 (ja) 2012-01-11

Similar Documents

Publication Publication Date Title
CN102212251B (zh) 由聚合物酸性胶体制备的水分散性聚噻吩
KR101075264B1 (ko) 중합체성 산 콜로이드를 사용하여 제조된 수-분산성폴리티오펜
CN1976969B (zh) 聚二氧噻吩与聚合酸的胶体和水混溶的有机液体的水分散体
US7351358B2 (en) Water dispersible polypyrroles made with polymeric acid colloids for electronics applications
US7744777B2 (en) Water dispersible polyanilines made with polymeric acid colloids for electronics applications
EP1730212B1 (en) Organic formulations of polythiophenes and polypyrrole polymers made with polymeric acid colloids for electronics applications
US7431866B2 (en) Water dispersible polythiophenes made with polymeric acid colloids
CN100497439C (zh) 用聚合物酸胶体制备的可水分散的聚噻吩
US20070004899A1 (en) Water dispersible polythiophenes made with polymeric acid colloids
US20120165467A1 (en) New polyelectrolyte complexes and the use thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130619

Termination date: 20160422