CN102153849B - 一种脂肪族聚碳酸酯合金材料 - Google Patents
一种脂肪族聚碳酸酯合金材料 Download PDFInfo
- Publication number
- CN102153849B CN102153849B CN 201110092575 CN201110092575A CN102153849B CN 102153849 B CN102153849 B CN 102153849B CN 201110092575 CN201110092575 CN 201110092575 CN 201110092575 A CN201110092575 A CN 201110092575A CN 102153849 B CN102153849 B CN 102153849B
- Authority
- CN
- China
- Prior art keywords
- aliphatic polycarbonate
- alloy material
- esterified cellulose
- cellulose
- vulcabond
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 75
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 75
- 125000001931 aliphatic group Chemical group 0.000 title claims abstract description 74
- 239000000956 alloy Substances 0.000 title claims abstract description 40
- 239000001913 cellulose Substances 0.000 claims abstract description 45
- 229920002678 cellulose Polymers 0.000 claims abstract description 42
- 238000002156 mixing Methods 0.000 claims abstract description 29
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002844 melting Methods 0.000 claims abstract description 12
- 230000008018 melting Effects 0.000 claims abstract description 12
- 229920001577 copolymer Polymers 0.000 claims abstract description 5
- 229920000379 polypropylene carbonate Polymers 0.000 claims description 55
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 42
- 239000000654 additive Substances 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 10
- 235000011089 carbon dioxide Nutrition 0.000 claims description 9
- 239000004927 clay Substances 0.000 claims description 7
- -1 polypropylene carbonate Polymers 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 4
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 229920001727 cellulose butyrate Polymers 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000004593 Epoxy Chemical class 0.000 claims description 2
- 239000001856 Ethyl cellulose Substances 0.000 claims description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical group CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004902 Softening Agent Substances 0.000 claims description 2
- 229920005603 alternating copolymer Polymers 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001249 ethyl cellulose Polymers 0.000 claims description 2
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000012745 toughening agent Substances 0.000 claims description 2
- 125000006839 xylylene group Chemical group 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 26
- 239000000203 mixture Substances 0.000 abstract description 20
- 230000015556 catabolic process Effects 0.000 abstract description 13
- 238000006731 degradation reaction Methods 0.000 abstract description 13
- 239000001569 carbon dioxide Substances 0.000 abstract description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 3
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 13
- 238000001291 vacuum drying Methods 0.000 description 13
- 230000007704 transition Effects 0.000 description 12
- 238000005303 weighing Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 238000007599 discharging Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 239000011118 polyvinyl acetate Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920002689 polyvinyl acetate Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920006125 amorphous polymer Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical group [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Images
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110092575 CN102153849B (zh) | 2011-04-13 | 2011-04-13 | 一种脂肪族聚碳酸酯合金材料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201110092575 CN102153849B (zh) | 2011-04-13 | 2011-04-13 | 一种脂肪族聚碳酸酯合金材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102153849A CN102153849A (zh) | 2011-08-17 |
CN102153849B true CN102153849B (zh) | 2013-08-07 |
Family
ID=44435543
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201110092575 Expired - Fee Related CN102153849B (zh) | 2011-04-13 | 2011-04-13 | 一种脂肪族聚碳酸酯合金材料 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102153849B (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103571166B (zh) * | 2012-07-20 | 2015-12-09 | 东北林业大学 | 纤维素、聚碳酸亚丙酯组合物 |
CN107793710B (zh) * | 2016-09-06 | 2020-09-04 | 中国石油化工股份有限公司 | 热塑性纤维素与脂肪族共聚酯共混物3d打印丝材及制备方法 |
CN106543424B (zh) * | 2016-11-25 | 2018-11-30 | 河南大学 | 一种聚碳酸亚丙酯/poss杂化材料及其制备方法 |
CN106543423B (zh) * | 2016-11-25 | 2018-12-28 | 河南大学 | 脂肪族聚碳酸酯复合材料及其制备方法 |
CN107353400B (zh) * | 2017-07-13 | 2019-02-01 | 华中科技大学 | 一种聚丙撑碳酸酯/纤维素纳米晶复合材料的制备方法 |
CN108559243B (zh) * | 2018-03-30 | 2021-03-30 | 佛山科学技术学院 | 一种高透光率的二氧化碳基聚碳酸酯复合材料及其制备方法和应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007217611A (ja) * | 2006-02-17 | 2007-08-30 | Dainichiseika Color & Chem Mfg Co Ltd | 生分解性樹脂組成物および成形品 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60158252A (ja) * | 1984-01-30 | 1985-08-19 | Idemitsu Petrochem Co Ltd | ポリカ−ボネ−ト樹脂組成物 |
-
2011
- 2011-04-13 CN CN 201110092575 patent/CN102153849B/zh not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007217611A (ja) * | 2006-02-17 | 2007-08-30 | Dainichiseika Color & Chem Mfg Co Ltd | 生分解性樹脂組成物および成形品 |
Non-Patent Citations (1)
Title |
---|
张志豪等.二氧化碳-环氧丙烷共聚物/乙基纤维素共混物的研究.《应用化学》.2002,(第11期),1027-1031. * |
Also Published As
Publication number | Publication date |
---|---|
CN102153849A (zh) | 2011-08-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102153849B (zh) | 一种脂肪族聚碳酸酯合金材料 | |
CN100378138C (zh) | 改进二氧化碳-环氧丙烷共聚物脆性和冷流性的方法 | |
CN102977319B (zh) | 可降解聚乳酸两嵌段共聚物、制备方法及其在改性聚乳酸中的应用 | |
CN102391628B (zh) | 一种聚乳酸/尼龙11合金材料 | |
CN110204879B (zh) | 聚碳酸酯组合物及其制备方法 | |
CN102443256A (zh) | 一种高耐热pc/asa合金材料及其制备方法 | |
CN111718591A (zh) | 一种含有木质素的生物基复合材料及其制备方法 | |
CN102690444B (zh) | 淀粉基生物降解树脂组合物及其制备方法 | |
WO2023005869A1 (zh) | 一种耐长期热氧老化的聚碳酸酯/聚酯合金组合物及其制备方法 | |
CN107880503A (zh) | 一种phbv/pbat/ehbp共混物及其制备方法 | |
CA2929129A1 (en) | Durable high performance heat resistant polycarbonate (pc) and polylactide (pla) blends and compositions and methods of making those | |
CN107501889A (zh) | 一种高黑高光泽易加工聚碳酸酯组合物及其制备方法 | |
CN113105723A (zh) | 一种增强耐热可降解聚乳酸眼镜框及其制备方法 | |
CN106189131A (zh) | 超韧耐热导电的聚乳酸/弹性体/碳纳米粒子复合材料或制品及其制备方法 | |
CN108707323B (zh) | 一种pla/ppc/hbp衍生物共混物及其制备方法 | |
CN108102320B (zh) | 一种聚乳酸/聚己内酯/聚甲醛共混物的制备方法 | |
CN105802099B (zh) | 热塑性组合物及其制备方法 | |
CN113683875B (zh) | 一种可降解高韧性耐热型聚乳酸-淀粉复合材料及制备方法 | |
CN102558816B (zh) | 一种聚碳酸酯复合材料及其制备方法 | |
CN103965599A (zh) | 一种聚乳酸/abs合金材料及其制备方法 | |
CN109851948B (zh) | 一种pvc相容共混物及其制备方法 | |
CN113831711A (zh) | 一种高韧聚乳酸组合物及其制备方法 | |
Zhang et al. | The study on the preparation and properties of PPO/PA66 Alloy with a new type of compatibtlizer B | |
CN114605800B (zh) | 一种pla/pga/(pbat/adr)共混合金及其制备方法 | |
CN112011158A (zh) | 一种共混材料的制备方法及共混材料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201124 Address after: No.428, South Road, Haian street, Hai'an City, Nantong City, Jiangsu Province, 226600 Patentee after: Nantong Jiusi Medical Equipment Co.,Ltd. Address before: 226300 No. 266 Century Avenue, hi tech Zone, Jiangsu, Nantong Patentee before: NANTONG WOTE OPTOELECTRONICS TECHNOLOGY Co.,Ltd. Effective date of registration: 20201124 Address after: 226300 No. 266 Century Avenue, hi tech Zone, Jiangsu, Nantong Patentee after: NANTONG WOTE OPTOELECTRONICS TECHNOLOGY Co.,Ltd. Address before: Hangzhou City, Zhejiang province 310036 Xiasha Higher Education Park forest Street No. 16 Patentee before: Hangzhou Normal University |
|
TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130807 |