CN102137716B - 制备甲醛的银催化剂 - Google Patents

制备甲醛的银催化剂 Download PDF

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Publication number
CN102137716B
CN102137716B CN2009801337397A CN200980133739A CN102137716B CN 102137716 B CN102137716 B CN 102137716B CN 2009801337397 A CN2009801337397 A CN 2009801337397A CN 200980133739 A CN200980133739 A CN 200980133739A CN 102137716 B CN102137716 B CN 102137716B
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CN
China
Prior art keywords
silver
colored crystal
crystal
catalyst
sol
Prior art date
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Expired - Fee Related
Application number
CN2009801337397A
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English (en)
Chinese (zh)
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CN102137716A (zh
Inventor
M·布兰科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aigexi Co ltd
Meimeike International Co ltd
Original Assignee
Degussa GmbH
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Publication of CN102137716A publication Critical patent/CN102137716A/zh
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Expired - Fee Related legal-status Critical Current
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/398—Egg yolk like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/04—Formaldehyde

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Powder Metallurgy (AREA)
CN2009801337397A 2008-09-01 2009-08-26 制备甲醛的银催化剂 Expired - Fee Related CN102137716B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008045148.7 2008-09-01
DE102008045148A DE102008045148A1 (de) 2008-09-01 2008-09-01 Silberkatalysator zur Formaldehyd-Herstellung
PCT/EP2009/006170 WO2010022923A1 (en) 2008-09-01 2009-08-26 Silver catalyst for formaldehyde preparation

Publications (2)

Publication Number Publication Date
CN102137716A CN102137716A (zh) 2011-07-27
CN102137716B true CN102137716B (zh) 2013-07-24

Family

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CN2009801337397A Expired - Fee Related CN102137716B (zh) 2008-09-01 2009-08-26 制备甲醛的银催化剂

Country Status (14)

Country Link
US (1) US8471071B2 (https=)
EP (2) EP2321044B1 (https=)
JP (1) JP5528450B2 (https=)
KR (1) KR101634082B1 (https=)
CN (1) CN102137716B (https=)
AU (1) AU2009287008B2 (https=)
BR (1) BRPI0918277B8 (https=)
CA (1) CA2735745C (https=)
DE (1) DE102008045148A1 (https=)
ES (1) ES2787550T3 (https=)
MY (1) MY153887A (https=)
RU (1) RU2503497C2 (https=)
TW (1) TWI436824B (https=)
WO (1) WO2010022923A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
US10035136B2 (en) 2014-03-25 2018-07-31 Tpc Group Llc Catalyst for reduced nitrogen oxide (NOx) emissions in an oxodehydrogenation process
CN105363320B (zh) * 2015-11-10 2018-05-01 沭阳县金辉化工有限公司 一种新型高效脱醇甲醛吸收塔
US10392333B2 (en) * 2017-12-21 2019-08-27 Purdue Research Foundation Method of producing formaldehyde from methanol

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1110647A2 (en) * 1999-12-22 2001-06-27 Mitsui Mining and Smelting Co., Ltd Paste to be fired for forming circuit board and method for preparing surface-modified silver powder

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JPS5630064B2 (https=) * 1974-06-04 1981-07-13
JPS5759637A (en) * 1980-09-22 1982-04-10 Suredoneajiatsuki Nii Nefutepe Manufacture of carbonyl compound
US4330437A (en) * 1980-11-05 1982-05-18 Borden, Inc. Supported silver catalyst and a process of preparing it
NL8502993A (nl) * 1985-11-01 1987-06-01 Dow Chemical Nederland Zilverkatalysator, alsmede werkwijze voor de bereiding daarvan.
JP2508847B2 (ja) * 1989-07-20 1996-06-19 株式会社ハイミラー ＳｉＯ２被膜が形成された銀コ―トガラスフレ―クの製造法
US5948726A (en) * 1994-12-07 1999-09-07 Project Earth Industries, Inc. Adsorbent and/or catalyst and binder system and method of making therefor
PT818561E (pt) * 1995-12-28 2000-10-31 Consejo Superior Investigacion Revestimentos protectores produzidos por sol-gel sobre reflectores de prata
AUPQ364699A0 (en) 1999-10-25 1999-11-18 University Of Queensland, The Polycrystalline silver catalysts for methanol oxidation to formal dehyde
US6994948B2 (en) * 2001-10-12 2006-02-07 E.I. Du Pont De Nemours And Company, Inc. Aqueous developable photoimageable thick film compositions
US20030166972A1 (en) * 2002-02-20 2003-09-04 Regents Of The University Of California Office Of Technology Licensing Process for production of formaldehyde from dimethyl ether
US7226953B1 (en) * 2003-11-17 2007-06-05 Los Alamos National Security, Llc Nanocrystal/sol-gel nanocomposites
JP4149385B2 (ja) * 2004-01-27 2008-09-10 三井金属鉱業株式会社 酸化アルミニウム被覆微粒銀粉およびその製造方法
JP4478526B2 (ja) * 2004-07-20 2010-06-09 大研化学工業株式会社 非合金金属粉末及び合金金属粉末の製造方法
EP1676625A1 (en) * 2004-12-28 2006-07-05 Mitsubishi Denki Kabushiki Kaisha Method and catalyst for the oxidative decomposition of formaldehyde gas
KR20070102717A (ko) * 2005-01-24 2007-10-19 신벤션 아게 금속 함유 복합 물질
ATE434024T1 (de) * 2005-02-28 2009-07-15 Samsung Sdi Germany Gmbh Metallische tinte und substrat für eine anzeige und deren fertigungsmethode
US20060192183A1 (en) * 2005-02-28 2006-08-31 Andreas Klyszcz Metal ink, method of preparing the metal ink, substrate for display, and method of manufacturing the substrate
FR2882746B1 (fr) * 2005-03-01 2007-04-27 Commissariat Energie Atomique Procede de preparation d'une solution sol-gel et utilisation de cette solution pour constituer un revetement pour proteger un substrat a surface metallique
KR20070095497A (ko) * 2005-09-30 2007-10-01 삼성에스디아이 주식회사 전극 형성용 전도성 분체, 이의 제조방법, 이를 이용한플라즈마 디스플레이 패널의 전극 형성방법, 및 이를포함하는 플라즈마 디스플레이 패널
CN101501864B (zh) * 2006-06-19 2012-08-08 卡伯特公司 光伏导电部件及其形成方法

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
EP1110647A2 (en) * 1999-12-22 2001-06-27 Mitsui Mining and Smelting Co., Ltd Paste to be fired for forming circuit board and method for preparing surface-modified silver powder

Also Published As

Publication number Publication date
TWI436824B (zh) 2014-05-11
US20110201843A1 (en) 2011-08-18
RU2011112015A (ru) 2012-10-10
US8471071B2 (en) 2013-06-25
TW201012543A (en) 2010-04-01
EP2321044B1 (en) 2020-02-26
ES2787550T3 (es) 2020-10-16
EP3685915A1 (en) 2020-07-29
BRPI0918277B8 (pt) 2023-05-09
MY153887A (en) 2015-04-15
AU2009287008A1 (en) 2010-03-04
WO2010022923A1 (en) 2010-03-04
JP5528450B2 (ja) 2014-06-25
AU2009287008B2 (en) 2014-10-02
JP2012501241A (ja) 2012-01-19
BRPI0918277B1 (pt) 2018-01-16
CA2735745C (en) 2016-11-01
KR101634082B1 (ko) 2016-06-28
DE102008045148A1 (de) 2010-03-04
EP2321044A1 (en) 2011-05-18
KR20110055705A (ko) 2011-05-25
CA2735745A1 (en) 2010-03-04
RU2503497C2 (ru) 2014-01-10
CN102137716A (zh) 2011-07-27
BRPI0918277A2 (pt) 2015-12-15

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Address after: German F Faure F Haim

Patentee after: Aigexi Co.,Ltd.

Address before: German F Faure F Haim

Patentee before: Meimeike International Co.,Ltd.

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TR01 Transfer of patent right

Effective date of registration: 20221125

Address after: German F Faure F Haim

Patentee after: Meimeike International Co.,Ltd.

Address before: German F Faure F Haim

Patentee before: ALLGEMEINE GOLD- UND SILBERSCHEIDEANSTALT AG

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Granted publication date: 20130724

CF01 Termination of patent right due to non-payment of annual fee