DE102008045148A1 - Silberkatalysator zur Formaldehyd-Herstellung - Google Patents

Silberkatalysator zur Formaldehyd-Herstellung Download PDF

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Publication number
DE102008045148A1
DE102008045148A1 DE102008045148A DE102008045148A DE102008045148A1 DE 102008045148 A1 DE102008045148 A1 DE 102008045148A1 DE 102008045148 A DE102008045148 A DE 102008045148A DE 102008045148 A DE102008045148 A DE 102008045148A DE 102008045148 A1 DE102008045148 A1 DE 102008045148A1
Authority
DE
Germany
Prior art keywords
silver
silver crystals
crystals
sol
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE102008045148A
Other languages
German (de)
English (en)
Inventor
Marco Brenk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agosi Ag De
Original Assignee
Degussa GmbH
Allgemeine Gold und Silberscheideanstalt AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH, Allgemeine Gold und Silberscheideanstalt AG filed Critical Degussa GmbH
Priority to DE102008045148A priority Critical patent/DE102008045148A1/de
Priority to TW098127604A priority patent/TWI436824B/zh
Priority to MYPI2011000725A priority patent/MY153887A/en
Priority to PCT/EP2009/006170 priority patent/WO2010022923A1/en
Priority to RU2011112015/04A priority patent/RU2503497C2/ru
Priority to JP2011524246A priority patent/JP5528450B2/ja
Priority to EP09778113.2A priority patent/EP2321044B1/en
Priority to US13/061,348 priority patent/US8471071B2/en
Priority to KR1020117007274A priority patent/KR101634082B1/ko
Priority to BRPI0918277A priority patent/BRPI0918277B8/pt
Priority to EP20158463.8A priority patent/EP3685915A1/en
Priority to ES09778113T priority patent/ES2787550T3/es
Priority to CA2735745A priority patent/CA2735745C/en
Priority to AU2009287008A priority patent/AU2009287008B2/en
Priority to CN2009801337397A priority patent/CN102137716B/zh
Publication of DE102008045148A1 publication Critical patent/DE102008045148A1/de
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/398—Egg yolk like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/04—Formaldehyde

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Powder Metallurgy (AREA)
DE102008045148A 2008-09-01 2008-09-01 Silberkatalysator zur Formaldehyd-Herstellung Pending DE102008045148A1 (de)

Priority Applications (15)

Application Number Priority Date Filing Date Title
DE102008045148A DE102008045148A1 (de) 2008-09-01 2008-09-01 Silberkatalysator zur Formaldehyd-Herstellung
TW098127604A TWI436824B (zh) 2008-09-01 2009-08-17 供甲醛製備用之銀觸媒
MYPI2011000725A MY153887A (en) 2008-09-01 2009-08-26 Silver catalyst for formaldehyde preparation
PCT/EP2009/006170 WO2010022923A1 (en) 2008-09-01 2009-08-26 Silver catalyst for formaldehyde preparation
RU2011112015/04A RU2503497C2 (ru) 2008-09-01 2009-08-26 Серебряный катализатор для получения формальдегида
JP2011524246A JP5528450B2 (ja) 2008-09-01 2009-08-26 ホルムアルデヒド製造用銀触媒
EP09778113.2A EP2321044B1 (en) 2008-09-01 2009-08-26 Coated silver particle catalyst for formaldehyde preparation
US13/061,348 US8471071B2 (en) 2008-09-01 2009-08-26 Silver catalyst for formaldehyde preparation
KR1020117007274A KR101634082B1 (ko) 2008-09-01 2009-08-26 포름알데히드 제조를 위한 은 촉매
BRPI0918277A BRPI0918277B8 (pt) 2008-09-01 2009-08-26 "processo para produzir cristais de prata, cristais de prata, catalisador de prata e uso dos referidos cristais"
EP20158463.8A EP3685915A1 (en) 2008-09-01 2009-08-26 Silver catalyst for formaldehyde preparation
ES09778113T ES2787550T3 (es) 2008-09-01 2009-08-26 Catalizador de partículas de plata recubiertas para la preparación de formaldehído
CA2735745A CA2735745C (en) 2008-09-01 2009-08-26 Silver catalyst for formaldehyde preparation
AU2009287008A AU2009287008B2 (en) 2008-09-01 2009-08-26 Silver catalyst for formaldehyde preparation
CN2009801337397A CN102137716B (zh) 2008-09-01 2009-08-26 制备甲醛的银催化剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102008045148A DE102008045148A1 (de) 2008-09-01 2008-09-01 Silberkatalysator zur Formaldehyd-Herstellung

Publications (1)

Publication Number Publication Date
DE102008045148A1 true DE102008045148A1 (de) 2010-03-04

Family

ID=41259600

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102008045148A Pending DE102008045148A1 (de) 2008-09-01 2008-09-01 Silberkatalysator zur Formaldehyd-Herstellung

Country Status (14)

Country Link
US (1) US8471071B2 (https=)
EP (2) EP2321044B1 (https=)
JP (1) JP5528450B2 (https=)
KR (1) KR101634082B1 (https=)
CN (1) CN102137716B (https=)
AU (1) AU2009287008B2 (https=)
BR (1) BRPI0918277B8 (https=)
CA (1) CA2735745C (https=)
DE (1) DE102008045148A1 (https=)
ES (1) ES2787550T3 (https=)
MY (1) MY153887A (https=)
RU (1) RU2503497C2 (https=)
TW (1) TWI436824B (https=)
WO (1) WO2010022923A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
US10035136B2 (en) 2014-03-25 2018-07-31 Tpc Group Llc Catalyst for reduced nitrogen oxide (NOx) emissions in an oxodehydrogenation process
CN105363320B (zh) * 2015-11-10 2018-05-01 沭阳县金辉化工有限公司 一种新型高效脱醇甲醛吸收塔
US10392333B2 (en) * 2017-12-21 2019-08-27 Purdue Research Foundation Method of producing formaldehyde from methanol

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001030492A1 (en) 1999-10-25 2001-05-03 The University Of Queensland Crystalline silver catalysts for methanol oxidation to formaldehyde

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JPS5630064B2 (https=) * 1974-06-04 1981-07-13
JPS5759637A (en) * 1980-09-22 1982-04-10 Suredoneajiatsuki Nii Nefutepe Manufacture of carbonyl compound
US4330437A (en) * 1980-11-05 1982-05-18 Borden, Inc. Supported silver catalyst and a process of preparing it
NL8502993A (nl) * 1985-11-01 1987-06-01 Dow Chemical Nederland Zilverkatalysator, alsmede werkwijze voor de bereiding daarvan.
JP2508847B2 (ja) * 1989-07-20 1996-06-19 株式会社ハイミラー ＳｉＯ２被膜が形成された銀コ―トガラスフレ―クの製造法
US5948726A (en) * 1994-12-07 1999-09-07 Project Earth Industries, Inc. Adsorbent and/or catalyst and binder system and method of making therefor
PT818561E (pt) * 1995-12-28 2000-10-31 Consejo Superior Investigacion Revestimentos protectores produzidos por sol-gel sobre reflectores de prata
EP1110647A3 (en) 1999-12-22 2004-02-11 Mitsui Mining and Smelting Co., Ltd Paste to be fired for forming circuit board and method for preparing surface-modified silver powder
US6994948B2 (en) * 2001-10-12 2006-02-07 E.I. Du Pont De Nemours And Company, Inc. Aqueous developable photoimageable thick film compositions
US20030166972A1 (en) * 2002-02-20 2003-09-04 Regents Of The University Of California Office Of Technology Licensing Process for production of formaldehyde from dimethyl ether
US7226953B1 (en) * 2003-11-17 2007-06-05 Los Alamos National Security, Llc Nanocrystal/sol-gel nanocomposites
JP4149385B2 (ja) * 2004-01-27 2008-09-10 三井金属鉱業株式会社 酸化アルミニウム被覆微粒銀粉およびその製造方法
JP4478526B2 (ja) * 2004-07-20 2010-06-09 大研化学工業株式会社 非合金金属粉末及び合金金属粉末の製造方法
EP1676625A1 (en) * 2004-12-28 2006-07-05 Mitsubishi Denki Kabushiki Kaisha Method and catalyst for the oxidative decomposition of formaldehyde gas
KR20070102717A (ko) * 2005-01-24 2007-10-19 신벤션 아게 금속 함유 복합 물질
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Also Published As

Publication number Publication date
TWI436824B (zh) 2014-05-11
US20110201843A1 (en) 2011-08-18
RU2011112015A (ru) 2012-10-10
US8471071B2 (en) 2013-06-25
TW201012543A (en) 2010-04-01
EP2321044B1 (en) 2020-02-26
ES2787550T3 (es) 2020-10-16
EP3685915A1 (en) 2020-07-29
BRPI0918277B8 (pt) 2023-05-09
MY153887A (en) 2015-04-15
AU2009287008A1 (en) 2010-03-04
WO2010022923A1 (en) 2010-03-04
JP5528450B2 (ja) 2014-06-25
AU2009287008B2 (en) 2014-10-02
JP2012501241A (ja) 2012-01-19
CN102137716B (zh) 2013-07-24
BRPI0918277B1 (pt) 2018-01-16
CA2735745C (en) 2016-11-01
KR101634082B1 (ko) 2016-06-28
EP2321044A1 (en) 2011-05-18
KR20110055705A (ko) 2011-05-25
CA2735745A1 (en) 2010-03-04
RU2503497C2 (ru) 2014-01-10
CN102137716A (zh) 2011-07-27
BRPI0918277A2 (pt) 2015-12-15

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Effective date: 20080901

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Owner name: AGOSI AG, DE

Free format text: FORMER OWNER: ALLGEMEINE GOLD- UND SILBERSCHEIDEANSTALT AKTIENGESELLSCHAFT, 75175 PFORZHEIM, DE