CN102113099B - 一种沉积低介电常数膜层的方法 - Google Patents

一种沉积低介电常数膜层的方法 Download PDF

Info

Publication number
CN102113099B
CN102113099B CN200980130954.1A CN200980130954A CN102113099B CN 102113099 B CN102113099 B CN 102113099B CN 200980130954 A CN200980130954 A CN 200980130954A CN 102113099 B CN102113099 B CN 102113099B
Authority
CN
China
Prior art keywords
dielectric constant
chamber
organosilicon compounds
porogen
low dielectric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200980130954.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN102113099A (zh
Inventor
任康树
亚历山德罗斯·T·迪莫斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Applied Materials Inc
Original Assignee
Applied Materials Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Applied Materials Inc filed Critical Applied Materials Inc
Publication of CN102113099A publication Critical patent/CN102113099A/zh
Application granted granted Critical
Publication of CN102113099B publication Critical patent/CN102113099B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02225Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
    • H01L21/0226Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
    • H01L21/02263Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/40Oxides
    • C23C16/401Oxides containing silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/56After-treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Formation Of Insulating Films (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
  • Chemical Vapour Deposition (AREA)
CN200980130954.1A 2008-07-31 2009-07-28 一种沉积低介电常数膜层的方法 Expired - Fee Related CN102113099B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/183,915 US7989033B2 (en) 2007-07-12 2008-07-31 Silicon precursors to make ultra low-K films with high mechanical properties by plasma enhanced chemical vapor deposition
US12/183,915 2008-07-31
PCT/US2009/051983 WO2010014626A2 (en) 2008-07-31 2009-07-28 Novel silicon precursors to make ultra low-k films with high mechanical properties by plasma enhanced chemical vapor deposition

Publications (2)

Publication Number Publication Date
CN102113099A CN102113099A (zh) 2011-06-29
CN102113099B true CN102113099B (zh) 2013-06-12

Family

ID=41610936

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200980130954.1A Expired - Fee Related CN102113099B (zh) 2008-07-31 2009-07-28 一种沉积低介电常数膜层的方法

Country Status (6)

Country Link
US (1) US7989033B2 (enExample)
JP (1) JP5312588B2 (enExample)
KR (1) KR101139593B1 (enExample)
CN (1) CN102113099B (enExample)
TW (1) TWI388685B (enExample)
WO (1) WO2010014626A2 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8298965B2 (en) * 2008-09-03 2012-10-30 American Air Liquide, Inc. Volatile precursors for deposition of C-linked SiCOH dielectrics
KR20130043084A (ko) 2010-02-17 2013-04-29 레르 리키드 쏘시에떼 아노님 뿌르 레?드 에렉스뿔라따시옹 데 프로세데 조르즈 클로드 SiCOH 로우-K 필름의 증착 방법
JP2011254041A (ja) * 2010-06-04 2011-12-15 Renesas Electronics Corp 半導体装置
US20120121823A1 (en) * 2010-11-12 2012-05-17 Applied Materials, Inc. Process for lowering adhesion layer thickness and improving damage resistance for thin ultra low-k dielectric film
US9054110B2 (en) 2011-08-05 2015-06-09 Taiwan Semiconductor Manufacturing Company, Ltd. Low-K dielectric layer and porogen
KR102053350B1 (ko) * 2013-06-13 2019-12-06 삼성전자주식회사 저유전율 절연층을 가진 반도체 소자를 형성하는 방법
US10453675B2 (en) * 2013-09-20 2019-10-22 Versum Materials Us, Llc Organoaminosilane precursors and methods for depositing films comprising same
CN105720005B (zh) * 2014-12-04 2019-04-26 中芯国际集成电路制造(上海)有限公司 超低k介质层的形成方法
US20160214165A1 (en) * 2015-01-26 2016-07-28 General Electric Company Porous ceramic materials for investment casting
KR102624608B1 (ko) 2016-01-19 2024-01-16 삼성전자주식회사 저유전막의 형성 방법 및 이를 이용한 반도체 소자의 제조 방법
US10249489B2 (en) * 2016-11-02 2019-04-02 Versum Materials Us, Llc Use of silyl bridged alkyl compounds for dense OSG films
WO2019055393A1 (en) * 2017-09-14 2019-03-21 Versum Material Us, Llc COMPOSITIONS AND METHODS FOR DEPOSITION OF FILMS CONTAINING SILICON
JP7230067B2 (ja) * 2018-06-15 2023-02-28 バーサム マテリアルズ ユーエス,リミティド ライアビリティ カンパニー シロキサン組成物、及び前記組成物を使用してケイ素含有膜を堆積させるための方法
US11594409B2 (en) 2020-02-28 2023-02-28 Applied Materials, Inc. Systems and methods for depositing low-k dielectric films
US20240087881A1 (en) * 2022-08-26 2024-03-14 Applied Materials, Inc. Systems and methods for depositing low-k dielectric films

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1367205A (zh) * 2001-01-17 2002-09-04 气体产品与化学公司 用于低介电常数层间介质薄膜的有机硅前体
CN1662676A (zh) * 2002-05-08 2005-08-31 应用材料公司 用电子束硬化低介电常数膜的方法

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3560435A (en) * 1968-10-24 1971-02-02 Dow Corning Method of polymerizing organosilicon compounds using a nitro catalyst
US5118530A (en) 1990-11-28 1992-06-02 Dow Corning Corporation Use of hydrogen silsesquioxane resin fractions as coating materials
US6303523B2 (en) * 1998-02-11 2001-10-16 Applied Materials, Inc. Plasma processes for depositing low dielectric constant films
JP3756666B2 (ja) * 1998-05-08 2006-03-15 松下電器産業株式会社 多孔質膜の形成方法及びその形成装置
US6541367B1 (en) 2000-01-18 2003-04-01 Applied Materials, Inc. Very low dielectric constant plasma-enhanced CVD films
KR20010106905A (ko) 2000-05-24 2001-12-07 황 철 주 저유전율 SiOC 박막의 형성방법
US6583048B2 (en) 2001-01-17 2003-06-24 Air Products And Chemicals, Inc. Organosilicon precursors for interlayer dielectric films with low dielectric constants
US6570256B2 (en) * 2001-07-20 2003-05-27 International Business Machines Corporation Carbon-graded layer for improved adhesion of low-k dielectrics to silicon substrates
US7384471B2 (en) 2002-04-17 2008-06-10 Air Products And Chemicals, Inc. Porogens, porogenated precursors and methods for using the same to provide porous organosilica glass films with low dielectric constants
US6936551B2 (en) 2002-05-08 2005-08-30 Applied Materials Inc. Methods and apparatus for E-beam treatment used to fabricate integrated circuit devices
US7056560B2 (en) 2002-05-08 2006-06-06 Applies Materials Inc. Ultra low dielectric materials based on hybrid system of linear silicon precursor and organic porogen by plasma-enhanced chemical vapor deposition (PECVD)
US7122880B2 (en) 2002-05-30 2006-10-17 Air Products And Chemicals, Inc. Compositions for preparing low dielectric materials
US7404990B2 (en) * 2002-11-14 2008-07-29 Air Products And Chemicals, Inc. Non-thermal process for forming porous low dielectric constant films
US6825130B2 (en) * 2002-12-12 2004-11-30 Asm Japan K.K. CVD of porous dielectric materials
US6897163B2 (en) * 2003-01-31 2005-05-24 Applied Materials, Inc. Method for depositing a low dielectric constant film
US7098149B2 (en) * 2003-03-04 2006-08-29 Air Products And Chemicals, Inc. Mechanical enhancement of dense and porous organosilicate materials by UV exposure
US7169715B2 (en) * 2003-03-21 2007-01-30 Intel Corporation Forming a dielectric layer using porogens
JP4295588B2 (ja) * 2003-09-22 2009-07-15 大日本印刷株式会社 反射防止ガスバリア性基板
US7345000B2 (en) * 2003-10-10 2008-03-18 Tokyo Electron Limited Method and system for treating a dielectric film
US20050161060A1 (en) 2004-01-23 2005-07-28 Johnson Andrew D. Cleaning CVD chambers following deposition of porogen-containing materials
JP4202951B2 (ja) * 2004-03-08 2008-12-24 東京エレクトロン株式会社 半導体装置の配線形成方法
US7547643B2 (en) * 2004-03-31 2009-06-16 Applied Materials, Inc. Techniques promoting adhesion of porous low K film to underlying barrier layer
JP4452546B2 (ja) * 2004-04-21 2010-04-21 Jsr株式会社 積層体膜、積層膜の製造方法、絶縁膜ならびに半導体装置
US7166544B2 (en) 2004-09-01 2007-01-23 Applied Materials, Inc. Method to deposit functionally graded dielectric films via chemical vapor deposition using viscous precursors
US7138767B2 (en) 2004-09-30 2006-11-21 Tokyo Electron Limited Surface wave plasma processing system and method of using
US7491658B2 (en) * 2004-10-13 2009-02-17 International Business Machines Corporation Ultra low k plasma enhanced chemical vapor deposition processes using a single bifunctional precursor containing both a SiCOH matrix functionality and organic porogen functionality
US7229934B2 (en) 2004-10-18 2007-06-12 International Business Machines Corporation Porous organosilicates with improved mechanical properties
US7892648B2 (en) * 2005-01-21 2011-02-22 International Business Machines Corporation SiCOH dielectric material with improved toughness and improved Si-C bonding
US7273823B2 (en) 2005-06-03 2007-09-25 Applied Materials, Inc. Situ oxide cap layer development
US7381659B2 (en) 2005-11-22 2008-06-03 International Business Machines Corporation Method for reducing film stress for SiCOH low-k dielectric materials
US7521377B2 (en) * 2006-01-11 2009-04-21 International Business Machines Corporation SiCOH film preparation using precursors with built-in porogen functionality
US7297376B1 (en) * 2006-07-07 2007-11-20 Applied Materials, Inc. Method to reduce gas-phase reactions in a PECVD process with silicon and organic precursors to deposit defect-free initial layers
US7615482B2 (en) * 2007-03-23 2009-11-10 International Business Machines Corporation Structure and method for porous SiCOH dielectric layers and adhesion promoting or etch stop layers having increased interfacial and mechanical strength

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1367205A (zh) * 2001-01-17 2002-09-04 气体产品与化学公司 用于低介电常数层间介质薄膜的有机硅前体
CN1662676A (zh) * 2002-05-08 2005-08-31 应用材料公司 用电子束硬化低介电常数膜的方法

Also Published As

Publication number Publication date
TWI388685B (zh) 2013-03-11
KR101139593B1 (ko) 2012-07-02
US7989033B2 (en) 2011-08-02
CN102113099A (zh) 2011-06-29
JP5312588B2 (ja) 2013-10-09
WO2010014626A2 (en) 2010-02-04
US20090017231A1 (en) 2009-01-15
WO2010014626A3 (en) 2010-04-15
TW201012962A (en) 2010-04-01
KR20110052674A (ko) 2011-05-18
JP2011530174A (ja) 2011-12-15

Similar Documents

Publication Publication Date Title
CN102113099B (zh) 一种沉积低介电常数膜层的方法
KR101154111B1 (ko) 플라즈마 증진 화학 기상 증착에 의한 높은 기계적 성질을 지니는 초저­k 필름을 제조하기 위한 실리콘 전구체
CN101109074B (zh) 在硅和有机前驱物的pecvd工艺中减少气相反应以沉积无缺陷起始层方法
TWI617693B (zh) 用於沉積含矽膜的組合物及其方法
JP4842251B2 (ja) 下にあるバリア層への多孔性低誘電率膜の接着を促進する手法
CN103210479A (zh) 用以降低超低k介电薄膜的黏着层厚度并提高抗破坏性的工艺
CN100594259C (zh) 改善低k叠层之间粘附性的界面工程
CN103238206A (zh) 原位低介电常数加盖以改良整合损坏抗性
TWI490363B (zh) 絕緣膜材料、使用該絕緣膜材料的成膜方法及絕緣膜
JP2004320005A (ja) 有機シリカ多孔性膜製造のための化学気相成長方法
CN102770580A (zh) 藉由等离子体增强化学气相沉积使用含有具有机官能基的硅的杂化前驱物所形成的超低介电材料
KR101376969B1 (ko) 저―κ의 유전 필름의 이중층 캡핑
US20100015816A1 (en) Methods to promote adhesion between barrier layer and porous low-k film deposited from multiple liquid precursors
CN101316945B (zh) 低介电常数薄膜的灰化/湿法蚀刻损伤的抵抗性以及整体稳定性的改进方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C53 Correction of patent of invention or patent application
CB02 Change of applicant information

Address after: American California

Applicant after: Applied Materials Inc.

Address before: American California

Applicant before: Applied Materials Inc.

C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130612

Termination date: 20150728

EXPY Termination of patent right or utility model