CN102070751B - 丁腈橡胶 - Google Patents

丁腈橡胶 Download PDF

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Publication number
CN102070751B
CN102070751B CN201010529496.3A CN201010529496A CN102070751B CN 102070751 B CN102070751 B CN 102070751B CN 201010529496 A CN201010529496 A CN 201010529496A CN 102070751 B CN102070751 B CN 102070751B
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China
Prior art keywords
sodium
nitrile
acid
emulsion polymerization
weight
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN201010529496.3A
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English (en)
Chinese (zh)
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CN102070751A (zh
Inventor
斯文·布兰道
汉斯·马格
迈克尔·克林佩尔
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Arlanxeo Deutschland GmbH
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Lanxess Deutschland GmbH
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Expired - Fee Related legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/08—Depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/60—Polymerisation by the diene synthesis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/16—Halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C08L15/005—Hydrogenated nitrile rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/21—Rubbery or elastomeric properties

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Springs (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201010529496.3A 2009-11-03 2010-11-02 丁腈橡胶 Expired - Fee Related CN102070751B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09174921.8 2009-11-03
EP09174921A EP2316861A1 (de) 2009-11-03 2009-11-03 Nitrilkautschuke

Publications (2)

Publication Number Publication Date
CN102070751A CN102070751A (zh) 2011-05-25
CN102070751B true CN102070751B (zh) 2015-12-16

Family

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Family Applications (1)

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CN201010529496.3A Expired - Fee Related CN102070751B (zh) 2009-11-03 2010-11-02 丁腈橡胶

Country Status (11)

Country Link
US (1) US8436091B2 (enExample)
EP (2) EP2316861A1 (enExample)
JP (1) JP5629553B2 (enExample)
KR (1) KR101680901B1 (enExample)
CN (1) CN102070751B (enExample)
AT (1) ATE557050T1 (enExample)
BR (1) BRPI1004130A2 (enExample)
CA (1) CA2720105A1 (enExample)
MX (1) MX2010011984A (enExample)
PL (1) PL2316860T3 (enExample)
TW (1) TWI475027B (enExample)

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ITMI20111170A1 (it) * 2011-06-27 2012-12-28 Polimeri Europa Spa "procedimento per la preparazione di gomme nitrile"
WO2013098056A1 (en) * 2011-12-28 2013-07-04 Lanxess Deutschland Gmbh Purification of optionally hydrogenated nitrile rubber
CN103450397B (zh) * 2012-05-28 2015-05-13 中国石油天然气股份有限公司 一种丁腈橡胶的制备方法
CN103450399B (zh) * 2012-06-01 2016-04-06 中国石油天然气股份有限公司 一种乳液聚合法制备丁腈橡胶方法
EP2676969B1 (en) * 2012-06-22 2016-06-01 University Of Waterloo Tandem metathesis and hydrogenation of diene-based polymers in latex
CN105102486B (zh) 2013-03-22 2018-12-28 日本瑞翁株式会社 含腈基共聚物橡胶、交联性橡胶组合物、以及橡胶交联物
CN103320903B (zh) * 2013-06-19 2016-02-24 福建三信织造有限公司 一种耐高温乳胶丝
KR20160065810A (ko) 2013-09-30 2016-06-09 제온 코포레이션 니트릴 공중합체 고무 및 그 제조 방법
EP2860196A1 (de) * 2013-10-14 2015-04-15 LANXESS Deutschland GmbH Nitrilkautschuke mit niedrigen Emissionswerten
EP2868677A1 (de) * 2013-10-30 2015-05-06 LANXESS Deutschland GmbH Nitrilgruppenhaltiger Copolymerkautschuk
MY182047A (en) 2013-12-23 2021-01-18 Cytec Ind Inc Method for producing carbon fibers from polyacrylonitrile (pan) polymers with low pol ydispersity index (pdi)
TWI653297B (zh) * 2013-12-30 2019-03-11 艾朗希歐德意志有限公司 含有膦氧化物或二膦氧化物之氫化腈橡膠（一）
EP2889326B1 (de) * 2013-12-30 2016-09-14 ARLANXEO Deutschland GmbH Lagerstabile Nitrilkautschuke und Verfahren zu deren Herstellung
TWI653245B (zh) * 2013-12-30 2019-03-11 Arlanxeo Deutschland Gmbh 含有苯酚之氫化腈橡膠
KR20170035894A (ko) * 2014-07-25 2017-03-31 니폰 제온 가부시키가이샤 가교성 고무 조성물 및 고무 가교물
WO2016121284A1 (ja) * 2015-01-27 2016-08-04 日本ゼオン株式会社 高飽和ニトリルゴムの製造方法
EP3604355B1 (en) * 2017-03-28 2021-09-01 Zeon Corporation Method for producing carboxylated nitrile rubber
WO2018180978A1 (ja) * 2017-03-28 2018-10-04 日本ゼオン株式会社 カルボキシル基含有ニトリルゴムの製造方法
CN107051552B (zh) * 2017-05-22 2019-09-27 安徽大学 一种磁性碳纳米管负载铑催化剂的制备及其在丁腈橡胶选择性加氢中的应用
EP3689927B1 (en) * 2017-09-28 2022-07-06 Zeon Corporation Method for producing nitrile group-containing copolymer rubber
US11136418B2 (en) * 2017-11-10 2021-10-05 Zeon Corporation Method for manufacturing hydrogenated nitrile rubber
CN113166333B (zh) * 2018-12-27 2024-03-26 阿朗新科德国有限责任公司 预交联丁腈橡胶的粉末状混合物
CN120172780A (zh) * 2025-03-18 2025-06-20 广东米高化工有限公司 一种包膜材料及其制备方法和在氯化钾颗粒用包膜剂上的应用

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CN1356342A (zh) * 2000-11-30 2002-07-03 罗姆和哈斯公司 氧化还原体系和方法
CN101323657A (zh) * 2008-03-07 2008-12-17 上海生大医保股份有限公司 戊腈橡胶乳液及戊腈橡胶的制备方法
CN101423586A (zh) * 2007-11-01 2009-05-06 中国石油天然气股份有限公司 一种高转化率丁二烯-丙烯腈共聚橡胶的制造方法

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CN1356342A (zh) * 2000-11-30 2002-07-03 罗姆和哈斯公司 氧化还原体系和方法
CN101423586A (zh) * 2007-11-01 2009-05-06 中国石油天然气股份有限公司 一种高转化率丁二烯-丙烯腈共聚橡胶的制造方法
CN101323657A (zh) * 2008-03-07 2008-12-17 上海生大医保股份有限公司 戊腈橡胶乳液及戊腈橡胶的制备方法

Also Published As

Publication number Publication date
BRPI1004130A2 (pt) 2012-06-12
TWI475027B (zh) 2015-03-01
CA2720105A1 (en) 2011-05-03
JP2011099100A (ja) 2011-05-19
EP2316861A1 (de) 2011-05-04
KR101680901B1 (ko) 2016-11-29
JP5629553B2 (ja) 2014-11-19
CN102070751A (zh) 2011-05-25
EP2316860B1 (de) 2012-05-09
US20110190441A1 (en) 2011-08-04
MX2010011984A (es) 2011-05-19
ATE557050T1 (de) 2012-05-15
TW201132649A (en) 2011-10-01
US8436091B2 (en) 2013-05-07
KR20110049698A (ko) 2011-05-12
EP2316860A1 (de) 2011-05-04
PL2316860T3 (pl) 2012-09-28

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