CN102046303A - 由轴向注入液体原料制造涂层的方法和系统 - Google Patents
由轴向注入液体原料制造涂层的方法和系统 Download PDFInfo
- Publication number
- CN102046303A CN102046303A CN200980119098XA CN200980119098A CN102046303A CN 102046303 A CN102046303 A CN 102046303A CN 200980119098X A CN200980119098X A CN 200980119098XA CN 200980119098 A CN200980119098 A CN 200980119098A CN 102046303 A CN102046303 A CN 102046303A
- Authority
- CN
- China
- Prior art keywords
- liquid
- charging stock
- converging
- plasma
- spray gun
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 238000000576 coating method Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims description 15
- 239000007921 spray Substances 0.000 claims abstract description 46
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- 239000007924 injection Substances 0.000 claims abstract description 16
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- 239000000843 powder Substances 0.000 claims description 29
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- 238000005507 spraying Methods 0.000 claims description 23
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- 238000007751 thermal spraying Methods 0.000 claims description 13
- 238000000889 atomisation Methods 0.000 claims description 11
- 239000012705 liquid precursor Substances 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
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- 238000004140 cleaning Methods 0.000 claims 4
- 238000005259 measurement Methods 0.000 claims 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims 2
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- 239000002245 particle Substances 0.000 description 17
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Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/42—Plasma torches using an arc with provisions for introducing materials into the plasma, e.g. powder or liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/16—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
- B05B7/20—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion
- B05B7/201—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion downstream of the nozzle
- B05B7/205—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion downstream of the nozzle the material to be sprayed being originally a particulate material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/134—Plasma spraying
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
- H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
- H01M8/1253—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing zirconium oxide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
- H01M2300/0077—Ion conductive at high temperature based on zirconium oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Combustion & Propulsion (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Nozzles (AREA)
- Coating By Spraying Or Casting (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5718408P | 2008-05-29 | 2008-05-29 | |
| US61/057,184 | 2008-05-29 | ||
| PCT/CA2009/000746 WO2009143626A1 (en) | 2008-05-29 | 2009-05-29 | Method and system for producing coatings from liquid feedstock using axial feed |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102046303A true CN102046303A (zh) | 2011-05-04 |
Family
ID=41376521
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200980119098XA Pending CN102046303A (zh) | 2008-05-29 | 2009-05-29 | 由轴向注入液体原料制造涂层的方法和系统 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20110237421A1 (enExample) |
| EP (1) | EP2296826A1 (enExample) |
| JP (1) | JP2011524944A (enExample) |
| CN (1) | CN102046303A (enExample) |
| CA (1) | CA2724012A1 (enExample) |
| WO (1) | WO2009143626A1 (enExample) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102879380A (zh) * | 2012-09-24 | 2013-01-16 | 厦门大学 | 一种拉曼光谱增强粒子施加装置 |
| CN102951846A (zh) * | 2011-08-18 | 2013-03-06 | 和舰科技(苏州)有限公司 | 一种用于旋转涂布玻璃的溶剂喷涂装置 |
| CN103774082A (zh) * | 2014-02-21 | 2014-05-07 | 北京矿冶研究总院 | 热障涂层的制备方法 |
| CN104114737A (zh) * | 2011-12-14 | 2014-10-22 | 普莱克斯S.T.技术有限公司 | 在悬浮液等离子喷涂工艺中利用被护罩的等离子喷涂或被护罩的液体悬浮液注射的系统和方法 |
| CN106605008A (zh) * | 2014-09-03 | 2017-04-26 | 福吉米株式会社 | 喷镀用浆料、喷镀皮膜及喷镀皮膜的形成方法 |
| CN107916389A (zh) * | 2017-11-16 | 2018-04-17 | 西北工业大学 | 一种微米级超音速悬浮等离子喷涂装置及喷涂方法 |
| CN110106463A (zh) * | 2019-05-20 | 2019-08-09 | 内蒙古工业大学 | 一种具有层间孔隙结构热障涂层的制备方法 |
| CN112090609A (zh) * | 2020-09-15 | 2020-12-18 | 季华实验室 | 悬浮液冷气动力喷涂系统及其应用 |
| CN112206937A (zh) * | 2020-09-30 | 2021-01-12 | 季华实验室 | 一种用于悬浮液冷喷涂工艺的液料供给系统 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI385272B (zh) * | 2009-09-25 | 2013-02-11 | Ind Tech Res Inst | 氣體分佈板及其裝置 |
| CA2816903C (en) * | 2010-12-15 | 2019-12-03 | Sulzer Metco (Us) Inc. | Pressure based liquid feed system for suspension plasma spray coatings |
| CN103492084B (zh) * | 2011-07-12 | 2016-05-25 | 伸和工业株式会社 | 轴向进给型等离子喷镀装置 |
| US9682892B2 (en) | 2013-03-13 | 2017-06-20 | Fujimi Incorporated | Powder for thermal spraying, thermal sprayed coating, and method for forming thermal sprayed coating |
| US10196536B2 (en) | 2013-03-13 | 2019-02-05 | Fujimi Incorporated | Slurry for thermal spraying, thermal spray coating, and method for forming thermal spray coating |
| US10377905B2 (en) | 2013-03-13 | 2019-08-13 | Fujimi Incorporated | Slurry for thermal spraying, thermal sprayed coating, and method for forming thermal sprayed coating |
| JP2014240511A (ja) * | 2013-06-11 | 2014-12-25 | 株式会社フジミインコーポレーテッド | 溶射皮膜の製造方法および溶射用材料 |
| US9890089B2 (en) * | 2014-03-11 | 2018-02-13 | General Electric Company | Compositions and methods for thermal spraying a hermetic rare earth environmental barrier coating |
| JP6741410B2 (ja) | 2015-09-25 | 2020-08-19 | 株式会社フジミインコーポレーテッド | 溶射用スラリー、溶射皮膜および溶射皮膜の形成方法 |
| JP6955744B2 (ja) * | 2017-03-29 | 2021-10-27 | 株式会社セイワマシン | 微粒子含有スラリー溶射装置及び該溶射システム |
| JP7224096B2 (ja) | 2017-07-13 | 2023-02-17 | 東京エレクトロン株式会社 | プラズマ処理装置用部品の溶射方法及びプラズマ処理装置用部品 |
| CN113637936A (zh) * | 2021-08-11 | 2021-11-12 | 惠州聚鑫隆金属制品有限公司 | 一种电子五金外壳用表面智能镀铜设备 |
| KR20230102606A (ko) * | 2021-12-30 | 2023-07-07 | 이창훈 | 플라즈마 서스펜션 코팅 시스템 및 방법 |
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| JPH02149358A (ja) * | 1988-11-30 | 1990-06-07 | Onoda Cement Co Ltd | 溶射膜の製造方法及びその装置 |
| US5008511C1 (en) * | 1990-06-26 | 2001-03-20 | Univ British Columbia | Plasma torch with axial reactant feed |
| US5073193A (en) * | 1990-06-26 | 1991-12-17 | The University Of British Columbia | Method of collecting plasma synthesize ceramic powders |
| DE4105407A1 (de) * | 1991-02-21 | 1992-08-27 | Plasma Technik Ag | Plasmaspritzgeraet zum verspruehen von festem, pulverfoermigem oder gasfoermigem material |
| US5420391B1 (en) * | 1994-06-20 | 1998-06-09 | Metcon Services Ltd | Plasma torch with axial injection of feedstock |
| US5514848A (en) * | 1994-10-14 | 1996-05-07 | The University Of British Columbia | Plasma torch electrode structure |
| US5556558A (en) * | 1994-12-05 | 1996-09-17 | The University Of British Columbia | Plasma jet converging system |
| US5749937A (en) * | 1995-03-14 | 1998-05-12 | Lockheed Idaho Technologies Company | Fast quench reactor and method |
| WO1997009454A1 (en) * | 1995-09-07 | 1997-03-13 | The Penn State Research Foundation | High production rate of nano particles by laser liquid interaction |
| US6569397B1 (en) * | 2000-02-15 | 2003-05-27 | Tapesh Yadav | Very high purity fine powders and methods to produce such powders |
| US5788738A (en) * | 1996-09-03 | 1998-08-04 | Nanomaterials Research Corporation | Method of producing nanoscale powders by quenching of vapors |
| US5851507A (en) * | 1996-09-03 | 1998-12-22 | Nanomaterials Research Corporation | Integrated thermal process for the continuous synthesis of nanoscale powders |
| US6472632B1 (en) * | 1999-09-15 | 2002-10-29 | Nanoscale Engineering And Technology Corporation | Method and apparatus for direct electrothermal-physical conversion of ceramic into nanopowder |
| US6600127B1 (en) * | 1999-09-15 | 2003-07-29 | Nanotechnologies, Inc. | Method and apparatus for direct electrothermal-physical conversion of ceramic into nanopowder |
| US6994837B2 (en) * | 2001-04-24 | 2006-02-07 | Tekna Plasma Systems, Inc. | Plasma synthesis of metal oxide nanopowder and apparatus therefor |
| US20020155059A1 (en) * | 2001-04-24 | 2002-10-24 | Tekna Plasma Systems Inc. | Plasma synthesis of titanium dioxide nanopowder and powder doping and surface modification process |
| US6689192B1 (en) * | 2001-12-13 | 2004-02-10 | The Regents Of The University Of California | Method for producing metallic nanoparticles |
| US6689190B2 (en) * | 2001-12-20 | 2004-02-10 | Cima Nanotech, Inc. | Process for the manufacture of reacted nanoparticles |
| US6861101B1 (en) * | 2002-01-08 | 2005-03-01 | Flame Spray Industries, Inc. | Plasma spray method for applying a coating utilizing particle kinetics |
| JP4109462B2 (ja) * | 2002-02-19 | 2008-07-02 | プラクスエア・テクノロジー・インコーポレイテッド | プラズマ溶射酸素輸送膜 |
| WO2004063416A2 (en) * | 2003-01-10 | 2004-07-29 | Inframat Corporation | Apparatus and method for solution plasma spraying |
| US7217407B2 (en) * | 2003-09-11 | 2007-05-15 | E. I. Du Pont De Nemours And Company | Plasma synthesis of metal oxide nanoparticles |
| TWI233321B (en) * | 2004-02-20 | 2005-05-21 | Ind Tech Res Inst | Method for producing nano oxide powder using D.C. plasma thermo-reaction |
| FR2877015B1 (fr) * | 2004-10-21 | 2007-10-26 | Commissariat Energie Atomique | Revetement nanostructure et procede de revetement. |
| WO2006116844A1 (en) * | 2005-05-02 | 2006-11-09 | National Research Council Of Canada | Method and apparatus for fine particle liquid suspension feed for thermal spray system and coatings formed therefrom |
| KR101380793B1 (ko) * | 2005-12-21 | 2014-04-04 | 슐저메트코(유에스)아이엔씨 | 하이브리드 플라즈마-콜드 스프레이 방법 및 장치 |
| CN101437605A (zh) * | 2006-03-29 | 2009-05-20 | 西北美泰克公司 | 利用轴向注入等离子体喷枪生产纳米级粉末和微米级粉末的方法和装置 |
| ES2534215T3 (es) * | 2006-08-30 | 2015-04-20 | Oerlikon Metco Ag, Wohlen | Dispositivo de pulverización de plasma y un método para la introducción de un precursor líquido en un sistema de gas de plasma |
-
2009
- 2009-05-29 WO PCT/CA2009/000746 patent/WO2009143626A1/en not_active Ceased
- 2009-05-29 US US12/991,853 patent/US20110237421A1/en not_active Abandoned
- 2009-05-29 CA CA2724012A patent/CA2724012A1/en not_active Abandoned
- 2009-05-29 JP JP2011510794A patent/JP2011524944A/ja active Pending
- 2009-05-29 EP EP09753387A patent/EP2296826A1/en not_active Withdrawn
- 2009-05-29 CN CN200980119098XA patent/CN102046303A/zh active Pending
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| CN102951846A (zh) * | 2011-08-18 | 2013-03-06 | 和舰科技(苏州)有限公司 | 一种用于旋转涂布玻璃的溶剂喷涂装置 |
| CN104114737A (zh) * | 2011-12-14 | 2014-10-22 | 普莱克斯S.T.技术有限公司 | 在悬浮液等离子喷涂工艺中利用被护罩的等离子喷涂或被护罩的液体悬浮液注射的系统和方法 |
| CN102879380A (zh) * | 2012-09-24 | 2013-01-16 | 厦门大学 | 一种拉曼光谱增强粒子施加装置 |
| CN102879380B (zh) * | 2012-09-24 | 2015-05-13 | 厦门大学 | 一种拉曼光谱增强粒子施加装置 |
| CN103774082A (zh) * | 2014-02-21 | 2014-05-07 | 北京矿冶研究总院 | 热障涂层的制备方法 |
| CN106605008B (zh) * | 2014-09-03 | 2019-08-27 | 福吉米株式会社 | 喷镀用浆料、喷镀皮膜及喷镀皮膜的形成方法 |
| CN106605008A (zh) * | 2014-09-03 | 2017-04-26 | 福吉米株式会社 | 喷镀用浆料、喷镀皮膜及喷镀皮膜的形成方法 |
| CN107916389A (zh) * | 2017-11-16 | 2018-04-17 | 西北工业大学 | 一种微米级超音速悬浮等离子喷涂装置及喷涂方法 |
| CN107916389B (zh) * | 2017-11-16 | 2019-11-22 | 西北工业大学 | 一种微米级超音速悬浮等离子喷涂装置及喷涂方法 |
| CN110106463A (zh) * | 2019-05-20 | 2019-08-09 | 内蒙古工业大学 | 一种具有层间孔隙结构热障涂层的制备方法 |
| CN110106463B (zh) * | 2019-05-20 | 2021-06-25 | 内蒙古工业大学 | 一种具有层间孔隙结构热障涂层的制备方法 |
| CN112090609A (zh) * | 2020-09-15 | 2020-12-18 | 季华实验室 | 悬浮液冷气动力喷涂系统及其应用 |
| CN112090609B (zh) * | 2020-09-15 | 2021-10-29 | 季华实验室 | 悬浮液冷气动力喷涂系统及其应用 |
| WO2022057112A1 (zh) * | 2020-09-15 | 2022-03-24 | 季华实验室 | 悬浮液冷气动力喷涂系统及其应用 |
| CN112206937A (zh) * | 2020-09-30 | 2021-01-12 | 季华实验室 | 一种用于悬浮液冷喷涂工艺的液料供给系统 |
| CN112206937B (zh) * | 2020-09-30 | 2022-02-22 | 季华实验室 | 一种用于悬浮液冷喷涂工艺的液料供给系统 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110237421A1 (en) | 2011-09-29 |
| JP2011524944A (ja) | 2011-09-08 |
| WO2009143626A1 (en) | 2009-12-03 |
| EP2296826A1 (en) | 2011-03-23 |
| CA2724012A1 (en) | 2009-12-03 |
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