CN101919100B - 包含杂多酸的聚合物电解质 - Google Patents

包含杂多酸的聚合物电解质 Download PDF

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Publication number
CN101919100B
CN101919100B CN200880123718.2A CN200880123718A CN101919100B CN 101919100 B CN101919100 B CN 101919100B CN 200880123718 A CN200880123718 A CN 200880123718A CN 101919100 B CN101919100 B CN 101919100B
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CN
China
Prior art keywords
polymer
polymer electrolyte
polyoxometalate
mea
typically
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN200880123718.2A
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English (en)
Chinese (zh)
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CN101919100A (zh
Inventor
史蒂文·J·哈姆罗克
马修·H·弗雷
迈克尔·A·扬德拉希茨
格雷戈里·M·豪根
安德鲁·M·赫林
詹姆斯·L·霍兰
尼科洛·V·埃塔
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3M Innovative Properties Co
Colorado School of Mines
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3M Innovative Properties Co
Colorado School of Mines
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Publication of CN101919100A publication Critical patent/CN101919100A/zh
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Expired - Fee Related legal-status Critical Current
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1048—Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
CN200880123718.2A 2007-11-09 2008-11-07 包含杂多酸的聚合物电解质 Expired - Fee Related CN101919100B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US98674907P 2007-11-09 2007-11-09
US60/986,749 2007-11-09
PCT/US2008/082783 WO2009108222A2 (en) 2007-11-09 2008-11-07 Polymer electrolytes including heteropolyacids

Publications (2)

Publication Number Publication Date
CN101919100A CN101919100A (zh) 2010-12-15
CN101919100B true CN101919100B (zh) 2014-10-01

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Country Status (5)

Country Link
US (1) US8206874B2 (enExample)
EP (2) EP3012895A3 (enExample)
JP (1) JP5432167B2 (enExample)
CN (1) CN101919100B (enExample)
WO (1) WO2009108222A2 (enExample)

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JP5183344B2 (ja) * 2007-07-31 2013-04-17 株式会社きもと 燃料電池用プロトン伝導性膜
CN102066468B (zh) 2008-04-24 2015-01-28 3M创新有限公司 质子传导材料
US9419300B2 (en) 2010-04-16 2016-08-16 3M Innovative Properties Company Proton conducting materials
EP3147982A1 (en) 2010-05-25 2017-03-29 3M Innovative Properties Company Reinforced electrolyte membrane
GB201308178D0 (en) * 2013-05-07 2013-06-12 Acal Energy Ltd Redox systems
GB201309806D0 (en) * 2013-05-31 2013-07-17 Itm Power Research Ltd Catalysts and methods of depositing same
CN109336917A (zh) 2013-06-04 2019-02-15 塞勒创尼克斯公司 腈-取代的硅烷和电解质组合物和包含它们的电化学装置
EP3043766B1 (en) * 2013-09-09 2023-07-19 3M Innovative Properties Company Dental composition containing polyoxometalates, process of production and use thereof
CN104051694B (zh) * 2014-06-16 2016-06-01 中国东方电气集团有限公司 一种锂电池用多金属氧酸锂盐复合隔膜的制备方法
US9976077B2 (en) 2014-06-30 2018-05-22 3M Innovative Properties Company Photochromic articles containing polyoxometalate derivatives and methods of making same
US9976076B2 (en) 2014-06-30 2018-05-22 3M Innovative Properties Company Photochromic articles containing a polyoxometalate and methods of making same
EP3197906B1 (en) * 2014-09-26 2023-10-25 Mebius d.o.o. Processes for preparing polyoxometalate salts for use in proton exchange membranes and fuel cells
CA2960294C (en) * 2014-10-03 2023-11-21 Silatronix, Inc. Functionalized silanes and electrolyte compositions and electrochemical devices containing them
US10722743B2 (en) * 2015-05-15 2020-07-28 Rutgers, The State University Of New Jersey Multicatalyst polyelectrolyte membranes and materials and methods utilizing the same
CN108306046B (zh) * 2018-01-22 2020-04-24 厦门大学 一种全固态复合聚合物电解质及其制备方法
CN109659601B (zh) * 2018-12-12 2021-09-28 南京师范大学 一种多酸/高分子聚合物杂化纳米线材料作为固态电解质的应用
CN112675926B (zh) * 2020-10-10 2022-05-20 南开大学 聚合度为100的质子型和碱金属离子型的多酸杂化聚合物及其制备方法
US20240274848A1 (en) * 2021-06-04 2024-08-15 3M Innovative Properties Company Fluorinated ionomers, polymer electrolyte membranes, fuel cells, and methods
WO2025094826A1 (ja) * 2023-10-31 2025-05-08 東京応化工業株式会社 欠損部位が修飾されたヘテロポリ酸塩又はその混合物

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Also Published As

Publication number Publication date
EP2218130B1 (en) 2017-04-19
WO2009108222A2 (en) 2009-09-03
EP3012895A2 (en) 2016-04-27
CN101919100A (zh) 2010-12-15
JP5432167B2 (ja) 2014-03-05
EP3012895A3 (en) 2016-06-01
EP2218130A2 (en) 2010-08-18
US20090208809A1 (en) 2009-08-20
WO2009108222A3 (en) 2010-03-04
JP2011503300A (ja) 2011-01-27
US8206874B2 (en) 2012-06-26

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