JP5432167B2 - ポリマー電解質膜 - Google Patents

ポリマー電解質膜 Download PDF

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Publication number
JP5432167B2
JP5432167B2 JP2010533275A JP2010533275A JP5432167B2 JP 5432167 B2 JP5432167 B2 JP 5432167B2 JP 2010533275 A JP2010533275 A JP 2010533275A JP 2010533275 A JP2010533275 A JP 2010533275A JP 5432167 B2 JP5432167 B2 JP 5432167B2
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JP
Japan
Prior art keywords
polymer
polymer electrolyte
typically
polyoxometalate
mea
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP2010533275A
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English (en)
Japanese (ja)
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JP2011503300A5 (enExample
JP2011503300A (ja
Inventor
ジェイ． ハムロック，スティーブン
エイチ． フリー，マシュー
エー． ヤンドラシッツ，マイケル
エム． ホーゲン，グレゴリー
エム． ヘリング，アンドリュー
エル． ホーラン，ジェイムズ
ブイ． アイエタ，ニッコロ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Colorado School of Mines
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3M Innovative Properties Co
Colorado School of Mines
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Publication of JP2011503300A publication Critical patent/JP2011503300A/ja
Publication of JP2011503300A5 publication Critical patent/JP2011503300A5/ja
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1048—Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
JP2010533275A 2007-11-09 2008-11-07 ポリマー電解質膜 Expired - Fee Related JP5432167B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US98674907P 2007-11-09 2007-11-09
US60/986,749 2007-11-09
PCT/US2008/082783 WO2009108222A2 (en) 2007-11-09 2008-11-07 Polymer electrolytes including heteropolyacids

Publications (3)

Publication Number Publication Date
JP2011503300A JP2011503300A (ja) 2011-01-27
JP2011503300A5 JP2011503300A5 (enExample) 2011-12-08
JP5432167B2 true JP5432167B2 (ja) 2014-03-05

Family

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Family Applications (1)

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JP2010533275A Expired - Fee Related JP5432167B2 (ja) 2007-11-09 2008-11-07 ポリマー電解質膜

Country Status (5)

Country Link
US (1) US8206874B2 (enExample)
EP (2) EP3012895A3 (enExample)
JP (1) JP5432167B2 (enExample)
CN (1) CN101919100B (enExample)
WO (1) WO2009108222A2 (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5183344B2 (ja) * 2007-07-31 2013-04-17 株式会社きもと 燃料電池用プロトン伝導性膜
EP2554579B1 (en) 2008-04-24 2016-03-30 3M Innovative Properties Company Proton conducting materials
WO2011129967A2 (en) 2010-04-16 2011-10-20 3M Innovative Properties Company Proton conducting materials
WO2011149732A2 (en) 2010-05-25 2011-12-01 3M Innovative Properties Company Reinforced electrolyte membrane
GB201308178D0 (en) * 2013-05-07 2013-06-12 Acal Energy Ltd Redox systems
GB201309806D0 (en) * 2013-05-31 2013-07-17 Itm Power Research Ltd Catalysts and methods of depositing same
EP3004119B1 (en) 2013-06-04 2019-01-16 Silatronix, Inc. Nitrile-substituted silanes and electrolyte compositions and electrochemical devices containing them
WO2015034977A1 (en) * 2013-09-09 2015-03-12 3M Innovative Properties Company Dental composition containing polyoxometalates, process of production and use thereof
CN104051694B (zh) * 2014-06-16 2016-06-01 中国东方电气集团有限公司 一种锂电池用多金属氧酸锂盐复合隔膜的制备方法
WO2016003685A1 (en) 2014-06-30 2016-01-07 3M Innovative Properties Company Photochromic articles containing a polyoxometalate and methods of making same
US9976077B2 (en) 2014-06-30 2018-05-22 3M Innovative Properties Company Photochromic articles containing polyoxometalate derivatives and methods of making same
WO2016045754A1 (en) * 2014-09-26 2016-03-31 Mebius D.O.O Polyoxometalate salts, proton exchange membranes and precursors, membrane-electrode assemblies, fuel cells and methods
KR102689458B1 (ko) 2014-10-03 2024-07-26 실라트로닉스, 인크. 관능화 실란 및 전해질 조성물 및 이들을 함유하는 전기화학 디바이스
US10722743B2 (en) * 2015-05-15 2020-07-28 Rutgers, The State University Of New Jersey Multicatalyst polyelectrolyte membranes and materials and methods utilizing the same
CN108306046B (zh) * 2018-01-22 2020-04-24 厦门大学 一种全固态复合聚合物电解质及其制备方法
CN109659601B (zh) * 2018-12-12 2021-09-28 南京师范大学 一种多酸/高分子聚合物杂化纳米线材料作为固态电解质的应用
CN112675926B (zh) * 2020-10-10 2022-05-20 南开大学 聚合度为100的质子型和碱金属离子型的多酸杂化聚合物及其制备方法
US20240274848A1 (en) * 2021-06-04 2024-08-15 3M Innovative Properties Company Fluorinated ionomers, polymer electrolyte membranes, fuel cells, and methods
WO2025094826A1 (ja) * 2023-10-31 2025-05-08 東京応化工業株式会社 欠損部位が修飾されたヘテロポリ酸塩又はその混合物

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JP4539896B2 (ja) * 1999-09-17 2010-09-08 独立行政法人産業技術総合研究所 プロトン伝導性膜、その製造方法及びそれを用いた燃料電池
US6706833B1 (en) * 2000-07-06 2004-03-16 Kansas State University Research Foundation Polymers incorporating covalently attached organoimido polyoxometalates
US20030027052A1 (en) * 2001-07-27 2003-02-06 Yuhong Huang Cationic conductive material
CN100428549C (zh) 2001-09-11 2008-10-22 积水化学工业株式会社 膜电极集合体、制备其的方法和使用其的聚合物电解质燃料电池
DE10208279A1 (de) * 2002-02-26 2003-10-23 Creavis Tech & Innovation Gmbh Flexible Elektrolytmembran auf Basis eines Polymerfasern umfassenden Trägers, Verfahren zu deren Herstellung und die Verwendung derselben
US20040116742A1 (en) * 2002-12-17 2004-06-17 3M Innovative Properties Company Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
JP2005154710A (ja) * 2003-03-10 2005-06-16 Toray Ind Inc 高分子固体電解質とその製造方法、およびそれを用いた固体高分子型燃料電池
US7285349B2 (en) * 2003-10-30 2007-10-23 3M Innovative Properties Company Polymer electrolyte membrane and method of making
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JP2006099999A (ja) * 2004-09-28 2006-04-13 Asahi Glass Co Ltd 固体高分子形燃料電池用電解質膜、その製造方法及び固体高分子形燃料電池用膜電極接合体
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JP5011662B2 (ja) * 2005-07-01 2012-08-29 旭硝子株式会社 固体高分子形燃料電池用電解質膜の製造方法
JP5130911B2 (ja) * 2005-07-27 2013-01-30 旭硝子株式会社 固体高分子形燃料電池用電解質材料、電解質膜および膜電極接合体
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US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
JP4946026B2 (ja) * 2005-12-09 2012-06-06 旭硝子株式会社 固体高分子形燃料電池用電解質膜の製造方法及び固体高分子形燃料電池用膜電極接合体の製造方法
JP2007188706A (ja) * 2006-01-12 2007-07-26 Asahi Glass Co Ltd 固体高分子形燃料電池用電解質膜および固体高分子形燃料電池用膜電極接合体
JP5219380B2 (ja) * 2006-02-01 2013-06-26 株式会社きもと 修飾フリーアシッド型ヘテロポリ酸、固定化修飾フリーアシッド型ヘテロポリ酸
CN101573823A (zh) * 2006-12-29 2009-11-04 3M创新有限公司 制备耐用聚合物电解质膜的方法
US8753997B2 (en) * 2007-05-18 2014-06-17 Colorado School Of Mines Immobilized heteropoly acids and the use of the same for electrode stabilization and enhancement

Also Published As

Publication number Publication date
EP3012895A3 (en) 2016-06-01
CN101919100A (zh) 2010-12-15
US20090208809A1 (en) 2009-08-20
WO2009108222A3 (en) 2010-03-04
CN101919100B (zh) 2014-10-01
EP2218130B1 (en) 2017-04-19
EP3012895A2 (en) 2016-04-27
WO2009108222A2 (en) 2009-09-03
JP2011503300A (ja) 2011-01-27
US8206874B2 (en) 2012-06-26
EP2218130A2 (en) 2010-08-18

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