CN101836692B - Amino acid biological fish fertilizer and preparation method thereof - Google Patents
Amino acid biological fish fertilizer and preparation method thereof Download PDFInfo
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- CN101836692B CN101836692B CN2010101832632A CN201010183263A CN101836692B CN 101836692 B CN101836692 B CN 101836692B CN 2010101832632 A CN2010101832632 A CN 2010101832632A CN 201010183263 A CN201010183263 A CN 201010183263A CN 101836692 B CN101836692 B CN 101836692B
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Abstract
The invention discloses an amino acid biological fish fertilizer and a preparation method thereof; the fertilizer comprises amino acid powder, fermented organic, inorganic fertilizers, trace elements, minerals and water conditioner which are mixed by a certain ratio; the preparation method comprises the following steps that: A. amino acid powder production: a. hydrolysis: hair; b. neutralization; c. filtration; d. concentration; e. drying: amino acid solution is dried by spraying to obtain the amino acid powder; B. fermentation organic matter production: a. mixing: the organic matter raw material and the amino acid solution are mixed uniformly; b. by species: the organic matter raw material is uniformly mixed with beneficial bacterium; c. fermentation; C. amino acid biological fish fertilizer production: a. mixing: the fermentation organic matter and the inorganic fertilizers are crushed, and then the amino acid powder, the minerals, the trace elements and the water conditioner are stirred and mixed uniformly; b. inspection: inspection is carried out according to relevant quality standards; and c. packaging. The invention improves fish immunity, reduces the occurrence of diseases, increases the fish production, reduces the fish cost, and improves the horn quality.
Description
Technical field
The invention belongs to the biological fish-fertilizer technical field; More specifically relate to a kind of aquaculture special-purpose fertilizer and raise the amino acid biological fish fertilizer of dual-purpose property, also relate to the method for a kind of amino acid biological fish fertilizer of " waste water " preparation that utilizes in L-cystine, L-leucine, the L-tyrosine production process simultaneously.This fishing fertilizer is a kind of biological fish-fertilizer of high-efficiency environment friendly, is applicable to each fish of freshwater aquiculture, shrimps, shellfish etc.
Technical background
There is the waste water of great deal of high concentration to produce with hair-hydrolyzation extraction L-cystine, L-leucine, L-tyrosine, mainly contains 18 seed amino acids and ammonium chloride, if directly discharging has not only been wasted valuable resource, and polluted water environment.How to turn waste into wealth, turn harm into good, the Chinese science worker has passed through long-term exploration and research, and report is that " amino acid journal 1992.4 also has report successively to soil and fertilizer research institute of the Chinese Academy of Sciences afterwards about " research of Fertilizer Efficiency of Amino Acids effect " the earliest.Research shows that amino acid can directly be absorbed by leaves of plants, stem, root, can promote plant tillering, and fertilizer efficiency is fast, and the effect of single amino acids is not so good as kilnitamin, the inorganic nitrogeneous fertilizer high about 50% of nitrogen such as fertility ratio amount.Amino acid in aquaculture fertilizer be efficiently, expensive luxury goods.How " waste water " in L-cystine, L-leucine, the L-tyrosine production process is effectively used in the biological fish-fertilizer production and goes; In order to improve the fertile effect of fishing; Reducing the cost of breeding fish, is the problem that a lot of scientific workers study for a long period of time and explore, and is effectively solved so far.Amino acid is common in the aquaculture fertilizer with trace element chelated attitude, can improve trace element utilizing rate, but amino acid content seldom, and fertilizer efficiency is very little.Existing at present in culture fishery used fertilizer mainly be three major types, promptly traditional fertilizer, inorganic fertilizer, a kind of being referred to as " ferment fungi biological organic fish guano ".Traditional fertilizer has its advantage, but fertilizer efficiency is slow, and the process of being utilized by planktonic organism is longer, and in decomposing mineralization process, consumes a large amount of oxygen in the water body, and this is unfavorable to growths such as fish; Simultaneously, in most of the cases, utilization ratio is low, causes water pollution easily; In addition, organic fish guano should be made base manure, and is mainly used in the Winter-Spring water temperature than low season.Though inorganic fertilizer comes rapidly fertile, function is also comparatively single, uses a series of problems such as quality of bringing environment, water quality and aquatic products in a large number.Name is called " a kind of organic type efficient guano " (the one Chinese patent application publication number is CN1480029A) and is called " a kind of inorganic type efficient guano " (the one Chinese patent application publication number is CN1480030A) and just belongs to traditional single type fish guano.Except that the fertilizer and inorganic fertilizer of simple function; From last century the eighties also begin to promote " rational application of fertilizers ", i.e. " composite organic-inorganic fertilizer "; Though composite fertilizer has absorbed the advantage of single fertilizer and inorganic fertilizer two aspects, their shortcoming is not fine to be overcome.Existing single type fish guano and compound fish guano also have a common shortcoming, and that is exactly not take into full account the chemical characteristic of water body and the nutritional need of fish and biological feed thereof, and the proportioning of a great number of elements and trace element is unreasonable; Do not add probio simultaneously, do not make full use of the ecological circulation self-purification function of Natural Circulation biological in the water body and performance water body.Prior art also discloses " high-performance bio fertilizer formula and manufacturing approach " (the one Chinese patent application publication number is CN1238321A) by name; Though also contain a spot of beneficial microbe; But do not allocate the technical scheme of inorganic fertilizer and trace element into, its technical purpose clearly is to satisfy different crops and all kinds of plant desired nutritional composition.Also have a kind of disclosed " ferment fungi biological organic fish guano and production method thereof " (the one Chinese patent application publication number is CN1757616), though contain microorganism and materials such as organic matter, inorganic fertilizer and trace element such as ferment bacterium, its nutrient proportioning is not considered the influence to various nutrient utilization rates of composition and the water body environment of fish and the various nutrients of food organisms itself thereof; That is added is micro-single; And consumption is excessive, and the adding proportion of any nutrient all has bound in fact, and crossing low or too highly all can influence its utilization ratio; Excessive microelement particularly; Not only can suppress aquatile to the absorbing of macronutrient, also can produce toxic action, suppress its growth aquatile; The polluted-water environment influences the foodsafeties of fish; Simultaneously, do not have ultramicro grinding in its production process, this can influence the solubility property of fertilizer and the utilization rate of its food organisms of fish; Only the concept nature material is set adding proportion, do not had the adding proportion of concrete material, more do not had the proportioning of concrete effective nutrient, lacked operability.The amino acid as fertilizer sources is used for aquaculture, retrieves through the applicant and does not also see a kind of amino acid biological fish fertilizer and preparation method at present and be disclosed or use.
Summary of the invention
The objective of the invention is to be to provide a kind of aquaculture special-purpose fertilizer to raise dual-purpose acidic amino acid biological fish-fertilizer; Special growth characteristics to fish and food organisms thereof; Adopt modern biotechnology to produce amino acid; Again with the rice bran co-fermentation, composite then inorganic fertilizer, trace element, mineral matter, beneficial bacterium, improver of water quality organically combine inorganic quick-acting, organic long-acting, bio-synergistic; Meticulously the fertilizer of development is raised dual-purpose property fishery fertilizer, 18 kinds of free amino acids that are rich in that planktonic organism very easily digests and assimilates and necessary 10 seed amino acids of fish growth.After making fishing fertilizer apply water body, can satisfy the nutritional need of fish growth and breed fish, can improve water quality again, improve fish immunity power, reduce the disease generation, increase the output of breeding fish, reduce the cost of breeding fish, improve the fish quality with the water body of fostering and apply fertilizer.
Another object of the present invention is to be to provide a kind of aquaculture special-purpose fertilizer to raise the preparation method of the amino acid biological fish fertilizer of dual-purpose property; Easy to implement the method; Easy and simple to handle; With " waste water " in L-cystine, L-leucine, the L-tyrosine production process through concentrate, dry, fermentation organically combines with preparing biological fish-fertilizer, both solved amino acid whose waste water, and the amino acid resource of a large amount of cheapness is provided for culture fishery again.If remove painstakingly to add amino acid in the fertile preparation of fishing, that is a kind of luxury goods.
The technical scheme of amino acid biological fish fertilizer provided by the present invention is:
The present invention is used for aquaculture with the amino acid as fertilizer sources; Resources effective utilization and environmental protection are closely combined,, reduce the cost of breeding fish in order to improve the fertile effect of fishing; The applicant has carried out reaching research and the exploration in 10 years, has obtained breakthrough.18 kinds of free amino acids that amino acid biological fish fertilizer of the present invention is rich in that planktonic organism very easily digests and assimilates and necessary 10 seed amino acids of fish growth; Lysine, glutamic acid, leucine glycine particularly wherein; Phytoplankton there is peculiar photosynthesis; Can increase the water body dissolved oxygen, improve water body environment, effectively avoid of the harm of dissolved oxygen deficiency fish.After fishing fertilizer applies water body, can satisfy the nutritional need of fish growth and breed fish, can improve water quality again, improve fish immunity power, reduce the fish diseases generation, increase the output of breeding fish, reduce the cost of breeding fish, improve the fish quality with the water body of fostering and apply fertilizer.
A kind of aquaculture special-purpose fertilizer is raised dual-purpose acidic amino acid biological fish-fertilizer, forms by mass percentage in 100 parts of finished products:
Amino acid powder 3～20%; Fermented organic 30～40%; Inorganic fertilizer 40～60%, wherein nitrogen: the phosphorus pentoxide mass percent is 10: 4～8; Mineral matter 1～5%; Trace element 0.1～1%; Beneficial bacterium 0.5～5%; Improver of water quality 0.5～2%.
Described amino acid powder derives from animal keratin such as the people sends out, pig hair, chicken feather, drake feather, goose feather, wool, ox hair through hydrochloric acid hydrolysis, and wherein each amino acid masses percentage is asparatate 5.5-6.4, threonine 3.4-4, serine 12.5-13.5, glutamic acid 8.1-8.9, proline 9.1-9.7, glycine 8.2-8.8, alanine 4.8-5.4, cystine 2.8-3.4, valine 7.5-8.2, methionine 1.-1.2, isoleucine 8.4-9.1, leucine 5.8-6.4, tyrosine 1.5-2.1, phenylalanine 8.4-8.9, lysine 1.2-1.8, histidine 0.5-0.9, tryptophan 0.4-0.9, arginine 5.4-6.1; A kind of or two to 18 kinds of combinations in proportion wherein.
Described fermented organic derives from fermentation grouts, vinasse, straw powder, system chaff a kind of or two to four kinds of combination in any wherein;
Described available nitrogen phosphorus derives from inorganic fertilizer, comprises urea, ammonium chloride, ammonium sulfate, carbonic hydroammonium, ammonium nitrate, ammonium humate, MAP, Diammonium phosphate (DAP), calcium magnesium phosphate, calcium superphosphate, double superhosphate a kind of or two to 11 kinds of combination in any wherein;
Described mineral matter comprises kaolin, diatomite, bentonite, atlapulgite, zeolite powder a kind of or two to five kinds of combination in any wherein;
Described trace element comprises ferrous sulfate, manganese chloride, copper sulphate, ammonium molybdate, zinc sulfate, cobaltous sulfate, Boratex, sodium metasilicate, sodium selenate a kind of or two to eight kinds of combination in any wherein;
Described beneficial bacterium comprises lactic acid bacteria, Bifidobacterium, bacillus, saccharomycete, nitrobacteria, photosynthetic bacteria a kind of or two to six kinds of combination in any wherein;
Described improver of water quality comprises potassium fulvate, sodium humate, calper calcium peroxide, sodium perborate a kind of or two to four kinds of combination in any wherein.
The production method that aquaculture special-purpose fertilizer according to the invention is raised dual-purpose acidic amino acid biological fish-fertilizer comprises the steps:
A. the production of amino acid powder:
A. hydrolysis:
Hair (people sends out, pig hair, chicken feather, drake feather, goose feather, wool, ox hair): hydrochloric acid (28～31%)=1: 2, temperature is controlled at 108～115 ℃, and the reaction time is at 6～8h.
B. neutralization:
Be neutralized to pH4.8～5.1 with under 40～70 ℃ in 99.9% liquefied ammonia.
C. filter (comprising rough and refining):
Filter cake extracts L-cystine, L-leucine, L-tyrosine.
It is subsequent use that filtrating changes enrichment process over to.
D. concentrate:
To filtrate-0.06～-be concentrated into 28～30Be ' under the 0.08Mpa, aminoacids solution.
E. spray-drying:
Aminoacids solution is spray-dried, and temperature is controlled at 200-220 ℃ and gets amino acid powder, dried moisture＜2%.
B. the production of fermented organic
A. spice:
Organic matter: aminoacids solution=1: 1, mix thoroughly.
B. inoculation:
The fermented organic raw material is equipped with 0.5～5% beneficial bacterium and mixes thoroughly and beat heap.
C. fermentation:
38～40 ℃ of bottom fermentations 6～8 days, obtain fermented organic;
C. amino acid biological fish fertilizer production
A. be mixed:
Fermented organic, inorganic fertilizer are pulverized, added amino acid powder, mineral matter, trace element, improver of water quality, stirring and evenly mixing more successively.
B. check:
Test according to the correlated quality standard.
C. pack:
Different finished products packing specification is on request carried out metering packing.
D. put in storage:
To be up to the standards, the finished product of Proper Packing warehouse-in.
The present invention compares with the various fishing fertilizer of other uses, has following outstanding advantage:
1. 18 kinds of free amino acids that are rich in that planktonic organism very easily digests and assimilates and necessary 10 seed amino acids of fish growth;
2. lysine, glutamic acid, leucine glycine particularly has peculiar photosynthesis to phytoplankton, can increase the water body dissolved oxygen amount, reduces fish and raises the nose above water to breathe the general pool;
3. various nutrient proportioning science, fish were both direct-edible, and the water body food organisms of can fostering and apply fertilizer again are edible indirectly by fish, and feed, fertilizer coefficient are low, can save concentrated feed 20～30%;
4. post-directed training fish high-quality food organisms breed zooplankter in a large number, can strengthen the input ratio of flower silver carp, are increased to 2: 3 by traditional 1: 3, even 1: 1;
5. beneficial bacterium and improver of water quality; Can effectively improve water quality and purifying water body environment, effectively decompose the residual bait of fish, ight soil, organic matter, reduce the content of ammonia nitrogen, nitrite; Suppress the breeding growth of harmful bacterium; Improve fish body immunity, the incidence of disease of prevention fish hemorrhage, enteritis, fin rot reduces dead;
6. consumption is few, and instant effect is easy to use, and fragrant odour has the distinctive sauce fragrance of dense amino acid, polluted-water not, and at the bottom of the pond of not hardening, environmental protection, efficient cheap;
7. input-output ratio is high, and the per kilogram amino acid biological fish fertilizer can be produced 2 kilograms of fresh fish.
8, amino acid " waste water " and resources conservation are organically combined, realized effective transfer by " luxury goods " to " popular ".
Description of drawings
Fig. 1 is a kind of amino acid powder process chart
Fig. 2 is a kind of fermented organic process chart
Fig. 3 is a kind of amino acid biological fish fertilizer process chart
The specific embodiment
A kind of aquaculture special-purpose fertilizer is raised dual-purpose acidic amino acid biological fish-fertilizer, and its proportioning is following:
Table 1 amino acid biological fish fertilizer formulation Example unit: mass percent
Described amino acid powder: wherein each amino acid masses percentage is asparatate 5.9, threonine 3.7, serine 13.1, glutamic acid 8.6, proline 9.4, glycine 8.6 alanine 5.1, cystine 3.1, valine 7.9, methionine 0.8, isoleucine 8.7, leucine 6.1, tyrosine 1.8, phenylalanine 8.6, lysine 1.5, histidine 0.7, tryptophan 0.6, arginine 5.8, a kind of or two to 18 kinds of combinations in proportion wherein.
Described fermented organic derives from fermentation grouts 25%, vinasse 25%, straw powder 20%, system chaff 30% a kind of or two to four kinds of combination in any wherein.
Described available nitrogen phosphorus derives from inorganic fertilizer, comprises urea 10%, ammonium chloride 20%, ammonium sulfate 10%, carbonic hydroammonium 10%, ammonium nitrate 5%, ammonium humate 5%, MAP 20%, Diammonium phosphate (DAP) 5%, calcium magnesium phosphate 5%, calcium superphosphate 5%, double superhosphate 5% a kind of or two to 11 kinds of combination in any wherein.
Described mineral matter comprises kaolin 10%, diatomite 20%, bentonite 20%, atlapulgite 10%, zeolite powder 40% a kind of or two to five kinds of combination in any wherein.
Described trace element comprises ferrous sulfate 15%, manganese chloride 15%, copper sulphate 5%, ammonium molybdate 5%, zinc sulfate 15%, cobaltous sulfate 5%, Boratex 15%, sodium metasilicate 20%, sodium selenate 5% a kind of or two to eight kinds of combination in any wherein.
Described beneficial bacterium comprises lactic acid bacteria 10%, Bifidobacterium 10%, bacillus 30%, saccharomycete 15%, nitrobacteria 15%, photosynthetic bacteria 20% a kind of or two to six kinds of combination in any wherein.
Described improver of water quality comprises potassium fulvate 60%, sodium humate 20%, calper calcium peroxide 10%, sodium perborate 10% a kind of or two to four kinds of combination in any wherein.
A kind of aquaculture special-purpose fertilizer is raised the preparation method of the amino acid biological fish fertilizer of dual-purpose property, the steps include:
A. the production of amino acid powder (seeing accompanying drawing 1 for details)
A. hydrolysis is 1.:
Hair (people sends out, pig hair, chicken feather, drake feather, goose feather, wool, ox hair): hydrochloric acid (28～31%)=1: 2, temperature are controlled at 108 or 110 or 111 or 113 or 114 or 115 ℃, the reaction time 6 or 7 or 8h.
B. neutralization is 2.:
Be neutralized to pH4.8 or 4.9 or 5 or 5.1 with under 99.9% liquefied ammonia 40 or 43 or 46 or 48 or 51 or 55 or 58 or 61 or 64 or 66 or 68 or 70 ℃.
C. filter (comprise rough 3. with refining 4.):
Filter cake extracts L-cystine, L-leucine, L-tyrosine.
It is subsequent use that filtrating changes enrichment process over to.
D. concentrate 5.:
To filtrate-0.06 or-0.07 or-be concentrated into 28 or 29 or 30Be ' under the 0.08Mpa, aminoacids solution 6.;
E. spray-drying is 7.:
Aminoacids solution is spray-dried, and temperature is controlled at 200 or 205 or 209 or 212 or 215 or 217 or 220 ℃, gets amino acid powder, dried moisture＜2%.
B. the production of fermented organic (seeing accompanying drawing 2 for details)
A. spice is 8.:
Organic matter: aminoacids solution=1: 1, mix thoroughly.
B. inoculation:
The fermented organic raw material is equipped with 0.5 or 0.9 or 1.3 or 1.9 or 2.5 or 3.3 or 3.8 or 4.2 or 4.6 or 5% beneficial bacterium and mixes thoroughly and beat heap.
C. fermentation is 9.:
38 or 39 or 40 ℃ of bottom fermentations 6 or 7 or 8 days, obtain fermented organic;
C. amino acid biological fish fertilizer production (seeing accompanying drawing 3 for details)
A.
is mixed
10. fermented organic, inorganic fertilizer are pulverized, added amino acid powder, mineral matter, trace element, improver of water quality, stirring and evenly mixing more successively.
B. check
Test according to the correlated quality standard.
C. pack
Different finished products packing specification is on request carried out metering packing.
D. put
in storage
To be up to the standards, the finished product of Proper Packing warehouse-in.
1. to the requirement of breeding water body
The quality of breeding water body is great to the growth relationship of fish, and so-called " breeding fish and supporting water exactly " is exactly this reason.Therefore, require during the whole breed of breeding fish, to require dissolved oxygen>=5mg/L, ammonia nitrogen≤0.02mg/L, nitrite≤0.1mg/L.
2. culture experiment and effect
Aquaculture special-purpose fertilizer of the present invention is raised and evenly is spilled in the breeding water body after dual-purpose acidic amino acid biological fish-fertilizer is soaked in water, and measured result is following:
The applicant has carried out one month test by a definite date 5～June in 2009; It is fertile in the close enclosure of primary condition, to use carbon ammonium+phosphate fertilizer, oronain+phosphate fertilizer and fishing of the present invention respectively; Every kind of fertilizer is done three groups of repetitions; Water quality, planktonic organism, fish bulk-growth are carried out qualitative and quantitative analysis, and the results list is following:
Table 2 is used the influence of different fertilizer to water quality
Can find out that from table 2 in using the fertile water body of fishing of the present invention, pH value changes little, the content of ammonia nitrogen and nitrite obviously reduces, and transparency change is bigger, and is favourable to breeding fish.
Table 3 is used the influence of different fertilizer to the phytoplankton output
Can find out that from table 3 fishing fertilizer of the present invention obviously is superior to other fertilizer to the propagation of phytoplankton, the dominant population growth and breeding is rapid.
Table 4 is used the influence of different fertilizer to the zooplankter output
Can find out that from table 4 fishing fertilizer of the present invention obviously is superior to other fertilizer to the propagation of zooplankter, the dominant population growth and breeding is rapid.
Table 5 is used the influence of different fertilizer to fish growth
Can find out that from table 5 fishing fertilizer of the present invention obviously is superior to other fertilizer, particularly variegated carp to fish multiplication, growing way is rapid.
Culture application example
Culture application example 1:
Built applications of breeding fish in 20 mu of fish ponds, township in 2003 in the Wuhan City: 2003 in the Wuhan City construction township, 20 mu in fish pond, 1.3～2 meters of the depth of waters are thrown in silver carp 7000 tails in January, 2003, variegated carp 2000 tails.Netting on June 2 is weighed, 11 4.3 jin of silver carps, average 0.39 jin every; 4 2.5 jin of variegated carps, average 0.63 jin.June 2 began to use our factory's amino acid biological fish fertilizer, June 9, June 16, June 24 were thrown fertile 4 160kg altogether, weighed 14 12.8 jin of silver carps, 0.52 jin of average every weightening finish to netting on July 3 in 2003; 3 3.9 jin of variegated carps, 0.67 jin of average weight gain.Close with it control group is used the carbon ammonium and is added phosphate fertilizer, throws fertile 4 carbon ammonium 800kg calcium superphosphate 400kg altogether, 0.4 jin of silver carp average weight gain, 0.5 jin of variegated carp average weight gain.
Culture application example 2:
The application of breeding fish in 80 mu of fish ponds, Zuo Ling town in the Wuhan City in 2004: 2004 in the Wuhan City Zuo Ling town, 80 mu of the waters surface, 1.5 meters of mean depths; Put silver carp 24000 tails, variegated carp 8000 tails in a suitable place to breed, use our factory's amino acid biological fish fertilizer, on July 24th, 2004 was to August 24; Silver carp by 0.8 jin long to 1.4 jin; Month the weightening finish 0.6 jin, variegated carp by 1.2 jin long to 1.9 jin, month the weightening finish 0.7 jin.
Culture application example 3:
The application of breeding fish in 65 mu of fish ponds, bight township in the Ezhou in 2005: 2005 in the Ezhou bight township, 65 mu of the waters surface, 1.5 meters of mean depths; Put silver carp 22000 tails in a suitable place to breed, variegated carp 7500 tails are used our factory's amino acid biological fish fertilizer; On August 17th, 2005 is to September 16, silver carp by 1.3 jin long to 1.95 jin, 0.65 jin of month weightening finish; Variegated carp by 2 jin long to 2.8 jin, month the weightening finish 0.8 jin.
Culture application example 4:
The application of breeding fish in 3200 mu of big lakes, futon township in the Ezhou in 2009, all obtain good effect: 2009 in the Ezhou futon township, 3200 mu of the big lake waters surface; 2.5～4 meters of the depth of waters were thrown in silver carp 230,000 tails, average 71 jin before the Spring Festival in 2009; Variegated carp 150,000 tails, individual not of uniform size.On-the-spot netting in the morning on June 8th, 2009,58.8 jin on silver carp 112 tails, 0.53 jin on average every tail, water body pH9.0, variegated carp is not of uniform size because of individuality, so do not weigh.June 8 began to use our factory's amino acid biological fish fertilizer, on-the-spot netting in morning July 8,67 jin of silver carps, 0.64 jin of monthly average weightening finish, water body pH8.6.Morning August 8, on-the-spot netting was weighed, 8 15.2 jin of silver carps, 0.73 jin of monthly average weightening finish, water body pH8.5.
Claims (10)
1. amino acid biological fish fertilizer, it is processed by following raw material by mass percentage:
Described amino acid powder is behaved and is sent out, pig hair, chicken feather, drake feather, goose feather, wool, ox hair be through hydrochloric acid hydrolysis, and wherein each amino acid masses percentage is asparatate 5.5-6.4, threonine 3.4-4, serine 12.5-13.5, glutamic acid 8.1-8.9, proline 9.1-9.7, glycine 8.2-8.8, alanine 4.8-5.4, cystine 2.8-3.4, valine 7.5-8.2, methionine 1.-1.2, isoleucine 8.4-9.1, leucine 5.8-6.4, tyrosine 1.5-2.1, phenylalanine 8.4-8.9, lysine 1.2-1.8, histidine 0.5-0.9, tryptophan 0.4-0.9, arginine 5.4-6.1;
Described fermented organic derives from fermentation grouts, vinasse, straw powder, system chaff a kind of or two to four kinds of combination in any wherein;
Available nitrogen phosphorus derives from inorganic fertilizer, and described inorganic fertilizer comprises urea, ammonium chloride, ammonium sulfate, carbonic hydroammonium, ammonium nitrate, ammonium humate, MAP, Diammonium phosphate (DAP), calcium magnesium phosphate, calcium superphosphate, double superhosphate a kind of or two to 11 kinds of combination in any wherein;
Described mineral matter comprises kaolin, diatomite, bentonite, atlapulgite, zeolite powder a kind of or two to five kinds of combination in any wherein;
Described trace element comprises ferrous sulfate, manganese chloride, copper sulphate, ammonium molybdate, zinc sulfate, cobaltous sulfate, Boratex, sodium metasilicate, sodium selenate a kind of or two to eight kinds of combination in any wherein;
Described beneficial bacterium comprises lactic acid bacteria, Bifidobacterium, bacillus, saccharomycete, nitrobacteria, photosynthetic bacteria a kind of or two to six kinds of combination in any wherein;
Described improver of water quality comprises potassium fulvate, sodium humate, calper calcium peroxide, sodium perborate a kind of or two to three kinds of combination in any wherein.
2. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
3. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
4. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
5. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
6. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
7. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
8. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
9. a kind of amino acid biological fish fertilizer according to claim 1 is characterized in that:
10. the preparation method of the described a kind of amino acid biological fish fertilizer of claim 1 the steps include:
A. the production of amino acid powder:
A. hydrolysis:
Hair: hydrochloric acid=1: 2,108～115 ℃ of reaction 6～8h;
B. neutralization:
Be neutralized to pH4.8～5.1 with under 40～70 ℃ in 99.9% liquefied ammonia;
C. filter:
Filter cake extracts L-cystine, L-leucine, L-tyrosine, and it is subsequent use that filtrating changes enrichment process over to;
D. concentrate:
To filtrate-0.06～-be concentrated into 28～30Be ' under the 0.08Mpa, aminoacids solution;
E. dry:
Aminoacids solution is spray-dried, gets amino acid powder, dried moisture＜2%;
B. the production of fermented organic:
A. spice:
Organic matter: aminoacids solution=1: 1, mix thoroughly;
B. inoculation:
The fermented organic raw material is equipped with 0.5～5% beneficial bacterium and mixes thoroughly and beat heap;
C. fermentation:
38～40 ℃ of bottom fermentations 6～8 days;
C. amino acid biological fish fertilizer production:
A. be mixed:
Fermented organic, inorganic fertilizer are pulverized, added amino acid powder, mineral matter, trace element, improver of water quality, stirring and evenly mixing more successively;
B. check.
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