CN101687160A - 通过多阶段绝热气相氧化制备氯的方法 - Google Patents

通过多阶段绝热气相氧化制备氯的方法 Download PDF

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Publication number
CN101687160A
CN101687160A CN200880024532A CN200880024532A CN101687160A CN 101687160 A CN101687160 A CN 101687160A CN 200880024532 A CN200880024532 A CN 200880024532A CN 200880024532 A CN200880024532 A CN 200880024532A CN 101687160 A CN101687160 A CN 101687160A
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China
Prior art keywords
catalyst
catalyst bed
heat exchanger
oxygen
hydrogen chloride
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Pending
Application number
CN200880024532A
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English (en)
Chinese (zh)
Inventor
R·谢伦
S·舒伯特
L·姆莱齐科
A·沃尔夫
O·F·-K·施卢特
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Bayer AG
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Bayer Technology Services GmbH
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Publication date
Priority claimed from DE200710033113 external-priority patent/DE102007033113A1/de
Priority claimed from DE200710033107 external-priority patent/DE102007033107A1/de
Priority claimed from DE102007033114A external-priority patent/DE102007033114A1/de
Application filed by Bayer Technology Services GmbH filed Critical Bayer Technology Services GmbH
Publication of CN101687160A publication Critical patent/CN101687160A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0438—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being placed next to each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
    • B01J8/048—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being superimposed one above the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C01B7/03—Preparation from chlorides
    • C01B7/04—Preparation of chlorine from hydrogen chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • B01J2208/00557—Flow controlling the residence time inside the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00628—Controlling the composition of the reactive mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0236—Metal based
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B01J2219/0286—Steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B01J2219/029—Non-ferrous metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of actinides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Catalysts (AREA)
CN200880024532A 2007-07-13 2008-06-26 通过多阶段绝热气相氧化制备氯的方法 Pending CN101687160A (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
DE102007033107.1 2007-07-13
DE200710033113 DE102007033113A1 (de) 2007-07-13 2007-07-13 Temperaturstabiler Katalysator für die Chlorwasserstoffgasphasenoxidation
DE200710033107 DE102007033107A1 (de) 2007-07-13 2007-07-13 Verfahren zur Herstellung von Chlor durch vielstufige adiabatische Gasphasenoxidation
DE102007033113.6 2007-07-13
DE102007033114.4 2007-07-13
DE102007033114A DE102007033114A1 (de) 2007-07-13 2007-07-13 Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff
PCT/EP2008/005184 WO2009010168A1 (de) 2007-07-13 2008-06-26 Verfahren zur herstellung von chlor durch vielstufige adiabatische gasphasenoxidation

Publications (1)

Publication Number Publication Date
CN101687160A true CN101687160A (zh) 2010-03-31

Family

ID=39809172

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880024532A Pending CN101687160A (zh) 2007-07-13 2008-06-26 通过多阶段绝热气相氧化制备氯的方法

Country Status (5)

Country Link
US (1) US20100260660A1 (enExample)
EP (1) EP2170495A1 (enExample)
JP (1) JP2010533113A (enExample)
CN (1) CN101687160A (enExample)
WO (1) WO2009010168A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016101523A1 (zh) * 2014-12-22 2016-06-30 上海方纶新材料科技有限公司 一种氯化氢催化氧化制备氯气的方法
CN105776141A (zh) * 2016-01-27 2016-07-20 烟台大学 一种氯化氢催化氧化制氯气新型固定床反应器
CN119386781A (zh) * 2025-01-06 2025-02-07 西北民族大学 一种氯化氢制氯气的多级催化氧化反应器

Families Citing this family (10)

* Cited by examiner, † Cited by third party
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DE102008050975A1 (de) * 2008-10-09 2010-04-15 Bayer Technology Services Gmbh Mehrstufiges Verfahren zur Herstellung von Chlor
DE102009021675A1 (de) * 2009-05-16 2010-11-18 Bayer Technology Services Gmbh Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff in Gegenwart eines Ceroxid-Katalysators
DE102009033640A1 (de) * 2009-07-17 2011-03-03 Bayer Technology Services Gmbh Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff in Anwesenheit von Schwefeloxiden
JP5636601B2 (ja) * 2010-03-11 2014-12-10 住友化学株式会社 固定床反応器による塩素の製造方法
EP2729407A1 (en) * 2011-07-05 2014-05-14 Bayer Intellectual Property GmbH Process for the production of chlorine using a cerium oxide catalyst in an adiabatic reaction cascade
DE102011081074A1 (de) * 2011-08-17 2013-02-21 Areva Np Gmbh Verfahren zur Herstellung eines Uranoxid als aktive Komponente enthaltenden Katalysators
CN104437268B (zh) * 2014-11-06 2017-07-14 南京大学 多级并联强化固定床反应器及其使用方法
JP2020019687A (ja) * 2018-08-02 2020-02-06 住友化学株式会社 臭素の製造方法
KR102709295B1 (ko) 2019-12-31 2024-09-23 한화솔루션 주식회사 염화수소 산화반응용 성형촉매 및 이의 제조방법
WO2023094364A1 (en) * 2021-11-23 2023-06-01 Basf Se Process for preparing a gas stream comprising chlorine

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CA1260229A (en) * 1986-06-30 1989-09-26 Mitsui Chemicals, Inc. Production process of chlorine
DE19734412B4 (de) * 1996-08-08 2008-04-10 Sumitomo Chemical Co. Ltd. Verfahren zur Herstellung von Chlor
CN1182717A (zh) * 1996-10-31 1998-05-27 住友化学工业株式会社 氯气的生产方法
US6977066B1 (en) * 1999-01-22 2005-12-20 Sumitomo Chemical Company, Limited Method for producing chlorine
WO2001054806A1 (en) * 2000-01-25 2001-08-02 Meggitt (Uk) Ltd Chemical reactor with heat exchanger
US7033553B2 (en) * 2000-01-25 2006-04-25 Meggitt (Uk) Limited Chemical reactor
DE10235476A1 (de) * 2002-08-02 2004-02-12 Basf Ag Integriertes Verfahren zur Herstellung von Isocyanaten
DE10250131A1 (de) * 2002-10-28 2004-05-06 Basf Ag Verfahren zur Herstellung von Chlor aus Salzsäure
DE10258153A1 (de) * 2002-12-12 2004-06-24 Basf Ag Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff
DE10361519A1 (de) * 2003-12-23 2005-07-28 Basf Ag Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff
DE102004006610A1 (de) * 2004-02-11 2005-09-01 Basf Ag Reaktor und Verfahren zur Herstellung von Chlor aus HCI
US7772447B2 (en) * 2004-12-22 2010-08-10 Exxonmobil Chemical Patents Inc. Production of liquid hydrocarbons from methane
DE102007020140A1 (de) * 2006-05-23 2007-11-29 Bayer Materialscience Ag Verfahren zur Herstellung von Chlor durch Gasphasenoxidation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016101523A1 (zh) * 2014-12-22 2016-06-30 上海方纶新材料科技有限公司 一种氯化氢催化氧化制备氯气的方法
RU2670301C1 (ru) * 2014-12-22 2018-10-22 Файнингс Ко. Лтд. Способ получения газообразного хлора путем каталитического окисления хлороводорода
CN105776141A (zh) * 2016-01-27 2016-07-20 烟台大学 一种氯化氢催化氧化制氯气新型固定床反应器
CN119386781A (zh) * 2025-01-06 2025-02-07 西北民族大学 一种氯化氢制氯气的多级催化氧化反应器

Also Published As

Publication number Publication date
EP2170495A1 (de) 2010-04-07
US20100260660A1 (en) 2010-10-14
JP2010533113A (ja) 2010-10-21
WO2009010168A1 (de) 2009-01-22

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Application publication date: 20100331