CN101610893B - 二硫醇烯金属配合物无色ir吸收剂 - Google Patents

二硫醇烯金属配合物无色ir吸收剂 Download PDF

Info

Publication number
CN101610893B
CN101610893B CN200780047902.9A CN200780047902A CN101610893B CN 101610893 B CN101610893 B CN 101610893B CN 200780047902 A CN200780047902 A CN 200780047902A CN 101610893 B CN101610893 B CN 101610893B
Authority
CN
China
Prior art keywords
unsubstituted
printing
replacing
substituted
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN200780047902.9A
Other languages
English (en)
Other versions
CN101610893A (zh
Inventor
U·莱曼
D·海兹勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Ciba SC Holding AG
Original Assignee
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba SC Holding AG filed Critical Ciba SC Holding AG
Publication of CN101610893A publication Critical patent/CN101610893A/zh
Application granted granted Critical
Publication of CN101610893B publication Critical patent/CN101610893B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00—Conditioning or physical treatment of the material to be shaped
    • B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
    • B29B13/023—Half-products, e.g. films, plates
    • B29B13/024—Hollow bodies, e.g. tubes or profiles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16—Laser beams
    • B29C65/1677—Laser beams making use of an absorber or impact modifier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/84—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/86—Oxygen and sulfur atoms, e.g. thiohydantoin
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/88—Nitrogen atoms, e.g. allantoin
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/20—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D239/22—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C07F15/0093—Platinum compounds without a metal-carbon linkage
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0822—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using IR radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/0272—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using lost heating elements, i.e. heating means incorporated and remaining in the formed article
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16—Laser beams
    • B29C65/1603—Laser beams characterised by the type of electromagnetic radiation
    • B29C65/1612—Infrared [IR] radiation, e.g. by infrared lasers
    • B29C65/1616—Near infrared radiation [NIR], e.g. by YAG lasers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16—Laser beams
    • B29C65/1629—Laser beams characterised by the way of heating the interface
    • B29C65/1674—Laser beams characterised by the way of heating the interface making use of laser diodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/733—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence
    • B29C66/7332—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence at least one of the parts to be joined being coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/733—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence
    • B29C66/7336—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence at least one of the parts to be joined being opaque, transparent or translucent to visible light
    • B29C66/73365—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence at least one of the parts to be joined being opaque, transparent or translucent to visible light at least one of the parts to be joined being transparent or translucent to visible light
    • B29C66/73366—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the optical properties of the material of the parts to be joined, e.g. fluorescence, phosphorescence at least one of the parts to be joined being opaque, transparent or translucent to visible light at least one of the parts to be joined being transparent or translucent to visible light both parts to be joined being transparent or translucent to visible light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10—Polymers of propylene
    • B29K2023/12—PP, i.e. polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
    • B29K2025/04—Polymers of styrene
    • B29K2025/08—Copolymers of styrene, e.g. AS or SAN, i.e. acrylonitrile styrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
    • B29K2027/16—PVDF, i.e. polyvinylidene fluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B29K2033/08—Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04—Polymers of esters
    • B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2055/00—Use of specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of main groups B29K2023/00 - B29K2049/00, e.g. having a vinyl group, as moulding material
    • B29K2055/02—ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/003—PET, i.e. poylethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/006—PBT, i.e. polybutylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2081/00—Use of polymers having sulfur, with or without nitrogen, oxygen or carbon only, in the main chain, as moulding material
    • B29K2081/04—Polysulfides, e.g. PPS, i.e. polyphenylene sulfide or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2081/00—Use of polymers having sulfur, with or without nitrogen, oxygen or carbon only, in the main chain, as moulding material
    • B29K2081/06—PSU, i.e. polysulfones; PES, i.e. polyethersulfones or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0085—Copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0088—Blends of polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • B29K2995/0017—Heat stable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/002—Coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0026—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0026—Transparent
    • B29K2995/0027—Transparent for light outside the visible spectrum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14—Security printing

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Thermal Sciences (AREA)
  • Electromagnetism (AREA)
  • Printing Methods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Optical Filters (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

本发明涉及二硫醇烯金属配合物无色IR吸收剂，具体地，本发明涉及式(I)和/或(II)的化合物作为无色IR吸收剂(colorless IR absorbers)的应用其中M为Ni、Pd、Pt、Au、Ir、Fe、Zn、W、Cu、Mo、In、Mn、Co、Mg、V、Cr或Ti，X1、X2及X3各自彼此独立地为硫或氧，R1、R2、R3、R4、R5及R6各自彼此独立地为氢、NR7R8、未取代或取代的C1-C18烷基、其中所述亚烷基链被氧间隔的C1-C18烷基、未取代或取代的C1-C18烯基、未取代或取代的芳基、未取代或取代的芳烷基或者未取代或取代的杂芳基烷基，R7及R8各自彼此独立地为未取代或取代的C1-C18烷基、未取代或取代的芳基、未取代或取代的芳烷基或者未取代或取代的杂芳基烷基，任选地，将另外的IR吸收剂加入到所述式(I)及(II)的化合物中。本发明还涉及新的式(I)及(II)的二硫醇烯(dithiolene)化合物，其中X1为氧以及X2和X3为氧或硫。进一步地，本发明涉及新的式(I)及(II)的二硫醇烯化合物，其中R1至R6为NR7R8。

Description

二硫醇烯金属配合物无色IR吸收剂
技术领域
本发明涉及特定二硫醇烯(dithiolene)金属配合物用作无色IR吸收剂的应用。本发明还涉及新的二硫醇烯金属配合物。
背景技术
无色或仅最低限度带颜色的IR吸收剂在宽泛的应用范围内满足重要的技术需求，例如保密印刷(银行票据、信用卡、身份证、护照等等)、不可见且IR可读条形码、塑料的激光焊接、使用IR辐射器的表面涂料固化、印刷的干燥及固化、调色剂在纸上的固定、PDPs(等离子显示板)用的光学过滤器、激光标记、塑料预成型体的加热等等。
已知数类IR吸收剂，例如，例如醌-二亚铵或铵盐、聚甲炔(例如菁蓝(cyanines)、方酸菁(squaraines)、克酮酸菁(croconaines))、酞菁及萘酞菁、二硫醇烯及其他金属配合物。最近还已知了更新的结构，例如，例如夸特锐烯二亚酰胺(quaterrylene diimides)。
除了那些有机物质外，还已知了无机物质，例如，例如以纳米微粒形式并涂覆了云母材料的六硼化镧、铟锡氧化物(ITO)、锑锡氧化物(ATO)(来自Merck的“Lazerflair”)。
尽管已知了许多化合物种类及结构，但至今还未知从技术角度来看令人满意的IR吸收剂。尤其是就“无色”亦即最低程度的固有颜色而言，还未知同时满足另一技术稳定性要求(热稳定性和/或光稳定性)的真正令人满意的解决方案。例如，IR吸收剂，例如用于保密印刷，可从“American Dye Source”获得，但实际上所有这些都在VIS光谱范围(从400到700nm)内具有吸收。
令人惊讶地，现在已经发现有一类杂环二硫醇烯金属配合物已知其本身就能够满足那些需求。尤其在无色方面，这些化合物明显优于已知的IR吸收剂，且同时满足其它的技术要求，例如，例如良好的耐光牢度(用于保密印刷)或者掺加入塑料材料(塑料的激光焊接)时的良好热稳定性。
发明内容因此，本发明涉及式I和/或II的化合物作为无色IR吸收剂的应用
其中
M为Ni、Pd、Pt、Au、Ir、Fe、Zn、W、Cu、Mo、In、Mn、Co、Mg、V、Cr或Ti，
X1、X2及X3各自彼此独立地为硫或氧，
R1、R2、R3、R4、R5及R6各自彼此独立地为氢、NR7R8、未取代或取代的C1-C18烷基、其中所述亚烷基链被氧间隔的C1-C18烷基、未取代或取代的C1-C18烯基、未取代或取代的芳基、未取代或取代的芳烷基或者未取代或取代的杂芳基烷基，R7及R8各自彼此独立地为未取代或取代的C1-C18烷基、未取代或取代的芳基、未取代或取代的芳烷基或者未取代或取代的杂芳基烷基，
任选地，将另外的IR吸收剂加入到所述式I及II化合物中。
优选其中所述金属M为Ni、Pd或Pt的式I化合物。(权利要求2)
如果所述取代基R1至R6或者R1至R4为C1-C18烷基基团，它们优选为未取代的C1-C18烷基基团，更优选为C1-C8烷基基团，包括直链和支链以及环状烷基基团。可作为实例提及的有以下基团：丙基、异丙基、正丁基、仲丁基、叔丁基、正己基、2-乙基己基、正辛基、环戊基、环己基。
如果所述取代基R1至R6或者R1至R4为其中所述亚烷基链被氧间隔的C1-C18烷基基团，它们优选为-(CH2)n-[O-(CH2)m]k-OCH3，且n＝2-6，m＝2或3，k＝1-6。
如果所述取代基R1至R6或者R1至R4为C1-C18烯基基团，它们优选为未取代的C1-C18烯基基团，更优选为C1-C6烯基基团。实例可以为乙烯基或烯丙基。
如果所述取代基R1至R6或者R1至R4为芳基基团，它们优选为未取代的芳基基团，例如苯基、萘基、蒽基或菲基基团。
如果所述取代基R1至R6或者R1至R4为芳烷基基团，它们优选为未取代的芳烷基基团，例如-(CH2)q-苯基，其中q＝1-6，特别是苄基、乙基苯基、丙基苯基。
如果所述取代基R1至R6或者R1至R4为杂芳基烷基基团，它们优选为未取代的杂芳基烷基基团，这意味着杂芳环直接连接到烷基基团。所述杂芳环例如为咪唑基、吡啶基、噻吩基、呋喃基、噻唑基、吲哚基、喹啉基、吡唑基、吡嗪基(pyrazyl)、哒嗪基(pyridazyl)或嘧啶基。
所述取代基R1至R6或者R1至R4优选为未取代的C1-C18烷基、-(CH2)n-[O-(CH2)m]k-OCH3且n＝2-6，m＝2或3，k＝1-6、未取代的C1-C18烯基、未取代的芳烷基或-N(C1-C6烷基)2。
所述取代基R7及R8优选为C1-C6烷基基团。
具体实施方式
在一个优选实施方案中，所述式I化合物用作无色IR吸收剂，其中
M为Ni、Pd、Pt，
X1、X2及X3各自彼此独立地为硫或氧，
R1、R2、R3、R4各自彼此独立地为-N(C1-C6烷基)2、未取代的C1-C8烷基、-(CH2)n-[O-(CH2)m]k-OCH3且n＝2-6，m＝2或3，k＝1-6、乙烯基或烯丙基、-(CH2)q-苯基且q＝1-6。(权利要求3)
特别感兴趣的是所述结构Ia至Ih。
(权利要求4)
无色IR吸收剂可被用于所有依赖于所述IR吸收剂保持不可见的应用领域。举例来说可以提及的应用有以下这些：保密印刷(银行票据、信用卡、身份证、护照等等)、不可见且IR可读条形码、塑料的激光焊接、使用IR辐射器的表面涂料固化、印刷的干燥及固化、调色剂在纸上的固定、激光标记(塑料材料、纸张、木材等等)以及塑料预成型体的加热。(权利要求5)
特别适合的应用领域为所述式I和/或II的化合物在保密印刷中以及在塑料材料的激光焊接中的应用。(权利要求6)
在另一个实施方案中，所述式I及II的化合物用于保密印刷及条形码印刷。
(权利要求7)
所述式I及II的IR吸收剂还可以是以与另外的已知IR吸收剂的混合物的形式，特别是与聚甲炔(菁蓝、方酸菁、克酮酸菁)的混合物。这种IR吸收剂混合物特别适用于保密印刷。(权利要求8)
优选的聚甲炔的实例列于下表：
菁蓝
方酸菁
克酮酸菁
取决于所选择的应用，所述IR吸收剂以10ppm到10％的浓度使用，优选100ppm到2％。
所述激光焊接优选使用ND:YAG激光器以1064nm或使用二极管激光器以980nm或940nm进行，以及IR吸收剂浓度为例如5到500ppm，优选10到100ppm。
在激光焊接中，塑料部件彼此焊接为一体。根据本发明的二硫醇烯特别适用于焊接透明塑料材料，例如聚丙烯、聚乙烯醇缩丁醛、聚酰胺、聚碳酸酯、聚碳酸酯-聚对苯二甲酸乙二酯混合物、聚碳酸酯-聚对苯二甲酸丁二酯混合物、聚碳酸酯-丙烯腈-苯乙烯-丙烯腈共聚物混合物、聚碳酸酯-丙烯腈-丁二烯-苯乙烯共聚物混合物、聚甲基丙烯酸甲酯-丙烯腈-丁二烯-苯乙烯共聚物混合物(MABS)、聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯、聚甲基丙烯酸甲酯、聚丙烯酸丁酯、聚甲基丙烯酸甲酯-聚偏二氟乙烯混合物、丙烯腈-丁二烯-苯乙烯共聚物(ABS)、苯乙烯-丙烯腈共聚物(SAN)及聚苯砜(polyphenylene sulfone)以及它们的混合物。
在焊接中特别有益的是使用两个相同透明的塑料工件，例如无色-透明/无色-透明或者有色-透明/有色-透明。
在保密印刷中，所述IR吸收剂加入到所述油墨中。合适的印刷油墨为水基的、油基的或基于溶剂的印刷油墨，根据色料或染料，用于墨喷式印刷、橡皮版印刷、丝网印刷、凹版印刷、胶板印刷、激光印刷或凸版印刷以及用于电子照相术。
本发明还涉及新的式I及II的二硫醇烯化合物，其中
M为Ni、Pd、Pt、Au、Ir、Fe、Zn、W、Cu、Mo、In、Mn、Co、Mg、V、Cr或Ti，
X1为氧以及X2及X3为氧或硫，
R1、R2、R3、R4、R5及R6各自彼此独立地为氢、NR7R8、未取代或取代的C1-C18烷基、其中所述亚烷基链被氧间隔的C1-C18烷基、未取代或取代的C1-C18烯基、未取代或取代的芳基、未取代或取代的芳烷基或者未取代或取代的杂芳基烷基，R7及R8各自彼此独立地为未取代或取代的C1-C18烷基、未取代或取代的芳基、未取代或取代的芳烷基或者未取代或取代的杂芳基烷基。(权利要求9)
那些化合物通过用适当的溶剂氧化相应的硫化合物(X1，X2，X3＝S)而获得或者按实施例所描述的方法获得。
举例来说可以提及以下化合物：
本发明还涉及新的式I及II的二硫醇烯化合物，其中
M为Ni、Pd、Pt、Au、Ir、Fe、Zn、W、Cu、Mo、In、Mn、Co、Mg、V、Cr或Ti，
X1、X2及X3各自彼此独立地为硫或氧，
R1、R2、R3、R4、R5及R6为NR7R8，其中R7及R8各自彼此独立地为未取代或取代的C1-C18烷基、未取代或取代的芳基、未取代或取代的芳烷基或者未取代或取代的杂芳基烷基(权利要求10)。
-NR7R8优选为-N(C1-C6烷基)2
举例来说可以提及以下化合物Ic及Id：
类似于已知的二硫醇烯化合物，所述新的二硫醇烯化合物适用于保密印刷(银行票据、信用卡、身份证、护照等等)、不可见且IR可读条形码、塑料的激光焊接、使用IR辐射器的表面涂料固化、印刷的干燥及固化、调色剂在纸上的固定、激光标记(塑料、纸张、木材等等)以及塑料预成型体的加热等等。
另外，所述新的式I及II的二硫醇烯化合物适于用作等离子显示板(PDPs)用的光学过滤器。对于此应用，特别有兴趣的是低于1000nm的吸收，尤其是大约900nm。
实施例
实施例1
的制备
所述化合物已知于J.Chem.Soc，Dalton Trans 1998，3731-3736，以及其制备方法描述于该文献中。
在回流条件下，将1，3-二异丙基-4，5-二氧代-咪唑啉-2-硫酮与金属镍及Lawesson试剂在氯苯中反应。
最大吸收(氯仿)：1001nm(79000)
实施例2
的制备
类似于实施例1，与二氯化铂及Lawesson试剂进行反应。
最大吸收(氯仿)：1000nm(113000)。
实施例3a
的制备
在室温、搅拌下，将12.26份N，N-二甲基肼加入到7.65份二硫化碳在250份二氯乙烷中的溶液中。然后，将温度升至40℃且在该温度下搅拌16小时直到反应完成。随后，将温度升至80℃持续一小时。然后，加入另外的750份二氯乙烷，且在90分钟期间内滴加入13.88份草酰氯(溶解于少量二氯乙烷中)。然后将所述反应混合物加热到回流并保持回流2小时，此后将其浓缩、滤出黄色晶体并用少量二氯乙烷洗涤。干燥后，得到14份具有如上所述结构的产物。实 施例3b
的制备
将0.333份二氯化铂加入到0.541份来自实施例3a的产物及1.085份Lawesson试剂在50份甲苯中的溶液中。将所述反应混合物保持在110℃下90分钟而后趁热过滤，待冷却后将500份正己烷加入到所述滤液中。将所得到的沉淀物滤出并干燥，得到0.5份产物(最大吸收994nm)。
实施例4
除了所使用的金属为钼外，所述过程类似于前述实施例，由此得到相应的1∶3钼配合物：
实施例5
的制备
在二氯甲烷中在回流温度下将来自实施例2的化合物用大气中的氧气氧化从而生成相应的氧代化合物。发现其最大吸收在968nm。
实施例6a
的制备
在40℃下将29.14份1，3-二-正丙基-脲溶解于300份甲苯中。在80℃下于40分钟期间内将27.18份草酰氯加入到搅拌的溶液中。在100℃下再进一步搅拌一小时后，在60℃下将所述溶液蒸发至干：得到36.8份所述产物。
实施例6b
的制备
在氮气氛下在100份甲苯中将1.59份来自实施例6a的产物、1.06份二氯化铂及3.47份Lawesson试剂加热到110℃。在45分钟的反应时间之后，将所述深色溶液冷却降至-10℃而后滤出所述沉淀，用乙醇及一些丙酮洗涤。为了纯化，将所述粗产物溶解于二氯甲烷并通过加入甲醇缓慢沉淀。通过过滤收集深蓝色晶体。发现所述产物的最大吸收在900nm(氯仿)。实施例7
的制备
除了用氯化钯代替氯化铂外，类似于实施例6b进行，得到最大吸收921nm的相应钯配合物。
实施例8
的制备
除了用金属镍代替氯化铂外，类似于实施例6b进行，得到最大吸收891nm的相应镍配合物。
实施例9至24
按如实施例1至8所描述的类似步骤得到实施例9到24的化合物(结构于下表给出)：
应用实施例
实施例A1(保密印刷)
在Skandex混合器中将11.9份乙烯基氯、2.1份乙酸乙烯酯、10份乙氧基丙醇、75.5份甲基乙基酮及0.5份来自实施例1的产物与150g玻璃珠一起振摇30分钟。
使用刮刀将所得到的印刷油墨施用于硬性像纸(湿膜厚度：6μm)。所述印迹在视觉上是无色的，但使用IR-观察装置(截止滤光片715nm)在IR范围内则是明显可见的。所述耐光牢度是优异的。
实施例A2(保密印刷)
除了使用来自实施例2的IR吸收剂外，按实施例A1中所示的方法进行，由此同样得到具有优异耐光牢度的无色印迹，其使用IR-观察装置在红外范围内是明显可见的。
实施例A3(塑料材料的激光焊接)
使用注射模塑机，将来自实施例1的IR吸收剂掺加入厚度2mm的聚碳酸酯圆片中(浓度：100ppm)。使用Nd:YAG激光器，在30瓦特功率下以20mm/s的前进速率将所得到的几乎无色的圆片焊接到第二块1mm厚的不包含IR吸收剂的纯聚碳酸酯圆片上。所得到的焊缝以优异的连接、无变化的透射度、无熔融侵入(melt irruptions)以及无鼓泡为特征。在重机械负荷下，所述圆片在所述焊缝处没有发生断裂。
实施例A4(塑料材料的激光焊接)
除了使用来自实施例2的IR吸收剂外，按实施例A3中所描述的方法进行，同样得到具有优异焊接特性的几乎无色的聚碳酸酯圆片。所得到的焊缝具有无变化的透明度，所述焊接没有留下熔融侵入或鼓泡而且所述焊缝的强度优异。
实施例A5及A6
除了使用具有980nm发射波长的二极管激光器代替使用Nd:YAG激光器(1064nm)外，按实施例A3及A4中所描述的方法进行，得到与实施例A3及A4中所描述的那些类似的良好结果。
实施例A7及A8
除了使用具有940nm发射波长的二极管激光器代替使用Nd:YAG激光器(1064nm)外，按实施例A3及A4中所描述的方法进行，在80瓦特激光功率下获得同等良好的焊缝。
实施例A9
除了使用具有1.5mm厚度的聚丙烯圆片外，按实施例A3中所描述的方法进行，所得到的焊缝同样优良。

Claims (4)

1.式I化合物作为无色IR吸收剂的应用，用于保密印刷、不可见且IR可读条形码、塑料的激光焊接、印刷的干燥、调色剂在纸上的固定、激光标记以及塑料预成型体的加热：
其中
M为Ni、Pd或Pt，
X1和X2为硫，
R1、R2、R3及R4各自彼此独立地为未取代的C1-C18烷基，
任选地，将另外的IR吸收剂加入到所述式I化合物中。
2.根据权利要求1的式I化合物的应用，用于塑料材料的激光焊接。
3.根据权利要求1的式I化合物的应用，用于保密印刷及条形码印刷中。
4.在与另外的来自聚甲炔类的IR吸收剂的混合物中的根据权利要求1的式I化合物的应用。
CN200780047902.9A 2007-01-17 2007-12-18 二硫醇烯金属配合物无色ir吸收剂 Active CN101610893B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07100657.1 2007-01-17
EP07100657 2007-01-17
PCT/EP2007/064102 WO2008086931A1 (en) 2007-01-17 2007-12-18 Dithiolene metal complex colorless ir absorbers

Publications (2)

Publication Number Publication Date
CN101610893A CN101610893A (zh) 2009-12-23
CN101610893B true CN101610893B (zh) 2015-02-11

Family

ID=39272568

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200780047902.9A Active CN101610893B (zh) 2007-01-17 2007-12-18 二硫醇烯金属配合物无色ir吸收剂

Country Status (5)

Country Link
US (4) US20100021833A1 (zh)
EP (1) EP2101986B1 (zh)
JP (4) JP2010516823A (zh)
CN (1) CN101610893B (zh)
WO (1) WO2008086931A1 (zh)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101610893B (zh) * 2007-01-17 2015-02-11 西巴控股有限公司 二硫醇烯金属配合物无色ir吸收剂
JP5581208B2 (ja) 2007-07-18 2014-08-27 データレース リミテッド レーザー感受性被覆配合物
EP2217533B1 (en) 2007-11-05 2012-10-03 Basf Se Heat shielding additives comprising a tungsten hydrogen bronze, a binary tungsten oxide and tungsten metal
US8853314B2 (en) * 2008-10-23 2014-10-07 Datalase Ltd. Heat absorbing additives
EP2342295A1 (en) 2008-10-27 2011-07-13 DataLase Ltd Coating composition for marking substrates
WO2011005631A2 (en) 2009-07-07 2011-01-13 Basf Se Potassium cesium tungsten bronze particles
MX353363B (es) * 2010-11-24 2018-01-10 Basf Se El uso de complejos metalicos de ditioleno sustituido por arilo o heteroarilo en calidad de absorbedores de ir.
CN102134248B (zh) * 2011-01-06 2013-01-30 南京大学 一种多硫代二硫烯镍配合物及其制法和用途
AU2012212388B2 (en) * 2011-02-01 2014-09-04 Reserve Bank Of Australia Transparent infrared absorbing materials
CN103502222B (zh) * 2011-05-06 2016-08-17 巴斯夫欧洲公司 具有全氟烷基取代基的发色团
JP6269657B2 (ja) * 2013-04-10 2018-01-31 旭硝子株式会社 赤外線遮蔽フィルタ、固体撮像素子、および撮像・表示装置
EP3202862A3 (en) 2015-03-10 2017-10-25 Basf Se Chromophoric compositions
WO2017014785A1 (en) * 2015-07-23 2017-01-26 Hewlett-Packard Development Company, L.P. Three-dimensional (3d) printing method
US11383433B2 (en) 2017-04-17 2022-07-12 Hewlett-Packard Development Company, L.P. Fusing agent(s)
EP3684759B1 (en) 2017-09-21 2021-11-10 Basf Se Crystal form of a dithiolene nickel complex
WO2019154974A1 (en) 2018-02-09 2019-08-15 Københavns Universitet Thermally stable nir dyes for laser welding of plastic materials
CN108424679B (zh) * 2018-04-08 2020-04-07 大连理工大学 一种具有红外光学特性的含双金属配位的聚合物涂层、制备方法及其应用
CN112955507A (zh) 2018-10-18 2021-06-11 巴斯夫欧洲公司 包含有机红外吸收颜料的微粒组合物
RU2703168C1 (ru) * 2019-01-28 2019-10-15 Акционерное общество "Гознак" (АО "Гознак") Пигмент для защитных элементов многослойных изделий на основе замещенных дитиоленовых комплексов никеля с несимметричными лигандами
DE102020133826A1 (de) 2020-12-16 2022-06-23 Bundesdruckerei Gmbh Verfahren zur Herstellung eines gedruckten Bildes auf einem Datenträger für ein Sicherheits- oder Wertdokument
EP3922473A1 (de) 2020-06-12 2021-12-15 Bundesdruckerei GmbH Verfahren zur herstellung eines gedruckten lichtbildes auf einem datenträger für ein sicherheits- oder wertdokument
AU2021308879A1 (en) 2020-07-16 2023-03-16 Basf Se Dithiolene metal complexes
RU2765644C9 (ru) * 2020-08-19 2022-04-12 Акционерное общество "Гознак" (АО "Гознак") Способ получения пигмента на основе замещенных дитиоленовых комплексов никеля
WO2022131191A1 (ja) 2020-12-16 2022-06-23 富士フイルム株式会社 組成物、膜、光学フィルタ、固体撮像素子、画像表示装置および赤外線センサ
WO2022130773A1 (ja) 2020-12-17 2022-06-23 富士フイルム株式会社 組成物、膜、光学フィルタ、固体撮像素子、画像表示装置および赤外線センサ
CN114854037B (zh) * 2022-03-21 2023-05-12 宿州学院 一种具有半导体性质的钴(ii)配合物及制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4753923A (en) * 1987-11-20 1988-06-28 Eastman Kodak Company Thermally-transferred near-infrared absorbing dyes
DE68927069T2 (de) * 1988-04-05 1997-01-23 Zeneca Ltd Sicherheitskodierung
US6197851B1 (en) * 1996-08-30 2001-03-06 Eastman Chemical Company Polyester compositions containing near infrared absorbing materials to improve reheat
JPH11144328A (ja) * 1997-11-04 1999-05-28 Canon Inc 光カード媒体のセキュリティ方法及びその光カード媒体
JPH11170700A (ja) * 1997-12-09 1999-06-29 Nippon Kayaku Co Ltd レーザーマーキング用ａｂｓ樹脂組成物、成形物及びマーキング方法
JPH11180079A (ja) * 1997-12-25 1999-07-06 Dainippon Printing Co Ltd 情報記録媒体及びその認証方式
GB9821375D0 (en) * 1998-10-01 1998-11-25 Welding Inst Welding method
DE10151847A1 (de) * 2001-10-24 2003-05-08 Bayer Ag Laserabsorbierende russarme Formmassen
EP1308485A1 (en) * 2001-10-31 2003-05-07 Sicpa Holding S.A. Ink set with an IR-taggant
JP2003203210A (ja) * 2002-01-07 2003-07-18 Canon Electronics Inc バーコード
JP2003262953A (ja) * 2002-03-11 2003-09-19 Fuji Photo Film Co Ltd 平版印刷版原版
JP4095852B2 (ja) * 2002-07-10 2008-06-04 富士フイルム株式会社 光学フィルター及び画像表示装置
JP2005165265A (ja) * 2003-08-19 2005-06-23 Mitsubishi Chemicals Corp 光学フィルター
JP2005099755A (ja) * 2003-08-20 2005-04-14 Mitsubishi Chemicals Corp 光学フィルター
JP2005181986A (ja) * 2003-11-28 2005-07-07 Shin Etsu Chem Co Ltd 液晶表示素子用シール剤組成物
US7122076B2 (en) * 2004-08-09 2006-10-17 Silverbrook Research Pty Ltd Synthetically expedient water-dispersible IR dyes
CA2599737A1 (en) * 2005-03-03 2006-09-08 E.I. Dupont De Nemours And Company Laser welding apparatus and laser welding method
JP2006267707A (ja) * 2005-03-24 2006-10-05 Fuji Xerox Co Ltd 画像形成装置
JP5063345B2 (ja) * 2005-04-28 2012-10-31 株式会社エーピーアイ コーポレーション 近赤外線吸収色素含有粘着剤
CN101610893B (zh) 2007-01-17 2015-02-11 西巴控股有限公司 二硫醇烯金属配合物无色ir吸收剂
MX353363B (es) * 2010-11-24 2018-01-10 Basf Se El uso de complejos metalicos de ditioleno sustituido por arilo o heteroarilo en calidad de absorbedores de ir.

Also Published As

Publication number Publication date
JP2017078173A (ja) 2017-04-27
EP2101986B1 (en) 2017-03-22
US9738611B2 (en) 2017-08-22
US9920087B2 (en) 2018-03-20
JP5733804B2 (ja) 2015-06-10
JP2010516823A (ja) 2010-05-20
WO2008086931A1 (en) 2008-07-24
CN101610893A (zh) 2009-12-23
EP2101986A1 (en) 2009-09-23
JP2015057492A (ja) 2015-03-26
US20180099988A1 (en) 2018-04-12
JP6526615B2 (ja) 2019-06-05
US20170285232A1 (en) 2017-10-05
US20160368940A1 (en) 2016-12-22
US10112964B2 (en) 2018-10-30
US20100021833A1 (en) 2010-01-28
JP2013216674A (ja) 2013-10-24
JP6358930B2 (ja) 2018-07-18

Similar Documents

Publication Publication Date Title
CN101610893B (zh) 二硫醇烯金属配合物无色ir吸收剂
CN103237853B (zh) 芳基或杂芳基取代的二硫醇烯金属配合物作为ir吸收剂的用途
CN102942818A (zh) 用于提高近红外辐射的热输入量的氧化钨
TW505647B (en) Structured pigment coating and its preparation and use
JP2010516823A5 (zh)
CN103502222B (zh) 具有全氟烷基取代基的发色团
CN102224204A (zh) 使用了花青化合物的近红外线吸收材料及花青化合物
KR100561466B1 (ko) 자가분산가능한 비피리딘계 금속 착화합물 및 이를 포함한잉크조성물
Deligeorgiev et al. Synthesis and properties of novel asymmetric monomethine cyanine dyes as non-covalent labels for nucleic acids
KR20050017755A (ko) 아조 모이어티를 포함하는 금속착물 착색제
GROZA et al. SYNTHESIS AND OPTICAL PROPERTIES OF NOVEL STRONTIUM TETRANITROPHTHALOCYANINE.
WO2008038679A1 (fr) Composé phtalocyanine et son procédé de production
JP2009057430A (ja) フタロシアニン化合物
CN116560147A (zh) 基于氧化还原开关效应的电致变色材料
WO2023025694A1 (en) Novel perylene-based nir emitters
CN114874638A (zh) 一种中位取代的五甲川菁染料及其制备方法和应用及一种荧光探针
CZ214896A3 (en) Substituted phthalocynins, process of their preparation and a colour containing thereof
MADHU REVIEW PAPERS
JP2015074754A (ja) 有機色素

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant