CN101563401B - 制备高度氟化的聚合物的可再分散颗粒的方法 - Google Patents

制备高度氟化的聚合物的可再分散颗粒的方法 Download PDF

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Publication number
CN101563401B
CN101563401B CN2007800474203A CN200780047420A CN101563401B CN 101563401 B CN101563401 B CN 101563401B CN 2007800474203 A CN2007800474203 A CN 2007800474203A CN 200780047420 A CN200780047420 A CN 200780047420A CN 101563401 B CN101563401 B CN 101563401B
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dispersion
weight
highly fluorinated
polymer
particles
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CN101563401A (zh
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V·M·菲利克斯
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C08J3/122—Pulverisation by spraying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1048—Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Composite Materials (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Inert Electrodes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2007800474203A 2006-12-20 2007-12-18 制备高度氟化的聚合物的可再分散颗粒的方法 Expired - Fee Related CN101563401B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US87589706P 2006-12-20 2006-12-20
US60/875,897 2006-12-20
PCT/US2007/025793 WO2008082496A1 (en) 2006-12-20 2007-12-18 Process for producing re-dispersable particles of highly fluorinated polymer

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CN101563401A CN101563401A (zh) 2009-10-21
CN101563401B true CN101563401B (zh) 2012-07-11

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US (1) US7973091B2 (https=)
EP (1) EP2097472A1 (https=)
JP (1) JP5220027B2 (https=)
CN (1) CN101563401B (https=)
TW (1) TW200842151A (https=)
WO (1) WO2008082496A1 (https=)

Families Citing this family (10)

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Publication number Priority date Publication date Assignee Title
ATE527907T1 (de) * 2004-04-23 2011-10-15 Panasonic Elec Works Co Ltd Gebläseheizung mit elektrostatischem zerstäuber
JP2009529478A (ja) * 2006-03-14 2009-08-20 ビーエーエスエフ ソシエタス・ヨーロピア 吸水性ポリマー粒子を空気により搬送する方法
JP5317654B2 (ja) * 2008-12-02 2013-10-16 東芝燃料電池システム株式会社 燃料電池用電極とその製造方法、及び燃料電池
JP5768956B2 (ja) * 2010-12-24 2015-08-26 芝浦メカトロニクス株式会社 固体粒子の製造装置及び固体粒子の製造方法
JP2014040539A (ja) * 2012-08-23 2014-03-06 Wingturf Co Ltd フッ素樹脂粒子
KR102066301B1 (ko) * 2013-11-25 2020-01-14 도쿄엘렉트론가부시키가이샤 패턴 형성 방법 및 가열 장치
US10381653B2 (en) 2017-03-02 2019-08-13 GM Global Technology Operations LLC PEMFC electrode mudcrack mitigation at low Pt loading
CN112955494B (zh) * 2018-11-05 2025-09-12 索尔维特殊聚合物意大利有限公司 可分散离聚物粉末和其制作方法
CN114395140B (zh) * 2022-01-30 2024-04-09 熵能创新材料(珠海)有限公司 一种环保型含氟聚合物的浓缩水性分散体及其制备方法和应用
KR20250169563A (ko) 2023-03-27 2025-12-03 더 케무어스 컴퍼니 에프씨, 엘엘씨 배합된 플루오르화 설포닐 플루오라이드 중합체 및 이로부터 제조된 이온 교환 막

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4433082A (en) * 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
CN1233267A (zh) * 1996-10-15 1999-10-27 纳幕尔杜邦公司 含有高度氟化的离子交换聚合物颗粒的组合物
US20060014068A1 (en) * 2004-06-10 2006-01-19 California Institute Of Technology Processing techniques for the fabrication of solid acid fuel cell membrane electrode assemblies

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
FR1600355A (https=) 1968-01-18 1970-07-20
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4940525A (en) 1987-05-08 1990-07-10 The Dow Chemical Company Low equivalent weight sulfonic fluoropolymers
JPH08115726A (ja) * 1994-10-17 1996-05-07 Tanaka Kikinzoku Kogyo Kk 高分子固体電解質型電気化学セル用電極の製造方法
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US6110333A (en) 1997-05-02 2000-08-29 E. I. Du Pont De Nemours And Company Composite membrane with highly crystalline porous support
US6518349B1 (en) 1999-03-31 2003-02-11 E. I. Du Pont De Nemours And Company Sprayable powder of non-fibrillatable fluoropolymer
JP5002874B2 (ja) * 2001-01-25 2012-08-15 トヨタ自動車株式会社 燃料電池の電極触媒層形成方法
JP2007535787A (ja) * 2004-03-15 2007-12-06 キャボット　コーポレイション 修飾炭素生成物、燃料電池および類似の装置における修飾炭素生成物の使用、および修飾炭素生成物に関する方法
JP2005285670A (ja) * 2004-03-30 2005-10-13 Matsushita Electric Ind Co Ltd 高分子電解質型燃料電池用膜・電極接合体の製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4433082A (en) * 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
CN1233267A (zh) * 1996-10-15 1999-10-27 纳幕尔杜邦公司 含有高度氟化的离子交换聚合物颗粒的组合物
US20060014068A1 (en) * 2004-06-10 2006-01-19 California Institute Of Technology Processing techniques for the fabrication of solid acid fuel cell membrane electrode assemblies

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US20080161429A1 (en) 2008-07-03
US7973091B2 (en) 2011-07-05
JP5220027B2 (ja) 2013-06-26
TW200842151A (en) 2008-11-01
JP2010513667A (ja) 2010-04-30
CN101563401A (zh) 2009-10-21
EP2097472A1 (en) 2009-09-09
WO2008082496A1 (en) 2008-07-10

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