CN101558032A - 包括氢化的复分解方法及与其相关的组合物 - Google Patents
包括氢化的复分解方法及与其相关的组合物 Download PDFInfo
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- CN101558032A CN101558032A CNA2007800463232A CN200780046323A CN101558032A CN 101558032 A CN101558032 A CN 101558032A CN A2007800463232 A CNA2007800463232 A CN A2007800463232A CN 200780046323 A CN200780046323 A CN 200780046323A CN 101558032 A CN101558032 A CN 101558032A
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- metathesis
- unsaturated
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
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- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
类型 | 通式 | 脂肪酸的实例 | 脂肪酯的实例 |
多不饱和 | 二不饱和CH3-(CH2)n1-[-(CH2)n3-CH=CH-]x-(CH2)n2-COOR其中x是2,n1、n2、n3和R如上定义三不饱和 | 亚油酸(x=2,n1=3;n2=7;n3=1;R是H)亚麻酸 | 亚油酸甲酯(x=2,n1=3;n2=7;n3=1;R是CH3)亚麻酸甲酯 |
CH3-(CH2)n1-[-(CH2)n3-CH=CH-]x-(CH2)n2-COOR其中x是3,n1、n2、n3和R如上定义 | (x=3,n1=0;n2=7;n3=1;R是H) | (x=3,n1=0;n2=7;n3=1;R是CH3) |
原料组合物 | 描述 | 分类 | 键的位置 |
亚油酸 | C18二不饱和脂肪酸(C18:2) | Δ9 | Δ9,12 |
亚麻酸 | C18三不饱和脂肪酸(C18:3) | Δ9 | Δ9,12,15 |
亚油酸烷基酯 | C18二不饱和脂肪酯(C18:2) | Δ9 | Δ9,12 |
亚麻酸烷基酯 | C18三不饱和脂肪酸(C18:3) | Δ9 | Δ9,12,15 |
植物油(例如大豆油) | C18:1、C18:2和C18:3脂肪酸的不饱和甘油酯 | Δ9 | Δ9Δ9,12Δ9,12,15 |
相对百分比 | C18:1化合物 |
0.090.236.015.889.758.644.896.6214.003.643.004.471.021.16 | C18:1,4tC18:1,5tC18:1,6-8tC18:1,9tC18:1,10tC18:1,11tC18:1,12tC18:1,13t+14t(C18:1,6-8c)C18:1,9c(油酸)(C18:1,14-16t)C18:1,10c(C18:1,15t)C18:1,11cC18:1,12cC18:1,13cC18:1,14c(C18:1,16t) |
样品 | IV | 多不饱和物总量(wt%) |
A | 120-140 | 61 |
B | 74.6 | 3.5 |
C | 79.2 | 8 |
D | 90.1 | 15.8 |
Claims (32)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US85162806P | 2006-10-13 | 2006-10-13 | |
US60/851,628 | 2006-10-13 | ||
PCT/US2007/021934 WO2008063322A2 (en) | 2006-10-13 | 2007-10-15 | Metathesis methods involving hydrogenation and compositions relating to same |
Publications (2)
Publication Number | Publication Date |
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CN101558032A true CN101558032A (zh) | 2009-10-14 |
CN101558032B CN101558032B (zh) | 2013-06-19 |
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Application Number | Title | Priority Date | Filing Date |
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CN2007800463232A Active CN101558032B (zh) | 2006-10-13 | 2007-10-15 | 包括氢化的复分解方法及与其相关的组合物 |
Country Status (5)
Country | Link |
---|---|
US (1) | US8614344B2 (zh) |
EP (1) | EP2074079B1 (zh) |
CN (1) | CN101558032B (zh) |
AT (1) | ATE519725T1 (zh) |
WO (1) | WO2008063322A2 (zh) |
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CN104080757A (zh) * | 2011-12-22 | 2014-10-01 | 艾勒旺斯可再生科学公司 | 抑制烯烃复分解产物异构化的方法、精炼天然油的方法以及生产燃料组合物的方法 |
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CN105189722A (zh) * | 2013-03-14 | 2015-12-23 | 埃莱万斯可再生能源科学股份有限公司 | 复分解得到的烯烃和不饱和酯的二烯选择性氢化 |
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CN110818564A (zh) * | 2019-11-21 | 2020-02-21 | 石河子大学 | 一种利用不饱和脂肪酸酯制备高碳二元酸酯的方法 |
CN111378533A (zh) * | 2018-12-27 | 2020-07-07 | 丰益油脂科技(连云港)有限公司 | 半氢化脂肪酸及半氢化脂肪酸的制备方法 |
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-
2007
- 2007-10-15 AT AT07870786T patent/ATE519725T1/de not_active IP Right Cessation
- 2007-10-15 US US12/444,791 patent/US8614344B2/en active Active
- 2007-10-15 EP EP07870786A patent/EP2074079B1/en active Active
- 2007-10-15 WO PCT/US2007/021934 patent/WO2008063322A2/en active Application Filing
- 2007-10-15 CN CN2007800463232A patent/CN101558032B/zh active Active
Cited By (12)
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CN104066822A (zh) * | 2011-12-22 | 2014-09-24 | 艾勒旺斯可再生科学公司 | 抑制烯烃复分解产物异构化的方法、精炼天然油的方法以及生产燃料组合物的方法 |
CN104080757A (zh) * | 2011-12-22 | 2014-10-01 | 艾勒旺斯可再生科学公司 | 抑制烯烃复分解产物异构化的方法、精炼天然油的方法以及生产燃料组合物的方法 |
CN104066822B (zh) * | 2011-12-22 | 2016-01-13 | 艾勒旺斯可再生科学公司 | 抑制烯烃复分解产物异构化的方法、精炼天然油的方法以及生产燃料组合物的方法 |
CN104080757B (zh) * | 2011-12-22 | 2016-01-13 | 艾勒旺斯可再生科学公司 | 抑制烯烃复分解产物异构化的方法、精炼天然油的方法以及生产燃料组合物的方法 |
CN104508101A (zh) * | 2011-12-28 | 2015-04-08 | 艾勒旺斯可再生科学公司 | 可再生脂肪酸蜡及其制造方法 |
CN105189722A (zh) * | 2013-03-14 | 2015-12-23 | 埃莱万斯可再生能源科学股份有限公司 | 复分解得到的烯烃和不饱和酯的二烯选择性氢化 |
CN105254493A (zh) * | 2014-07-08 | 2016-01-20 | Sk新技术株式会社 | 交内酯化合物及其制备方法 |
CN105254494A (zh) * | 2014-07-08 | 2016-01-20 | Sk新技术株式会社 | 含有酮官能团的交内酯化合物及其制备方法 |
CN105602739A (zh) * | 2015-12-31 | 2016-05-25 | 天津斯瑞吉高新科技研究院有限公司 | 对含多不饱和烯酸酯类植物油进行最适部分氢化的方法 |
CN105602739B (zh) * | 2015-12-31 | 2018-10-23 | 天津斯瑞吉高新科技研究院有限公司 | 对含多不饱和烯酸酯类植物油进行最适部分氢化的方法 |
CN111378533A (zh) * | 2018-12-27 | 2020-07-07 | 丰益油脂科技(连云港)有限公司 | 半氢化脂肪酸及半氢化脂肪酸的制备方法 |
CN110818564A (zh) * | 2019-11-21 | 2020-02-21 | 石河子大学 | 一种利用不饱和脂肪酸酯制备高碳二元酸酯的方法 |
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WO2008063322A2 (en) | 2008-05-29 |
EP2074079B1 (en) | 2011-08-10 |
CN101558032B (zh) | 2013-06-19 |
US8614344B2 (en) | 2013-12-24 |
WO2008063322A3 (en) | 2008-08-21 |
EP2074079A4 (en) | 2010-06-09 |
ATE519725T1 (de) | 2011-08-15 |
EP2074079A2 (en) | 2009-07-01 |
US20100094034A1 (en) | 2010-04-15 |
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