CN101553453B - 制备氟化烯烃的方法 - Google Patents

制备氟化烯烃的方法 Download PDF

Info

Publication number
CN101553453B
CN101553453B CN2007800400996A CN200780040099A CN101553453B CN 101553453 B CN101553453 B CN 101553453B CN 2007800400996 A CN2007800400996 A CN 2007800400996A CN 200780040099 A CN200780040099 A CN 200780040099A CN 101553453 B CN101553453 B CN 101553453B
Authority
CN
China
Prior art keywords
reaction
catalyst
fluorinated
formula
conversion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2007800400996A
Other languages
English (en)
Chinese (zh)
Other versions
CN101553453A (zh
Inventor
M·范德皮伊
G·R·库克
P·H·谢德尔
K·D·乌尔里希
H·王
H·S·董
I·尚克兰德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell International Inc
Original Assignee
Honeywell International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=39201461&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN101553453(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Honeywell International Inc filed Critical Honeywell International Inc
Publication of CN101553453A publication Critical patent/CN101553453A/zh
Application granted granted Critical
Publication of CN101553453B publication Critical patent/CN101553453B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/354—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2007800400996A 2006-10-27 2007-10-26 制备氟化烯烃的方法 Active CN101553453B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/588,464 US7560602B2 (en) 2005-11-03 2006-10-27 Process for manufacture of fluorinated olefins
US11/588,464 2006-10-27
PCT/US2007/082601 WO2008057794A1 (en) 2006-10-27 2007-10-26 Process for the manufacture of fluorinated olefins

Publications (2)

Publication Number Publication Date
CN101553453A CN101553453A (zh) 2009-10-07
CN101553453B true CN101553453B (zh) 2013-05-29

Family

ID=39201461

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800400996A Active CN101553453B (zh) 2006-10-27 2007-10-26 制备氟化烯烃的方法

Country Status (8)

Country Link
US (2) US7560602B2 (enExample)
EP (1) EP2076478B2 (enExample)
JP (1) JP5588174B2 (enExample)
KR (2) KR20140090702A (enExample)
CN (1) CN101553453B (enExample)
ES (1) ES2394870T5 (enExample)
RU (1) RU2457195C2 (enExample)
WO (1) WO2008057794A1 (enExample)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7880040B2 (en) * 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
US8067649B2 (en) * 2004-04-29 2011-11-29 Honeywell International Inc. Method for producing fluorinated organic compounds
US8766020B2 (en) * 2008-07-31 2014-07-01 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
EP2046704A2 (en) * 2006-06-27 2009-04-15 E.I. Du Pont De Nemours And Company Tetrafluoropropene production processes
JP5393454B2 (ja) 2006-06-27 2014-01-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー １，２，３，３，３−ペンタフルオロプロペンの製造方法
US7722781B2 (en) * 2006-06-27 2010-05-25 E.I. Du Pont De Nemours And Company Tetrafluoropropene production processes
US8377327B2 (en) 2006-06-27 2013-02-19 E I Du Pont De Nemours And Company Tetrafluoropropene production processes
US8013194B2 (en) * 2008-03-14 2011-09-06 Honeywell International Inc. Process for the manufacture of fluorinated olefins
EP4328213A3 (en) * 2006-10-27 2024-04-03 Honeywell International Inc. A high purity 2,3,3,3-tetrafluoropropene
GB0625214D0 (en) 2006-12-19 2007-01-24 Ineos Fluor Holdings Ltd Process
US9040759B2 (en) * 2007-07-06 2015-05-26 Honeywell International Inc. Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons
US7884254B2 (en) 2007-08-08 2011-02-08 Honeywell International Inc. Dehydrochlorination of hydrochlorofluorocarbons using pre-treated activated carbon catalysts
US8044250B2 (en) * 2007-11-16 2011-10-25 Honeywell International Inc. Manufacture of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2-tetrafluoropropane via catalytic hydrogenation
JP4849058B2 (ja) 2007-11-21 2011-12-28 ダイキン工業株式会社 含フッ素オレフィンの製造方法
ES2400365T3 (es) 2007-12-27 2013-04-09 Arkema France Procedimiento para la producción de 1,1,1,2-tetrafluorpropeno
GB0801209D0 (en) 2008-01-23 2008-02-27 Ineos Fluor Holdings Ltd Process
JP5136111B2 (ja) * 2008-02-19 2013-02-06 セントラル硝子株式会社 フルオロオレフィンとフッ化水素の分離方法
US8710282B2 (en) * 2008-03-14 2014-04-29 Honeywell International Inc. Integrated process for the manufacture of fluorinated olefins
FR2929272B1 (fr) * 2008-03-28 2010-04-09 Arkema France Procede pour la preparation du 2,3,3,3-tetrafluoro-1-propene
CN102015956B (zh) 2008-05-07 2014-06-11 纳幕尔杜邦公司 包含1,1,1,2,3-五氟丙烷或2,3,3,3-四氟丙烯的组合物
GB0808836D0 (en) 2008-05-15 2008-06-18 Ineos Fluor Ltd Process
FR2935703B1 (fr) * 2008-09-11 2010-09-03 Arkema France Procede de preparation de composes fluores.
US8609909B2 (en) * 2009-01-30 2013-12-17 Honeywell International Inc. Process for the purification of hydrofluoroolefins
JP5620478B2 (ja) * 2009-06-03 2014-11-05 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ ２，３，３，３−テトラフルオロプロペンを製造するための触媒および方法
US8487145B2 (en) 2009-06-03 2013-07-16 E I De Pont De Nemours And Company Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene
FR2948362B1 (fr) * 2009-07-23 2012-03-23 Arkema France Procede de preparation de composes fluores
FR2948361B1 (fr) 2009-07-23 2011-08-05 Arkema France Procede de preparation de composes fluores
CN101628850B (zh) * 2009-08-14 2012-09-19 西安近代化学研究所 Z-1,2,3,3,3-五氟丙烯的制备方法
CN101628849B (zh) * 2009-08-14 2012-10-10 西安近代化学研究所 Z-1,2,3,3,3-五氟丙烯的制备方法
US8129574B2 (en) * 2009-08-31 2012-03-06 Honeywell International Inc. Hydrogenation process for fluorocarbons
US8158549B2 (en) 2009-09-04 2012-04-17 Honeywell International Inc. Catalysts for fluoroolefins hydrogenation
EP2558544B2 (en) 2010-04-16 2024-09-04 The Chemours Company FC, LLC Chillers containing a composition comprising 2,3,3,3-tetrafluoropropene and 1,1,1,2-tetrafluoroethane
US20110269999A1 (en) 2010-04-29 2011-11-03 Honeywell International Inc. Process for dehydrohalogenation of halogenated alkanes
US8436218B2 (en) * 2010-05-27 2013-05-07 Honeywell International Inc. Azeotrope-like composition of hexafluoropropane, hexafluoropropene and hydrogen fluoride
US8513474B2 (en) * 2010-06-24 2013-08-20 Honeywell International Inc. Process for the manufacture of fluorinated olefins
FR2962130B1 (fr) * 2010-06-30 2012-07-20 Arkema France Composition a base de 2,3,3,3-tetrafluoropropene
FR2962442B1 (fr) 2010-07-09 2016-02-26 Arkema France Composition stable de 2,3,3,3-tetrafluoropropene
JP5434970B2 (ja) * 2010-07-12 2014-03-05 セントラル硝子株式会社 ドライエッチング剤
US8680345B2 (en) 2011-01-07 2014-03-25 Honeywell International Inc. Low temperature production of 2-chloro-3,3,3-trifluoropropene
EP2671860B2 (en) 2011-02-04 2024-05-29 AGC Inc. Method for purifying 2,3,3,3-tetrafluoropropene
TW201247315A (en) * 2011-05-16 2012-12-01 Du Pont Catalytic hydrogenation of fluoroolefins, alpha-alumina supported palladium compositions and their use as hydrogenation catalysts
JP6034653B2 (ja) * 2012-10-22 2016-11-30 住友精化株式会社 パラフィンの製造方法
CN103073386B (zh) * 2012-12-31 2014-08-20 浙江衢化氟化学有限公司 一种2,3,3,3-四氟丙烯的制备方法
US9290424B2 (en) * 2013-03-14 2016-03-22 Honeywell International Inc. Processes for the hydrogenation of halogenated alkenes and the manufacture of fluorinated olefins
US9272968B2 (en) 2013-03-14 2016-03-01 Honeywell International Inc. Process to suppress the formation of 3,3,3-trifluoropropyne in fluorocarbon manufacture
KR101500655B1 (ko) 2013-09-17 2015-03-12 한국과학기술연구원 금속불소화물 촉매 제조방법 및 이를 이용한 탈불산화 방법
WO2016025288A1 (en) 2014-08-14 2016-02-18 The Chemours Company Fc, Llc Process for the production of e-1,3,3,3-tetrafluoropropene (hfc-1234ze) by dehydrofluorinatiokl
FR3033791B1 (fr) 2015-03-18 2017-04-14 Arkema France Stabilisation du 1-chloro-3,3,3-trifluoropropene
JP6623561B2 (ja) * 2015-05-29 2019-12-25 ダイキン工業株式会社 含フッ素オレフィンの製造方法
WO2016196240A1 (en) 2015-06-05 2016-12-08 3M Innovative Properties Company Hydrofluoroolefins and methods of using same
GB2540427B (en) 2015-07-17 2017-07-19 Mexichem Fluor Sa De Cv Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf)
GB201512510D0 (en) 2015-07-17 2015-08-19 Mexichem Fluor Sa De Cv Process
KR20160017661A (ko) 2016-01-29 2016-02-16 한국과학기술연구원 헥사플루오로프로필렌으로부터 2,3,3,3-테트라플루오로프로펜과 1,3,3,3-테트라플루오로프로펜의 제조방법
KR101914236B1 (ko) 2017-01-11 2018-12-28 한국과학기술연구원 1,2,3,3,3-펜타플루오로프로펜 제조방법
JP6624126B2 (ja) * 2017-03-13 2019-12-25 ダイキン工業株式会社 含フッ素オレフィンの製造方法
CN119118781A (zh) 2018-06-06 2024-12-13 霍尼韦尔国际公司 用于HCFC-244bb的脱氯化氢以制备HFO-1234yf的方法
WO2020130042A1 (ja) * 2018-12-19 2020-06-25 ダイキン工業株式会社 フルオロエタンの製造方法及びフルオロオレフィンの製造方法
JP6835060B2 (ja) * 2018-12-27 2021-02-24 ダイキン工業株式会社 シクロブテンの製造方法
CN111558386B (zh) * 2020-04-10 2023-05-12 西安近代化学研究所 气相氟化合成氢氟烯烃用氟化铁基催化剂及其制备方法和应用
JP7749693B2 (ja) 2021-04-15 2025-10-06 ジョージアン リサーチ インスティテュート オブ ケミカル インダストリー カンパニー，リミテッド ２，３，３，３－テトラフルオロプロペンを製造する方法
CN116874345B (zh) * 2023-09-06 2024-08-06 北京宇极科技发展有限公司 气相连续制备e-1,1,1,4,5,5,5-七氟-4-(三氟甲基)戊-2-烯的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1070903A (zh) * 1991-08-28 1993-04-14 纳幕尔杜邦公司 偕二氢多氟烷烃及其制备方法和清洗用途
US5986151A (en) * 1997-02-05 1999-11-16 Alliedsignal Inc. Fluorinated propenes from pentafluoropropane

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4033899A (en) * 1974-12-30 1977-07-05 Texaco Inc. Alkylation fluosulfonic-sulfuric acid catalyst recovery process with silica-alumina removal of fluoride compounds
US4138355A (en) * 1976-08-10 1979-02-06 Halocarbon Products Corporation Fluorine substitution in 1,1,1-trihalomethanes
US5334783A (en) * 1988-03-14 1994-08-02 Hoechst Aktiengesellschaft Process for the preparation of hexafluoropropene
RU2026279C1 (ru) * 1989-02-03 1995-01-09 Е.И.Дюпон Де Немур Энд Компани Способ гидрогенолиза и/или дегидрогалогенирования фторгалоуглеродов и/или фторгалоуглеводородов
US5180860A (en) * 1990-06-28 1993-01-19 E. I. Du Pont De Nemours And Company Dehydrohalogenation process
US5171902A (en) * 1990-10-11 1992-12-15 E. I. Du Pont De Nemours And Company Saturated linear polyfluorohydrocarbons, processes for their production, and their use in cleaning compositions
US5459275A (en) * 1991-12-28 1995-10-17 Ricoh Company, Ltd. Pyrenylamine derivatives
BR9306493A (pt) * 1992-06-05 1998-09-15 Daikin Ind Ltd Método para a manufatura de 1,1,1,2,3-pentafluoropropeno e método para a manufatura de 1,1,1,2,3-pentafluoropropano
US5396000A (en) * 1993-05-24 1995-03-07 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2,3,-pentafluoropropane
US5488189A (en) * 1993-12-14 1996-01-30 E. I. Du Pont De Nemours And Company Process for fluorinated propanes and pentanes
DE4421702A1 (de) * 1994-06-21 1996-01-04 Bayer Ag Verfahren zur Herstellung von 1,1,1,4,4,4-Hexafluorbutan in flüssiger Phase
JP3543863B2 (ja) * 1994-12-16 2004-07-21 ダイキン工業株式会社 １，１，１，２，３，３−ヘキサフルオロプロパンの製造方法
US5895639A (en) * 1996-07-03 1999-04-20 Alliedsignal Inc. Separation of hydrogen fluoride from a fluorocarbon/hydrogen fluoride azeotropic mixture by sulfuric acid
US5710352A (en) * 1996-09-19 1998-01-20 Alliedsignal Inc. Vapor phase process for making 1,1,1,3,3-pentafluoropropane and 1-chloro-3,3,3-trifluoropropene
EP0958265B1 (en) 1997-01-31 2003-04-02 E.I. Du Pont De Nemours And Company The catalytic manufacture of pentafluoropropenes
US5945573A (en) * 1997-01-31 1999-08-31 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,3,3-pentafluoropropane
US6031141A (en) * 1997-08-25 2000-02-29 E. I. Du Pont De Nemours And Company Fluoroolefin manufacturing process
WO1999033771A1 (en) * 1997-12-26 1999-07-08 Nippon Zeon Co., Ltd. Process for the preparation of compounds having -ch2-chf- groups
JP2001240569A (ja) * 2000-02-29 2001-09-04 Nippon Zeon Co Ltd −ｃｈ２−ｃｈｆ−基を有する化合物の製造方法
US6548719B1 (en) * 2001-09-25 2003-04-15 Honeywell International Process for producing fluoroolefins
US7230146B2 (en) * 2003-10-27 2007-06-12 Honeywell International Inc. Process for producing fluoropropenes
US7405334B2 (en) * 2003-05-23 2008-07-29 E. I. Du Pont De Nemours And Company Process for the reduction of acidic contaminates in fluorinated hydrocarbons
US7371363B2 (en) * 2003-07-15 2008-05-13 Honeywell International Inc. Methods of purifying hydrogen fluoride
KR101125312B1 (ko) * 2003-10-14 2012-03-27 이 아이 듀폰 디 네모아 앤드 캄파니 1,1,1,3,3-펜타플루오로프로판 및1,1,1,2,3-펜타플루오로프로판의 제조 방법
US7285690B2 (en) * 2003-10-14 2007-10-23 E.I. Du Pont De Nemours And Company Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,3,3,3-hexafluoropropane
JP4864879B2 (ja) * 2004-04-29 2012-02-01 ハネウェル・インターナショナル・インコーポレーテッド １，３，３，３−テトラフルオロプロペンの合成方法
CA2564991C (en) * 2004-04-29 2013-03-19 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropene
CA2564897C (en) * 2004-04-29 2012-11-27 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene
US7897823B2 (en) * 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US20060106262A1 (en) * 2004-11-18 2006-05-18 Optimer Photonics, Inc. Electrooptic chromophores with large optical birefringence for applications at high speed and short wavelengths
US8044250B2 (en) † 2007-11-16 2011-10-25 Honeywell International Inc. Manufacture of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2-tetrafluoropropane via catalytic hydrogenation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1070903A (zh) * 1991-08-28 1993-04-14 纳幕尔杜邦公司 偕二氢多氟烷烃及其制备方法和清洗用途
US5986151A (en) * 1997-02-05 1999-11-16 Alliedsignal Inc. Fluorinated propenes from pentafluoropropane

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
I. L. Knunyants et al.REACTIONS OF FLUORO OLEFINS COMMUNICATION 13. CATALYTIC HYDROGENATION OF PERFLUORO OLEFINS.《BULLETION OF THE ACADEMY OF SCIENCES OF THE USSR,DIVISION OF CHEMICAL SCIENCES》.1960,(第8期), *

Also Published As

Publication number Publication date
CN101553453A (zh) 2009-10-07
JP2010508294A (ja) 2010-03-18
EP2076478A1 (en) 2009-07-08
RU2008122213A (ru) 2010-04-27
KR20140090702A (ko) 2014-07-17
US20070179324A1 (en) 2007-08-02
ES2394870T3 (es) 2013-02-06
US7560602B2 (en) 2009-07-14
RU2457195C2 (ru) 2012-07-27
US7786333B2 (en) 2010-08-31
ES2394870T5 (es) 2021-07-27
EP2076478B2 (en) 2020-11-25
WO2008057794A1 (en) 2008-05-15
US20090209791A1 (en) 2009-08-20
JP5588174B2 (ja) 2014-09-10
EP2076478B1 (en) 2012-10-03
KR20090071510A (ko) 2009-07-01

Similar Documents

Publication Publication Date Title
CN101553453B (zh) 制备氟化烯烃的方法
US9994503B2 (en) Process for the manufacture of fluorinated olefins
CN101182280B (zh) 制备氟化烷烃的方法
CN106167445B (zh) 用于制造氟化烯烃的集成方法
CN105189422B (zh) 用于制备氟代烯烃的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant