CN101489978A - 烃的直接胺化方法 - Google Patents

烃的直接胺化方法 Download PDF

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Publication number
CN101489978A
CN101489978A CNA200780027633XA CN200780027633A CN101489978A CN 101489978 A CN101489978 A CN 101489978A CN A200780027633X A CNA200780027633X A CN A200780027633XA CN 200780027633 A CN200780027633 A CN 200780027633A CN 101489978 A CN101489978 A CN 101489978A
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CN
China
Prior art keywords
hydrogen
catalyst
weight
benzene
ammonia
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Pending
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CNA200780027633XA
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English (en)
Chinese (zh)
Inventor
J-T·安德斯
J-P·梅尔德
P·库巴内克
E·施瓦布
W·马肯罗特
K·黑尔曼
F·范拉尔
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BASF SE
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BASF SE
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Publication of CN101489978A publication Critical patent/CN101489978A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/885—Molybdenum and copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/46—Aniline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNA200780027633XA 2006-07-21 2007-07-17 烃的直接胺化方法 Pending CN101489978A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06117623.6 2006-07-21
EP06117623 2006-07-21

Publications (1)

Publication Number Publication Date
CN101489978A true CN101489978A (zh) 2009-07-22

Family

ID=38699829

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA200780027633XA Pending CN101489978A (zh) 2006-07-21 2007-07-17 烃的直接胺化方法

Country Status (6)

Country Link
US (1) US20090292144A1 (https=)
EP (1) EP2046721A1 (https=)
JP (1) JP2009544651A (https=)
KR (1) KR20090031623A (https=)
CN (1) CN101489978A (https=)
WO (1) WO2008009668A1 (https=)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103570553A (zh) * 2012-08-01 2014-02-12 中国科学院兰州化学物理研究所 一种通过催化烷基化制备n-取代胺类化合物的方法
CN103649338A (zh) * 2011-06-09 2014-03-19 安格斯化学公司 去除过量甲醛的组合物及方法
CN104525240A (zh) * 2014-12-10 2015-04-22 河北工业大学 硝酸铁作为催化剂在苯与羟胺盐反应一步法制苯胺反应中的应用方法
CN107801392A (zh) * 2015-04-02 2018-03-13 亨茨曼国际有限公司 烃的直接胺化
CN108654594A (zh) * 2017-03-27 2018-10-16 万华化学集团股份有限公司 一种固体酸催化剂及其制备方法以及用途
CN112300005A (zh) * 2019-07-26 2021-02-02 中石化南京化工研究院有限公司 一种苯一步氨化制苯胺的方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102548952B (zh) * 2009-07-10 2014-05-14 巴斯夫欧洲公司 在电化学分离氢气的情况下将烃直接胺化成氨基烃的方法
WO2011003934A2 (de) 2009-07-10 2011-01-13 Basf Se Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff
PT2451770E (pt) 2009-07-10 2015-03-04 Basf Se Processo para a aminação direta de hidrocarbonetos em amino-hidrocarbonetos com a separação eletroquímica de hidrogénio e a transformação eletroquímica do hidrogénio em água
WO2011003932A2 (de) 2009-07-10 2011-01-13 Basf Se Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff
WO2013131723A1 (de) 2012-03-06 2013-09-12 Basf Se Verfahren zur herstellung von aminokohlenwasserstoffen durch direktaminierung von kohlenwasserstoffen
WO2013131864A1 (de) 2012-03-06 2013-09-12 Basf Se Verfahren zur herstellung von aminokohlenwasserstoffen durch direktaminierung von kohlenwasserstoffen
KR102666708B1 (ko) * 2017-09-19 2024-05-17 다우 글로벌 테크놀로지스 엘엘씨 불균일 촉매를 사용하여 산화적 에스터화에 의해 메틸 메타크릴레이트를 제조하는 방법

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3919155A (en) * 1970-12-18 1975-11-11 Du Pont Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US3929889A (en) * 1971-02-16 1975-12-30 Du Pont Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US4031106A (en) * 1973-12-19 1977-06-21 E. I. Du Pont De Nemours And Company Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US4001260A (en) * 1973-12-19 1977-01-04 E. I. Du Pont De Nemours And Company Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
WO2000009473A1 (en) * 1998-08-17 2000-02-24 Imperial Chemical Industries Plc Amine production
WO2000069804A1 (en) * 1999-05-13 2000-11-23 Symyx Technologies Inc. Amination of aromatic hydrocarbons and heterocyclic analogs thereof
CN100551899C (zh) * 2004-06-09 2009-10-21 四川大学 一种由甲苯一步直接氨基化合成甲苯胺的方法
WO2007096297A1 (de) * 2006-02-24 2007-08-30 Basf Se Direktaminierung von kohlenwasserstoffen

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103649338A (zh) * 2011-06-09 2014-03-19 安格斯化学公司 去除过量甲醛的组合物及方法
CN103649338B (zh) * 2011-06-09 2016-08-17 安格斯化学公司 去除过量甲醛的组合物及方法
CN103570553A (zh) * 2012-08-01 2014-02-12 中国科学院兰州化学物理研究所 一种通过催化烷基化制备n-取代胺类化合物的方法
CN103570553B (zh) * 2012-08-01 2016-08-10 中国科学院兰州化学物理研究所 一种通过催化烷基化制备n-取代胺类化合物的方法
CN104525240A (zh) * 2014-12-10 2015-04-22 河北工业大学 硝酸铁作为催化剂在苯与羟胺盐反应一步法制苯胺反应中的应用方法
CN107801392A (zh) * 2015-04-02 2018-03-13 亨茨曼国际有限公司 烃的直接胺化
CN107801392B (zh) * 2015-04-02 2021-02-05 亨茨曼国际有限公司 烃的直接胺化
CN108654594A (zh) * 2017-03-27 2018-10-16 万华化学集团股份有限公司 一种固体酸催化剂及其制备方法以及用途
CN108654594B (zh) * 2017-03-27 2021-01-29 万华化学集团股份有限公司 一种固体酸催化剂及其制备方法以及用途
CN112300005A (zh) * 2019-07-26 2021-02-02 中石化南京化工研究院有限公司 一种苯一步氨化制苯胺的方法

Also Published As

Publication number Publication date
KR20090031623A (ko) 2009-03-26
EP2046721A1 (de) 2009-04-15
JP2009544651A (ja) 2009-12-17
US20090292144A1 (en) 2009-11-26
WO2008009668A1 (de) 2008-01-24

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Application publication date: 20090722