CN101484506B - 多羟基官能性聚硅氧烷、其制造方法及其应用 - Google Patents
多羟基官能性聚硅氧烷、其制造方法及其应用 Download PDFInfo
- Publication number
- CN101484506B CN101484506B CN2007800253963A CN200780025396A CN101484506B CN 101484506 B CN101484506 B CN 101484506B CN 2007800253963 A CN2007800253963 A CN 2007800253963A CN 200780025396 A CN200780025396 A CN 200780025396A CN 101484506 B CN101484506 B CN 101484506B
- Authority
- CN
- China
- Prior art keywords
- zgk
- poly
- hydroxy functionality
- alkyl
- functionality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- -1 polysiloxanes Polymers 0.000 title claims abstract description 119
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims description 27
- 238000004519 manufacturing process Methods 0.000 title abstract description 13
- 229920000570 polyether Polymers 0.000 claims abstract description 114
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims abstract description 108
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 86
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 37
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 37
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- 239000000654 additive Substances 0.000 claims abstract description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 152
- 150000001875 compounds Chemical class 0.000 claims description 60
- 238000006243 chemical reaction Methods 0.000 claims description 50
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 claims description 40
- 239000008199 coating composition Substances 0.000 claims description 39
- 125000000217 alkyl group Chemical group 0.000 claims description 34
- 238000006116 polymerization reaction Methods 0.000 claims description 34
- 239000000206 moulding compound Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 32
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 31
- 125000003118 aryl group Chemical group 0.000 claims description 30
- 229920000728 polyester Polymers 0.000 claims description 28
- 238000007259 addition reaction Methods 0.000 claims description 26
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 25
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 19
- 238000006482 condensation reaction Methods 0.000 claims description 15
- 241000555268 Dendroides Species 0.000 claims description 14
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 12
- 125000000746 allylic group Chemical group 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 10
- 238000007151 ring opening polymerisation reaction Methods 0.000 claims description 9
- 235000011187 glycerol Nutrition 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 229940059574 pentaerithrityl Drugs 0.000 claims description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 7
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 claims description 7
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 claims description 6
- 238000006459 hydrosilylation reaction Methods 0.000 claims description 6
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 5
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000000539 dimer Substances 0.000 claims description 4
- GDCVWNMIFDZYRE-UHFFFAOYSA-N (2-ethyloxetan-2-yl)methanol Chemical compound CCC1(CO)CCO1 GDCVWNMIFDZYRE-UHFFFAOYSA-N 0.000 claims description 3
- SHSBMPDSSWZEPU-UHFFFAOYSA-N (2-methyloxetan-2-yl)methanol Chemical compound OCC1(C)CCO1 SHSBMPDSSWZEPU-UHFFFAOYSA-N 0.000 claims description 3
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 3
- LCOOMOSZMKFHOC-UHFFFAOYSA-N 3,3,5,5-tetrakis(hydroxymethyl)oxan-4-ol Chemical compound OCC1(CO)COCC(CO)(CO)C1O LCOOMOSZMKFHOC-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 3
- 229930195725 Mannitol Natural products 0.000 claims description 3
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000594 mannitol Substances 0.000 claims description 3
- 235000010355 mannitol Nutrition 0.000 claims description 3
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims description 2
- 229920006037 cross link polymer Polymers 0.000 claims description 2
- 229920005565 cyclic polymer Polymers 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 229920003232 aliphatic polyester Polymers 0.000 claims 2
- 125000004185 ester group Chemical group 0.000 claims 2
- 239000011248 coating agent Substances 0.000 abstract description 24
- 238000000465 moulding Methods 0.000 abstract 2
- 238000000576 coating method Methods 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 239000001257 hydrogen Substances 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 18
- 239000000047 product Substances 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 239000000463 material Substances 0.000 description 14
- 230000000996 additive effect Effects 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 125000005113 hydroxyalkoxy group Chemical group 0.000 description 10
- 239000002966 varnish Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 229910052697 platinum Inorganic materials 0.000 description 9
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 9
- 230000032050 esterification Effects 0.000 description 8
- 238000005886 esterification reaction Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000003373 anti-fouling effect Effects 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- 238000001723 curing Methods 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 230000000007 visual effect Effects 0.000 description 6
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 6
- 239000005357 flat glass Substances 0.000 description 5
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- DQLATGHUWYMOKM-UHFFFAOYSA-L cisplatin Chemical compound N[Pt](N)(Cl)Cl DQLATGHUWYMOKM-UHFFFAOYSA-L 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 238000007046 ethoxylation reaction Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 125000005429 oxyalkyl group Chemical group 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 229920003270 Cymel® Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 230000006837 decompression Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920001843 polymethylhydrosiloxane Polymers 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 239000005046 Chlorosilane Substances 0.000 description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 230000003044 adaptive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 229920005603 alternating copolymer Polymers 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000000181 anti-adherent effect Effects 0.000 description 2
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 description 2
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000001035 methylating effect Effects 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920003257 polycarbosilane Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229960000380 propiolactone Drugs 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 238000004018 waxing Methods 0.000 description 2
- JHEPBQHNVNUAFL-AATRIKPKSA-N (e)-hex-1-en-1-ol Chemical compound CCCC\C=C\O JHEPBQHNVNUAFL-AATRIKPKSA-N 0.000 description 1
- DIOZVWSHACHNRT-UHFFFAOYSA-N 2-(2-prop-2-enoxyethoxy)ethanol Chemical compound OCCOCCOCC=C DIOZVWSHACHNRT-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 1
- GCYHRYNSUGLLMA-UHFFFAOYSA-N 2-prop-2-enoxyethanol Chemical compound OCCOCC=C GCYHRYNSUGLLMA-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- XDODWINGEHBYRT-UHFFFAOYSA-N [2-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCCC1CO XDODWINGEHBYRT-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000005055 alkyl alkoxy group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 150000004646 arylidenes Chemical group 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- JHEPBQHNVNUAFL-UHFFFAOYSA-N hex-1-en-1-ol Chemical class CCCCC=CO JHEPBQHNVNUAFL-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 239000001034 iron oxide pigment Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 125000003566 oxetanyl group Chemical group 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- LBUSGXDHOHEPQQ-UHFFFAOYSA-N propane-1,1,1-triol Chemical compound CCC(O)(O)O LBUSGXDHOHEPQQ-UHFFFAOYSA-N 0.000 description 1
- 230000001141 propulsive effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052990 silicon hydride Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
- C08L83/12—Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Silicon Polymers (AREA)
- Polyethers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
油 | 沥青 | Edding | Edding擦除 | |
对照样 | 5 | 5 | 5 | 5 |
实施例1 | 1 | 1 | 3 | 2 |
实施例2 | 1 | 1 | 3 | 3 |
实施例3 | 2 | 1 | 3 | 2 |
实施例4 | 2 | 1 | 1 | 1 |
实施例5 | 1 | 1 | 1 | 1 |
Tego Protect 5100 | 1 | 1 | 4 | 2 |
Worlee Add 720 | 3 | 3 | 5 | 5 |
Bayferrox | 油 | 沥青 | Edding | Edding擦除 | |
对照样 | 3 | 5 | 5 | 5 | 5 |
实施例3 | 1 | 2 | 1 | 1 | 1 |
实施例4 | 1 | 1 | 1 | 1 | 1 |
实施例6 | 1 | 1 | 1 | 1 | 1 |
实施例7 | 1 | 1 | 1 | 1 | 1 |
Worlee Add 720 | 5 | 2 | 1 | 1 | 2 |
凝胶涂层混合物A | 凝胶涂层混合物B | |
凝胶涂层 | 98.5 | 98 |
Beschleuniger NL-49 P | 1 | 2 |
来自实施例3的聚硅氧烷溶液 | 0.5 |
样品 | 滑动阻力(以牛顿计) | 透明性 |
不含添加剂的对照样 | 5.3 | 透明 |
实施例6 | 1.5 | 透明 |
实施例7 | 1.7 | 透明 |
Worlee Add 720 | 2.3 | 透明 |
Claims (46)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006031152A DE102006031152A1 (de) | 2006-07-04 | 2006-07-04 | Polyhydroxyfunktionelle Polysiloxane als anti-adhäsive und schmutzabweisende Zusätze in Beschichtungen, polymeren Formmassen und Thermoplasten, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE102006031152.3 | 2006-07-04 | ||
PCT/EP2007/005895 WO2008003470A1 (de) | 2006-07-04 | 2007-07-04 | Polyhydroxyfunktionelle polysiloxane, verfahren zu ihrer herstellung und ihre verwendung |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101484506A CN101484506A (zh) | 2009-07-15 |
CN101484506B true CN101484506B (zh) | 2012-06-06 |
Family
ID=38610745
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007800253963A Active CN101484506B (zh) | 2006-07-04 | 2007-07-04 | 多羟基官能性聚硅氧烷、其制造方法及其应用 |
Country Status (10)
Country | Link |
---|---|
US (1) | US20100240842A1 (zh) |
EP (1) | EP2035487B1 (zh) |
JP (1) | JP5478246B2 (zh) |
KR (1) | KR101427992B1 (zh) |
CN (1) | CN101484506B (zh) |
AT (1) | ATE509059T1 (zh) |
DE (1) | DE102006031152A1 (zh) |
ES (1) | ES2364780T3 (zh) |
TW (1) | TW200808874A (zh) |
WO (1) | WO2008003470A1 (zh) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8119717B2 (en) | 2006-11-21 | 2012-02-21 | Basf Corporation | Coating composition having a low volatile organic compound content |
DE102007050046A1 (de) | 2007-10-17 | 2009-04-23 | Byk-Chemie Gmbh | Wasserspeicher |
US8431639B2 (en) * | 2007-11-08 | 2013-04-30 | Basf Corporation | Wetting additive and composition including the same |
DE102008032064A1 (de) | 2008-07-08 | 2010-01-14 | Byk-Chemie Gmbh | Polyhydroxyfunktionelle Polysiloxane zur Erhöhung der Oberflächenenergie von Thermoplasten, Verfahren zu ihrer Herstellug und ihre Verwendung |
DE102008032066A1 (de) | 2008-07-08 | 2010-01-14 | Byk-Chemie Gmbh | Polyhydroxyfunktionelle Polysiloxane als anti-adhäsive und schmutzabweisende Zusätze in Beschichtungen, polymeren Formmassen und Thermoplasten, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE102008043343A1 (de) * | 2008-10-31 | 2010-05-06 | Evonik Goldschmidt Gmbh | Silikonpolyetherblock-Copolymere mit definierter Polydispersität im Polyoxyalkylenteil und deren Verwendung als Stabilisatoren zur Herstellung von Polyurethanschäumen |
DE102009021912A1 (de) * | 2009-05-19 | 2010-12-02 | Byk-Chemie Gmbh | Aus oxetan-basierten Makromonomeren erhältliche Polymere, Verfahren zu deren Herstellung und deren Verwendung als Additive in Beschichtungsmitteln und Kunststoffen |
DE102009021913A1 (de) * | 2009-05-19 | 2010-12-02 | Byk-Chemie Gmbh | Terminal ungesättigte, oxetan-basierte Makromonomere und Verfahren zu deren Herstellung |
CN101712842B (zh) * | 2009-11-09 | 2013-10-16 | 深圳市广田环保涂料有限公司 | 一种防粘贴防涂鸦涂料 |
US20110143148A1 (en) * | 2009-12-13 | 2011-06-16 | General Electric Company | Articles comprising a weather resistant silicone coating |
EP2360205A1 (de) | 2010-02-19 | 2011-08-24 | BYK-Chemie GmbH | Verfahren zur kontinuierlichen Hydrosilylierung |
DE102011076019A1 (de) | 2011-05-18 | 2012-11-22 | Evonik Goldschmidt Gmbh | Alkoxylierungsprodukte und Verfahren zu ihrer Herstellung mittels DMC-Katalysatoren |
DE102011109541A1 (de) | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Verwendung von Polysiloxanen enthaltend verzweigte Polyetherreste zur Herstellung von Polyurethanschäumen |
DE102011109545A1 (de) | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyethersiloxanen enthaltend Polyethercarbonatgrundstrukturen |
DE102011109614A1 (de) | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von verzweigten Polyethercarbonaten und ihre Verwendung |
EP2703426A1 (de) * | 2012-08-27 | 2014-03-05 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
PL3023467T3 (pl) * | 2014-11-20 | 2017-10-31 | Byk Chemie Gmbh | Masa do formowania, termoplast lub środek powłokowy zawierający polisiloksany jako dodatki antyadhezyjne i odpychające zanieczyszczenia |
JP6613566B2 (ja) * | 2015-01-09 | 2019-12-04 | 信越化学工業株式会社 | ポリオキシアルキレン変性ジオルガノポリシロキサン化合物及びその製造方法並びにオルガノポリシロキサン乳化組成物 |
DE102017100932A1 (de) | 2016-01-19 | 2017-07-20 | Lisa Dräxlmaier GmbH | Hydroxyfunktionelle dendritische Polymere als Haftvermittler |
EP3448937B1 (en) | 2016-04-25 | 2020-10-28 | Dow Silicones Corporation | Aqueous coating composition |
CN106345147A (zh) * | 2016-10-18 | 2017-01-25 | 合肥新万成环保科技有限公司 | 一种高抗剪切性能的超支化聚醚改性有机硅消泡剂及其制备方法 |
CN106474775A (zh) * | 2016-10-18 | 2017-03-08 | 合肥新万成环保科技有限公司 | 一种含纳米二氧化硅的超支化聚醚改性有机硅消泡剂及其制备方法 |
CN106474776A (zh) * | 2016-10-18 | 2017-03-08 | 合肥新万成环保科技有限公司 | 一种可以快速消泡的超支化聚醚改性有机硅消泡剂及其制备方法 |
CN106474778A (zh) * | 2016-10-18 | 2017-03-08 | 合肥新万成环保科技有限公司 | 一种高效抑泡性能的超支化聚醚改性有机硅消泡剂及其制备方法 |
CN106362441A (zh) * | 2016-10-18 | 2017-02-01 | 合肥新万成环保科技有限公司 | 一种含有羟基聚醚改性环氧大豆油的有机硅消泡剂及其制备方法 |
CN106237663A (zh) * | 2016-10-18 | 2016-12-21 | 合肥新万成环保科技有限公司 | 一种抑菌型超支化聚醚改性有机硅消泡剂及其制备方法 |
CN106310726A (zh) * | 2016-10-18 | 2017-01-11 | 合肥新万成环保科技有限公司 | 一种经济高效的超支化聚醚改性有机硅消泡剂及其制备方法 |
CN106310727A (zh) * | 2016-10-18 | 2017-01-11 | 合肥新万成环保科技有限公司 | 一种具有持久抑泡效果的超支化聚醚改性有机硅消泡剂及其制备方法 |
KR101949403B1 (ko) * | 2017-01-20 | 2019-02-19 | 효성첨단소재 주식회사 | 공중합 폴리에틸렌테레프탈레이트 중합물을 포함하는 bcf |
WO2018135787A1 (ko) * | 2017-01-20 | 2018-07-26 | (주)효성 | 공중합 폴리에틸렌테레프탈레이트 중합물, 이를 포함하는 원사/bcf/필름 및 이의 제조방법 |
KR101949401B1 (ko) * | 2017-01-20 | 2019-02-19 | 효성화학 주식회사 | 공중합 폴리에틸렌테레프탈레이트 중합물을 포함하는 필름 |
EP3802716B1 (en) * | 2018-06-05 | 2022-07-06 | Byk-Chemie GmbH | Polymer with polyether polyester segment and polysiloxane segment |
KR20200070810A (ko) | 2018-12-10 | 2020-06-18 | 삼성전자주식회사 | 조성물, 이의 경화물을 포함하는 필름, 상기 필름을 포함하는 적층체 및 디스플레이 소자 |
JP7158362B2 (ja) * | 2019-10-29 | 2022-10-21 | 信越化学工業株式会社 | 水系塗料用添加剤、水系塗料組成物、及びコーティング層 |
CN116438225A (zh) * | 2020-11-09 | 2023-07-14 | 毕克化学有限公司 | 聚硅氧烷聚合物 |
CN112778904A (zh) * | 2020-12-17 | 2021-05-11 | 上海涂固安高科技有限公司 | 一种金属表面硬度易洁抗菌车盾及其制备方法 |
WO2022190464A1 (ja) * | 2021-03-08 | 2022-09-15 | 関西ペイント株式会社 | アクリル樹脂変性シリカ粒子、塗料組成物及び複層塗膜形成方法 |
CN116829661B (zh) * | 2021-03-08 | 2025-03-18 | 关西涂料株式会社 | 丙烯酸系树脂改性二氧化硅粒子、涂料组合物以及多层涂膜形成方法 |
CN117487395A (zh) * | 2022-07-21 | 2024-02-02 | 佛山市顺德区美的电热电器制造有限公司 | 聚硅氧烷不粘助剂、涂料组合物、涂料、涂层和具有不粘涂层的制品及形成涂层的方法 |
CN115894851B (zh) * | 2022-12-19 | 2023-11-24 | 江苏钟山新材料有限公司 | 一种皮革涂饰用有机硅改性水性聚氨酯的制备方法 |
CN116003799A (zh) * | 2023-01-06 | 2023-04-25 | 国科广化(南雄)新材料研究院有限公司 | 一种硅氢加成反应合成羟基含氢硅油的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4431789A (en) * | 1981-03-13 | 1984-02-14 | Shin-Etsu Chemical Co., Ltd. | Novel organopolysiloxane having alcoholic hydroxy groups and a method for the preparation thereof |
US5208311A (en) * | 1991-02-13 | 1993-05-04 | Th. Goldschmidt Ag | Organopolysiloxanes with polyether and ester groups linked to a common spacer group |
CN1464886A (zh) * | 2001-05-14 | 2003-12-31 | 阿姆诺洼化学有限公司 | 由含侧氟碳基的环状单体得到的聚合物表面活性剂 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2258892A (en) * | 1938-08-25 | 1941-10-14 | Benjamin R Harris | Ethers of polyglycerols |
US2615008A (en) * | 1945-09-18 | 1952-10-21 | Devoe & Raynolds Co | Epoxide resin compositions |
US4640940A (en) * | 1985-08-13 | 1987-02-03 | Loctite Corporation | Polyol terminated silicones and derivatives thereof |
JPH0229428A (ja) * | 1988-06-03 | 1990-01-31 | Arizona Board Of Regents | 3―ヒドロキシオキセタンの重合体、共重合体及びそれらの誘導体 |
US5428142A (en) * | 1993-10-20 | 1995-06-27 | Siltech Inc. | Silicone based glycosides |
JPH10139853A (ja) * | 1996-11-08 | 1998-05-26 | Nippon Kayaku Co Ltd | シリコン変性エポキシ樹脂、及びエポキシ樹脂組成物及びその硬化物 |
JPH10316540A (ja) * | 1997-05-19 | 1998-12-02 | Kose Corp | 頭髪化粧料 |
US5916992A (en) * | 1997-08-01 | 1999-06-29 | Ppg Industries Ohio, Inc. | Polysiloxane polyols |
US5939491A (en) | 1997-08-01 | 1999-08-17 | Ppg Industries Ohio, Inc. | Curable compositions based on functional polysiloxanes |
FR2779641B1 (fr) * | 1998-06-16 | 2000-07-21 | Oreal | Compositions cosmetiques detergentes et utilisation |
JP4635295B2 (ja) * | 2000-04-25 | 2011-02-23 | 日立化成工業株式会社 | 接着フィルム |
FR2811670B1 (fr) * | 2000-07-13 | 2004-05-14 | Rhodia Chimie Sa | Stabilisation de compositions polymeriques, organosiliciques ou silicone |
SE524174C2 (sv) * | 2000-11-14 | 2004-07-06 | Perstorp Specialty Chem Ab | Förfarande för framställning av en dendritisk polyeter |
JP2002270235A (ja) * | 2001-03-07 | 2002-09-20 | Nisshinbo Ind Inc | 高分子ゲル電解質用プレゲル組成物及びその脱水方法並びに二次電池及び電気二重層キャパシタ |
US6660828B2 (en) * | 2001-05-14 | 2003-12-09 | Omnova Solutions Inc. | Fluorinated short carbon atom side chain and polar group containing polymer, and flow, or leveling, or wetting agents thereof |
JP4485134B2 (ja) * | 2002-03-25 | 2010-06-16 | 花王株式会社 | 分岐ポリグリセロール変性シリコーン |
JP2003313286A (ja) * | 2002-04-18 | 2003-11-06 | Mitsubishi Chemicals Corp | ポリエーテルポリオール誘導体の製造方法 |
US9090755B2 (en) * | 2002-09-12 | 2015-07-28 | Shin-Etsu Chemical Co., Ltd. | Organopolysiloxane polymer, pasty composition, and cosmetic preparation containing the composition |
JP5037782B2 (ja) * | 2003-07-07 | 2012-10-03 | 信越化学工業株式会社 | 新規なオルガノポリシロキサン・グリセリン誘導体交互共重合体およびそれを含有する化粧料 |
GB2403722A (en) * | 2003-07-11 | 2005-01-12 | Sun Chemical Ltd | Process for the preparation of a low viscosity, hyperbranched polymer |
JP4357909B2 (ja) * | 2003-09-12 | 2009-11-04 | 花王株式会社 | 分岐ポリグリセロール変性シリコーンの製法 |
JP3946680B2 (ja) * | 2003-09-24 | 2007-07-18 | 花王株式会社 | 皮膚用化粧料 |
DE102004033060A1 (de) * | 2004-07-08 | 2006-01-26 | Byk-Chemie Gmbh | Polyestermodifizierte Polysiloxane und deren Verwendung als Additive für Thermoplaste, Formmassen und Lacke |
US7135535B2 (en) * | 2004-07-29 | 2006-11-14 | National Starch And Chemical Investment Holding Corporation | Siloxane resins with oxetane functionality |
JP5079245B2 (ja) * | 2005-03-09 | 2012-11-21 | 国立大学法人九州大学 | 3位に置換基を有するオキセタン誘導体の重合方法および重合物 |
WO2007075927A1 (en) * | 2005-12-22 | 2007-07-05 | The Dow Chemical Company | Branched polyglycols and branched polyether functional organopolysiloxanes and coatings containing same |
-
2006
- 2006-07-04 DE DE102006031152A patent/DE102006031152A1/de not_active Ceased
-
2007
- 2007-07-03 TW TW096124097A patent/TW200808874A/zh unknown
- 2007-07-04 CN CN2007800253963A patent/CN101484506B/zh active Active
- 2007-07-04 WO PCT/EP2007/005895 patent/WO2008003470A1/de active Application Filing
- 2007-07-04 ES ES07765035T patent/ES2364780T3/es active Active
- 2007-07-04 AT AT07765035T patent/ATE509059T1/de active
- 2007-07-04 KR KR1020097000141A patent/KR101427992B1/ko active Active
- 2007-07-04 US US12/308,597 patent/US20100240842A1/en not_active Abandoned
- 2007-07-04 EP EP07765035A patent/EP2035487B1/de active Active
- 2007-07-04 JP JP2009517036A patent/JP5478246B2/ja active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4431789A (en) * | 1981-03-13 | 1984-02-14 | Shin-Etsu Chemical Co., Ltd. | Novel organopolysiloxane having alcoholic hydroxy groups and a method for the preparation thereof |
US5208311A (en) * | 1991-02-13 | 1993-05-04 | Th. Goldschmidt Ag | Organopolysiloxanes with polyether and ester groups linked to a common spacer group |
CN1464886A (zh) * | 2001-05-14 | 2003-12-31 | 阿姆诺洼化学有限公司 | 由含侧氟碳基的环状单体得到的聚合物表面活性剂 |
Non-Patent Citations (1)
Title |
---|
JP特开平10-316540A 1998.12.02 |
Also Published As
Publication number | Publication date |
---|---|
WO2008003470A1 (de) | 2008-01-10 |
CN101484506A (zh) | 2009-07-15 |
KR101427992B1 (ko) | 2014-08-08 |
US20100240842A1 (en) | 2010-09-23 |
ATE509059T1 (de) | 2011-05-15 |
JP2009541542A (ja) | 2009-11-26 |
EP2035487A1 (de) | 2009-03-18 |
ES2364780T3 (es) | 2011-09-14 |
KR20090024780A (ko) | 2009-03-09 |
JP5478246B2 (ja) | 2014-04-23 |
TW200808874A (en) | 2008-02-16 |
DE102006031152A1 (de) | 2008-01-10 |
EP2035487B1 (de) | 2011-05-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101484506B (zh) | 多羟基官能性聚硅氧烷、其制造方法及其应用 | |
US8486188B2 (en) | Polyhydroxyfunctional polysiloxane as anti-adhesive and dirt-repellant additives | |
KR101999346B1 (ko) | 습윤분산제, 그 제조 방법 및 용도 | |
CN102089355A (zh) | 用于增大热塑性塑料表面能的多羟基官能性聚硅氧烷、其制造方法及其应用 | |
US9938432B2 (en) | Polysiloxanes as anti-adhesive and dirt-repellant additives, method for the production and use thereof | |
US20130289134A1 (en) | Copolymers containing polysiloxane groups and having an epoxy/amine skeletal structure, and use thereof | |
CN112218924B (zh) | 具有聚醚聚酯链段和聚硅氧烷链段的聚合物 | |
CN108948065B (zh) | 亲水性含烷氧基硅烷的异氰脲酸酯 | |
EP4240787B1 (en) | Polysiloxane polymer |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Frank Albert Inventor after: Griesel Wolfgang Inventor after: Valentina Petra Della Inventor after: Vorderwuelbeke Michaela Inventor before: Frank Albert Inventor before: Griesel Wolfgang Inventor before: Valentina Petra Della Inventor before: Vorderwuelbeke Michaela |
|
COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: FRANK ALBERT GRIESEL WOLFGANG VALENTINA PETRA DELLA VORDERWUELBEKE MICHAELA TO: FRANK ALBERT GRIESEL WOLFGANG VALENTINA PETRA DELLA MICHELBRINK MICHAELA |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |