CN101432339B - 无规聚噁二唑共聚物的两步制备 - Google Patents

无规聚噁二唑共聚物的两步制备 Download PDF

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Publication number
CN101432339B
CN101432339B CN2007800157985A CN200780015798A CN101432339B CN 101432339 B CN101432339 B CN 101432339B CN 2007800157985 A CN2007800157985 A CN 2007800157985A CN 200780015798 A CN200780015798 A CN 200780015798A CN 101432339 B CN101432339 B CN 101432339B
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China
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oleum
hydrazine
moles
acid
amount
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Expired - Fee Related
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CN2007800157985A
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English (en)
Chinese (zh)
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CN101432339A (zh
Inventor
K·-S·李
H·L·小史密斯
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/08—Polyhydrazides; Polytriazoles; Polyaminotriazoles; Polyoxadiazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/22—Polybenzoxazoles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polyamides (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
CN2007800157985A 2006-05-01 2007-04-26 无规聚噁二唑共聚物的两步制备 Expired - Fee Related CN101432339B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/415,026 US7528216B2 (en) 2006-05-01 2006-05-01 Two step preparation of random polyoxadiazole copolymer and articles resulting therefrom
US11/415,026 2006-05-01
PCT/US2007/010029 WO2007133409A2 (en) 2006-05-01 2007-04-26 Two step preparation of random polyoxadiazole copolymer and articles resulting therefrom

Publications (2)

Publication Number Publication Date
CN101432339A CN101432339A (zh) 2009-05-13
CN101432339B true CN101432339B (zh) 2012-02-15

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CN2007800157985A Expired - Fee Related CN101432339B (zh) 2006-05-01 2007-04-26 无规聚噁二唑共聚物的两步制备

Country Status (9)

Country Link
US (1) US7528216B2 (https=)
EP (1) EP2013263B1 (https=)
JP (1) JP5036807B2 (https=)
KR (1) KR101414397B1 (https=)
CN (1) CN101432339B (https=)
BR (1) BRPI0710333A2 (https=)
CA (1) CA2647185C (https=)
MX (1) MX2008013840A (https=)
WO (1) WO2007133409A2 (https=)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
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US7528217B2 (en) 2006-10-06 2009-05-05 E.I. Du Pont De Nemours And Company Polymers and fibers formed therefrom
EP2652010A1 (en) 2010-12-16 2013-10-23 E.I. Du Pont De Nemours And Company Flame resistant spun staple yarns made from blends of fibers derived from sulfonated polyoxadiazole polymers
US20130212780A1 (en) 2010-12-16 2013-08-22 E I Du Pont De Nemours And Company Sulfonated polyoxadiazole polymers articles
CN103261275A (zh) 2010-12-16 2013-08-21 纳幕尔杜邦公司 磺化的聚噁二唑聚合物的制备
EP2861649B1 (en) 2012-06-15 2019-07-24 E. I. du Pont de Nemours and Company Sulfonated naphthalene polyoxadiazole polymers
EP2861789B1 (en) 2012-06-15 2020-09-09 DuPont Safety & Construction, Inc. Flame resistant spun staple yarns made from blends of fibers derived from sulfonated naphthalene polyoxadiazole polymers
US9150693B2 (en) 2012-06-15 2015-10-06 E I Du Pont De Nemours And Company Preparation of sulfonated naphthalene polyoxadiazoles polymers
EP2861648B1 (en) * 2012-06-15 2016-07-27 E. I. du Pont de Nemours and Company Sulfonated polyoxadiazole polymers articles
CN104844799B (zh) * 2015-05-22 2018-02-06 江苏宝德新材料有限公司 一种高环化度芳族聚噁二唑及其纤维
CN104831400B (zh) * 2015-05-22 2017-07-18 江苏宝德新材料有限公司 一种低粘度芳族聚噁二唑溶液及由其制得的纤维
CN104817687B (zh) * 2015-05-22 2018-02-06 江苏宝德新材料有限公司 一种高纯度芳族聚噁二唑溶液及由其制得的纤维
CN109401309A (zh) * 2018-09-29 2019-03-01 刘文熙 一种耐紫外线高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109280381A (zh) * 2018-09-29 2019-01-29 王庭辉 一种阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109280383A (zh) * 2018-09-29 2019-01-29 刘文熙 一种高强度耐紫外线高透明的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109306183A (zh) * 2018-09-29 2019-02-05 王庭辉 一种高强度耐紫外线阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109337049A (zh) * 2018-09-29 2019-02-15 潘鑫 一种高强度耐紫外线高透明的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109293899A (zh) * 2018-09-29 2019-02-01 潘鑫 一种高强度阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109293894A (zh) * 2018-09-29 2019-02-01 王庭辉 一种高强度耐紫外线的芳杂环聚合物薄膜及其制备方法和应用
CN109401308A (zh) * 2018-09-29 2019-03-01 潘鑫 一种高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109401306A (zh) * 2018-09-29 2019-03-01 刘文熙 一种芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109280384A (zh) * 2018-09-29 2019-01-29 潘鑫 一种高强度耐紫外线高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109306180A (zh) * 2018-09-29 2019-02-05 王庭辉 一种高透明的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109337050A (zh) * 2018-09-29 2019-02-15 潘鑫 一种高强度耐紫外线高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109293898A (zh) * 2018-09-29 2019-02-01 潘鑫 一种耐紫外线高透明的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109401307A (zh) * 2018-09-29 2019-03-01 刘文熙 一种高透明的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109306182A (zh) * 2018-09-29 2019-02-05 刘文熙 一种高强度高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109293897A (zh) * 2018-09-29 2019-02-01 王庭辉 一种高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109306181A (zh) * 2018-09-29 2019-02-05 刘文熙 一种耐紫外线阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109293891A (zh) * 2018-09-29 2019-02-01 王庭辉 一种高强度的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109337048A (zh) * 2018-09-29 2019-02-15 潘鑫 一种高强度耐紫外线的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109280382A (zh) * 2018-09-29 2019-01-29 王庭辉 一种耐紫外线高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109280380A (zh) * 2018-09-29 2019-01-29 刘文熙 一种高强度高透明阻燃的芳杂环聚合物树脂及其制备方法和在纤维或薄膜的应用
CN109762165A (zh) * 2018-12-29 2019-05-17 江苏宝德新材料有限公司 一种可控低粘度聚芳噁二唑原液及其制备方法
CN119842231B (zh) * 2025-03-20 2025-06-24 烟台泰和新材高分子新材料研究院有限公司 一种pod前驱膜、pod基石墨膜及制备方法

Citations (3)

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US3886251A (en) * 1967-04-11 1975-05-27 Furukawa Electric Co Ltd Method for forming polyoxadiazole series resin solution into shaped articles
US4046731A (en) * 1976-05-13 1977-09-06 Monsanto Company Process for preparing dopes from which shaped articles of oxadiazole/N-alkylhydrazide copolymers are obtained
US4205038A (en) * 1975-09-05 1980-05-27 Imperial Chemical Industries Limited Process for producing shaped articles of polyoxadiazoles

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GB1252508A (https=) 1968-10-23 1971-11-03
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US4115503A (en) 1973-08-22 1978-09-19 Monsanto Company Novel process for the preparation of fiber of arylene oxadiazole/arylene N-alkylhydrazide copolymer
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FR2318841A1 (fr) * 1975-07-25 1977-02-18 Comp Generale Electricite Procede de liaison entre pieces en alumine beta alcaline et en alumine alpha
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Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
US3886251A (en) * 1967-04-11 1975-05-27 Furukawa Electric Co Ltd Method for forming polyoxadiazole series resin solution into shaped articles
US4205038A (en) * 1975-09-05 1980-05-27 Imperial Chemical Industries Limited Process for producing shaped articles of polyoxadiazoles
US4046731A (en) * 1976-05-13 1977-09-06 Monsanto Company Process for preparing dopes from which shaped articles of oxadiazole/N-alkylhydrazide copolymers are obtained

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YOSHIO IMAI et al.Direct Fiber Formation and Fiber Properties.《journal of applied polymer science》.1970,第14卷(第1期),225-239. *

Also Published As

Publication number Publication date
EP2013263A2 (en) 2009-01-14
US20070255035A1 (en) 2007-11-01
KR101414397B1 (ko) 2014-07-01
CA2647185A1 (en) 2007-11-22
JP2009535482A (ja) 2009-10-01
JP5036807B2 (ja) 2012-09-26
CA2647185C (en) 2014-07-08
EP2013263B1 (en) 2012-04-11
US7528216B2 (en) 2009-05-05
BRPI0710333A2 (pt) 2011-08-09
KR20090006223A (ko) 2009-01-14
CN101432339A (zh) 2009-05-13
WO2007133409A3 (en) 2008-01-10
MX2008013840A (es) 2008-11-10
WO2007133409A2 (en) 2007-11-22

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